甘肃庄浪全新世黄土-古土壤序列元素分布特征及意义

通过对渭河上游XJN全新世剖面的Fe、Al、Si、K、Ca、Mg、Na、Ti和Sr元素含量的分析,发现这些元素的分布与气候密切相关。在剖面中表现为:迁移序列是Ca>Sr>Na>Mg,Fe、Al、Si、K和Ti则相对富集;Ca-Sr关系呈两段式分布,指示全新世早期的一次环境变化;Ki残积系数增大,Ca/Mg比值减小,指示化学风化作用增强。     

华北地块东南缘中生代侵入杂岩中所含榴辉岩类包体矿物微量元素地球化学特征及其意义

华北地块东南缘中生代侵入杂岩中所含榴辉岩类包体中矿物的分析结果表明, 组成榴辉岩类包体的各矿物之间元素的分配在榴辉岩相变质阶段已经达到了化学平衡;石榴石中Al、Fe、Mn, 单斜辉石中Na、Mg、Ca, 角闪石中Na、Mg、Fe等主量元素含量与其全岩之间均呈良好的正相关, 受全岩成分制约;石榴石明显富集HREE、贫LREE, 单斜辉石相对富集LREE、MREE、贫HREE, 两者轻、重稀土含量呈相互消长的互补关系, 石榴石和单斜辉石中分别富集Y、Sr, Ga和过渡族元素Sc、Ti、V、Cr、Co等含量较高, 其含量受全岩成分控制;金红石中稀土元素的含量很少, Fe、Al、Mg、Ca、Mn、Nb、Ta、Cr和Zr含量相对较高, Rb、Sr、Ba含量极低, 部分微量元素(如Nb、Cr、Fe、V、W等)含量与其原岩有继承和对应关系;部分原生或/和退变角闪石的REE配分模式分别与单斜辉石和石榴石相似, 过渡族金属元素等的含量与石榴石、单斜辉石和全岩具有一定的相关性, 角闪石容纳Na、K、Sr、Rb、Ba等元素的能力较强, 其成分除受全岩成分的制约外, 石榴石、单斜辉石对其形成也有影响。榴辉岩类包体与其寄主中生代侵入杂岩中部分高价态/高场强元素(HFSE)和重稀土元素(HREE)呈相互消长的关系。榴辉岩的形成与扬子地块和华北地块之间的俯冲-碰撞作用有关。     

Environmental quality evaluation of the Vacacaí River, Rio Grande do Sul, Brazil

The water quality of the Vacacaí River was assessed at different sites in the period between winter 2005 and autumn 2006. All samples were analyzed for 52 elements (Sc, Y, La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu, Th, Li, Be, Mg, Al, Ca, V, Cr, Mn, Fe, Ni, Co, Cu, Zn, Ga, As, Se, Rb, Sr, Ag, Cd, In, Cs, Ba, Tl, Pb, Bi, U, Na, K, Hg, B, Mo, Sn, Te, Ti), temperature, pH, ammonia, and alkalinity levels. Water from the Vacacaí River ranged from slightly acidic to alkaline. No difference was observed in the chemical composition at different sites of the Vacacaí River. Levels of Ba, Ca, Sr and Mg increase in the dry seasons and reach their highest concentrations in autumn; Be and U decrease in the dry season and reach their highest concentration in spring. Al, Fe, Cr, Ni, Th, U Mn, Ca and Mg are highly positively related, indicating a common origin. Se and Cu are probably from anthropogenic source, from the rice crops of the margins of the river. Waterborne Al and Fe levels were above the desirable level for drinking water at all sites during all seasons. These results demonstrate the need for constant monitoring of water parameters, which is crucial to ensure water quality for the population of this region.     

