Geopolymer formation and its unique properties

The characteristic property of naturally-occurring geopolymers is a high content of humic materials that are recognized by the nitrogen function. Through a simulated geopolymerization, biopolymers with non-nitrogen function, such as xanthan gum, were found to have the characteristics of humic acid by means of UV–Vis spectrometry. This fact ascertains that any kind of biopolymer may naturally transform to a geopolymer. A geopolymer is a type of crosslinked long-chain compound, built in three-dimensional structures whose property is immune to microbial degradation. A crosslinked biopolymer was shown to have the same characterization as a geopolymer that has a long life due to its crosslinking capacity and anti-microbial properties. In this study, the formation of petroleum-based geopolymers (e.g., kerogen) was introduced. This study may elucidate the structure of geomacromolecules and the mechanism of their formation, closely related with crosslink reaction between inorganic and organic molecules. This will further change the conventional definition of geopolymer that involves only the inorganic geopolymer.     

压裂液快速混配技术的研究与应用

水力压裂是低渗透油藏改造的重要措施,压裂液性能则是影响压裂增产效果的一个关键因素,配液质量好、配液效率高是压裂液配制的发展趋势。通过分析当前压裂液配制难题,以及稠化剂和固体添加剂的特性,指出制约配液快速性的关键因素。基于实验研究成果,提出一种压裂液快速配制新工艺,并采用PLC控制,实现配液过程自动化。新的配液工艺和配液装备已经在大庆油田应用两年,工业化应用表明：该工艺胶液粘度释放快,胶液中没有水包粉现象,且具有计量精度高、添加剂混合均匀,发液速度快等诸多优点,证实了新工艺的合理性和有效性。     

A-C复合交联剂的合成及其应用

合成了3种交联剂:柠檬酸铝、柠檬酸铬、A-C复合交联剂,利用傅立叶红外光谱、紫外光谱对它们进行了表征,并将其用于清水和处理后油田采出污水配制HPAM型聚合物弱凝胶的对比实验。实验表明:A-C复合交联剂用于油田采出污水配制的聚合物弱凝胶的成胶效果最优;当pH值为6、成胶温度为60℃、成胶时间为1 d时所配制的弱凝胶黏度最大,其黏度值达到1 129 mPa.s。随后考察了A-C复合交联剂浓度、成胶温度、矿化度、pH值、S2-及Fe2+等因素对A-C复合交联剂弱凝胶体系黏度的影响效果,结果表明:A-C复合交联剂基本上可用于油田处理后污水配制弱凝胶体系,有望实现油田处理后污水的资源化利用。     

Geostatistical integration using 2-D electrical resistivity and 3-D gravity methods for detecting cavities in a karst area

Two-dimensional (2-D) electrical resistivity and three-dimensional (3-D) gravity explorations were undertaken to estimate the 3-D distribution of karst cavities at the area of Yongweol-ri in Korea where ground subsidence has occurred. Although the gravity method is a low-cost way of analyzing a 3-D continuous structure, its vertical resolving power is poor. In contrast, the electrical resistivity method can provide a 2-D and/or 3-D subsurface structure with a much higher lateral and vertical resolution than the gravity method. Accordingly, geostatistical methods and density information were used to enhance the 2-D resistivity structure revealed by the electrical resistivity method into a 3-D structure. The assumptions are, first, that each data set senses the same underlying geological structure in terms of different material properties and, secondly, that two different material properties are correlated locally or globally throughout the entire target area. As a result, the distribution of limestone cavities can be estimated under the assumption that they are mostly filled with groundwater and clayey soils and have abnormally low levels of resistivity and density. The estimated distribution corresponds with the grouting, borehole imaging and monitoring data. In this example, it can be seen that the integration analysis of 2-D electrical resistivity and 3-D gravity methods is a very powerful tool for 3-D subsurface imaging and that the method can provide enhanced imaging capabilities for 3-D cavities.     

