Weathering of coastal defensive structures in southwest England: a 500 year stone durability trial

Historic structures can be viewed as exposure trials of the stone of which they are constructed. As such, they represent a geomorphological weathering experiment. Several structures of Henrician (sixteenth century) and greater age on the coast of southwest England have been exposed to coastal salt weathering for 500–600 years. Long‐term weathering rates on five different rock groups are derived from careful study of weathering depths and forms. There is significant variation in weathering rate between five major rock groups. Rank ordering of weathering rate values reveals a durability order of these rock groups, which is confirmed by local juxtapositions. Controls on rock durability in the coastal weathering environment include both mechanical and mineralogical characteristics. Specific density, and combined quartz and muscovite content, are positively related to durability; high feldspar and chlorite content are associated with low durability. Copyright © 2000 John Wiley & Sons, Ltd.     

Rates and patterns of erosion on inter-tidal shore platforms,Kaikoura Peninsula,South Island,New Zealand

This paper presents measured rates of erosion on shore platforms at Kaikoura Peninsula, South Island, New Zealand. Surface lowering rates were measured with a micro-erosion meter and traversing micro-erosion meter. The mean lowering rate for all shore platforms was 1·130 mm a⁻¹. Differences in lowering rates were found between different platform types and lithologies. The rate of surface lowering on Type A (sloping) mudstone platforms was 1·983 mm a⁻¹, and 0·733 mm a⁻¹ on Type B mudstone platforms (subhorizontal). On limestone platforms the lowering rate was 0·875 mm a⁻¹. A previously reported cross-shore pattern of surface lowering rates from Kaikoura was not found. Rates were generally higher on the landward margins and decreased in a seaward direction. Season is shown statistically to influence erosion rates, with higher rates during summer than winter. The interpretation given to this is that the erosive process is subaerial weathering in the form of wetting and drying and salt weathering. This is contrary to views of shore platform development that have favoured marine processes over subaerial weathering. Copyright © 1998 John Wiley & Sons, Ltd.     

Rock-weathering by the lichen Lecidea auriculata in an arctic alpine environment

Scanning electron microscopy reveals that Lecidea auriculata penetrates rock surfaces, detaching, incorporating and expelling flakes of rock. Measurements on an age sequence of moraine ridges illustrate changes in the extent and intensity of weathering over time. A minimum rate of surface lowering (0·0012 mm a^?1) is 25 to 50 times faster than weathering due to other processes in the same area. The spatial pattern of weathering is influenced by the narrow ecological range of the species. Surface rocks on dry, exposed sites are probably weathering much more rapidly than those in adjacent damp hollows and beneath snowpatches.     

Surface‐climate attributes at Injisuthi Outpost,Drakensberg, and possible ramifications for weathering

Aerial and sub‐aerial climatic data were collected from a station at 1920 m a.s.l. in the Injisuthi region of the South African Drakensberg. Sensors monitored air temperature, soil surface and rock surface temperature, for two rock types, over the summer and winter of 2001/2002. Rainfall was measured from the summer of 2001 to January 2004. These are the first rock and soil surface‐climate data to be collected for an exposed site at this altitude in the area. Rainfall over the two calendar years 2002 and 2003 was found to be below estimates for the region, but patterns imply numerous rock wetting and drying cycles in summer. At the site, air, rock and soil temperatures differ considerably on a diurnal basis with respect to both absolute temperature and daily ranges. Mean rock daily ranges, as conducive to possible thermal fatigue, are found to be similar in the summer and winter periods. Of the two rock types monitored, the darker coloured basalt attained higher maximum and marginally lower minimum temperatures than the sandstone. Soil frost did not occur at 2·5 cm depth, but rock did reach below ?6 °C in winter. Both rock types maintain relatively high rock temperatures in winter (exceeding 25 °C), thus chemical weathering is probably only moisture restricted during this dry period. Findings highlight the importance of directly monitoring rock temperature when attempting to discern the rock weathering environment. Copyright © 2006 John Wiley & Sons, Ltd.     