松嫩平原西部碱尘气溶胶的元素特征分析

碱尘暴期间松嫩平原西部碱尘气溶胶的主要元素质量浓度排序为Na、Al、Fe、Ca、Mg、K、Ti、Ba、Zn,与当地盐碱化土壤的元素组成吻合,而与沙尘、城市气溶胶的元素组成有差别。风力对碱尘气溶胶元素组成有明显的影响,当风速在8.0~17.1 m/s时,元素组成的质量浓度排序为Na、Ca、Al、Fe、Mg、K、Ba、Ti、Zn。Na元素质量浓度的激增是碱尘暴元素组分的一大特征,明显富集元素为Na和B;相对于当地背景大气气溶胶的富集情况,Zn、Cu、Ba、B的富集因子值在碱尘暴期间明显降低;在各种天气情况下,B、Cu均具有较高的富集因子。碱尘中Ti元素的富集因子值均小于1,而Ca、Fe、K、Mg、Mn、Sr、V的富集因子值为1~4。两个采样点的Ca、Na、Al、Fe、Mg、Ti、Zn的富集因子近似,表明该区碱尘的主要元素具有特定的一致性;而B、Ba、Cu、V的富集因子相差较大,可以作为区分不同碱尘源的标志性元素。     

内蒙古潮水盆地西部侏罗系煤的岩石学、矿物学及地球化学特征

潮水盆地位于内蒙古西南部和甘肃省东部地区,是我国中新生代含煤断陷盆地.采用粉晶X衍射、ICP-MS、ICP-AES 方法,从煤的岩石学、煤化学及煤地球化学的理论出发,对潮水盆地西部煤样进行了煤化学、显微组分、矿物学及地球化学分析.其研究结果表明潮水盆地西部煤以中等水分、低一中灰分和硫质量分数、高挥发分产率为特征,煤级为烟煤—亚烟煤;煤中有机显微组分以镜质组为主,惰性组次之,煤相类型以潮湿森林沼泽相为主,其次为较浅覆水森林沼泽相;煤中的常量矿物以石英和高岭石为主,部分样品中含有黄铁矿、方解石、菱铁矿和少量的微斜长石;煤中除Sr、B和Cs质量分数相对较高外,其他微量元素质量分数普遍较低.Cr、Ga、Pb、Li、Cu、Ge、V、Sc、Be、W、Th和As,以及Ti和Nb主要与硅铝酸盐矿物有好的亲和性;B和Sr可能主要以碳酸盐矿物的形式存在;S和Mo可能主要以硫化物矿物的形式存在;另外,Ti、Zr、Nb和Ta有好的相关性,可能与重矿物有关.     

残坡积土壤层中铁锰氧化物的吸附特性及其地球化学找矿意义

作者用不同方法研究了粤北某铅锌矿区近矿灰岩风化土壤中铁锰氧化物对微量元素的富集作用。发现铁锰氧化物对Sb、Pb、Cd、Ni等元素具有强烈的吸附作用;对Zn、Cu等21种元素有程度不等的吸附;对Ti、Sr等12种元素不吸附。据此,作者认为在土壤地球化学找矿中,应着重在铁锰结核层和铁锰粘土层取样,或用编提取方法分析铁锰氧化物相的元素含量,强化异常,提高找矿效果。     

X射线荧光光谱法同时测定土壤样品中的36种组分的探讨

采用粉末压片法制样,使用新型X射线荧光光谱仪,对土壤样品中的C、N、S、Cl、Na、Mg、Al、Si、K、Ca、Fe、As、Ba、Br、Ce、Co、Cr、Cu、Ga、Hf、La、Mn、Nb、Ni、P、Pb、Rb、Sc、Sr、Th、Ti、U、V、Y、Zn、Zr等36种组分的直接同时测试进行了探讨测试。研究了测试中各种分析条件及存在问题。结果表明,方法的检出限、精密度和准确度大多数满足多目标地球化学调查样品分析质量的要求,标准物质的测定值与其标准值相吻合,适合土壤样品中多组分的同时直接测定。     

