Soil simulant sourcing for the ExoMars rover testbed

ExoMars is the European Space Agency (ESA) mission to Mars planned for launch in 2018, focusing on exobiology with the primary objective of searching for any traces of extant or extinct carbon-based micro-organisms. The on-surface mission is performed by a near-autonomous mobile robotic vehicle (also referred to as the rover) with a mission design life of 180 sols (Patel et al., 2010). In order to obtain useful data on the tractive performance of the ExoMars rover before flight, it is necessary to perform mobility tests on representative soil simulant materials producing a Martian terrain analogue under terrestrial laboratory conditions. Three individual types of regolith shown to be found extensively on the Martian surface were identified for replication using commercially available terrestrial materials, sourced from UK sites in order to ensure easy supply and reduce lead times for delivery. These materials (also referred to as the Engineering Soil (ES-x) simulants) are: a fine dust analogue (ES-1); a fine aeolian sand analogue (ES-2); and a coarse sand analogue (ES-3). Following a detailed analysis, three fine sand regolith types were identified from commercially available products. Each material was used in its off-the-shelf state, except for ES-2, where further processing methods were used to reduce the particle size range. These materials were tested to determine their physical characteristics, including the particle size distribution, particle density, particle shape (including angularity/sphericity) and moisture content. The results are analysed to allow comparative analysis with existing soil simulants and the published results regarding in situ analysis of Martian soil on previous NASA (National Aeronautics and Space Administration) missions. The findings have shown that in some cases material properties vary significantly from the specifications provided by material suppliers. This has confirmed the need for laboratory testing to determine the actual parameters to prove that standard geotechnical processes are indeed suitable. The outcomes have allowed the confirmation of each simulant material as suitable for replicating their respective regolith types.     

Development and testing of subsurface sampling devices for the Beagle 2 lander

For planetary landing missions, the capability to acquire samples of soil and rock is of high importance whenever complex analyses (e.g. isotopic studies) on these materials are to be carried out, or when samples are to be returned to Earth. Not only surface samples are of relevance, but in recent concepts at least for Mars landing missions also subsurface samples are required. Subsurface material on Mars is believed to have been protected from the inferred oxidants at the immediate surface while also being protected from the UV influx. Therefore, there is considerable hope that in subsurface soil samples on Mars, at least organic matter delivered by meteorites may be detected, and possibly also relics of earlier simple microbial life on the planet. Likewise, samples from the inside of Martian surface rocks promise to have been protected from weathering and for the same reason they are important for organic chemistry studies. In this paper, an overview is given of the development and science of two different subsurface sampling devices for the Beagle 2 lander of ESA's Mars Express mission, being a “Mole” subsurface soil sampler and a small rock coring and sampling mechanism. Besides their sampling function, both the Mole and the Corer/Grinder will provide data on physical properties of Martian soils and rock, respectively, through the way they interact with the sampled materials. Details of the Mole and Corer/Grinder design are presented, along with results of recent tests with prototypes in the laboratory on physically analogous sample materials.     

Characterization of lunar dust and a synopsis of available lunar simulants

Understanding the formation and evolution of the soil and dust of the Moon addresses the fundamental question of the interactions of space with the surface of an airless body. The physical and chemical properties of the lunar dust, the <20 μm portion of lunar soil, are key properties necessary for studies of the toxicity and the electrostatic charging of the dust. These properties have been largely overlooked until recent years. Although chemical and physical studies of the <20 μm portion of lunar soil have been the topic of several studies, there is still need for further studies, primarily of the <1 μm particles. This paper presents a review of the studies of lunar dust that have been conducted to date. As many preparations for future exploration or science activities on the Moon require testing using lunar soil/dust simulants, we also include a brief review of past and current simulants.     

