Environmental evaluation of alternative chemicals to methyl bromide for fumigation of quarantine pests in transit

The majority of recent quarantine schedules have relied on methyl bromide fumigation. However, due to the phase-out of this fumigant in January 2005 alternative treatments are needed. Four alternative chemical fumigants were tested for their potential to replace methyl bromide as a control agent for Bemisia tabaci, Liriomyza huidobrensis and Frankliniella occidentalis. Phosphine at 2 g/m³ gave promising results at 15 °C with complete mortality of all insects after 24 h exposure. Sulphuryl fluoride, ethyl formate and acetaldehyde caused severe damage to plant foliage after only 4 h exposure. However, sulphuryl fluoride produced 100 % mortality of L. huidobrensis pupae after only 2 h exposure. In a large scale test using phosphine 2 g/m³ at 15 °C complete mortality of L. huidobrensis eggs and pupae was recorded after a 24 h exposure. However, only 98.5 and 86 % mortality of B. tabaci eggs and F. occidentalis eggs, respectively, was recorded after this treatment. Treatments with phosphine produced no significant detrimental effects on subsequent plant growth. The potential of these chemicals to act as alternatives to methyl bromide as quarantine fumigants is discussed.     

High tolerance to tributyltin in embryos and larvae of the horseshoe crab,Limulus polyphemus

The effects of acute and chronic exposure to tributyltin (TBT) were examined in bioassays using horseshoe crab (Limulus polyphemus) embryos and “trilobite” larvae. Larvae had>95% survival after 24-h exposure to nominal concentrations of 1–500 μg l^?1 TBT. Survival was also high following 48-h and 72-h exposure to ≤100 μg l^?1 TBT; >50% mortality was seen only after 48-h and 72-h exposure to 500 μg l^?1 TBT. Estimated median lethal concentrations (LC₅₀) were >1000 μg l^?1, 742 μg l^?1, and 594 μg l^?1 for 24-h, 48-h, and 72-h exposure, respectively. Much higher toxicity LC₅₀=42 μg l^?1) was seen following chronic exposure of larvae to TBT. Acute exposure to TBT significantly increased the time required by larvae to molt into the first-tailed stage. LC₅₀ for horseshoe crab embryos exposed to TBT were 44 μg l^?1, 20 μg l^?1, and 14 μg l^?1 for 24, 48, and 72 h acute exposure, indicating that this earlier developmental stage was about 30–40 fold more susceptible to TBT than larvae. Horseshoe crabs are highly tolerant of TBT in comparison to early developmental stages of other marine arthropods. The ability of horseshoe crab embryos and larvae to survive in the presence of organotin pollution suggests the possibility of bioaccumulation and movement into the estuarine food chain via shorebirds, gulls, and fish.     

Sensitivity of early life stages of blueback herring to moderate acidity and aluminum in soft freshwater

The sensitivity of the blueback herringAlosa aestivalis to acidity and aluminum (AI) in reconstituted, soft freshwater (23–25 mg I^?1 hardness as CaCO₃) was investigated in a continuous exposure laboratory study. Mature (20–24 h postfertilization) embryos were more tolerant than 1- to 5-day-old yolk-sac larvae. Significant mortality of embryos occurred only when pH was 5.0 and the total Al concentration was 0.42 mg I^?1 (predicted MIBK-extracted total monomeric AI=0.34 mgI^?1). Moderate acidity dramatically decreased the survival of yolksac larvae. Mean mortality was 99% in pH 5.0 and 89% in pH 5.7 compared to 38% in pH 6.5 and 16% in pH 7.8 without AI. The toxicity of AI to yolk-sac larvae was pH- and dose-dependent. Total AI concentrations up to 0.34 mg l^?1 (predicted total monomeric AI up to 0.21 mg l^?1) were not toxic at pH 6.5 and 7.8. At pH 5.0 and 5.7, AI increased the rate at which yolk-sac larvae died during a 96-h exposure (i.e., time to 50% mortality decreased with increasing AI). Continuous exposure to a predicted total monomeric AI level of only 0.03 mg I^?1 at pH 5.0 killed all yolk-sac larvae in <24 hours. The mechanisms of acid and AI toxicity were apparently physiological and not associated with extensive cellular damage. Acidification events measured in Chesapeake Bay tributaries may reduce survival of blueback herring yolk-sac larvae and embryos exposed to those events.     