Two‐hourly surface change on supra‐tidal rock (Marengo,Victoria, Australia)

A traversing micro‐erosion meter was used to measure rock surface micro‐topography over 40 cm² on a supra‐tidal cliff face from early morning to late evening in late spring. From 06:00 hours to 22:00 hours the relative heights of 188 coordinates were obtained using the meter at 2‐hour intervals, resulting in a data set of 1607 readings. Monitoring shows that rock surfaces are dynamic entities, with significant rise and fall relative to the first measurement at shorter timescales than previously reported. The maximum positive rise between readings was 0·261 mm and lowering was 0·126 mm. The pattern of change did not relate as expected to environmental variables such as temperature or insolation. Rather, the surface showed greater surface change in the early morning and late afternoon. It is hypothesized that this pattern relates to the expansion and contraction of lichen thalli as moisture is absorbed during higher humidity in the morning and late afternoon. The implications of these results for weathering studies are considered. Copyright © 2006 John Wiley & Sons, Ltd.     

A new method for determining weathering rates in weathering pits

Determining the rates of rock weathering is difficult because, firstly, the weathering rate of rocks is usually so slow that it is difficult to measure; secondly, it is also difficult to determine the start time and duration of weathering. The Shanxi River Valley in Fujian, China dried up after a reservoir was built upstream in 1959, and became a stone quarry site. Quarrying ceased in 1977, so a large amount of quarry wastes with artificially excavated surfaces were left in the valley. The concave-upward curved rocky surface, broken by manual excavation, easily contains rainwater in its central part, which was easily weathered into a more concave surface. Plaster mould casting was performed in situ on such a concave surface of an excavated stone rock in the valley and scanned with a high-precision 3D scanner to obtain 3D data of the concave-upward rock surface and its more concave middle part, which was considered as an initial weathering pit. The 3D model provided an in-depth understanding of the initial formation process of weathering pits, indicating that: (1) the average weathering rate of a weathering pit is 10.8 ± 0.49 cm ka⁻¹; (2) weathering pits are generally formed by standing water in depressions on a flat near-horizontal rock surface due to weathering actions involving water; (3) the deepening rate of a weathering pit is about four times greater than that of the surrounding area; (4) the growth of a weathering pit can begin in some small concavities on the flat rock surface without pre-existing depressions and gradually expands; (5) a weathering pit is generally wider than deep or with a flat bottom due to expansion with a lateral weathering rate that is greater than that of the vertical, and the lamination of the host rock is not necessary for the formation of flat-floored weathering pits. © 2020 John Wiley & Sons, Ltd.     

A Morphological Study of Greenschist Weathering on Dated Coastal Structures,South Devon,UK

Three dated structures up to 450 years in age display the effects of coastal weathering of the greenschist of which they are constructed. A variety of weathering forms is present. The various topographic surfaces of the structures create variation in weathering environments and consequent weathering processes and rates. Weathering is enhanced by direct exposure to salt-bearing spray and by humid conditions, and apparently limited by direct exposure to solar radiation. The maximum rates of weathering on the three surfaces approximate to 0·6 mm a⁻¹ over this period, consistent with measured contemporary weathering rates for a natural surface formed by this rock type in a nearby coastal location. © 1997 by John Wiley & Sons, Ltd.     

Processes controlling rapid temperature variations on rock surfaces

In arid environments, thermal oscillations are an important source of rock weathering. Measurements of temperature have been made on the surface of rocks in a desert environment at a sampling interval of 0·375 s, with simultaneous measurements of wind speed, air temperature, and incoming shortwave radiation. Over timescales of hours, the temperature of the rock surface was determined primarily by shortwave radiation and air temperature, while rapid temperature variations, high dT/dt, at intervals of seconds or less, were determined by wind speed. The maximum values of temperature change and time spent above 2°C min^?1 increased at high measurement rates and were much higher than previously reported. The maximum recorded value of dT/dt was 137°C min^?1 and the average percentage time spent above 2°C min^?1 was ～70 ± 13%. Maximum values of dT/dt did not correlate with the maximum values of time spent above 2°C min^?1. Simultaneous measurements of two thermocouples 5·5 cm apart on a single rock surface had similar temperature and dT/dt values, but were not correlated at sampling intervals of less than 10 s. It is suggested that this is resulting from rapid fluctuations due to small spatial and timescale wind effects that are averaged out when data is taken at longer sampling intervals, ～10 s or greater. Published in 2010 by John Wiley & Sons, Ltd.     