Simulation Experiments with Cometary Analogous Material

Comet simulation experiments are discussed, in the context of physical models and the results in cometary physics, gathered especially from the GIOTTO space mission to comet P'Halley. The “status of the today knowledge” about comets, the experiments could start from, is briefly reviewed. The setup of the KOSI (German = Kometen Simulation) - experiments and the techniques to produce cometary analogous material, on the basis of that knowledge are described in general, as for the different KOSI experiments. The limitations of the simulation of physical processes at the surface of real comets in an earth-bound laboratory are discussed, and the possibilities to receive common insights in cometary physics are shown. Methods and procedures are described, and the major results reviewed. As with attempting to reproduce any natural phenomenon in the laboratory, there are short-comings to these experiments, but there are possibly major new insights to be gained. Physical laws only have the same consequences under same experimental or environmental conditions. A number of small-scale comet simulation experiments have been performed, since the early 60ties in many laboratories, but the largest and most ambitious series of comet simulation experiments to date were performed between 1987 and 1993 using the German space agency's (DLR) space hardware testing facilities in Cologne. These experiments were triggered by the scientific community after the comet P'Halley's recurrence in 1986 and the many data gathered by the space missions in this year. Simulation experiments have proved valuable in developing methods for making cometary analogues, and for exploring specific properties of such materials in detail. These experiments provided new insights into the morphology and physical behavior of aggregates formed out of silicate- /water-ice -grains likely to exist in comets. The formation of a dust mantle on the surface, and a system of ice layers below the mantle from the different admixed materials, have been detected after the insolation of the artificial comet. The mechanisms for heat transfer between the comet's surface and its interior, compositional, structural, and isotopic changes that occur near the comet's surface, were described by modeling in accordance with the experimental results. The mechanisms of the ejection of dust and ice grains from the surface, and the importance of gas-drag in propelling grains were investigated by close-up video cameras. This revised version was published online in July 2006 with corrections to the Cover Date.     

Simulated asteroid materials based on carbonaceous chondrite mineralogies

A set of high‐fidelity simulated asteroid materials, or simulants, was developed based on the mineralogy of carbonaceous chondrite meteorites. Three varieties of simulant were developed based on CI1 chondrites (typified by Orgueil), CM2 chondrites (typified by Murchison), and CR2/3 chondrites (multiple samples). The simulants were designed to replicate the mineralogy and physical properties of the corresponding meteorites and anticipated asteroid surface materials as closely as is reasonably possible for bulk amounts. The simulants can be made in different physical forms ranging from larger cobbles to fine‐grained regolith. We analyzed simulant prototypes using scanning electron microscopy, X‐ray fluorescence, reflectance spectroscopy at ambient conditions and in vacuum, thermal emission spectroscopy in a simulated asteroid environment chamber, and combined thermogravimetry and evolved gas analysis. Most measured properties compare favorably to the reference meteorites and therefore to predicted volatile‐rich asteroid surface materials, including boulders, cobbles, and fine‐grained soils. However, there were also discrepancies, and mistakes were made in the original mineral formulations that will be updated in the future. The asteroid simulants are available to the community from the nonprofit Exolith Lab at UCF, and the mineral recipes are freely published for other groups to reproduce and modify as they see fit.     

Physical and mechanical properties of the lunar soil (a review)

We review the data on the physical and mechanical properties of the lunar soil that were acquired in the direct investigations on the lunar surface carried out in the manned and automatic missions and in the laboratory examination of the lunar samples returned to the Earth. In justice to the American manned program Apollo, we show that a large volume of the data on the properties of the lunar soil was also obtained in the Soviet automatic program Lunokhod and with the automatic space stations Luna-16, -20, and -24 that returned the lunar soil samples to the Earth. We consider all of the main physical and mechanical properties of the lunar soil, such as the granulometric composition, density and porosity, cohesion and adhesion, angle of internal friction, shear strength of loose soil, deformation characteristics (the deformation modulus and Poisson ratio), compressibility, and the bearing capacity, and show the change of some properties versus the depth. In most cases, the analytical dependence of the main parameters is presented, which is required in developing reliable engineering models of the lunar soil. The main physical and mechanical properties are listed in the summarizing table, and the currently available models and simulants of the lunar soil are reviewed.     

On the sources of ultraviolet absorption in spectra of Titan and the outer planets

In response to the observations of the ultravioler deficiencies shown by all of the outer planets and Titan, models have been proposed to explain the low albedos by absorption by particles in the upper atmospheres of these objects. These particles are generally believed to be photochemically formed from gases in the upper atmospheres, primarily methane and hydrogen. Such processes may also be operative on Titan. The results of some laboratory experiments of the proton irradiation of mixtures of gases including CH₄ H₂, NH₃, etc., have shown that liquid and solid materials are produced that are strong ultraviolet absorbers. However, the material produced from the CH₄ + H₂ mixture was colorless, indicating that species containing elements other than carbon and hydrogen are necessary for the production of color. Two such elements are nitrogen (as NH₃ or N₂) and sulfur (as H₂S) and colored materials have been produced from such mixtures. None of these materials has spectral properties identical to those shown by the planets. Therefore it is necessary that mixtures (and/or cloud layers) of the photochemical materials be present.     

