Seepage loss from a canal in Sri Lanka measured using tritium tracer

Using single borehole dilution technique, and tritiated water as tracer, lateral flow rate of water near the phreatic line has been measured at 24 points along the banks of an unlined canal. Permeability values range from 0.5×10^?6 m sec^?1 to 34×10^?6 m sec^?1; the median value being 5×10^?6m sec^?1. The seepage loss is estimated to be 5×10^?5 m³ sec^?1 m^?1. For the entire canal the value is 0.74 m³ sec^?1 which is 12% of the total flow. Limitations and merits of the technique are discussed.     

Biogeochemical cycling in an organic-rich coastal marine basin—I. Methane sediment-water exchange processes

Methane produced in anoxic organic-rich sediments of Cape Lookout Bight, North Carolina, enters the water column via two seasonally dependent mechanisms: diffusion and bubble ebullition. Diffusive transport measured in situ with benthic chambers averages 49 and 163 μmol · m ^?2 · hr ^?1 during November–May and June–October respectively. High summer sediment methane production causes saturation concentrations and formation of bubbles near the sediment-water interface. Subsequent bubble ebullition is triggered by low-tide hydrostatic pressure release. June–October sediment-water gas fluxes at the surface average 411 ml (377 ml STP: 16.8 mmol) · m^?2 per low tide. Bubbling maintains open bubble tubes which apparently enhance diffusive transport. When tubes are present, apparent sediment diffusivities are 1.2–3.1-fold higher than theoretical molecular values reaching a peak value of 5.2 × 10^?5 cm² · sec^?1. Dissolution of 15% of the rising bubble flux containing 86% methane supplies 170μmol · m^?2 · hr^?1 of methane to the bight water column during summer months; the remainder is lost to the troposphere. Bottom water methane concentration increases observed during bubbling can be predicted using a 5–15 μm stagnant boundary layer dissolution model. Advective transport to surrounding waters is the major dissolved methane sink: aerobic oxidation and diffusive atmospheric evasion losses are minor within the bight.     

The effect of groundwater seepage on nutrient delivery and seagrass distribution in the northeastern Gulf of Mexico

A hypothesis was tested to determine if a relationship exists between rates of submarine groundwater discharge and the distribution of seagrass beds in the coastal, nearshore northeastern Gulf of Mexico. As determined by nonparametric statistics, four of seven seagrass beds in the northeastern Gulf of Mexico had significantly greater submarine groundwater discharge compared with adjacent sandy areas, but the remainder exhibited the opposite relationship. We were thus unable to verify if a relationship exists between submarine groundwater discharge and the distribution of seagrass beds in the nearshore sites selected. A second objective of this study was to determine the amount of nitrogen and phosphorus delivered to nearshore areas by submarine groundwater discharge. We considered new nutrient inputs to be delivered to surface waters by the upward flux of fresh water. This upward flux of water encounters saline porewaters in the surficial sediments and these porewaters contain recycled nutrients; actual nutrient flux from the sediment to overlying waters includes both new and recycled nutrients. New inputs of nitrogen to overlying surface waters for one 10-km section of coastline, calculated by multiplying groundwater nutrient concentrations from freshwater wells by measured seepage rates, were on the order of 1,100±190 mol N d⁻¹. New and recycled nitrogen fluxes, calculated by multiplying surficial porewater concentrations by measured seepage rates, yielded fluxes of 3,600 ±1,000 mol N d⁻¹. Soluble reactive phosphate values were 150±40 mol P d⁻¹ using freshwater well concentrations and 130±3.0 mol P d⁻¹ using porewater concentrations. These values are comparable to the average nutrient delivery of a small, local river.     

Estimation of Groundwater and Nutrient Fluxes to the Neuse River Estuary, North Carolina