Recycling process and proto-kimberlite melt metasomatism in the lithosphere-asthenosphere boundary beneath the Amazonian Craton recorded by garnet xenocrysts and mantle xenoliths from the Carolina kimberlite

Here we present new data on the major and trace element compositions of silicate and oxide minerals from mantle xenoliths brought to the surface by the Carolina kimberlite, Pimenta Bueno Kimberlitic Field, which is located on the southwestern border of the Amazonian Craton. We also present Sr-Nd isotopic data of garnet xenocrysts and whole-rocks from the Carolina kimberlite. Mantle xenoliths are mainly clinopyroxenites and garnetites. Some of the clinopyroxenites were classified as GPP–PP–PKP (garnet-phlogopite peridotite, phlogopite-peridotite, phlogopite-K-richterite peridotite) suites, and two clinopyroxenites (eclogites) and two garnetites are relicts of an ancient subducted slab. Temperature and pressure estimates yield 855–1102 °C and 3.6–7.0 GPa, respectively. Clinopyroxenes are enriched in light rare earth elements (LREE) (La_N/Yb_N = 5–62; Ce_N/Sm_N = 1–3; where N = primitive mantle normalized values), they have high Ca/Al ratios (10–410), low to medium Ti/Eu ratios (742–2840), and low Zr/Hf ratios (13–26), which suggest they were formed by metasomatic reactions with CO₂-rich silicate melts. Phlogopite with high TiO₂ (>2.0 wt.%), Al₂O₃ (>12.0 wt.%), and FeO_t (5.0–13.0 wt.%) resemble those found in the groundmass of kimberlites, lamproites and lamprophyres. Conversely, phlogopite with low TiO₂ (<1.0 wt.%) and lower Al₂O₃ (<12.0 wt.%) are similar to those present in GPP-PP-PKP, and in MARID (mica-amphibole-rutile-ilmenite-diopside) and PIC (phlogopite-ilmenite-clinopyorxene) xenoliths. The GPP-PP-PKP suite of xenoliths, together with the clinopyroxene and phlogopite major and trace element signatures suggests that an intense proto-kimberlite melt metasomatism occurred in the deep cratonic lithosphere beneath the Amazonian Craton. The Sr-Nd isotopic ratios of pyrope xenocrysts (G3, G9 and G11) from the Carolina kimberlite are characterized by high ¹⁴³Nd/¹⁴⁴Nd (0.51287–0.51371) and εNd (+4.55 to +20.85) accompanied with enriched ⁸⁷Sr/⁸⁶Sr (0.70405–0.71098). These results suggest interaction with a proto-kimberlite melt compositionally similar with worldwide kimberlites. Based on Sr-Nd whole-rock compositions, the Carolina kimberlite has affinity with Group 1 kimberlites. The Sm-Nd isochron age calculated with selected eclogitic garnets yielded an age of 291.9 ± 5.4 Ma (2 σ), which represents the cooling age after the proto-kimberlite melt metasomatism. Therefore, we propose that the lithospheric mantle beneath the Amazonian Craton records the Paleozoic subduction with the attachment of an eclogitic slab into the cratonic mantle (garnetites and eclogites); with a later metasomatic event caused by proto-kimberlite melts shortly before the Carolina kimberlite erupted.     

Bound carboxylic acids in the Alberta oil sands

The Alberta oil sands contain 1–2% organic solvent insoluble organic matter chemisorbed to the inorganic matrix. Analysis of the monocarboxylic fraction (1–14%) of the chemisorbed material has revealed the presence of C₁₂–C₃₂ normal, iso, anteiso alkenoic acids, mono and diunsaturated acids, cyclopropylalkanoic and cyclic terpenoid carboxylic acids. Some of the main components of the acyclic acids were similar to those which have been identified in various petroleums and Alberta oil sand bitumens (in small concentrations) by Mackenzie et al. (Advances in Organic Geochemistry 1981, pp 637–649, Wiley/Heyden, 1983), and attributed to bacterial degradation of the oils via the aerobic pathway of biosynthesis.The presence of these acids in the chemisorbed fraction and virtual absence in the bitumen lends additional support to earlier proposals that the Alberta oil sand bitumens have undergone severe microbial degradation.     

