湿地生态系统中的多环芳烃研究进展

湿地是人类最重要的生存环境之一,但由于人类活动的干扰,湿地正遭受不同程度的污染,湿地功能也处在不断退化之中。如何保护并合理利用湿地,已成为人类共同面临的一个严峻问题。对湿地生态系统中的多环芳烃(PAHs)的国内外研究热点问题进行概括总结,介绍了湿地中PAHs的污染状况、来源解析、分布特征、修复技术、对生物的毒害及风险评价等研究的主要进展,讨论了湿地中PAHs变化趋势,此外还提出了目前湿地PAHs研究中一些亟待解决的问题:如何确定分散污染源的贡献率问题,进而提出有针对性的防治措施;提高高活性微生物的环境适应能力;研究人类活动影响的比例,并预测未来的变化趋势;PAHs污染生态风险阈值的研究。并对该领域未来可能的发展趋势进行了展望。     

Hydrobios and Control of Eutrophication in Dongping Lake, Shandong Province

The Hydrobios in Dongping Lake, Shandong Province, mainly includes phytoplankton, zooplankton, benthic animals, fishes and hydrophytic vascular plants. Nitrogen and phosphorus are the restrictive factors for the growth and propagation of hydrophyta, therefore the key to the prevention and control of eutrophication in lakes lies in the control of the contents of the two elements in the water. Artificial fishing of algae can reduce the concentrations of trophic substances such as nitrogen and phosphorus in the water bodies, and biological measures may decrease the contents of these trophic substances in the bottom sediments and the water bodies, thereby playing an active role in modifying the eutrophication of the lake.     

Evidence of Abrupt Climate Change during the Mid‐ to Late‐Holocene Recorded in a Tropical Lake,Southern China

Research on abrupt paleoclimatic and paleoenvironmental change provides a scientific basis for evaluating future climate. Because of spatial variability in monsoonal rainfall, our knowledge about climate change during the mid-to lateHolocene in southern China is still limited. We present a multi-proxy record of paleoclimatic change in a crater lake, Lake Shuangchi. Based on the age-depth model from 210 Pb, 137 Cs and AMS14 C data, high-resolution mid-to late-Holocene climatic and environmental r...     

巢湖富营养化过程的沉积记录

土地利用和人类活动加剧所导致的营养元素输入的增加是引起湖泊富营养化趋势增强的重要原因。巢湖沉积钻孔柱状样中总有机碳和总氮自20世纪70年代以来呈明显升高趋势,分别增加了2.5、2.9倍。由柱状样中的TOC/TN比值、TARHC、OEP判断得出,19世纪末到20世纪40年代中期TOC是陆源和内源两种来源并重;20世纪40年代中期到20世纪70年代初期以陆源为主,并可能存在石油污染;20世纪70年代以来沉积物有机质中藻类来源的有机质占主要地位。巢湖沉积柱状样的研究表明20世纪70年代以来巢湖富营养化开始恶化。     

太湖富营养化与蓝藻水华引起的饮用水危机——原因与对策

[ZW（*][HT6H]〓收稿日期：. 〓作者简介：[HT6SS]（1963 ）,男,江苏苏州人,研究员,主要从事水环境研究.[WT6HZ]E mail:[WT6BZ]qinbq@niglas.ac.cn[ZW)] [HT4F][HT5K]()[JZ）] [HT5H][GK2] 摘〓要：[HT5K]2007年5月份发生在无锡太湖蓝藻水华引起的自来水危机事件进一步凸现我国湖泊富营养化的严峻局面和蓝藻水华频发的现状。从分析太湖富营养化发生、发展,蓝藻水华爆发的原因和机制入手,提出湖泊富营养化治理和蓝藻水华控制的途径和措施。研究表明,太湖富营养化之所以如此严重而且治理起来异常艰难,主要是由于太湖发育于长江中下游洪泛平原,营养本底高;由于水浅和沉水植被的退化使得频繁的风浪扰动造成内源营养盐负荷维持在一个非常高的水平;而流域内社会经济的高速发展,进一步加剧了太湖富营养化进程。蓝藻水华爆发一方面与蓝藻本身的生理特征有关,如固碳、伪空泡、光吸收及营养盐利用的能力;另一方面则与系统内物理、化学、生物环境有关,如独特的浅水湖泊水下光场结构和低的捕食压力。太湖的富营养化治理需遵循控源截污、湖泊生态修复和流域管理的原则,具体措施包括前置库和人工湿地的面源污染物控制技术;物理机械和生物去除内源营养盐削减技术;沉水植被恢复的湖泊生态修复技术。而蓝藻水华的控制技术则包括围隔拦截和导流的物理工程方法、絮凝沉降和抑藻物添加的化学工程方法以及生态浮床和生物操纵的生态工程方法。具体使用时,需要先诊断、后治理。       