广东三水盆地古近系心组生油层的元素地球化学特征

沉积物的元素地球化学特征是对沉积盆地水体环境以及古气候条件变化的响应。本文根据元素（Al、Fe、Mg、Ca、K、Na、P、V、Ni、Co、Cr、Cu、Zn、Sr、Ba、Cd、Li、Mn、Pb、Ti）的含量及其比值（Al/Ti、Fe/Mn、Sr/Ba、Mg/Ca、Sr/Ca、Na/Ca、V/Cr、Ni/Co、Ni/V）的变化，对三水盆地古近系心组红岗段生油层的沉积条件进行了系统分析。心组红岗段下部（亚段A）表现为较稳定的地球化学特征。各元素丰度及其比值指示这一时期陆源输入持续较高、且物源组成变化不大。由于海水入侵的影响，湖盆水体盐度相对较高，底部水体以弱氧化条件为主，O₂-H₂S界面位于水/沉积物界面附近。红岗段中上部（亚段B、C）的元素地球化学特征变化较为频繁且幅度很大，反映古气候和湖盆沉积条件的迅速变迁。在潮湿气候条件下，沉积物的地球化学特征表现为以Al、Ti为代表的外源元素含量及其比值较高，而Mg、Ca等盆内化学沉积元素含量较低。古氧气指标指示底部水体为还原环境，有利于有机质保存。因而，相应于较高的有机碳含量。在间歇性干旱时期，陆源输入减少，外源元素含量及其比值显著降低。随着蒸发作用的加强，水体盐度加大，内源元素丰度以及Mg/Ca、Sr/Ba、Sr/Ca和Na/Ca比值大幅度上升。底部水体为氧化环境，O₂-H₂S界面多位于水/沉积物界面或沉积物中。上述两种气候条件在红岗段中上部沉积时期交替出现。红岗段沉积后期由于淡水的长期输入，湖水出现逐渐淡化趋势。     

用X射线荧光光谱法测定Cl、S等31个元素

采用硼酸镶边垫底的粉末样品压片制样,用ARL ADVANT′XP＋型X射线荧光光谱仪对土壤和水系沉积物样品中Na、Mg、Al、Si、P、S、Cl等31个组分进行测定。重点研究了Cl和S等元素的测定条件、痕量元素的背景选择和谱线重叠校正问题。使用经验系数法和康普敦散射作内标校正基体效应。经标准物质校验,结果与标准值吻合。方法的检出限、精密度和准确度能满足多目标地球化学调查样品的分析要求。     

Regional Metasomatism and the Geochemistry of the Dalradian Metasediments of Connemara, Western Ireland

Based on 225 analyses of quartzites, siliceous granoblastites,calc silicate rocks, calcite and dolomite marbles, including120 analyses of pelites and semipelites, sedimentary trendsof chemical variation are identified in staurolite and sillimanitegrade rocks. The correlation of original clay mineral contentwith Ti, Fe, K, Rb, Y, Nb, Ca, Ni, Ga, Zn and probably Ba andMn is shown. A similar clay mineral (whose composition is calculated)was added to all the sediments except the quartz-rich sandstones,now quartzites. This pattern appears to be general for mostsediments, based on crustal averages. The form of the originaladdition of Sr in the sediments might be identified as eithercarbonate or feldspar by a Ca vs. Sr plot. The southern pelites in a 2–4 km peripheral zone to theConnemara orthogneisses and migmatites have been metasomatized.The crude order of elemental enrichment from the elements increasedthe most to those increased the least relative to the same stratigraphicalhorizons in the north is: Mn, Ba, Th, Cu, Ca, Sr, Y, Pb, Zn,Pr, Ge, Nd, La, Mg, S, Ce, Rb, Sm, Ti, Na, K and Ga while Si,Al, Cr, Ni, Co, Fe and P are unchanged or removed. The sourceof the material added is postulated to be the water-rich residualfraction of the migmatitic quartz diorite gneiss, the transportbeing by movement of a water-rich fluid out of the migmatites,the fixation being mainly in biotite and new, more calcic, plagioclaseporphyroblasts, there being a positive correlation between elementenrichment and ionic radius.     