Discovery of the “Phantom” dinoflagellate in Chesapeake Bay

Since its discovery in natural estuarine habitat of North Carolina in 1991, the widespread impact of the toxic dinoflagellate, Pfiesteria piscicida (gen. et sp. nov.), popularly called the “phantom” dinoflagellate, on North Carolina fish stocks has been established, yet little is known about its influence outside of North Carolina estuaries. Here, we document the presence of P. piscicida in Chesapeake Bay. A fish kill was observed after inoculating an aquarium containing mummichogs with sediment samples from Jenkins Creek, a brackish creek (salinity 11‰) of the Chesapeake Bay system. P. piscicida was the cause of the kill, as supported by morphological, physiological, and histological evidence. The appearance and behavior of the algae and symptoms associated with fish mortality were consistent with those previously observed in P. piscicida-associated aquaria fish kills in North Carolina. The discovery of P. piscicida in Chesapeake Bay supports the speculation that these toxic dinoflagellates have a dramatic and far-reaching impact on fish stocks in shallow, eutrophic estuaries along the eastern United States.     

Photometric parameters of the dwarf nova SS Cygni in the quiescent state

The mean 1983–1996 UBV light curves of the dwarf nova SS Cyg are used to derive the binary parameters in the quiescent state. Solutions are obtained for a classical hot-spot model and a model with an energy source lying outside the accretion disk. Photometric and spectroscopic data are combined to infer the masses and radii of the binary components. The white dwarf in SS Cyg is one and a half times as massive as the red dwarf, q=M _wd /M _rd ～1.45, M _rd ～0.46M _⊙ and M _wd ～0.66M _⊙. The orbital inclination of the system is i?51°–54°. The contribution of the accretion disk to the total flux in the quiescent state is estimated to be ～47–49% and ～54% in the VU and B filters, respectively. The hot spot contributes less than ～3% to the total optical flux. In the “non-classical” hot-spot model, the disk and bulge contributions are 27 and 2–8%, respectively, depending on the orbital phase. The shape of the mean light curves of SS Cyg suggests asymmetric heating of the red-dwarf surface in the quiescent state by high-temperature radiation generated in the hot-spot region.     

Experimental geochemistry of Pu and Sm and the thermodynamics of trace element partitioning

The partitioning of Pu and Sm between diopside/liquid and whitlockite/liquid has been investigated experimentally to evaluate the geochemical coherence of Pu and the light REEs. ${}^{\mathrm{Pu}}\text{D}{}^{\mathrm{Sm}}\text{D}$ is 2̃ for both diopsidic pyroxene and whitlockite. This small amount of fractionation would be decreased further if Pu were compared to Ce or Nd. Our experimental results thus validate the suggestion that Pu behaves as a LREE during igneous processes in reducing environments.Our data and the data of Ray et al. (1983) indicate that temperature rather than melt composition is the most important control on elemental partitioning. This is true even though we demonstrate that additions of only 1–2 wt.% of P₂O₅ to the diopside-anorthite-albite system change ^PuD_cpx by a factor of two. Our data suggest that P₂O₅ in aluminosilicate melts serves as a complexing agent for the actinides and lanthanides.     