Eutrophication of a Maryland/Virginia Coastal Lagoon: a Tipping Point,Ecosystem Changes,and Potential Causes

Water quality in the Maryland/Virginia Coastal Bays has been declining for many years from anthropogenic inputs, but conditions appear to have worsened abruptly following a shift from long-term dry to long-term wet conditions in the early 2000s. Annually and regionally averaged total nitrogen concentrations are approximately twofold higher, but ammonium (NH₄ ⁺) concentrations are up to an order of magnitude higher than in the early 1990s. Averaged nitrate concentrations, however, changed to a lesser degree throughout the time course; water column concentrations remain very low. Total phosphorus has only increased in some bay segments, but increases in phosphate (PO₄ ^3?) have been more pervasive. There were differences in the year in which large increases in each nutrient were first noted: PO₄ ^3? in ~2001–2002, followed by NH₄ ⁺ ~a year later. The effects of a combination of steadily increasing anthropogenic nutrient increases from development, superimposed on nutrient loads from farming and animal operations, and groundwater inputs were accelerated by changes in freshwater flow and associated, negatively reinforcing, biogeochemical responses. Regionally, chlorophyll a concentrations have increased, and submersed aquatic vegetation has decreased. The system is now characterized by sustained summer picoplanktonic algal blooms, both brown tide and cyanobacteria. The retentive nature of this coastal lagoon combined with the reducing nature of the system will make these changes difficult to reverse if the current dual nutrient management practices are not accelerated.     

Spatial and Seasonal Patterns of Salinity in a Large and Shallow Tropical Estuary of the Western Caribbean

Salinity profiles and meteorological data were analyzed during February, May, and September 2006 in Chetumal Bay, a large, shallow estuary of the Western Caribbean. Local meteorological conditions revealed three seasons: (1) a dry season (March–May); (2) a wet season (June–October); and (3) the nortes season, with northerly wind events (October–February). During the nortes and wet seasons, salinity ranged between 13 and 16 psu, and salinity was highest in the dry season, ranging between 18 and 22 psu over most of the area; a strong stratification and a significant contribution of salty water characterized this season. Strong horizontal gradients were observed near Rio Hondo during the three seasons. Deep and narrow peculiar bathymetric features called the pozas showed a strong stratification and a relatively high salinity. The northern part of Chetumal Bay and probably the entire system are far from being homogeneous.     

基于高光谱技术的湖泊富营养化综合评价研究——以贵阳市百花湖为例

为了能够准确、快速、大范围地对湖泊富营养化进行监测评价,以贵阳市百花湖为实例,首先,对其水体进行光谱实测与水体采样实验,以及对水体光谱进行归一化、一阶微分、二阶微分等处理,诊断各水质参数的敏感波段,建立其水质参数的高光谱遥感定量模型;其次,探讨湖泊水质高光谱反射率与水质参数浓度之间的定量关系,并采用综合营养状态指数法(TLI)对百花湖富营养化进行评价。结果表明:(1)利用水体光谱的一阶微分反射率分析光谱与水质参数之间的相关性,得出水质参数(Chl-a、TP、TN、SD、CODMn)的敏感波段分别为699nm、823nm、399 nm、563nm、504nm;(2)利用水质参数敏感波段对湖泊水质参数进行估测的效果较为理想,各估测模型R2分别达到0.8276、0.7711、0.7917、0.9213、0.8328;(3)采用水质参数的实测值与估测值对百花湖富营养化评价结果是一致的,且均为中营养化,说明采用高光谱技术对湖泊富营养化的监测与评价是可行的。     

Evidence for Non-Conservative Behaviour of Chlorine in Humid Tropical Environments