A study was conducted between April 2004 and September 2005 to estimate groundwater and nutrient discharge to the Neuse River estuary in North Carolina. The largest groundwater fluxes were observed to occur generally within 20 m of the shoreline. Groundwater flux estimates based on seepage meter measurements ranged from 2.86?×?10⁸ to 4.33?×?10⁸ m³ annually and are comparable to estimates made using radon, a simple water-budget method, and estimates derived by using Darcy’s Law and previously published general aquifer characteristics of the area. The lower groundwater flux estimate (equal to about 9 m³ s^?1), which assumed the narrowest groundwater discharge zone (20 m) of three zone widths selected for an area west of New Bern, North Carolina, most closely agrees with groundwater flux estimates made using radon (3–9 m³ s^?1) and Darcy’s Law (about 9 m³ s^?1). A groundwater flux of 9 m³ s^?1 is about 40% of the surface-water flow to the Neuse River estuary between Streets Ferry and the mouth of the estuary and about 7% of the surface-water inflow from areas upstream. Estimates of annual nitrogen (333 tonnes) and phosphorus (66 tonnes) fluxes from groundwater to the estuary, based on this analysis, are less than 6% of the nitrogen and phosphorus inputs derived from all sources (excluding oceanic inputs), and approximately 8% of the nitrogen and 17% of the phosphorus annual inputs from surface-water inflow to the Neuse River estuary assuming a mean annual precipitation of 1.27 m. We provide quantitative evidence, derived from three methods, that the contribution of water and nutrients from groundwater discharge to the Neuse River estuary is relatively minor, particularly compared with upstream sources of water and nutrients and with bottom sediment sources of nutrients. Locally high groundwater discharges do occur, however, and could help explain the occurrence of localized phytoplankton blooms, submerged aquatic vegetation, or fish kills.     

Assessing Nitrogen Dynamics Throughout the Estuarine Landscape

Assessing nitrogen dynamics in the estuarine landscape is challenging given the unique effects of individual habitats on nitrogen dynamics. We measured net N₂ fluxes, sediment oxygen demand, and fluxes of ammonium and nitrate seasonally from five major estuarine habitats: salt marshes, seagrass beds (SAV), oyster reefs, and intertidal and subtidal flats. Net N₂ fluxes ranged from 332?±?116 μmol?N-N₂?m^?2?h^?1 from oyster reef sediments in the summer to ?67?±?4 μmol?N-N₂?m^?2?h^?1 from SAV in the winter. Oyster reef sediments had the highest rate of N₂ production of all habitats. Dissimilatory nitrate reduction to ammonium (DNRA) was measured during the summer and winter. DNRA was low during the winter and ranged from 4.5?±?3.0 in subtidal flats to 104?±?34 μmol?¹⁵NH ₄ ⁺ ?m^?2?h^?1 in oyster reefs during the summer. Annual denitrification, accounting for seasonal differences in inundation and light, ranged from 161.1?±?19.2 mmol?N-N₂?m^?2?year^?1 for marsh sediments to 509.9?±?122.7 mmol?N-N₂?m^?2?year^?1 for SAV sediments. Given the current habitat distribution in our study system, an estimated 28.3?×?10⁶?mol of N are removed per year or 76 % of estimated watershed nitrogen load. These results indicate that changes in the area and distribution of habitats in the estuarine landscape will impact ecosystem function and services.     

Groundwater balance in the Khor Arbaat basin, Red Sea State, eastern Sudan

The Khor Arbaat basin is the main source of potable water supply for the more than 750,000 inhabitants of Port Sudan, eastern Sudan. The variation in hydraulic conductivity and storage capacity is due to the heterogeneity of the sediments, which range from clay and silt to gravely sand and boulders. The water table rises during the summer and winter rainy seasons; it reaches its lowest level in the dry season. The storage capacity of the Khor Arbaat aquifer is estimated to be 21.75?×?10⁶ m³. The annual recharge through the infiltration of flood water is about 1.93?×?10⁶ m³. The groundwater recharge, calculated as underground inflow at the ‘upper gate’, is 1.33?×?10⁵ m³/year. The total annual groundwater recharge is 2.06?×?10⁶ m³. The annual discharge through underground outflow at the ‘lower gate’ (through which groundwater flows onto the coastal plain) is 3.29?×?10⁵ m³/year. Groundwater discharge due to pumping from Khor Arbaat basin is 4.38?×?10⁶ m³/year on average. The total annual groundwater discharge is about 4.7?×?10⁶ m³. A deficit of 2.6?×?10⁶ m³/year is calculated. Although the total annual discharge is twice the estimated annual recharge, additional groundwater flow from the fractured basement probably balances the annual groundwater budget since no decline is observed in the piezometric levels.     