太平洋北部铁锰结核富集区沉积物的元素地球化学特征

本文对太平洋北部铁锰结核富集区沉积物的元素地球化学作了较为详细的研究。因子分析提供的信息表明,元素的分布主要受三个因子控制:（1）粘土及Fe、Mn氧化物水化物胶体的吸附作用;（2）生物化学作用过程有关的自生沉积作用;（3）海底页岩风化及附近海区的火山喷发作用。元素的来源:（1）Fe、Mn、Cu、Co、Ni、Zn、Cr、Cr、Mg、Al、Ti、K共生,主要来自粘土吸附;（2）C_有机、N、Sr、Na及Si、Ca、Sr主要来自生物化学过程沉积;（3）Pb主要来源于岩石碎屑（火山喷发碎屑）。     

Die Verteilung und Korrelation einiger Elemente in einem Erzkalkprofil der Bleiberger Fazies (Bleiberg/Kärnten-Rudolfschacht)

Zusammenfassung Es wurde in einem Profil des oberladinischen Erzkalkes der typischen Bleiberger Fazies (Bleiburg/Rudolfschacht, Kärnten) röntgenfluoreszenzspektrometrisch die Elementverteilung von Mg, Ca, Sr, Ba, K, Si, Ti, Fe, Mn, V und Zn untersucht. Die Strontiumverteilung wurde auch in einem weiteren Profil (Kreuth-Antonischacht) gemessen.Im Vergleich zu der Durchschnittszusammensetzung von Carbonatgesteinen sind die vorliegenden Gesteine arm an Fe, Mn und Sr. Mit Annäherung an den ersten Raibler Schiefer (Karn) nimmt in den Edlen Flächen der Gehalt an Sr und Mg zu.Dies wird als steigende Tendenz zur Ausscheidung salinarer Absätze gedeutet. Das Vorkommen von blauem Anhydrit und Strontiummineralisationen (Coelestin, Strontianit) wird letztlich auf salinare Absätze zurückgeführt. Die Bleiberger Fazies, die in der Erzmineralisation Baryt und Fluorit führt, hat lagunaren Charakter.

---

The distribution and correlation of some elements in a Erzkalk-profile of the bleiberg facies (Bleiberg/Carinthia-Rudolfschacht)

Summary A profile of the ore bearing Upper Ladinian limestone series of the typical facies of Bleiberg (Carinthia) was investigated with aid of X-ray-spectrometric analysis for the element distribution of Mg, Ca, Sr, Ba, K, Sr, Ti, Fe, Mn, V and Zn. Another profile (Kreuth/Antonischacht) was analyzed for Sr only.Compared with the average of carbonate rocks the investigated samples are poor in Fe, Mn and Sr. Approaching the first Raiblian Schist (Carnian) the contents of Sr and Mg of the Edle Flächen (ore bearing banks) increase. This can be explained by an increasing tendency towards the deposition of saline gypsum-bearing banks. The occurrences of blue anhydrite and strontium mineralization (celestite, strontianite) is caused originally by saline sedimentation. The limestone series of Bleiberg, known by stratiform barite and fluorite bearing ore mineralisations, contains sediments of lagunal character.

---

---

Mit 1 Abbildung     

X射线荧光光谱法同时测定土壤样品中碳氮等多元素

报道了采用粉末压片制样-X射线荧光光谱法测定土壤样品中C、N、S、Cl、Br、Hf、Mo、Sn、Se、Na、Mg、Al、Si、P、K、Ca、Ti、V、Cr、Mn、Fe、Co、Ni、Cu、Zn、Ga、As、Rb、Sr、Y、Zr、Nb、Ba、La、Ce、U、Th、Pb等38种元素的分析方法。着重研究了C和N的分析条件、存在问题和注意事项。所拟方法的检出限，精密度和准确度大多数满足覆盖区多目标地球化学调查样品分析质量的要求。     

Rare earth and other trace element mobility during mylonitization: a comparison of the Brevard and Hope Valley shear zones in the Appalachian Mountains, USA