Recruitment failure of the bay scallop,Argopecten irradians concentricus,during the first red tide,Ptychodiscus brevis,outbreak recorded in North Carolina

In the presence of the first recorded red tide (Ptychodiscus brevis) outbreak in North Carolina, autumn 1987 recruitment of bay scallops (Argopecten irradians concentricus) in the state’s most productive scallop beds was a virtual failure. Recruitment averaged across all of Bogue and Back sounds was only 2% of the mean of three previous red tide-free (control) years. Only from central Core Sound northward, where the red tide occurred later and not as intensively, was bay scallop recruitment normal (93% of control years). Mortality of adult scallops from early December 1987 to late January 1988, while red tide was at bloom concentrations but fishing was prohibited, was 21%. No comparable natural mortality data exist for control years because intense fishing mortality in this period is confounded with natural mortality. Data on abundance of articulated pairs of empty shells strongly suggest that the red tide caused mortality of both adult and newly recruited bay scallops. Bay scallop recruitment in autumn 1988 again failed to restock the traditionally productive scallop beds in western Bogue Sound and in Back Sound, perhaps because the only concentrations of spawners surviving the red tide in central Core Sound and further north were too far distant for successful transport of bay scallop larvae in sufficient abundance to these traditional beds. This potential explanation implies continuing impact of the red tide on North Carolina’s bay scallop fishery until spawning populations increase in Back Sound and western Bogue Sound.     

Short ingestion tests as alternative proposal for conventional range finding assays with Thamnocephalus platyurus and Brachionus calyciflorus

The goal of this study was to evaluate whether short 1 h sublethal assays may predict the results of 24 h lethality assays with rotifers Brachionus calyciflorus and anostracan crustaceans Thamnocephalus platyurus. The test bionts were hatched from cysts. Inhibition of ingestion was observed after 15 min of incubation of rotifers and crustaceans with the suspension of carmine and latex beads, respectively. Nine compounds with different modes of action were used as toxicants zinc ions, sodium dodecyl sulphate, p-nitrophenol, 3, 5-dichlorophenol and pharmaceuticals propranolol, fluoxetine, abamectin, doramectin and ivermectin. The toxicity values observed in the ingestion tests were very close to the mortality values over a wide range of toxicity from a low toxic surfactant to very toxic avermectins. The ratio between the 1 h EC₅₀’s in the ingestion test and the 24 h LC₅₀’s in the lethality test was below 2 in all cases for rotifers, and 7 in 9 cases for crustaceans. The toxicity of zinc and 3,5-dichlorophenol in the Thamnotoxkit F? was 15-fold higher and 10 fold lower than in the ingestion test, respectively. The 24 h LC₅₀ values are within the range of 25–400 % of the 1 h EC₅₀ values for almost all toxicants tested with the exception of p-nitrophenol for B. calyciflorus and zinc and 3, 5-dichlorophenol for T. platyurus. Short, 1 h ingestion assays Rotoxrapid and Rapidtoxkit are good predictors of the mortality over the next 24 h and can be used as a range finding tests for representatives of pharmaceuticals and surfactants.     

Stress field in the central and northern parts of the Gulf of Suez area,Egypt from earthquake fault plane solutions

Earthquake focal mechanism solutions from 18 events in the central and northern parts of the Gulf of Suez with local magnitudes ranging from 2.8 to 5.2 and occurring between 1983 and 2004 are used to determine the type of motion and stress pattern of the region. Fault plane solutions show mostly normal component; pure normal faulting mechanisms and normal faulting with a strike-slip component. Only some mechanisms show pure strike-slip faulting. The fault planes strike in NW, WNW, NNE and ENE directions, in conformity with the geologically observed striking faults in the northern and central parts of the gulf. The principal stress orientation is also estimated by inverting the selected focal mechanism solutions. The results show that the northern part of the Gulf is subjected to NE–SW to NNE–SSW extension, with a horizontal σ₃ (plunge 3°) and subvertical σ₁ (plunge 80°). This means that the horizontal extensional stresses are still present in the central/northern Gulf of Suez.     

A note on the isolation of the bacteriumVibrio parahaemolyticus from estuarine North Carolina

The potentially pathogenic bacterium,Vibrio parahaemolyticus, was isolated from water, sediment, and oyster samples collected from estuarine North Carolina. In October, when water temperatures were 15–18°C,V. parahaemolyticus was still detected in all substrates. However, the organism was detected only in one sediment sample in January when water temperatures were 4–5°C. No correlation was observed between the occurrence of the bacterium and domestic wastewater contamination.     