Weathering of granite in Antarctica: I. Light penetration into rock and implications for rock weathering and endolithic communities

Where rocks are composed of translucent minerals, light penetrates the rock and, in so doing, impacts on the thermal conditions. Where minerals are not translucent all the heat transformation must be at the rock surface, and steep thermal gradients can occur. Where light does penetrate, a component of the incoming radiation is transformed to heat at differing depths within the rock, thereby decreasing the thermal gradient. Equally, light transmissive minerals facilitate endolithic communities, which can also play a role in rock weathering. The attribute of light transmission within rock and the impact this has on the resulting thermal conditions has not been considered within rock weathering studies. An attempt was made to monitor the amount of light penetrating the outer 2 mm of coarse granite under Antarctic summer conditions and to evaluate the thermal impact of this. It was found that the amount of light penetration at this site exceeded modeled or postulated values from biological studies and that it could significantly impact the thermal conditions within the outer shell of the rock. Although the resulting data highlighted a number of flaws in the experimental procedure, sufficient information was generated to provide the first assessment of the range of thermal responses due to light transmissive minerals in rock. Copyright © 2007 John Wiley & Sons, Ltd.     

Ozone concentration studies and ozone flux measurements near the ground at Poona

Using a modified Brewer bubbler ozone sensor, continuous measurements of the ozone concentration near the ground were made at Poona (18°N, 73°E) for one year 1969–1970. The surface ozone concentration shows a pronounced seasonal variation, with a minimum during the monsoon months and a maximum during the pre-monsoon summer months. There is also a marked diurnal variation in surface ozone concentration which clearly follows the diurnal variation of temperature and is again a maximum during the summer months and a minimum during the monsoon. A secondary maximum in ozone concentration occurs in the forenoon during the winter months, associated with the temperature inversions that occur near the ground in this season.Both ozone and radioactive tracers, such as Cs-137 both in air and in precipitation show variations indicating that they have identical source regions and sinks. The latitudinal anomaly of surface ozone and Cs-137 observed in the low latitudes over India is explained as arising from the reduction in the rate of transfer of these tracers from the stratosphere to the troposphere, as a result of the reversed circulation at the upper levels in this season.From continuous measurements of surface ozone made with three electrochemical sensors exposed at three levels, 0, 15 and 35 m above the ground, the ozone flux has been directly calculated for the first time in the tropics. The ozone flux was calculated using both the rate of decay method used by Kroening and Ney and Regener's profile method. The profile method gives values of the order of 1.71 to 7.04×10¹¹ mol/cm²/sec and that obtained by the rate of decay method is found to be 4.2 to 5.6×10¹¹ mol/cm²/sec and are in good agreement with the flux values reported by other investigators.     

Variations in the index of refraction of the atmosphere

Summary This paper discusses the atmospheric refractive index (a) throughout the year at the surface of the earth and (b) for each season in various air masses. Mean monthly or seasonal values, respectively, are employed.The annual variation in the refractive index at the earth's surface is examined by noting the contributions of the optical and the water vapor terms. The former exhibits a sinusoidal variation with a period of a year, having a maximum in winter and a minimum during summer. The amplitude of the cycle is latitude dependent, appearing greater in polar than in tropical regions. The magnitude of the water vapor term is more strongly dependent upon both season and latitude. Excepting areas where the dew point changes little from month to month, the water vapor term attains a single yearly maximum at about mid July.Graphs of the variation of refiactive index with altitude for the major air masses are included. Highest values of the index up to a height of 6 km are found in tropical maritime and monsoon air masses; lowest values, in arctic air masses. The rate of decrease of refractive index with height is usually quite different for diverse air masses. From the surface to an altitude of 6 km, the most constant rate of decrease with altitude, considering all air mass types, was found in the superior air mass.     