In progressing from a granitoid mylonite to an ultramylonite in the Brevard shear zone in North Carolina, Ca and LOI (H₂O) increase, Si, Mg, K, Na, Ba, Sr, Ta, Cs and Th decrease, while changes in Al, Ti, Fe, P, Sc, Rb, REE, Hf, Cr and U are relatively small. A volume loss of 44% is calculated for the Brevard ultramylonite relative to an Al–Ti–Fe isocon. The increase in Ca and LOI is related to a large increase in retrograde epidote and muscovite in the ultramylonite, the decreases in K, Na, Si, Ba and Sr reflect the destruction of feldspars, and the decrease in Mg is related to the destruction of biotite during mylonitization. In an amphibolite facies fault zone separating grey and pink granitic gneisses in the Hope Valley shear zone in New England, compositional similarity suggests the ultramylonite is composed chiefly of the pink gneisses. Utilizing an Al–Ti–Fe isocon for the pink gneisses, Sc, Cr, Hf, Ta, U, Th and M-HREE are relatively unchanged, Si, LOI, K, Mg, Rb, Cs and Ba are enriched, and Ca, Na, P, Sr and LREE are lost during deformation. In contrast to the Brevard mylonite, the Hope Valley mylonite appears to have increased in volume by about 70%, chiefly in response to an introduction of quartz. Chondrite-normalized REE patterns of granitoids from both shear zones are LREE-enriched and have prominent negative Eu anomalies. Although REE increase in abundance in the Brevard ultramylonites (reflecting the volume loss), the shape of the REE pattern remains unchanged. In contrast, REE and especially LREE decrease in abundance with increasing deformation of the Hope Valley gneisses. Mass balance calculations indicate that ≥95% of the REE in the Brevard rocks reside in titanite. In contrast, in the Hope Valley rocks only 15–40% of the REE can be accounted for collectively by titanite, apatite and zircon. Possible sites for the remaining REE are allanite, fluorite or grain boundaries. Loss of LREE from the pink gneisses during deformation may have resulted from decreases in allanite and perhaps apatite or by leaching ofy REE from grain boundaries by fluids moving through the shear zone. Among the element ratios most resistant to change during mylonitization in the Brevard shear zone are La/Yb, Eu/Eu*, Sm/Nd, La/Sc, Th/Sc, Th/Yb, Cr/Th, Th/U and Hf/Ta, whereas the most stable ratios in the Hope Valley shear zone are K/Rb, Rb/Cs, Th/U, Eu/Eu*, Th/Sc, Th/Yb, Sm/Nd, Th/Ta, Hf/Ta and Hf/Yb. However, until more trace element data are available from other shear zones, these ratios should not be used alone to identify protoliths of deformed rocks.     

Petrology and geothermometry of retrograded Hercynian charnockites and host gneisses, Agly Massif, French Pyrenees

Abstract A Hercynian charnockite occurs within high-grade gneisses in the Agly Massif, French Pyrenees. Its thermal history has been evaluated using the Fe-Mg distribution coefticient ( K _D) between garnet and biotite. These minerals have different origins but similar compositions in the charnockites and host gneisses. In the charnockite, the Bi–Ga pairs are the retrograde products of Opx alteration. This Opx reaction with feldspar can be written. Opx + PI + Fluid 1(H₂O + Al + K + Fe + Ti) = Bi + Ga + Q + Fluid 2(H₂O + Na). The garnets are relatively Ca poor (4–2.5% grossular); they are automorphic and zoned in the gneisses and poikiloblastic in the charnockites. Both types show a retrograde rim (of few hundred microns'width) across which Fe and Mn increase as Mg decreases. The biotites show a good correlation between the octahedral cations (Ti⁴⁺+ Fe²⁺) and (Mg²⁺+ Al³⁺_VI); Ti and Fe both increase, whereas Mg and Al_VI decrease. There is an inverse linear correlation between Fe²⁺ and Mg²⁺ and the Fe/Mg ratio increases as Ti increases. The relation between Ti and K ^Ga-Bi_DFe-Mg is less clear: it seems that K _D slightly decreases as Ti increases. The equilibration temperatures of Ga–Bi pairs are discussed: the charnockite Ga-Bi pairs have equilibrated between 550°C and 600°C; whereas those of the gneisses have equilibrated between 550°C and 650°C. Two main thermal steps appear: one in the gneisses between 600-650°C and a second one in both the gneisses and the charnockites between 550°C and 600°C.     