The knowledge of the biogeochemical cycle of chlorine (Cl)is important since this element is used as a tracer of geochemical and hydrological processes in oceanic or continental environments. More specifically, Cl can be used to correct surface water composition from atmospheric contribution in order to calculate precise chemical weathering rates in watersheds. Beyond the problem of potential Cl sources in a given watershed, which is directly related to the lithology, vegetation, and industrial activities, the Cl normalization is based on the assumption that this element behaves conservatively during surface processes (e.g., chemical weathering, adsorption/desorption processes).The purpose of the present study is to forecast the geochemical behavior of Cl in a forested ecosystem located under humid tropical environment.For this reason, we have analyzed the Cl (and also Ca and Na) concentrations ofsurface waters (rainwater, groundwater, river water) over a two-year period in the Nsimi–Zoetele watershed (Cameroon).The Cl mass balance for the watershed appears to be equilibrated over the studied period (1995–1996) but Cl behavior in Mengong River draining the watershed suggests a non-conservative behavior. Indeed, Cl concentrationsin the Mengong River are low during dry seasons and high during wet seasons, which is the reverse tendency to what is usually observed taking into account dilution and evaporation processes. As Cl concentrations in the Mengong River are lower than those measured in all the feeding reservoirs, Cl should be adsorbed onto the soils of the watershed. However, as the Cl mass balance is equilibrated over the whole-year, Cl should be adsorbed and releasedat a seasonal scale. The results we obtained for this small watershed were not generalized for a larger studied basin (i.e., Nyong River basin). Even if these results should be followed by further investigations, this study suggests that Cl normalization should be used with caution to avoid under- or over-estimation of chemical weathering rates.     

Wetland Plant Diversity in a Coastal Nature Reserve in Italy: Relationships with Salinization and Eutrophication and Implications for Nature Conservation

Wetlands are important centers of biodiversity. Coastal wetlands are subject to anthropogenic threats that can lead to biodiversity loss and consequent negative effects on nature conservation. We investigated relationships between wetland vegetation and habitat conditions in a coastal Nature Reserve in Northern Italy that has undergone seawater intrusion and eutrophication for several decades. The wetland vegetation in the Nature Reserve consisted of nine communities of hygrophytic and helophytic vegetation and five communities of waterplant vegetation. The hygrophytic and helophytic communities were arranged according to a salinity gradient, from salt-free habitats to strongly saline habitats. The saline habitats had high nutrient levels, due to the influx of nitrate-rich saltwater from an adjacent lagoon. The waterplant communities were all typical of freshwater habitats. Water-table depth and concentration of dissolved nutrients in the water were the main factors structuring waterplant vegetation. The main driver of future changes in the wetland vegetation of the Nature Reserve is the ongoing increase in salinity levels which may enhance expansion of halophilic species and communities, thus outcompeting locally rare freshwater species. If nutrient, especially nitrate, load further increases in the next future, this may exert negative effects on wetland species and communities preferring nutrient-poor habitats.     

桂林会仙岩溶湿地水化学昼夜动态变化 及其影响因素

岩溶区地表河流与岩溶湖水化学的动态变化及水生植物固碳作用的研究,有助于加深对岩溶作用的生物地球化学过程特性,即短时间尺度属性的认识。本文利用自动化高精度在线监测和高密度取样,探讨岩溶湖(地下河水补给)水化学的昼夜动态变化及不同水生植物的影响。受气温和水生植物光合作用的影响,白天水温、pH、溶解氧、无机碳同位素值呈同步上升,而Ca2+、HCO-3含量、电导率下降。沉水植物群落分布区水化学等指标昼夜变幅大于挺水植物群落分布区,水温、pH、Ca2+、HCO-3、溶解氧、无机碳同位素值在挺水植物区的昼夜变化幅度分别为442 °C、065、18 mg/L、08 mmol/L、1402 mg/L、-2.27‰(δ13CV-PDB),在沉水植物区则分别上升到632 °C、143、24 mg/L、15 mmol/L、2386 mg/L、-5.03‰(δ13CV-PDB),说明沉水植物区的钙沉降与固碳效率更高。结果可为深入认识岩溶湿地水生生态系统,估算岩溶区水生植物固碳潜力奠定科学基础。     

洞庭湖区浅层地下水安全供水研究

应用模糊综合评价方法,选取浓度和毒理性双权重对洞庭湖区浅层地下水进行了环境质量评价,认为湖区浅层地下水主要遭受总铁、锰、pH值、氨氮、亚硝酸盐氮、硝酸盐氮、铍、化学耗氧量等污染,基本上没有遭受重金属污染;湖区浅层地下水水质整体较好,以优质水为主,占39．37％,合格水占26．04％;不合格水（较差水）占34．59％。在此基础上,根据不同区域水质的好坏,指出了湖区薪农村建设供水方向,并提出了若干安全供水的措施以供决策参考。     