Groundwater budget for the upper and middle parts of the River Gash Basin, eastern Sudan

The River Gash Basin is filled by the Quaternary alluvial deposits, unconformably overlying the basement rocks. The alluvial deposits are composed mainly of unconsolidated layers of gravel, sand, silt, and clays. The aquifer is unconfined and is laterally bounded by the impermeable Neogene clays. The methods used in this study include the carry out of pumping tests and the analysis of well inventory data in addition to the river discharge rates and other meteorological data. The average annual discharge of the River Gash is estimated to be 1,056?×?10⁶ m³ at El Gera gage station (upstream) and 587?×?10⁶ m³ at Salam-Alikum gage station (downstream). The annual loss mounts up to 40% of the total discharge. The water loss is attributed to infiltration and evapotranspiration. The present study proofs that the hydraulic conductivity ranges from 36 to 105 m/day, whereas the transmissivity ranges from 328 to 1,677 m²/day. The monitoring of groundwater level measurements indicates that the water table rises during the rainy season by 9 m in the upstream and 6 m in the midstream areas. The storage capacity of the upper and middle parts of the River Gash Basin is calculated as 502?×?10⁶ m³. The groundwater input reach 386.11?×?10⁶ m³/year, while the groundwater output is calculated as 365.98?×?10⁶ m³/year. The estimated difference between the input and output water quantities in the upper and middle parts of the River Gash Basin demonstrates a positive groundwater budget by about 20?×?10⁶ m³/year     

Fair weather and storm sand transport on the Long Island, New York, inner shelf

Both spring-summer and fall-winter sand transport have been observed on the Long Island, New York, inner shelf at water depths of 20-22 m using a radio-isotope sand tracer system. The extent of dispersal of the tagged, fine sand was measured at 3 week intervals in two 70 day experiments. In the late spring and early summer, movement was primarily diffusive in nature, extending 100 m around the line of tracer injection, while late fall-winter patterns had strong advective features, including an ellipsoidal outline extending approximately 1500 m westward of the injection points after the passage of several storms with strong northeasterly winds. Near-bottom current observations made with Savonius rotor sensors identify the event responsible for the bulk of the transport over the 135 day observation period as a storm flow of 2 days duration. Tracer and current observations together suggest that westward winter storm flow along the Long Island shelf is the major mechanism of sand transport at these depths on a yearly time scale. A least-squares fit of several of the observed winter patterns with a plume model yields average sediment mass flux lower bounds of 3.2 × 10^?3 gm/cm/sec and 1.7 × 10^?1 gm/cm/sec for ‘typical’ and extreme winter storm activity.     

Evaluation of the bearing capacity of near-surface soils using integrated methods: A case study of Otukpa,Ogbadibo Lga,Benue state,North-Central Nigeria

The load bearing capacity of soils in Otukpa area of Benue state, Nigeria was evaluated by characterizing the geotechnical, geophysical and structural properties of the soil. The evaluation was necessary because aside the area holding good prospect for future increase in human population, sparsely distributed low-weight buildings in the area have cracks and other signs of failure. Remote sensing/GIS, geophysical and geotechnical approaches were integrated to achieve the objective. 2-D tomography and processed remotely sensed data confirmed the presence of areas of strength especially to the north. Stratigraphy of the northern portion consist of four layers; loose top soil (0-0.26m), compact clayey sand (0.26m-3.33m), dry clayey sand (3.33m-74.21m) and saturated clayey sands (74.21m-201.58m) While the stratigraphy in the south is slightly different; compact topsoil (0-1.2m), loose sand (1.2m-10.81m), compact sand (10.82m-19.71m) and compact clay sand (19.71m-56.03m). The plastic limit range from 11-17% with average specific gravity of 2.64g/cm³. Permeability ranges from 7.8×10^-6m/sec to 3.36×10^-4m/sec while volume compressibility under 250kN ranges from 7.27×10^-5m²/kN to 1.3×10^-4m²/kN and the rate of consolidation under 250kN is within 12.43 m²/year to 1.33m²/year. MDD peaks at 1.85g/cm³ at an OMC of 12.11% and is lowest at 1.67g/cm³ at an OMC of 11.99%. UCS ranges from 31-45kN/m² while shear strength is between 258.81kN/m² to 338 kN/m². Due to the variability of engineering properties of soils, the southern part of the area is preferred for locating the buildings. Generally, careful foundation design in the area is necessary.     