新疆库-拜煤田侏罗系塔里奇克组煤的地球化学特征

以新疆库拜煤田塔里奇克组煤层为研究对象,对其煤化学及地球化学特征进行分析。认为研究区煤层属低水分、低灰分、特低硫分、高挥发分的长焰煤-气肥煤;煤中的常量元素Al、Ca、Fe、Mg和K平均含量低于中国煤常量元素的平均含量,并有较大的变化范围,仅Na平均含量高于中国煤的平均含量;煤中的微量元素Cu和Co含量高于中国煤的平均含量,Ni和Zn含量接近中国煤的平均含量．其它微量元素含量均明显低于中国煤的平均含量。阐明了Al、Li、Cr、Ti、Zr、Ga、Nb以及轻稀土元素（La、Ce和Nd）具有较强的亲无机性,在煤中主要以无机态存在;Li、Sc、Ti、V、Cr、Ga、Rb、Zr、Nb及重稀土元素中的La、Ce、Pr、Nd、Sm、Gd元素主要与硅铝酸盐矿物及微量的重矿物组合有较好的亲和性：As、Sr元素主要以碳酸盐矿物的形式存在。     

浙西北萧山—诸暨地区晚中生代侵入岩地球化学特征及构造意义

浙西北萧山—诸暨地区晚侏罗世末期花岗(石英)闪长岩与早白垩世末期(辉石)闪长岩具有以下地球化学特征:低硅、贫碱、富钙镁铁,弱负铕异常,稀土配分曲线右倾,富集K,Rb,Ba,Th,U等,亏损Nb,Ta等,Sr,Ti亏损不明显。晚侏罗世末期花岗岩与早白垩世末期花岗(斑)岩均具有高硅、富碱、贫钙镁,强负铕异常的特征;晚侏罗世侵入岩具"V"型稀土配分曲线,强富集K,Rb,Th,U等,相对富集Nb,Ta,强亏损Ba,Sr,Ti等特征;早白垩世侵入岩具右倾稀土配分曲线,富集K,Rb,Th,U等,亏损Nb,Ta,Sr,Ti,Ba不亏损等特征。岩石构造地球化学图解分析表明,晚侏罗世末期I-A型花岗岩类成岩构造环境具有从俯冲挤压碰撞作用向后碰撞或后造山作用演化的特征;早白垩世末期(高分异)I型花岗岩类岩石主要与火山-次火山喷发-侵入作用关系密切,成岩构造环境主要与区域伸展作用有关。     

Geochemistry of Late Proterozoic volcanic rocks from Tassendjanet area (N.W. Hoggar,Algeria)

The Late Proterozoic calc-alkaline andesitic rocks of the Tassendjanet volcanic complex, north-western Hoggar, Algeria resemble the continental margin rocks and also are closely comparable to the Archaean andesites. Most Tassendjanet rocks were affected to various extents by low grade hydrous metamorphism which led to an increase of Na, P, Fe, Ti, and V and a decrease of Mg, Ca, Sr, Cr, and Ni. Although K, Rb, Ba, and Li are enriched in the majority of altered rocks, these elements are strongly depleted in the albitized Na-rich volcanics. REE are enriched in albitized andesites but their fractionation patterns remain unchanged. The trace element data are consistent with the derivation of the Tassendjanet andesites by partial melting of an upper mantle source enriched in LILE and presumably overlying the subduction zone.     