Particle transport and distribution on the Mars Science Laboratory mission: Effects of triboelectric charging

We report on the nature of fine particle (<150 μm) transport under simulated martian conditions, in order to better understand the Mars Science Laboratory’s (MSL) sample acquisition, processing and handling subsystem (SA/SPaH). We find that triboelectric charging due to particle movement may have to be controlled in order for successful transport of fines that are created within the drill, processed through the Collection and Handling for In situ Martian Rock Analysis (CHIMRA) sample handing system, and delivered to the Sample Analysis at Mars (SAM) and Chemistry and Mineralogy (CheMin) instruments. These fines will be transferred from the surface material to the portioner, a 3 mm diameter, 8 mm deep distribution center where they will drop ∼2 cm to the instrument inlet funnels. In our experiments, movement of different material including terrestrial analogs and martian soil simulants (Mars Mojave Simulant - MMS) resulted in 1-7 nanocoulombs of charge to build up for several different experimental configurations. When this charging phenomenon occurs, several different results are observed including particle clumping, adherence of material on conductive surfaces, or electrostatic repulsion, which causes like-charged particles to move away from each other. This electrostatic repulsion can sort samples based upon differing size fractions, while adhesion causes particles of different sizes to bind into clods. Identifying these electrostatic effects can help us understand potential bias in the analytical instruments and to define the best operational protocols to collect samples on the surface of Mars.     

First experimental investigation of dual-reciprocating drilling in planetary regoliths: Proposition of penetration mechanics

The search for life in the solar system requires sub-surface exploration capabilities of extra-terrestrial bodies like the Moon and Mars. To do so different techniques are being developed: from the classical rotary drilling techniques widely used on Earth to more original techniques like ultrasonic drilling. Dual-reciprocating drilling (DRD) is a bio-mimetic drilling principle inspired by the manner wood-wasps drill into wood to lay its eggs. It was proposed as an efficient extra-terrestrial drilling technique requiring low over-head force. To deepen the understanding of this novel drilling technique, DRD has been tested for the first time in planetary regolith simulants. These experiments are reported here. To do so a new test bench was built and is presented. The soil forces on the drill bit are analysed and the final depth reached by the DRD system is compared to the final depth reached by static penetration. The experiments have shown very high levels of slippage (defined here specifically for DRD). The observations of the surface deformations and the importance of slippage lead to the proposal of DRD penetration mechanics in regoliths. Finally a re-evaluation of previous DRD experiments conducted on low compressive strength rocks also show the high levels of slippage during DRD.     

Spectroscopy of Loose and Cemented Sulfate-Bearing Soils: Implications for Duricrust on Mars

The goal of this work is to determine the spectroscopic properties of sulfate in martian soil analogs over the wavelength range 0.3 to 25 μm (which is relevant to existing and planned remotely sensed data sets for Mars). Sulfate is an abundant component of martian soil (up to 9% SO₃ by weight) and apparently exists as a particulate in the soil but also as a cement. Although previous studies have addressed the spectroscopic identity of sulfates on Mars, none have used laboratory mixtures of materials with sulfates at the abundances measured by landed spacecraft, nor have any works considered the effect of salt-cementation on spectral properties of soil materials. For this work we created mixtures of a palagonitic soil (JSC Mars-1) and sulfates (MgSO₄ and CaSO₄·2H₂O). The effects of cementation were determined and separated from the effects of packing and hydration by measuring the samples as loose powders, packed powders, cemented materials, and disaggregated materials. The results show that the presence of particulate sulfate is best observed in the 4-5 μm region. Soils cemented with sulfate exhibit a pronounced restrahlen band between 8 and 9 μm as well as well-defined absorptions in the 4-5 μm region. Cementation effects are distinct from packing effects and disaggregation of cemented samples rapidly diminishes the strength of the restrahlen bands. The results of this study show that sulfate in loose materials is more detectable in the near infrared (4-5 μm) than in the thermal infrared (8-9 μm). However, cemented materials are easily distinguished from loose mixtures in the thermal infrared because of the high values of their absorption coefficient in this region. Together these results suggest that both wavelength regions are important for determining the spatial extent and physical form of sulfates on the surface of Mars.     