Simulating the growth of tafoni

Throughout the world, large caves in rocks (tafoni) are found, which originate from salt weathering. The mechanisms that control their development are poorly understood. The growth of tafoni has been studied with a model that describes how a rock surface, containing a small pit, disintegrates by salt crystallization during wetting/drying cycles. In the model the rock is mapped on a grid. The migration and crystallization of salts are simulated explicitly in the drying phase of a cycle. At the end of each wetting/drying cycle the amount of salt deposited at the grid nodes is evaluated and the shape of the rock surface is adjusted by removing nodes. The length of the drying period in a single cycle proved to be the key parameter. For short drying periods the amount of crystallized salt at the surface is proportional to the drying rate. Therefore, for short drying periods most salts are deposited at the more exterior parts of the rock surface. As a result, most damage will develop at these parts of the surface, which results in smooth surfaces. Due to the characteristics of the drying process for long drying periods, most salts accumulate at regions with low evaporation rates, which are the sheltered parts of the rock surface. These parts are not exposed to the wind or the sun. As a result, the pit grows and a tafone develops. Copyright © 2004 John Wiley & Sons, Ltd.     

Rock thermal data at the grain scale: applicability to granular disintegration in cold environments

Consideration of the mechanisms associated with the granular disintegration of rock has been limited by available data. In most instances, both the size of the transducer and the nature of the study have negated any applicability of the resulting data to the understanding of grain‐to‐grain separation within rock. The application of microthermocouples (≤0·15 mm diameter) and high‐frequency logging (20 s intervals) at a taffoni site on southern Alexander Island and from a rock outcrop on Adelaide Island (Antarctica) provide new data pertaining to the thermal conditions, at the grain scale, of the rock surface. The results show that thermal changes (ΔT/t) can be very high, with values of 22 °C min^?1 being recorded. Although available data indicate that there can be differences in frequency and magnitude of ?uctuations as a function of aspect, all aspects experienced some large magnitude (≥2 °C min^?1) ?uctuations. Further, in many instances, large thermal changes in more than one direction could occur within 1 min or in subsequent minutes. These data suggest that the surface grains experience rapidly changing stress ?elds that may, with time, effect fatigue at the grain boundaries; albedo differences between grains and the resulting thermal variations are thought to exacerbate this. The available data failed to show any indication of water freezing (an exotherm) and thus it is suggested that microgelivation may not play as large a role in granular breakdown as is often postulated for cold regions, and that in this dry, Antarctic region thermal stress may play a signi?cant role. Copyright © 2003 John Wiley & Sons, Ltd.     

Temporal variations in Sr and 87Sr/86Sr of the Ganga headwaters: estimates of dissolved Sr flux to the mainstream

The headwaters of the Ganga (the Alaknanda, Bhagirathi and the Ganga) were analysed for their dissolved major ions, Sr and ⁸⁷Sr/⁸⁶Sr on a biweekly to monthly basis over a period of one year to determine their temporal variations and the factors contributing to them. The concentrations of major ions and Sr show significant seasonal variation with lower values during monsoon period in all the three rivers. A similar trend is also observed for ⁸⁷Sr/⁸⁶Sr and Na*/Ca (Na* = Na_r? Cl_r) suggesting relatively lower contribution of Sr and Na from silicates (which are more radiogenic in Sr) during monsoon. Budget calculations show that silicate derived dissolved Sr (Sr_s) in the river Ganga, Alaknanda and the Bhagirathi varied from 10 ± 4 to 27 ± 11, 7 ± 3 to 30 ± 12, 16 ± 6 to 57 ± 23% of measured Sr respectively with lower values during monsoon. The relative decrease in silicate erosion compared to carbonate during monsoon can result from several factors, these include higher dissolution kinetics of the carbonates, lower water–rock interaction time and availability of larger area for weathering. The annual discharge weighted Sr flux derived from the time series data is higher by ～20% from that based on peak flow Sr, and lower by ～40% compared to that derived from lean flow Sr concentration. The area‐normalized annual flux of dissolved Sr from the Ganga at Rishikesh is about five times its flux at Rajshahi (Bangladesh) and a few other major global rivers, such as the Amazon, indicating higher erosion rate over the Himalaya. Copyright © 2010 John Wiley & Sons, Ltd.     