Numerical simulations to assess thermal potential at Tauranga low-temperature geothermal system,New Zealand

Tauranga low-temperature geothermal system (New Zealand) has been used for the last 40 years for direct uses including space heating, bathing and greenhouses. Warm-water springs in the area are between 22 and 39 °C, with well temperatures up to 67 °C at 750 m depth. A heat and fluid flow model of the system is used to determine reservoir properties and assess thermal potential. The model covers 130 km by 70 km to 2 km depth, and was calibrated against temperatures measured in 17 wells. Modelling shows that to maintain the observed primarily conductive heat flow regime, bulk permeability is ≤2.5?×?10^?14 m² in sedimentary cover and ≤1?×?10^?16 m² in the underlying volcanic rocks. The preferred model (R ²?=?0.9) corresponds to thermal conductivities of 1.25 and 1.8 W/m² for sedimentary and volcanic rocks, respectively, and maximum heat flux of 350 mW/m². The total surface heat flow is 258 MW over 2,200 km². Heat flux is highest under Tauranga City, which may be related to inferred geology. Model simulations give insights into rock properties and the dynamics of heat flow in this low-temperature geothermal system, and provide a basis to estimate the effects of extracting hot fluid.     

Magnetic,geochemical and mineralogical properties of sediments from karstic and flysch rivers of Croatia and Slovenia

The aim of the present work was to investigate links between the low-field magnetic susceptibility (MS) and chemical and mineral composition of sediments from several Croatian and Slovenian rivers, as well as to determine possible anthropogenic influence on these sediments. MS measurements are a fast and simple method, which serves as a proxy for the estimation of pollution in different environmental systems. The investigated rivers are predominantly unpolluted rivers from Croatian and Slovenian karstic and flysch areas, which belong to the Adriatic or the Black Sea watersheds: the Dragonja, the Mirna, the Ra?a, the Ri?ana, the Reka, the Rak, the Cerkni?nica, the Unec and the Ljubljanica rivers. It was assumed that, due to their mostly unpolluted status, they could serve as a database for natural MS background values for this region. For comparison, several rivers and a lake from the Celje old metallurgic industrial area (Slovenia) were also investigated: the Savinja, the Hudinja, the Voglajna rivers and Slivni?ko Lake. They form a sub-basin of the Sava River drainage basin. Sediments of the clean karstic and flysch rivers showed extremely low MS values, with mass susceptibility values ranging from 0.58 × 10^?7 to 5.11 × 10^?7 m³/kg, and isothermal remanent magnetism (IRM) values ranging from 0.71 to 7.88 A/m. In the Celje industrial area, river sediments showed much higher MS values, with mass susceptibility values ranging from 1.31 × 10^?7 to 38.3 × 10^?7 m³/kg, and IRM values ranging from 0.91 to 100.42 A/m. The highest MS value was found in the Voglajna River at Teharje-?tore, a point which showed a significant number of anomalies of toxic metals in earlier investigations. Semiquantitative determination of relations between grain size and concentration of magnetite was performed using the Thompson-Oldfield method. X-ray diffraction (XRD) mineralogical analysis showed that sediments of the Celje area have mostly quartz as major mineral, with relatively small amount of carbonate minerals, while in sediments of karstic rivers carbonate minerals prevail. Statistically significant correlations were obtained between MS and Cr, Mn, Fe, Co, Ni, Cu, Zn, Cd and Ba in the Slovenian karstic region and between MS and Cr, Fe, Co, Ni and Zn in flysch drainage basins. On the contrary, no correlation of MS and Hg content was obtained.     

Study of the water saving potential of an irrigation area based on a remote sensing evapotranspiration model

To estimate the water saving potential of an irrigation area and create a scientific water saving plan, the irrigation water use efficiency and water productivity of the Hulanhe irrigation area for 2007–2014 were calculated, and the water saving potentials of different water saving plans were determined from the perspectives of engineering and crop water saving. The results showed that the evapotranspiration calculated from the surface energy balance algorithm for land model (SEBAL) agreed well with the measured results. The irrigation water use efficiency in the Hulanhe irrigation area was positively correlated with precipitation of irrigated land and was negatively correlated with the net irrigation water volume. The engineering water saving potential ranges for periods of 5, 8, 11, and 15 years were (1.702?×?10⁸, 5.103?×?10⁸) m³, (1.783?×?10⁸, 5.184?×?10⁸) m³, (1.865?×?10⁸, 5.266?×?10⁸) m³, and (2.301?×?10⁸, 5.702?×?10⁸) m³, respectively, and the water saving potential increased year over year. Low amounts of precipitation of irrigated land corresponded with small amounts of net irrigation water and greater water saving potential. Based on the cumulative frequency of the water productivity calculated for the Hulanhe irrigation area from 2007 to 2014, the target water productivity for short (50% of the multi-year average cumulative water productivity) and long (70% of the multi-year average cumulative water productivity) terms were 1.03 kg/m³ and 1.22 kg/m³, respectively, and the cumulative crop water saving potentials for short and long terms were 1.18?×?10⁸ and 2.74?×?10⁸ m³, respectively. These results provided a theoretical reference for creating water saving plans for irrigation areas.     