Morphology,sedimentology and palaeohydraulic significance of large gravel dunes,Altai Mountains,Siberia

Coarse-gravel bedforms which resulted from Pleistocene glacial outburst floods are identified as subaqueous dunes. Comparison of the morphology of these ‘fossil’ structures with modern dunes shows that the form of two-dimensional (2-D) transverse dunes and 3-D cuspate and lunate dunes developed in coarse gravels is comparable with sand-dune morphology within lesser-scale geophysical flows. The similarity of the steepest gravel dunes with equilibrium dunes in sand indicates that grain size is not a major factor in constraining primary duneform. Internal structure indicates that flow over 2-D dunes was relatively uniform but over 3-D bedforms flow was locally variable. Flow separation and complex streaming of flow occurred over the steepest 3-D dunes. Cross-beds are thin and few approach the angle of repose; consequently most dunes did not migrate primarily by avalanching but by stoss-entrained gravel transported over the crests rolling-down and depositing on the lee slopes. Lee-side sediments are often finer than the stoss-slope sediments, which indicates the lee formed when flood power was waning. Some dunes were slightly planed-down during falling stage because lee-side cross-beds tend to be steeper than the angle of the preserved lee slope. However, silt-rich caps indicate that any height reduction was contemporary with the final deposition of foresets. Post-flood modification has been negligible although the modern topography is subdued by loess deposits within the dune troughs.     

环保型弱凝胶护壁护心钻井液研究与应用

海域浅层气地质调查和盐湖环境科学钻探在松散砂岩钻探取样工程中,存在孔壁易坍塌、成孔率低等技术难题,为此开展了松散砂岩地层环保型弱凝胶护壁护心钻井液技术研究。通过弱凝胶结构研究及成胶剂、交联剂及抗盐降滤失剂等材料优选,研发了一套环保型弱凝胶护壁护心钻井液,评价了钻井液的流变性、滤失性、抑制性、护心性能、环保性能等性能,并在山西某盐湖环境科学钻探工程进行现场应用。室内及现场应用结果表明：研制的弱凝胶护壁护心钻井液具有良好的流变性、降滤失性、抑制性（岩屑回收率96.3%）、护壁护心性能及环保性能（BOD5/COD比值24.6%,EC50值47950 mg/L）,能有效解决松散砂岩类地层孔壁坍塌、岩屑不易携带等问题,在松散地层钻探工程中具有广阔的应用前景。     

Architecture of fault zones determined from outcrop, cores, 3-D seismic tomography and geostatistical modeling: example from the Albalá Granitic Pluton, SW Iberian Variscan Massif

The 3-D seismic tomographic data are used together with field, core and well log structural information to determine the detailed 3-D architecture of fault zones in a granitic massif of volume 500×575×168 m at Mina Ratones area in the Albalá Granitic Pluton. To facilitate the integration of the different data, geostatistical simulation algorithms are applied to interpolate the relatively sparse structural (hard) control data conditioned to abundant but indirect 3-D (soft) seismic tomographic data. To effectively integrate geologic and tomographic data, 3-D migration of the velocity model from the time domain into the depth domain was essential. The resulting 3-D model constitutes an image of the fault zone architecture within the granitic massif that honours hard and soft data and provides an evaluation of the spatial variability of structural heterogeneities based on the computation of 3-D experimental variograms of Fracture Index (fault intensity) data. This probabilistic quantitative 3-D model of spatially heterogeneous fault zones is suitable for subsequent fluid flow simulations. The modeled image of the 3-D fault distribution is consistent with the fault architecture in the Mina Ratones area, which basically consists of two families of subvertical structures with NNE–SSW and ENE–WSW trends that displaces the surfaces of low-angle faults (North Fault) and follows their seismically detected staircase geometry. These brittle structures cut two subvertical dykes (27 and 27′ Dykes) with a NNE–SSW to N–S trend. The faults present high FI (FI>12) adjacent bands of irregular geometry in detail that intersect in space delimiting rhombohedral blocks of relatively less fractured granite (FI<6). Both structural domains likely correspond with the protolith and the damaged zone/fault core in the widely accepted model for fault zone architecture. Therefore, the construction of 3-D grids of the FI in granitic areas affected by brittle tectonics permits the quantitative structural characterization of the rock massif.     