Extreme Eutrophication in Shallow Estuaries and Lagoons of California Is Driven by a Unique Combination of Local Watershed Modifications That Trump Variability Associated with Wet and Dry Seasons

Rapidly growing human populations have caused heavy modifications to the watersheds of many Mediterranean climate estuaries, subjecting them to excessive nutrient enrichment and harmful macroalgal blooms. Despite these impacts, comprehensive studies in these systems are rare and comparisons between systems are lacking. We surveyed five southern California estuaries that ranged in size from 93 to 1,000 ha and incorporated differing land usages and watershed sizes. We sampled environmental variables (sediment redox potential, organic content, total nitrogen and total phosphorus, water column nitrate, ammonium, and salinity) and macroalgal cover and biomass quarterly at three locations within each estuary over 15 months to compare spatial and wet vs. dry season patterns. Maximum mean water column nitrate concentration across all estuaries ranged from 47 to 1,700 μM, showing that all estuaries were highly enriched with nitrogen, at least at some times. Mean macroalgal biomass ranged from 0 to 1,500 g wet wt m^?2. However, neither nutrient concentrations nor algal biomass showed consistent seasonal patterns as maximum values occurred in different seasons in different estuaries. Three-dimensional principal components analysis followed by regression analyses confirmed that macroalgal abundance was not directly related to water or sediment N concentrations. Rather each of these southern California estuaries showed individual patterns in all measured variables, which were most likely induced by a suite of physical modifications unique to each system and its watershed.     

桂林岩溶湿地沉积物地球化学元素变化的环境影响因子分析

湖泊湿地的环境演变受到多种因素作用的影响。本研究采集桂林岩溶湿地寺湖沉积物,分析了该地区近450年来导致环境变化的影响因子。对岩芯的地球化学元素进行了主成分分析,得出沉积物的化学组成主要受控于流域过程的侵蚀程度、径流与成岩作用强弱、区域背景和人类活动等4个影响因子。其中区域背景和人类活动影响因子所占比重较小,但近年来人类活动影响因子数值迅速增大,表现为磷元素沉积通量迅速增大。地球化学元素含量的变化具有明显的阶段性特征,表明不同的阶段影响因子的作用也不一样。     

乌梁素海富营养化主控因子年季变化分析及综合评价

运用均匀随机数以等级评价标准产生建模样本和验证样本，利用实数编码的加速遗传算法(RAGA)求解逻辑斯缔曲线(Logistic Curve)水环境评价模型中的参数，建立了富营养化等级评价模型，据此计算了乌梁素海1996∽2003年夏初、仲夏、秋末3个时点的富营养化等级，分析了乌梁素海富营养化主控因子及其等级的年季动态变化特征和它们之间的影响关系。结果表明：1996∽2003年乌梁素海各富营养化主控因子均变化在4级富营养化指标左右，除总磷波动性较大以外，其他各项指标均呈逐年恶化趋势；而综合富营养化等级均超过4级，且呈逐年增加趋势，目前已十分接近5级——极富营养化状态。     

Eutrophication,health risk assessment and spatial analysis of water quality in Gucheng Lake,China

The water characteristics of the Gucheng Lake, such as eutrophication, health and spatial distribution, were investigated. On the basis of the trophic state index (TSI) and entropy weight, a synthesized trophic state index (STSI) model was established to assess lake eutrophication condition through calculating STSI, choosing TP, TN, COD, BOD and NH₃-N as trophic variables. The STSI ranged from 50.58 to 62.44, which showed that the water has been between eutrophic and supereutrophic. A histogram was applied to health risk assessment which was analyzed from carcinogenic substances (Cr⁺⁶, As and Cd) and non-carcinogenic substances (hydroxybenzene, Pb, Hg, CN⁻ and NH₃), and the results showed that the former was much greater than the latter for effect. The total risk for each resident caused by all pollutants ranged from 5.18E-05 to 8.34E-05, which is far higher than the standard, recommended by Sweden Bureau of Environment Protection and Holland Ministry of Building and Environment Protection (1.0E-05). Cluster analysis was used to detect similarities and dissimilarities among the seven sampling sites and explain the observed clustering in terms of affected conditions. Twenty-one variables were used to divide seven sampling sites into three groups, namely, north lake, south lake and lake center.     