Rate of mercury loss from contaminated estuarine sediments

The concentration of mercury in contaminated estuarine sediments of Bellingham Bay, Washington was found to decrease with a half-time of about 1.3 yr after the primary anthropogenic source of mercury was removed. In situ measurements of the mercury flux from sediments, in both dissolved and volatile forms, could not account for this decrease. This result suggests that the removal of mercury is associated with sediment particles transported out of the study area. This decrease was modeled using a steady-state mixing model.Mercury concentrations in anoxic interstitial waters reached 3.5 μg/l, 126 times higher than observed in the overlying seawater. Mercury fluxes from these sediments ranged from 1.2 to 2.8 × 10^?5 ng/cm²/sec, all in a soluble form. In general, higher Hg fluxes were associated with low oxygen or reducing conditions in the overlying seawater. In contrast, no flux was measurable from oxidizing interstitial water having mercury concentrations of 0.01-0.06 μ/l.     

Geochemical Charactristics and Genesis of Topaz—Bearing Porphyries in Yangbin Area of Taishun County,Zhejiang Province

The host rocks of the porphyry tin deposits in the Yangbin area are principally topaz-bearing porphyry dikes about 2 km long and 2–20m wide. Three lithologie types are identified for the dikes: topaz-bearing potassium feldspar granitic porphyry, topaz-bearing monzonitic granitic porphyry and topaz-bearing quartz porphyry. The content of topaz in the rocks ranges from 10 to 20 vol.%. Porphyritic texture is characteristic, with quartz, potassium feldspar and albite as main phenocryst minerals. The phenocryst occupies 10–20 vol% of the rocks. The rock groundmass consists of subhedral topaz, quartz and protolithionite. Topaz has a unit-cell parameter b=8.797 (Å), and F:OH=1.92:0.18, indicating a F-rich variety formed at high temperature. The topaz-bearing porphyries occurring in this area are strongly peraluminous (A/NKC=1.574–12.94), with high ratios of F/Cl (146–303) and Rb/Sr (5–122). They are rich in incompatible elements (Sn, 313 × 10^?6–1042 × 10^?6; W, 6 × 10^?6–218 × 10^?6; Nb, 27 × 10^?6–54 × 10^?6), but poor in compatible elements (Sr, 10 × 10^?6–28 × 10^?6; Ba, 58 × 10^?6–73 × 10^?6; V, 3 × 10^?6–12 × 10^?6, Cl, 150 × 10^?6–226 × 10^?6). The rocks are also characterized by high total REE amount (281.69 × 10^?6–319.76 × 10^?6), with strong Eu depletion (δEu=0.01–0.03) and low ratio of LREE/HREE (0.78–0.84). In summary, the authors propose an idea of S-type genesis for the topaz-bearing porphyries with tin mineralization, instead of I-type.     

Quantification of methane emission from bacterial mat sites at Quepos Slide offshore Costa Rica

Seafloor methane emission from the Quepos Slide on the submarine segment of the Costa Rica fore-arc margin was estimated by extrapolating flux measurements from individual seeps to the total area covered by bacterial mats. This approach is based on the combination of detailed mapping to determine the abundance of seeps and the application of a numerical model to estimate the amount of benthic methane fluxes. Model results suggest that the majority of the studied seeps transport rather limited amount of methane (on average: ~177 μmol cm^?2 a^?1) into the water column due to moderate upward advection, allowing for intense anaerobic oxidation of methane (AOM; on average: 53 % of the methane flux is consumed). Depth-integrated AOM rates (56–1,538 μmol CH₄ cm^?2 a^?1) are comparable with values reported from other active seep sites. The overall amount of dissolved methane released into the water column from the entire area covered by bacterial mats on the Quepos Slide is estimated to be about 0.28 × 10⁶ mol a^?1. This conservative estimate which relies on rather accurate determinations of seafloor methane fluxes emphasizes the potential importance of submarine slides as sites of natural methane seepage; however, at present the global extent of methane seepage from submarine slides is largely unknown.     