高岭土/聚丙烯酸高吸水材料合成及表面改性

采用高温快速的水溶液聚合方法合成了高岭土／聚丙烯酸高吸水性复合材料,探讨了复合材料合成过程中各种因素,如引发剂用量、交联剂用量、中和度、高岭土超细粉用量等对复合材料吸水倍数的影响,还对该高吸水性复合材料进行表面亲水改性研究,结果表明表面亲水改性有利于提高复合材料的吸水速率。     

大地电磁测深在潍坊滨海区划分断裂和构造单元中的应用

研究区位于莱州湾南畔,为查明该区域的地质构造,采用大地电磁测深等探测方法在该区进行勘探。通过对大地电磁勘探剖面视电阻率断面图和三维反演结果的分析研究,结合该区的地质、钻探和物性特征,对该区的隐伏断裂构造进行了推断解释,划分出9条隐伏断裂。同时对研究区内两个Ⅳ级构造单元进行重新厘定,划分出五个Ⅴ级构造单元。从不同方向,不同深度三维反演切片图中能较为直观获得断裂空间展布情况、构造单元的形态、地质体电性特征等信息,为地质解释提供参考依据。     

六价铬污染模拟含水层的注入型黄原胶凝胶阻截屏障试验研究

由于工业废物的不合理排放,大量的重金属污染物Cr(Ⅵ)进入地下环境,严重威胁着人类健康和生态环境。Cr(Ⅵ)在地下水环境中高度易迁移的特性,造成其污染修复上的困难,亟待一种绿色、经济、有效的阻截方式提高地下水对Cr(Ⅵ)的阻控能力。研究利用焦亚硫酸钠原位还原地下水中的Cr(Ⅵ),产生Cr³⁺作为黄原胶交联剂,形成凝胶阻截屏障,探究了各类成分对凝胶时间、黏度变化的影响及凝胶屏障对含水层的阻截效果,得到如下结论：(1)在Cr(Ⅵ)质量浓度达到200 mg/L的体系中,质量分数0.4%的黄原胶溶液在1.5 h内即可形成具有一定机械强度的凝胶;(2)凝胶具有耐盐性,适用于常见含水层,2.5～5 g/L的Na⁺和K⁺对凝胶起促进作用;(3)注入型凝胶阻截屏障能够大幅降低中砂介质的渗透系数至1×10^-7 cm/s,满足地下水阻截需求。注入型凝胶屏障的形成无需引入有害物质,阻截结束后注入型屏障可经生物作用自然降解,不会长期改变含水层水力条件。研究成果可为Cr(Ⅵ)污染地下水中凝胶阻截屏障的构筑提供理论基础。     

基岩水井水力压裂专用压裂液试验研究

为了开发高粘、低滤失、抗水敏性好的基岩水井专用压裂液,通过胶凝剂、交联剂、破胶剂、防腐剂选配,以及配方试验等方法,确定了以田菁粉为主剂,辅以交联剂、防腐剂、破胶剂等添加剂的基岩水井水力压裂专用压裂液。该压裂液具有成本低、性能稳定、环保无污染等特点。作为基岩水井水力分段压裂技术的关键技术之一,压裂液研究为实现基岩水井水力分段压裂技术整体突破奠定了基础。同时,积累了针对不同岩性岩层压裂液研究的经验,供同行参考。     

分层岸滩侧蚀坍塌过程及其水动力响应模拟

非均质岸滩广泛分布于冲积河流中,其侧蚀过程沿垂向具有分层特点。基于全三维水沙模型及河岸侧蚀坍塌力学模式,提出动态网格跟踪技术,构建了非均质岸滩侧蚀沿垂向差异的三维动力学模拟方法。以连续弯道概化水槽为例,模拟分析了非均质河岸侧蚀过程中三维水流结构的响应特征。研究结果表明:坡脚冲刷后,底部主流向凹岸偏移,在已有弯道环流的基础上,于坡脚处出现一反向次生流;上部粘性土层坍塌后,崩塌土体堆积于坡脚处,上部主流明显左偏,下部次生流消失;随着坡脚堆积体的冲刷搬运,下部主流进一步向凹岸偏移;如此循环,主流不断向凹岸偏移,致使岸坡持续崩退、河道摆动。     