Rock damage and regolith transport by frost: an example of climate modulation of the geomorphology of the critical zone

In this article we craft process‐specific algorithms that capture climate control of hillslope evolution in order to elucidate the legacy of past climate on present critical zone architecture and topography. Models of hillslope evolution traditionally comprise rock detachment into the mobile layer, mobile regolith transport, and a channel incision or aggradation boundary condition. We extend this system into the deep critical zone by considering a weathering damage zone below the mobile regolith in which rock strength is diminished; the degree of damage conditions the rate of mobile regolith production. We first discuss generic damage profiles in which appropriate length and damage scales govern profile shapes, and examine their dependence upon exhumation rate. We then introduce climate control through the example of rock damage by frost‐generated crack growth. We augment existing frost cracking models by incorporating damage rate limitations for long transport distances for water to the freezing front. Finally we link the frost cracking damage model, a mobile regolith production rule in which rock entrainment is conditioned by the damage state of the rock, and a frost creep transport model, to examine the evolution of an interfluve under oscillating climate. Aspect‐related differences in mean annual surface temperatures result in differences in bedrock damage rate and mobile regolith transport efficiency, which in turn lead to asymmetries in critical zone architecture and hillslope form (divide migration). In a quasi‐steady state hillslope, the lowering rate is uniform, and the damage profile is better developed on north‐facing slopes where the frost damage process is most intense. Because the residence times of mobile regolith and weathered bedrock in such landscapes are on the order of 10 to 100 ka, climate cycles over similar timescales result in modulation of transport and damage efficiencies. These lead to temporal variation in mobile regolith thickness, and to corresponding changes in sediment delivery to bounding streams. Copyright © 2012 John Wiley & Sons, Ltd.     

Rock moisture measurements: techniques,results, and implications for weathering

Rock moisture is an important factor for the intensity and distribution of frost weathering processes. However, quantitative measurements are scarce, which is partly due to the lack of reliable measurement techniques. This paper presents five different techniques for obtaining rock moisture data. While collecting rock pieces and two‐dimensional geoelectric measurements allow determination of the spatial moisture distribution, the temporal variability can be derived from conductivity and time domain reflectometry records. Computer simulations, using rock properties and climatic records as input data, render it possible to clarify the important aspects that are responsible for the moisture distribution. It proved to be advisable to use several methods to check and validate the results. The results, obtained in study areas in the Bavarian Alps, make it clear that direct rainfall is the main source of rock moisture. The influence of snow is limited to the immediate vicinity of the snow fields and is not equally pronounced at different times and positions. Rock moisture levels are higher in summer than they are in winter, since in winter less water is supplied in liquid form. Northerly exposed rockwalls are generally more moist than those exposed in a southerly direction, which is due to the different insolation as well as to the wind direction during rainfall. In every position the rock is, on average, wetter on the inside than it is on the surface. This means that shallow frost cycles, as typical for south‐exposed sites, are not affecting weathering, since they take place at a depth level that is mostly dried out. Numerous spatial and temporal patterns of rockfall found in the same study areas can be explained through variations in rock moisture. Thus, the moisture content of the rock is considered to be one of the major controlling factors of the frost‐shattering rate. Copyright © 2005 John Wiley & Sons, Ltd.     

Techniques for measuring rock weathering: application to a dated fan segment sequence in southern Tunisia

There are a number of techniques for estimating the amount of weathering a clast has undergone. These usually have the objective of establishing an ordinal chronology of geomorphological surfaces, or investigation of site-specific conditions affecting weathering rates. Three such techniques are applied to a dated sequence of alluvial fan segments in southern Tunisia. Two of these techniques depend on measuring surface roughness (the micro-roughness meter and a displacement approach) and one uses the structural weakening of the rock fabric (Schmidt hammer). The micro-roughness meter enables calculation of standard deviation of surface height variation, root mean square roughness and surface autocorrelation function. Of these techniques, Schmidt hammer rebound values, standard deviation, root mean square roughness and the displacement technique show systematic changes on the three fan segments which are statistically significant at the 0·05 level. However, the amount of variance in all datasets is very large, indicating the need for caution in application of these techniques for relative dating. © 1998 John Wiley & Sons, Ltd.     