Estimating the hydraulic properties of an aquitard from in situ pore pressure measurements

A workflow is described to estimate specific storage (S _s) and hydraulic conductivity (K) from a profile of vibrating wire piezometers embedded into a regional aquitard in Australia. The loading efficiency, compressibility and S _s were estimated from pore pressure response to atmospheric pressure changes, and K was estimated from the earliest part of the measurement record following grouting. Results indicate that S _s and K were, respectively, 8.8?×?10^?6 to 1.2?×?10^?5 m^?1 and 2?×?10^?12 m s^?1 for a claystone/siltstone, and 4.3?×?10^?6 to 9.6?×?10^?6 m^?1 and 1?×?10^?12 to 5?×?10^?12 m s^?1 for a thick mudstone. K estimates from the pore pressure response are within one order of magnitude when compared to direct measurement in a laboratory and inverse modelled flux rates determined from natural tracer profiles. Further analysis of the evolution and longevity of the properties of borehole grout (e.g. thermal and chemical effects) may help refine the estimation of formation hydraulic properties using this workflow. However, the convergence of K values illustrates the benefit of multiple lines of evidence to support aquitard characterization. An additional benefit of in situ pore pressure measurement is the generation of long-term data to constrain groundwater flow models, which provides a link between laboratory scale data and the formation scale.     

Velocity of ground water percolation at Indaram, Godavari sub-basin, India

We present values of velocity of ground water percolation (Vg) over large depth intervals, varying from shallow to deeper depths in Indaram area of Godavari sub-basin. The velocities have been estimated using available measured geothermal data. Sub-surface temperatures were measured in seven boreholes. Terrestrial heat flow values are calculated using temperature data and measured values of thermal conductivity of core samples. The results show that Vg is ～3.4 ×10^?7 cm /sec in the top layers (70–150 m) and decreases to ～0.04×10^?7 cm/sec in the deeper levels around 350 m depth and becomes negligibly small thereafter, thereby, indicating that the overall permeability of the sub-surface layers, due to the occurrence of successions of permeable, semi-permeable layers gets reduced to more or less zero at depths around 350 m. The value of Thermal Peclet Number, which is the ratio of the heat transfer through convection to that through conduction, naturally becomes negligible around this depth in the area. The observed consistency of the magnitude of heat flow through various deep sections is a clear indicator that water percolation is practically reduced to zero at depths around 320–400 m and that conduction is the dominant mechanism of heat transfer below the inferred depth section, while the upper layers are dominated by recharge at various depths by near surface water from streams at Indaram.     

Development of a Darcy-Brinkman model to simulate water flow and tracer transport in a heterogeneous karstic aquifer (Val d’Orléans, France)

Darcy’s law is the equation of reference widely used to model aquifer flows. However, its use to model karstic aquifers functioning with large pores is problematic. The physics occurring within the karstic conduits requires the use of a more representative macroscopic equation. A hydrodynamic model is presented which is adapted to the karstic aquifer of the Val d’Orléans (France) using two flow equations: (1) Darcy’s law, used to describe water flow within the massive limestone, and (2) the Brinkman equation, used to model water flow within the conduits. The flow equations coupled with the transport equation allow the prediction of the karst transfer properties. The model was tested by using six dye tracer tests and compared to a model that uses Darcy’s law to describe the flow in karstic conduits. The simulations show that the conduit permeability ranges from 5?×?10^?6 to 5.5?×?10^?5?m² and the limestone permeability ranges from 8?×?10^?11 to 6?×?10^?10?m². The dispersivity coefficient ranges from 23 to 53 m in the conduits and from 1 to 5 m in the limestone. The results of the simulations carried out using Darcy’s law in the conduits show that the dispersion towards the fractures is underestimated.     