Laboratory simulation of the physical processes occurring on and near the surfaces of comet nuclei

Abstract— Laboratory comet simulation experiments are discussed in the context of theoretical models and recent ground-based and spacecraft observations, especially the Giotto observations of P/Halley. The set-up of various comet simulation experiments is reviewed. A number of small-scale experiments have been performed in many laboratories since the early 1960s. However, the largest and most ambitious series of experiments were the comet simulation experiments known as KOSI (German = Kometen Simulation). These experiments were prompted by the appearance of Comet P/Halley in 1986 and in planning for the European Space Agency's Rossetta mission that was originally scheduled to return samples. They were performed between 1987 and 1993 using the German Space Agency's (DLR) space hardware testing facilities in Cologne. As with attempts to reproduce any natural phenomenon in the laboratory, there are deficiencies in such experiments while there are major new insights to be gained. Simulation experiments have enabled the development of methods for making comet analogues and for exploring the properties of such materials in detail. These experiments have provided new insights into the morphology and physical behavior of aggregates formed from silicate grains likely to exist in comets. Formation of a dust mantle on the surfaces and a system of ice layers below the mantle caused by chemical differentiation have been identified after the insolation of the artificial comet. The mechanisms for heat transfer between the comet's surface and its interior, the associated gas diffusion from the interior of the surface, and compositional, structural, and isotopic changes that occur near the surface have been described by modeling the experimental results. The mechanisms of the ejection of dust and ice grains from the surface and the importance of gas-drag in propelling grains have also been explored.     

On volatilization in vacuum of the elements from the planet surface soil melts

Endogeneous and exogeneous events resulting in the appearance of the large volumes of melted substance on the lunar surface should be accompanied by volatilization of some elements from melts in vacuum [1]. However, it is not clear up to now whether volatilization on the Moon has indeed occurred and how the lower (in comparison with the Earth) content of some elements (Na, K and others) in lunar soil can be explained. There are contradictory opinions on these problems in publications (O'Hara, Ringwood and others) [2]. The numerous laboratory investigations of the similar processes are insufficient [3–15; 36] for interpretation of the results for the lack of an adequate physical model and the theory of these processes and also due to the narrow range of the parameters used (T, p, τ) and the experimental regimes. In the present paper a physical model is developed, which is based on experimental data; together with a theory of the process of volatilization of the volatile components of rock melts in vacuum, taking into account an adsorption of the residual atmosphere gases; all these allow us to interpret such processes successfully. As a result, some preliminary conclusions have been drawn about such phenomena on the Moon and their laboratory simulation.     

Evaluation of the AMIP soil moisture simulations

The Atmospheric Model Intercomparison Project (AMIP) conducted simulations by 30 different atmospheric general circulation models forced by observed sea surface temperatures for the 10-year period, 1979–1988. These models include a variety of different soil moisture parameterizations which influence their simulations of the entire land surface hydrology, including evaporation, soil moisture, and runoff, and their simulations of the energy balance at the surface. Here we compare these parameterizations, and evaluate their simulations of soil moisture by comparing them with actual observations of soil moisture, literally ground truth. We compared model-generated ‘data sets' and simulations of soil moisture with observations from 150 stations in the former Soviet Union for 1979–1985 and Illinois for 1981–1988. The spatial patterns, mean annual cycles, and interannual variations were compared to plant-available soil moisture in the upper 1 m of soil. The model-generated ‘data sets' are quite different from the observations, and from each other in many regions, even though they use the same bucket model calculation method. The AMIP model simulations are also quite different from each other, especially in the tropics. Models with 15-cm field capacities do not capture the observed large high latitude values of soil moisture. In addition, none of the models properly simulate winter soil moisture variations in high latitudes, keeping soil moisture constant, while observations show that soil moisture varies in the winter as much as in other seasons. The observed interannual variations of soil moisture were not captured by any of the AMIP models. Several models have large soil moisture trends during the first year or two of the AMIP simulations, with potentially large impacts on global hydrological cycle trends and on other climate elements. This is because the simulations were begun without spinning up the soil moisture to the model climatology. The length of time it took for each to reach equilibrium depended on the particular parameterization. Although observed temporal autocorrelation time scales are a few months, some models had much longer time scales than that. In particular, the three parameterizations based on the Simple Biosphere model (SiB) had trends in some regions for virtually the entire AMIP simulation period.     

