Water isotope characteristics of a flood: Brisbane River,Australia

Flooding associated with tropical storms can cause extreme perturbations in riverine and coastal ecosystems. Measuring isotope variability of tropical storm events can help investigate the impacts of flooding. We measured the water isotope composition (δD and δ¹⁸O) of rain and associated floodwater collected during two storms and subsequent major and minor flooding events in the subtropical coast of eastern Australia. Compared with baseline regional rainfall isotope values of ?15.0 ± 1.9‰ for δD and ?3.3 ± 0.2‰ for δ¹⁸O, floodwater had lower values with ?33.8 ± 2.5‰ δD and ?5.1 ± 0.4‰ δ¹⁸O for the major flood and ?29.4 ± 1.0‰ δD and ?4.6 ± 0.1‰ δ¹⁸O for the minor flood. The low isotope composition of the floodwater was associated with the transport of large quantities of suspended sediments, with sediment loads 30 to 70 times larger than during base flow conditions. Floods carried up to 35% of the annual phosphorus and up to 208% of the currently calculated average annual nitrogen load of the Brisbane River. The dramatic changes caused by a rapid increase in discharge from 2 to 2015 m³ s^?1 over 2 days in the major flood would have major consequences in riverine and coastal ecosystems of the region. These changes could potentially be traced using the isotope composition of the floodwaters. Copyright © 2015 John Wiley & Sons, Ltd.     

Polychlorinated biphenyls in the Mediterranean Sea

Although concentrations of polychlorinated biphenyls (PCBs) in biota, sediment and water of the Mediterranean Sea have been determined, most available data are for samples collected within the narrow coastal zone at relatively few locations. PCB concentrations in samples from the open Mediterranean Sea have not previously been reported. We report here the concentrations of PCBs in surface and sub-surface water from 36 locations. Analysis of our data indicate that there may be some correlation between PCB concentration in Mediterranean seawater and certain demographic and oceanographic features of the region.     

Detection of anthropogenic gadolinium in the Brisbane River plume in Moreton Bay, Queensland, Australia

Wastewater effluent is known to contain macro and micropollutants, which may be deleterious to environmental health. One such class of micropollutants is chelated gadolinium, which are used as MRI contrast agents. As these MRI contrast agents can be assumed to behave conservatively during estuarine mixing, it is possible to calculate how much wastewater is represented in any particular sample. In this study, the percentage contribution of wastewater at specific locations in Moreton Bay, Qld, were determined by calculating the additional anthropogenic gadolinium contribution to the total rare earth element concentrations. Wastewater contributions were measured at concentrations as low as 0.2%, demonstrating the applicability of this technique for wastewater effluent plume mapping.     

Polychlorinated biphenyls in North Atlantic seabirds

Polychlorinated biphenyls are usually thought to be discharged in industrial effluents and therefore to be commonest in inshore waters close to centres of industry. It now appears that high concentrations are found in pelagic-feeding seabirds from the North Atlantic, far from possible industrial sources of these compounds.     

Distribution of polychlorinated biphenyls in the water, sediment and fish from the Pearl River estuary, China

The concentrations and distribution of polychlorinated biphenyls were determined in water, surface sediments and fishes from the estuaries of Pearl River, PR China. The results showed that the concentrations ranged from 2.47 ng l-1 to 6.75 ng l-1 in water, from 11.13 ng g-1 to 23.23 ng g-1 in sediments (dry weight) and from 68.64 ng g-1 to 316.85 ng-1 in fish (lipid weight). It was found that the feeding habits of fish were very significant in the accumulation of polychlorinated biphenyls and pattern of congeners. Carnivorous and benthic fishes such as eel (Anguilla japonica) and Chinese sea catfish (Arius sinensis) were found to have high concentrations of polychlorinated biphenyls and of high-chlorinated congeners, while herbivores such as shad (Clupanodon punctatus) and mullet (Mugil cephalus) exhibited an opposite trend. Congeners IUPAC Nos. 153, 138, 118, 87/81, 170 and 52 were found frequently in most samples (both sediment and fish). In comparison with other places in the world, the concentration of polychlorinated biphenyls in sediment and fish from the estuary of Pearl River were low.     

Distributions of polychlorinated biphenyls in the Daliao River estuary of Liaodong Bay,Bohai Sea (China)

The distributions of 41 polychlorinated biphenyls (PCBs) were determined in the aqueous phase, suspended particulate matter (SPM), and sediment of the Daliao River estuary in Liaodong Bay, Bohai Sea (China). The total PCB concentrations ranged from 5.51 to 40.28 ng L⁻¹ in the surface water, from 6.78 to 66.55 ng L⁻¹ dry weight in the SPM, and from 0.83 to 7.29 ng g⁻¹ dry weight in the sediment. The PCB concentrations in water, SPM, and sediment were moderate relative to those reported for other estuary and marine systems around the world. Sedimentary PCB concentrations decreased offshore due to the active deposition of laterally transported river-borne particles. The predominance of the highly chlorinated congeners for the water, SPM, and sediment samples are an indication of either a lack of degradation or the presence of nearby or recent releases into the environment.     