Cryosphere as a temporal sink and source of microplastics in the Arctic region

Microplastics (MPs) pollution has become a serious environmental issue of growing global concern due to the increasing plastic production and usage. Under climate warming, the cryosphere, defined as the part of Earth’s layer characterized by the low temperatures and the presence of frozen water, has been experiencing significant changes. The Arctic cryosphere (e.g., sea ice, snow cover, Greenland ice sheet, permafrost) can store and release pollutants into environments, making Arctic an important temporal sink and source of MPs. Here, we summarized the distributions of MPs in Arctic snow, sea ice, seawater, rivers, and sediments, to illustrate their potential sources, transport pathways, storage and release, and possible effects in this sentinel region. Items concentrations of MPs in snow and ice varied about 1–6 orders of magnitude in different regions, which were mostly attributed to the different sampling and measurement methods, and potential sources of MPs. MPs concentrations from Arctic seawater, river/lake water, and sediments also fluctuated largely, ranging from several items of per unit to >40,000 items m^?3, 100 items m^?3, and 10,000 items kg^?1 dw, respectively. Arctic land snow cover can be a temporal storage of MPs, with MPs deposition flux of about (4.9–14.26) × 10⁸ items km^?2 yr^?1. MPs transported by rivers to Arctic ocean was estimated to be approximately 8–48 ton/yr, with discharge flux of MPs at about (1.65–9.35) × 10⁸ items/s. Average storage of MPs in sea ice was estimated to be about 6.1×10¹⁸ items, with annual release of about 5.1×10¹⁸ items. Atmospheric transport of MPs from long-distance terrestrial sources contributed significantly to MPs deposition in Arctic land snow cover, sea ice and oceanic surface waters. Arctic Great Rivers can flow MPs into the Arctic Ocean. Sea ice can temporally store, transport and then release MPs in the surrounded environment. Ocean currents from the Atlantic brought high concentrations of MPs into the Arctic. However, there existed large uncertainties of estimation on the storage and release of MPs in Arctic cryosphere owing to the hypothesis of average MPs concentrations. Meanwhile, representatives of MPs data across the large Arctic region should be mutually verified with in situ observations and modeling. Therefore, we suggested that systematic monitoring MPs in the Arctic cryosphere, potential threats on Arctic ecosystems, and the carbon cycle under increasing Arctic warming, are urgently needed to be studied in future.     

Oceanographic controls on shallow‐water temperate carbonate sedimentation: Spencer Gulf,South Australia

Spencer Gulf is a large (ca 22 000 km²), shallow (<60 m water depth) embayment with active heterozoan carbonate sedimentation. Gulf waters are metahaline (salinities 39 to 47‰) and warm‐temperate (ca 12 to ?28°C) with inverse estuarine circulation. The integrated approach of facies analysis paired with high‐resolution, monthly oceanographic data sets is used to pinpoint controls on sedimentation patterns with more confidence than heretofore possible for temperate systems. Biofragments – mainly bivalves, benthic foraminifera, bryozoans, coralline algae and echinoids – accumulate in five benthic environments: luxuriant seagrass meadows, patchy seagrass sand flats, rhodolith pavements, open gravel/sand plains and muddy seafloors. The biotic diversity of Spencer Gulf is remarkably high, considering the elevated seawater salinities. Echinoids and coralline algae (traditionally considered stenohaline organisms) are ubiquitous. Euphotic zone depth is interpreted as the primary control on environmental distribution, whereas seawater salinity, temperature, hydrodynamics and nutrient availability are viewed as secondary controls. Luxuriant seagrass meadows with carbonate muddy sands dominate brightly lit seafloors where waters have relatively low nutrient concentrations (ca 0 to 1 mg Chl‐a m^?3). Low‐diversity bivalve‐dominated deposits occur in meadows with highest seawater salinities and temperatures (43 to 47‰, up to 28°C). Patchy seagrass sand flats cover less‐illuminated seafloors. Open gravel/sand plains contain coarse bivalve–bryozoan sediments, interpreted as subphotic deposits, in waters with near normal marine salinities and moderate trophic resources (0·5 to 1·6 mg Chl‐a m^?3) to support diverse suspension feeders. Rhodolith pavements (coralline algal gravels) form where seagrass growth is arrested, either because of decreased water clarity due to elevated nutrients and associated phytoplankton growth (0·6 to 2 mg Chl‐a m^?3), or bottom waters that are too energetic for seagrasses (currents up to 2 m sec^?1). Muddy seafloors occur in low‐energy areas below the euphotic zone. The relationships between oceanographic influences and depositional patterns outlined in Spencer Gulf are valuable for environmental interpretations of other recent and ancient (particularly Neogene) high‐salinity and temperate carbonate systems worldwide.