Characteristics of soil moisture in permafrost observed in East Siberian taiga with stable isotopes of water

Soil moisture and its isotopic composition were observed at Spasskaya Pad experimental forest near Yakutsk, Russia, during summer in 1998, 1999, and 2000. The amount of soil water (plus ice) was estimated from volumetric soil water content obtained with time domain reflectometry. Soil moisture and its δ¹⁸O showed large interannual variation depending on the amount of summer rainfall. The soil water δ¹⁸O decreased with soil moisture during a dry summer (1998), indicating that ice meltwater from a deeper soil layer was transported upward. On the other hand, during a wet summer (1999), the δ¹⁸O of soil water increased due to percolation of summer rain with high δ¹⁸O values. Infiltration after spring snowmelt can be traced down to 15 cm by the increase in the amount of soil water and decrease in the δ¹⁸O because of the low δ¹⁸O of deposited snow. About half of the snow water equivalent (about 50 mm) recharged the surface soil. The pulse of the snow meltwater was, however, less important than the amount of summer rainfall for intra‐annual variation of soil moisture. Excess water at the time just before soil freezing, which is controlled by the amount of summer rainfall, was stored as ice during winter. This water storage stabilizes the rate of evapotranspiration. Soil water stored in the upper part of the active layer (surface to about 120 cm) can be a water source for transpiration in the following summer. On the other hand, once water was stored in the lower part of the active layer (deeper than about 120 cm), it would not be used by plants in the following summer, because the lower part of the active layer thaws in late summer after the plant growing season is over. Copyright © 2002 John Wiley & Sons, Ltd.     

Evidence for freeze–thaw events and their implications for rock weathering in northern Canada

Discussions regarding weathering in cold environments generally centre on mechanical processes and on the freeze–thaw mechanism in particular. Despite the almost ubiquitous assumption of freeze–thaw weathering, unequivocal proof of interstitial rock water actually freezing and thawing is singularly lacking. Equally, many studies have used the crossing of 0 °C, or values close to that, as the basis for determining the number of ‘freeze–thaw events’. In order to assess the weathering regime at a site in northern Canada, temperatures were collected at the surface, 1 cm and 3 cm depth for sets of paving bricks, with exposures both vertical and at 45°, orientated to the four cardinal directions. Temperature data were collected at 1 min intervals for 1 year. These data provide unequivocal proof for the occurrence of the freezing and thawing of water on and within the rock (freeze–thaw events). The freeze event is evidenced by the exotherm associated with the release of latent heat as the water actually freezes. This is thought to be the ?rst record of such events from a ?eld situation. More signi?cantly, it was found that the temperature at which freezing occurred varied signi?cantly through the year and that on occasion the 1 cm depth froze prior to the rock surface. The change in freeze temperature is thought to be due to the chemical weathering of the material (coupled with on‐going salt inputs via the melting of snowfall), which, it is shown, could occur throughout the winter despite air temperatures down to ?30 °C. This ?nding regarding chemical weathering is also considered to be highly signi?cant. A number of thermal stress events were also recorded, suggesting that rock weathering in cold regions is a synergistic combination of various chemical and mechanical weathering mechanisms. Copyright © 2003 John Wiley & Sons, Ltd.     

Microchemistry of small desert varnish samples,western New South Wales,Australia

The chemistry of varnish scrapings from within and adjacent to rock engravings on sandstone outcrops in semiarid Australia was analysed using an electron microprobe (WDS mode). Small-area analyses were used to reduce potential contamination from identifiable within-varnish detrital grains and from substrate material. Ratios of (Ca + K):Ti were compared for rock engravings on older and younger rock surfaces, and between different engraving styles. Although ratios from varnish on the older surface were lower than for the younger surface, differences were not statistically significant. Sorting of analyses for potentially anomalous amounts of minor elements had little effect on the ranking of individual ratio values. Rankings of within-engraving ratio values were generally in accord with relative age expectations but differences between samples were not significant, with the chemical variability of varnish being high even without the contribution of discernible detrital inclusions. © 1998 John Wiley & Sons, Ltd.