Toxicity of methyl parathion on growth and reproduction of three ecologically different tropical earthworms

This work illustrates the toxicological impact of pesticide methyl parathion (MP) (dust—2 % active ingredient, a.i.) on growth and reproduction performance in tropical earthworms: Metaphire posthuma (endogeic), Lampito mauritii (anecic) and Allolobophora parva (epigeic). A total of three concentrations (a.i. g kg^?1 dry test soil), 1.00 (T ₁), 1.125 (T ₂) and 2.25 (T ₃) of MP, were applied in test substrate to examine the impact on mortality, individual live weight changes and reproduction patterns in test species over 60 days under laboratory conditions. MP caused significant mortality in all tested species, and median lethal dose (LD₅₀) for L. mauritii, M. posthuma and A. parva was 24.85, 23.64 and 22.67 mg a.i., respectively. The individual live weight loss was 27.0–37.0 % in L. mauritii, 36.0–57.1 % in M. posthuma and 1.2–11.0 % in A. parva in different test concentrations. The pesticide-exposed worms produced less cocoons than control, but in L. mauritii, an unusual reproduction (hormesis) was recorded. Results suggested the species-specific toxicity of MP against tropical earthworms.     

Influence of the 2008 Wenchuan earthquake (Mw 7.9) on the occurrence probability of future earthquakes on neighboring faults

The Longquan–Shan fault and the Huya fault are two major neighboring faults of the Longmen–Shan fault zone where the 12 May 2008 Wenchuan earthquake (M_w 7.9) occurred. To study the influence of the Wenchuan event on these two active faults, we calculate changes of Coulomb stress on the Longquan–Shan fault and the Huya fault caused by the Wenchuan mainshock. Our results indicate that the Coulomb stress in the northern section (Zone A) of the Longquan–Shan fault is increased by 0.07–0.10 bars, that in the middle section (Zone B) by 0.04–0.11 bars, and that in the southern section (Zone C) shows almost no change. For the Huya fault, the Coulomb stress is decreased by 0.01–0.03 bars in the northern section (Zone A), 0.10–0.35 bars in the middle section (Zone B), and nearly 0.5 bars in the southern section (Zone C). The epicenter distribution of small earthquakes (M_L ⩾ 1.5) on the Longquan–Shan fault and the Huya fault after the Wenchuan earthquake is consistent with the distribution of the Coulomb stress change. This implies that the Wenchuan earthquake may have triggered small events on the Longquan–Shan fault, but inhibited those on the Huya fault. We then use the rate/state friction law to calculate the occurrence probability of future earthquakes in the study region for the next decade. They include the distribution of b-values, magnitude of completeness (M_c), the background seismicity rate, a value of Aσ_n and the duration for the transient effect (t_a) in the study region. We also estimate the earthquake occurrence probabilities on the neighboring faults after the Wenchuan earthquake. Our results show that, the occurrence probability of future earthquakes in the Longquan–Shan has a slight increase, being 7% for M ⩾ 5.0 shocks during the next decade, but the earthquake probability in the Huya region is reduced obviously, being 5–20%, 7–26% and 3–9% for M ⩾ 5.0 shocks during the next decade in sections A, B and C of the Huya fault, respectively.     

Temperature effects on the timing of striped bass egg production,larval viability,and recruitment potential in the Patuxent River (Chesapeake Bay)