Testing materials to mitigate terrestrial organic contamination of meteorites: Implications for collection,curation, and handling of astromaterials

Organic matter in astromaterials can provide important information for understanding the chemistry of our solar system and the prebiotic conditions of the early Earth. However, once astromaterials reach the Earth's surface, they can be readily contaminated through contact with the Earth's surface as well as during processing and curation. Here, we investigate how typical handling and curation materials interact with meteorite specimens by documenting hydrophobic organic compound contamination in the laboratory environment and on materials that might be used for their collection and storage. We use gas chromatography–mass spectrometry analysis of soluble organic compounds in dichloromethane extracts of these materials to gain insights into what materials and methods are best for the collection and curation of astromaterials. Our results have implications for how extraterrestrial samples—especially those containing significant intrinsic organic matter—are handled and curated to preserve them in their most pristine states. Following recommendations of other researchers in the area of returned sample curation, we advocate for a thorough investigation into the materials used in handling and curation of meteorites to create a contamination baseline to inform soluble organic analyses on astromaterials and enable the discrimination of terrestrial and extraterrestrial compounds.     

Progress towards robotic in-situ dating of martian sediments using optically stimulated luminescence

Recent exploratory efforts to reveal the evolution and the climatic history of Mars have shown that the planet is still active. The surface of Mars has been, and continues to be, shaped by fluvial, eolian and glacial processes. The timeframe of these events is, however, poorly established. We describe efforts and challenges to adapt optically stimulated luminescence (OSL) dating for robotic in-situ dating of martian sediments. Mineral mixtures were devised as simulants of martian regolith. The single-aliquot regeneration (SAR) procedure was modified to enable the determination of the equivalent dose for polymineral samples. Low-temperature measurements and simulations indicate that known doses delivered at low temperatures can be effectively estimated as long as the stimulation temperature is greater than the highest temperature experienced during the initial irradiation. Bleaching experiments with a solar simulator suggest efficient zeroing of the OSL signal for solar-exposed sediments on Mars. Irradiations with proton and heavy-charged particles show a lower efficiency in luminescence production than that found for beta and gamma radiation.     

UVolution: Compared photochemistry of prebiotic organic compounds in low Earth orbit and in the laboratory

Solar UV radiation is a major source of energy for chemical evolution of organic materials in the Solar System. Therefore studies on the photostability of organic compounds in extraterrestrial environments are of prime importance for the understanding of the extraterrestrial origin of organic materials on Earth. A series of organic samples have been photolysed in Earth orbit during the ESA BIOPAN 6 mission (14-26/09/2007). Their photochemical lifetime has been measured and compared to results recorded in the laboratory using a lamp that simulates the solar radiation in the VUV domain. The half-lives at a distance of 1 AU from the Sun have been measured for glycine, xanthine, hypoxanthine, adenine, guanine, urea, carbon suboxide polymer ((C₃O₂)_n) and HCN polymer. They range from a few days to a lower limit of a few tens of days for the most photoresistant (e.g. adenine, guanine, hypoxanthine). Lifetimes measured in terrestrial orbit are very different from those derived with laboratory experiments. These measurements confirm that it is difficult to simulate the solar spectrum below 200 nm in the laboratory. Results are discussed and highlight the necessity to conduct experiments in orbit, and for longer duration. It also appears that the laboratory measurements made in VUV must be extrapolated very cautiously to the different environments they are supposed to simulate.     