Spatio-temporal assessment of perfluorinated compounds in the Brisbane River system,Australia: Impact of a major flood event

Perfluorinated chemicals including PFOA and PFOS have been widely used in consumer products and have become ubiquitous pollutants widely distributed in the aqueous environment. Following a major flood event in 2011, water samples were collected along a spatial gradient of the Brisbane River system to provide an initial estimate of the release of PFASs from flooded urban areas. PFOA (mean concentrations 0.13–6.1 ng L⁻¹) and PFOS (mean concentrations 0.18–15 ng L⁻¹) were the most frequently detected and abundant PFASs. Mean total PFASs concentrations increased from 0.83 ng L⁻¹ at the upstream Wivenhoe Dam to 40 ng L⁻¹ at Oxley Creek, representing an urban catchment. Total masses of PFOA and PFOS delivered into Moreton Bay from January to March were estimated to be 5.6 kg and 12 kg respectively. From this study, urban floodwaters appear to be a previously overlooked source of PFASs into the surrounding environment.     

Miocene lava flows and eruptive centres near Brisbane,Australia

Three ring-complexes are considered as possible sources for the volcanic sequences of the Lamington Group and Main Range Volcanics, all of Lower Miocene age. The Lamington Group lavas comprise transitional tholeiitic basalts and rhyolites with alkali basalts at the base; the Main Range Volcanics are an alkali olivine basalt - trachyte - soda rhyolite association. The Mt. Warning intrusive complex is thought to be the source of most of the lavas of the Lamington Group. It consists largely of plutonic rocks which have probably moved upwards by ring-faulting determining the initiation of erosion of the wide caldera in which the complex lies. Most of the members of the Mt. Barney complex preceded the Lamington Group lavas; the Mt. Alford complex was synchronous with the Main Range lavas, but is unlikely, from structural considerations, to have contributed to them. The two major volcanic groups are compared with each other and with the intrusive rocks of Mt. Warning and Mt. Alford by an alkali-silica diagram and 0 values.     

Polychlorinated biphenyls and organochlorine pesticides in plastics ingested by seabirds

The occurrence of plastic objects in the digestive tract was assessed in eight species of Procellariiformes collected in southern Brazil and the occurrence of polychlorinated biphenyls (PCBs) and organochlorine pesticides (OCPs) in the ingested plastics pellets and plastic fragments was evaluated. PCBs were detected in plastic pellets (491 ng g⁻¹) and plastic fragments (243-418 ng g⁻¹). Among the OCPs, p,p′-DDE had the highest concentrations, ranging from 68.0 to 99.0 ng g⁻¹. The occurrence of organic pollutants in post-consumer plastics supports the fact that plastics are an important source carrying persistent organic pollutants in the marine environment. Although transfer through the food chain may be the main source of exposure to POPs to seabirds, plastics could be an additional source for the organisms which ingest them, like Procellariiformes which are the seabirds most affected by plastic pollution.     

Polychlorinated biphenyls and organochlorine pesticides in bottom sediments of the Irkutsk Reservoir

The concentrations of organochlorine pesticides (HCCH, DDT, and HCB) and 34 congeners of polychlorinated biphenyls were studied in bottom sediments of the Irkutsk Reservoir, the first in the Angara Chain of Reservoirs. The degree of pollution of bottom sediments was evaluated in accordance with classifications of regional and international standards. A correlation was found to exist between the distribution of some organic compounds and organic carbon concentration.     

Polychlorinated biphenyls in sewage sludge and sediments of the New York Bight

Sediments of the New York Bight were analysed for polychlorinated biphenyls (PCB) and found to be heavily contaminated by such substances. The highest concentrations are adjacent to an offshore sludge dump zone, implying that the primary source of PCBs is sewage sludge in the area under consideration. Widespread transport of PCBs out of the bight is not evident as the area of contamination is limited to areas of mud accumulation. The PCB profile in a core of these mud facies can be historically correlated to the commercial production of PCBs.     

Polychlorinated biphenyls (PCBs) in a benthic ecosystem in Gwangyang Bay, South Korea

Benthic ecosystem in Gwangyang Bay, a fast developing industrial area with steel production, port container handling, petroleum and other chemical processing in South Korea was studied. The average levels of polychlorinated biphenyls (ΣPCB) in the benthic components were: seawater 2.99 ± 0.13 (ng/L); sediment 294 ± 118 (ng/g TOC); [biota=ng/g lipid] starfish 92; prawn 131 ± 2; mussels 127 ± 22; crab 182 ± 114; clam 187; polychaeta 215; sea cucumber 497 ± 90; squill 603 ± 38; fish 396 ± 159. Levels in the inner bay samples were higher than the outer bay samples suggesting land based pollution. Good correlation (r(2)=0.79; p<0.05) existed between PCB concentration and lipid content indicating partitioning processes in action. PCB signature in the abiotic and biotic components shows enrichment of lower chlorinated congeners emitted by a unique source nearby, viz. steel manufacturing plant.     

Polychlorinated biphenyls and hydrocarbons in bottom sediments of Pechora Basin Rivers

The quantitative concentrations of 21 congeners of polychlorinated biphenyls and 16 priority polycyclic aromatic hydrocarbons were studied in bottom sediments of the Usa River, the largest Pechora’s tributary, and its tributaries located in the central part of Timan-Pechora petroleum province. In accordance with the classification of the regional and international standards, the pollution degree of bottom sediments by organic compounds of those classes was evaluated. Pollution profiles were examined and the character of the dominating source of polychlorinated biphenyls and polycyclic aromatic hydrocarbons for bottom sediments in the region under study was identified. Key words: bottom sediments, polychlorinated biphenyls, profiles of polycyclic aromatic hydrocarbons, petrogenic, pyrogenic pollution source.