The relationships between egg production (spawning behavior), larval growth and survival, and environmental conditions that larvae encounter were investigated in the Patuxent River tributary of Chesapeake Bay in 1991. Striped, bass (Morone saxatilis) eggs and larvae occurred predominantly above the salt front where conductivity was ≤800 μmhos cm^?1. There were three prominent peaks in egg production, each coinciding with increasing temperatures. Estimated growth rates of 6-d, otolith-aged cohorts, which ranged from 0.15 mm d^?1 to 0.22 mm d^?1 (mean=0.17 mm d^?1), were not demonstrated to differ significantly from each other. Observed zooplankton densities and temperature did not significantly affect growth rates. Stage-specific cumulative mortalities of combined cohorts were calculated for eggs (Z_stage=0.20=18.1%), yolk-sac larvae (Z_stage=5.80=99.7%), and first-feeding larvae (Z_stage=2.95=94.8%). The very high mortality of yolk-sac larvae suggests that dynamic during this stage may have had a major impact on subsquent recruitment. Cohort-specific mortality rates of larvae were variable, ranging from Z=0.045 d^?1 to 0.719 d^?1, and were strongly temperature-dependent. Cohorts that experiented average temperature <15°C or >20°C during the first 25 d after hatching had significantly higher mortality rates than those which experienced intermediate temperatures. Estimated hatch-date frequencies of larvae ≥8 mm SL indicated goo, very good, and very low potential recruitments for cohorst spawned during early-season (April 2–11), mid-season (April 12–24) and late-season (April 25–May 5), respectively. Because seasonal temperature trends and fluctuations are unpredictable, striped bass females cannot select a spawning time that guarantees their offspring will be exposed to optimum temperatures. Consequently, selection may have occured for spawning over a broad range of temperatures and dates, a behavior insuring that some larval cohorts will encounter favorable temperatures.     

Age and growth,movements and distribution of the cownose ray,Rhinoptera bonasus,in Chesapeake Bay

Ages were estimated for 115 of 899 cownose rays,Rhinoptera bonasus, collected primarily from commercial fishing gear, in lower Chesapeake Bay and vicinity from May through October, 1976–78. Age determinations were made using sectioned vertebral centra and estimates of von Bertalanffy parameters were for males DW_∞=119.2, K=0.126, and t₀=?3.699, and for females DW_∞=125.0, K=0.119, and t₀=?3.764. Females attained a larger adult size and the oldest specimen aged was a female 13 years old and 107 cm disc width. Both sexes mature after reaching about 70% of their maximum size and ages at maturity were estimated at 5 to 6 years for males and 7 to 8 years for females. In spring migrating rays schooled by size; they arrived along the North Carolina coast by April and entered Chesapeake Bay by early May. Rays were abundant in the major Virginia tributaries of Chesapeake Bay throughout summer and occurred in salinities as low as 8‰ and at water temperatures between 15–29 °C. Size segregation continued during summer and adults schooled by sex. Most rays left Chesapeake Bay by early October.     

Ionic diffusion in naturally-occurring aqueous solutions: use of activity coefficients in transition-state models

The model of Lane and Kirkaldy (Can. J. Chem. 43, 1812–1828, 1965; 44, 477–485, 1966) for estimating diffusion coefficients in aqueous electrolyte solutions from limiting ionic conductances is rederived for a system of n salts with a common anion, by utilizing the equations of Miller (J. Chem. Phys. 71, 616–632, 1967b; 71, 3588–3592, 1967c). Salt and water activities are used, and it is of necessity assumed that the diffusion mechanism does not change with concentration.The revised model predicts the on-diagonal D^v_ik of a 3 M solution in NaCl-KCl-H₂O to within 5%, compared with errors of 20–30% for the original model. Errors remain constant or decrease as concentrations increase to 3 M, so that predictions of these D^v_ik at even higher concentrations appear promising. Relatively large errors persist in our estimates of the small, off-diagonal coefficients in this system.Measured diffusion coefficients in MgCl₂-NaCl-H₂O extend over only a limited concentration range and are of only moderate accuracy. Nevertheless, the revised model predicts D^v₁₁D^v₂₂, and D^v₂₁, the larger of the off-diagonal coefficients, with errors of only 5–20%.     

Apsidal motion and the third-body problem in the binary HS Her

Our analysis of a 22-year uniform series of photoelectric U BV measurements of HS Her, started in 1969–1983 by D.Ya. Martynov and completed by us in 1984–1991, enabled us to determine new times of minima and revise some times of minima published earlier. Combined with other published data, this information can be used to improve the system’s apsidal elements: U _obs = (89.7 ± 5.1) years and log-k ₂ ^obs = ?2.33(4), testifying to a somewhat stronger concentration of matter towards the center than is predicted by current models for main-sequence stars (log -k ₂ ^th = ?2.21). This provides additional evidence that the system’s secondary is at the pre-main-sequence stage of evolution, as we suggested earlier based on our analysis of the system’s photometric elements. We confirm the presence of a third body in the system in a long-period eccentric orbit, as was first suggested in 2002 by Wolf et al. However, in contrast to the results of that paper, we demonstrate that the currently available observational data are insufficient to reliably determine this orbit’s parameters. We estimate the mass of the third body to be M ₃ = (1.0?2.0)M _⊙ for M ₁ = 5M _⊙ and M ₂ = 1.6 M _⊙.     