Shallow seismic stratigraphy and pockmarks of a hydrothermally influenced lake, Lake Rotoiti, New Zealand

Lake Rotoiti formed 11 850–20 000 years ago when lava flows dammed the drainage system through the Okataina caldera, one of the major rhyolitic centres of the intracontinental, back-arc, Taupo Volcanic Zone of North Island, New Zealand. The lake morphology reflects this complex origin, with remnants of the old caldera rim, the lava dam and relict river system being preserved. High resolution seismic reflection profiles (7 kHz) show the drowned river system channelled inflowing water into the lake basin, scouring and depositing sediments and maintaining an active sublacustrine channel in the former river valley. Airfall tephras are preserved in lake sediments. The tephrachronology, established from the surrounding catchments, can be correlated with the siesmic stratigraphy for eight major eruptions over the last 11 850 years. Hydrothermal fields underlying the lake generate gaseous sediments which mask seismic penetration. This is indistinguishable from seismic masking caused by biogenic gas accumulation within the sediments. Venting of hydrothermal gases at the surface creates pockmarks. From the seismic stratigraphy beneath pockmarks seven stages of pockmark genesis have been identified which show pockmarks grow, decay, migrate and persist over several thousand years.     

Geochemical Characteristics of Amino Acids in Sediments of Lake Taihu, A Large, Shallow, Eutrophic Freshwater Lake of China

To examine the biogeochemistry of amino acids (AAs) in the sediment of Lake Taihu, surface sediments (0–3 cm) and deeper sediments (18–21 cm) were collected at 21 sites from different ecotype zones of the lake. AAs were extracted from the sediments, and the total hydrolyzable amino acids (THAA) were determined by high-performance liquid chromatography instrument. The THAA contents in Taihu sediment were much lower than that in marine sediments, ranging from 6.84 to 38.24 μmol g⁻¹ in surface sediments and from 2.91 to 18.75 μmol g⁻¹ in deeper sediments in Taihu, respectively. AAs were a major fraction of the organic matter (OM) and organic nitrogen in Taihu sediments. The AAs on average contributed 8.2% of organic carbon (OC) and 25.0% of total nitrogen (TN) from surface sediments, and 5.9% of OC and 20.5% of TN in deeper sediments, respectively. AA composition provided very useful information about the degradation of OM. Glycine (Gly) and lysine (Lys) were the predominant forms of AAs in the sediments, irrespective of lake regions, followed by alanine, glutamic acid, serine (Ser), and aspartic acid (Asp). The high concentrations of Gly, Lys, and Ser suggested that these forms of AAs were relatively refractory during OM degradation in sediments. The relationship between the Asp/Gly ratio and Ser + Thr [mol%] indicated that OM in surface sediment was relatively fresher than that in deeper sediments. The AAs-based degradation index (DI) gave a similar conclusion. The composition and DI of AAs in surface sediments are markedly different across different zones in Taihu. The percentages of AAs to organic carbon (AA-C%) and total nitrogen (AA-N%) were higher in phytoplankton-dominated zones than those in macrophyte-dominated zones. These results suggest that DI could provide useful information about the degradation of OM in shallow lakes such as Taihu.     

Biogeochemistry of Major Redox Elements and Mercury in a Tropical Reservoir Lake (Petit Saut,French Guiana)

The hydroelectric reservoir of Petit Saut, French Guiana, was created in 1994–1995 by flooding 350 km² of tropical forest. When sampled in 1999, the lake exhibited a permanent stratification separating the 3–5 m thick, oxygenated epilimnion from the anoxic hypolimnion. The rate of anaerobic organic carbon mineralization below the oxycline was on the order of 1 μmol C m⁻² s⁻¹ and did not show a pronounced difference between wet and dry seasons. Methanogenesis accounted for 76–83% of anaerobic carbon mineralization, with lesser contributions of sulfate reduction and dissimilatory iron reduction. Upward mixing of reduced inorganic solutes explained 90% of the water column O ₂ demand during the dry season, while most O ₂ consumption during the wet season was coupled to aerobic respiration of organic matter synthesized in the surface waters. Inorganic mercury species represented 10–40% of total dissolved mercury in the epilimnion, but were of relatively minor importance (≤10%) in the anoxic portion of the water column. Net production of soluble organic mercury compounds in the flooded soils and anoxic water column did not vary significantly between wet and dry seasons. Methylmercury accounted for about 15% of total dissolved mercury below the oxycline. Its estimated net production rate, 0.04 mg m⁻² yr⁻¹, is of the same order of magnitude as values reported for contaminated lakes and flooded terrestrial ecosystems.