Geology and Geochemistry of Highly Metamorphosed Footwall Alteration Zones in the Hongtoushan Volcanogenic Massive Sulfide Deposit,Liaoning Province,China

The Hongtoushan Archean Cu–Zn volcanogenic massive sulfide (VMS) deposit, which was metamorphosed (3.0–2.8 Ga) to upper amphibolite facies at temperatures between 600 and 650°C, occurs in the Hunbei granite–greenstone terrane, Liaoning Province of NE China. Stratiform cordierite–anthophyllite gneiss (CAG) that occurs hundreds of meters below the ore horizon in the Hongtoushan district corresponds to the metamorphosed semi‐conformable alteration zone of the VMS hydrothermal system, whereas the CAG that contains abundant deformed sulfide‐bearing quartz veins immediately below the main ore layer represents the metamorphosed discordant alteration zone. Whole‐rock geochemistry indicates that stratiform CAG was derived ultimately from five lithologies (basalt, basaltic andesite, andesite, dacite, and rhyolite), while discordant CAG derived from a single lithology (rhyolite). Amphibolite and biotite‐rich gneiss are identified as a metamorphosed least‐altered precursor for these CAGs. Mass change calculation indicates that, compared to the least‐altered rocks, stratiform CAG is enriched in Fe and Mg, and depleted in Na, K, Ca, Cu, Pb and Zn, while discordant CAG is enriched in Fe, Mg, Si, Na, Pb, Cu and Zn, and depleted in K. HREE and HFSE (Zr, Ti, Nb and Ta) behaved inertly during submarine alteration, whereas Rb, Sr, Ba and LREE (especially Eu) were leached off. Both stratiform and discordant CAGs are depleted in ¹⁸O, with values up to 7‰ lower than their corresponding least‐altered precursors. Addition of Fe, Mg, and depletion of Ca, K, Sr, and ¹⁸O, indicate that hydrothermal alteration for both types of CAGs was characterized by chloritization prior to metamorphism. Stratiform CAG could be used to evaluate the mineralization potential of VMS in metamorphic terranes, while discordant CAG containing sulfide‐bearing quartz veins could be a good indication for overlying stratiform massive sulfide ores as well as an exploration target itself.     

滇东南都龙锡锌铟多金属矿床磁铁矿矿物化学组成特征及其对成矿作用的约束

都龙锡锌铟多金属矿床位于著名的滇东南钨锡多金属成矿区之老君山矿集区,成矿与白垩纪大规模花岗岩活动关系密切,沿隐伏花岗岩接触带周边发育石榴子石、透辉-透闪石等矽卡岩蚀变和条带状(似层状)、脉状(囊状)的锡石、闪锌矿及磁铁矿、辉钼矿、黄铁黄铜矿等矿化,形成超大规模的岩浆热液-矽卡岩成矿系统。野外观测及研究发现,早期(矽卡岩期)高温阶段形成的磁铁矿可分为I阶段交代型磁铁矿(I-Mag)和II阶段充填型磁铁矿(II-Mag)两类:前者多呈囊状、条带状,与矽卡岩矿物共生;后者为脉状,与金属硫化矿物共生。利用ICP-AES、ICP-MS对两类磁铁矿进行主、微量元素测试,从I-Mag到II-Mag,Si、Ca、Mn及ΣREE、Pb、Zn、Ti含量增加,Mg及Sn、W、In、V、Cr、Ga含量减少,REE配分型式也由平缓向右倾的逐渐变化。TiO 2-Al 2 O 3-(MgO+MnO)、(Ti+V)-(Ca+Al+Mn)、Ni/Cr-Ti、(Ti+V)-Ni/(Cr+Mn)成因判别图解表明,磁铁矿属岩浆热液-矽卡岩成因类型;Ti、V与Zr、Hf、Nb、Ta,以及Y/Ho(24~3414)、Ni/Co(<2→>2)、Ti/V(<25→>25)、Hf/Zr(003~006→004~005)存在着线性关系和规律变化特征,指示两类型磁铁矿具有相同的物质来源,为同一成矿过程不同阶段的产物。而代表成矿流体REE组成的II-Mag的REE组成继承了老君山花岗岩REE配分趋势和Eu负异常特征,表明磁铁矿与白垩纪老君山花岗岩具有一致的物质来源。Cr-V、(Ti+V)-(Al+Mn)、Ga-Mg及Ga-Sn图解显示相同的成因类型和一致的线性关系,指示磁铁矿主体形成于较高氧逸度和温度(约300℃)的成矿环境下,并且从I-Mag到II-Mag,存在着氧逸度逐渐升高、温度逐渐降低的演化趋势。