Source dynamic parameters of four Greek earthquakes and a possible correlation with the lead-times of their precursor seismic electric signals

Since 1982, eighteen telemetric stations in Greece have continuously been recording variations in the telluric field. Transient changes of the telluric field, called seismic electric signals, SES, have been observed simultaneously at some stations from several hours to several days before an earthquake. The lead-time, Δt, of the SES, which is the time difference between the occurrence of the earthquake and the SES, varies between 6 h and 4 days.Four large earthquakes (M = 5.3–6.4) which occurred in 1983 in the Cephalonia region in Greece, showed clear SES with lead-times falling into two groups (I and II) of several hours and a few days respectively.For the four events, we studied P-wave spectra of the UME Swedish seismological station, at a teleseismic distance of 26°. Both short- and long-period instruments were employed. Brune's model (1970) was used to calculate source dimensions and relative values of other source dynamic parameters.Two groups of high and low stress-drop were found. Events with lead-times of group I show high stress-drop, while events with lead-times of group II show low stress-drop. The relative values of stress-drop differ by a factor of 4 between the two groups (high and low) while within each group they exhibit only a small scatter.The largest relative seismic moment, M₀, is found for the largest event. The three other events with comparable magnitudes have similar seismic moments. The same relation was found for the radiated energy, E_s.     

Carboniferous ridge subduction in the Xingmeng Orogenic Belt: Constraints from geochronological,geochemical, and Sr-Nd-Hf isotopic analysis of strongly peraluminous granites and gabbro-diorites in the Xilinhot micro-continent

The Xingmeng Orogenic Belt evolved through a long-lived orogeny involving multiple episodes of subduction and accretion. However, there is a debate on its tectonic evolution during the Late Paleozoic. Here, we report geochemical, geochronological, and isotopic data from strongly peraluminous granites and gabbro-diorites from the Sunidzuoqi–Xilinhot region. Zircon U–Pb ages suggest that the intrusive rocks were emplaced during the Early Carboniferous (333–322 Ma). The granites exhibit geochemical characteristics similar to S-type granites, with high SiO₂ (72.34–76.53 wt.%), Al₂O₃ (12.45–14.65 wt.%), and A/CNK (1.07–1.16), but depleted Sr, Nb, and Ta contents. They exhibit positive ε_Nd(t) and ε_Hf(t) values (?0.3 to 2.8 and 2.7–5.7, respectively) and young Nd and Hf model ages (T_DM2(Nd)=853–1110 Ma and T_DM2(Hf)=975–1184 Ma), suggesting that they may be the partial melting products of heterogeneous sources with variable proportions of pelite, psammite, and metabasaltic rocks. The meta-gabbro-diorites from the Maihantaolegai pluton have low SiO₂ (47.06–53.49 wt.%) and K₂O (0.04–0.99 wt.%) contents, and demonstrate slight light rare earth element (REE) depletion in the chondrite-normalized REE diagrams. They have high zircon ε_Hf(t) values (14.41–17.34) and young Hf model ages (T_DM2(Hf)= 230–418 Ma), indicating a more depleted mantle source. The variations of the Sm/Yb and La/Sm ratios can thus be used to assess the melting degree of the mantle source from 5% to 20%, suggesting a quite shallow mantle melting zone. We propose that the petrogenesis and distribution of the strongly peraluminous granites and gabbro-diorites, as well as the tectonic architecture of the region, can be explained by a ridge subduction model. Based on these results, and previous studies, we suggest a southward ridge subduction model for the Sunidzuoqi–Xilinhot region.