Ionospheric temperature and density measurements by means of spherical double probes

Rocket-borne double probes for electric field measurements can be intermittently operated in special, diagnostic modes involving current bias and low-impedance shunts to obtain information on the properties of the ambient ionospheric plasma along the flight path. Several such modes, and the information that they can provide, are analyzed. For example, in a low-impedance mode with asymmetric bias, the attenuation ratio (i.e. signal amplitude in this mode over the signal amplitude in the electric-field measuring mode) is in a simple way related to the electron temperature of the ambient plasma. The special surface coatings (Aquadag or vitreous carbon) normally used for electric field probes provide very homogeneous surface properties, a feature which also contributes to the reliability of the electron temperature measurements. In addition to electron temperature, the modes analyzed can be used to measure electron density and to give some information on ion temperature. The data from four rocket flights from ESRANGE are discussed in the light of these results. Electron temperature was measured in three of these flights. In all cases the temperature profile is in good agreement with theoretically predicted profiles based on the CIRA 1965 reference atmosphere and the solar illumination prevailing during the respective flights (twilight). Electron density profiles obtained by means of the double probe are in good agreement with the density measured by the Langmuir probe in the two flights for which both kinds of data are available. They are also in agreement with the electron density data available from ionosondes. Finally, pulses occurring when one of the probes passed through the rocket's shadow, are used to determine the photoelectron yield of the probe coatings (Aquadag or vitreous carbon). The values obtained, (7 ± 3) × 10^?6 A/m² for Aquadag and (4 ± 2) × 10^?6 A/m² for vitreous carbon are in good agreement with expectations based on laboratory data and solar Lyman α radiation.     

Boulder tracks and nature of lunar soil

Boulder tracks from 19 different locations on the Moon, observable in Lunar Orbiter photographs, have been examined. Measurements of the track width indicate that some of the boulders sank considerably deeper than others. It is suggested that lunar surface materials vary from place to place; the state of compaction (density of lunar soil) is probably one of the significant variables. Using bearing capacity theory, modified to be applicable to the rolling boulder problem by theoretical studies and extensive testing, the friction angle of the lunar soil was estimated. Most of the results were between 24 and 47 degrees with an arithmetic average of 37 degrees. These values suggest corresponding density variations of 1.25 to 2.00 g/cm³.     

The distribution of water ice in the interior of Comet Tempel 1

The Deep Impact flyby spacecraft includes a 1.05 to 4.8 μm infrared (IR) spectrometer. Although ice was not observed on the surface in the impact region, strong absorptions near 3 μm due to water ice are detected in IR measurements of the ejecta from the impact event. Absorptions from water ice occur throughout the IR dataset beginning three seconds after impact through the end of observations, ∼45 min after impact. Spatially and temporally resolved IR spectra of the ejecta are analyzed in conjunction with laboratory impact experiments. The results imply an internal stratigraphy for Tempel 1 consisting of devolatilized materials transitioning to unaltered components at a depth of approximately one meter. At greater depths, which are thermally isolated from the surface, water ice is present. Up to depths of 10 to 20 m, the maximum depths excavated by the impact, these pristine materials consist of very fine grained (∼1±1 μm) water ice particles, which are free from refractory impurities.     

Ganymede,Europa, Callisto,and Saturn's rings: Compositional analysis from reflectance spectroscopy

The reflectance spectra of Ganymede, Europa, Callisto, and Saturn's rings are analyzed using recent laboratory reflectance studies of water frost, water ice, and water and mineral mixtures. It is found that the spectra of the icy Galilean satellites are characteristic of water ice (e.g., ice blocks or possibly very large ice crystals ? 1 cm) or frost on ice rather than pure water frost, and that the decrease in reflectance at visible wavelengths is caused by other mineral grains in the surface. The spectra of Saturn's rings are more characteristic of water frost with some other mineral grains mixed in the frost but not on the surface. The impurities on all these objects are not in spectrally isolated patches but appear to be intimately mixed with the water. The impurity grains appear to have reflectance spectra typical of minerals containing Fe³⁺. Some carbonaceous chondrite meteorite spectra show the necessary spectral shape. Ganymede is found to have more water ice on the surface than previously thought (～90 wt%), as is Callisto (30–90 wt%). The surface of Europa has a vast frozen water surface with only a few percent impurities. Saturn's rings also have only a few percent impurities. The amount of bound water or bound OH for these objects is 5 ± 5 wt% averaged over the entire surface. Thus with the small amount of nonicy material present on these objects, no hydrated minerals can be ruled out. A new absorption feature is identified in Ganymede, Callisto, and probably Europa at 1.5 μm which is also seen in the spectra of Io but not in Saturn's rings. This feature has not been seen in laboratory studies and its cause is unknown.