宁深1井深井高温钻井液技术

针对麻黄山西部区块深部地层特点及难点,在室内优选抗高温钻井液体系,并对该体系进行性能优化研究,逐步改善其抗温、抗污染能力,并引入SPC-220与磺化处理剂发生高温交联,进一步增强体系的抗盐污染能力。宁深1井现场应用证明,该抗温钻井液体系性能稳定,对井下复杂情况的处理及顺利钻达目的层起到了关键作用。     

Evaluation of land subsidence by considering underground structures that penetrate the aquifers of Shanghai, China

Underground structures that penetrate into aquifers can cause groundwater-level drawdown and land subsidence. Numerical analyses, based on a three-dimensional (3-D) groundwater flow model incorporated with a 1-D consolidation model, have been conducted to assess the behaviour of seepage and effect on subsidence by considering underground structures in the multi-aquifer?Caquitard system of Shanghai, China. Two extreme scenarios were examined: (1) distributed underground structures, and (2) concentrated underground structures around the heavily urbanized area. In the first scenario, the aquifer with underground structures was substituted with another material that possessed a lower hydraulic conductivity, established using the effective-medium theory; when the ratio of the volume of the underground structures to that of selected aquifer layers??(1) low-pressure partially-confined aquifer (Aq02), (2) the first confined aquifer (AqI), and (3) the second confined aquifer (AqII)??increases by 10?%, subsidence increases by about 3, 3 and 32?%, respectively. In the second scenario, part of the aquifer material was directly replaced by the structure material (very low hydraulic conductivity). In this situation, when the ratio of the volume of the underground structure to the volume of aquifers Aq02, AqI or AqII increases by 10?%, subsidence increases by about 5, 8 or 20?%, respectively.     

基坑土体卸荷平面应变试验离散元数值分析

对基坑开挖影响范围内土体的应力路径进行平面应变试验离散元数值模拟,以研究结构性与卸荷形式对坑周土体宏微观力学特性的影响。首先,将一个描述土颗粒间胶结效应的简单三维胶结接触模型植入三维离散元软件PFC3D;其次,对初始K0固结状态的重塑土、结构性土试样分别进行常规三轴以及平面应变条件下4种不同卸荷应力路径的离散元模拟;最后,对经历不同卸荷形式的坑底土体单元进行再加荷模拟。模拟结果表明,在卸荷过程中,被动区土体峰值强度以及破坏时竖向应变随卸荷比增大而增大,且其强度小于主动区土体强度;在卸荷、再加荷过程中,被动区土体峰值强度随卸荷比增大而增大,但均小于不卸荷而直接加荷条件下的峰值强度;由于结构性的存在,土体由应变硬化向应变软化过渡,且强度增长;结构性与卸荷形式显著影响土体体积改变。在微观尺度,增大卸荷比或结构性均会增大垂直大主应力方向的平面上的法向接触力,进而提高其强度。     

Three-dimensional seismic modelling of crustal structure in the TESZ region based on POLONAISE''97 data

This paper reports the results of 3-D tomographic modelling of crustal structure in the Trans European Suture Zone region (TESZ) of Poland, eastern Germany and Lithuania. The data are the product of a large-scale seismic experiment POLONAISE'97, which was carried out in 1997. This experiment was designed to provide some 3-D coverage. The TESZ forms the boundary between the Precambrian crustal terranes of the East European Craton (EEC) and the younger Phanerozoic terranes to the southwest. The 3-D results generally confirm the earth models derived by earlier 2-D analyses, but also add some important details as well as a 3-D perspective on the structure. The velocity model obtained shows substantial horizontal variations of crustal structure across the study area. Seismic modelling shows low (<6.1 km/s) velocities suggesting the presence of sedimentary rocks down to a depth of about 20 km in the Polish basin. The shape of the basin in the vicinity of the profile P4 shows significant asymmetry. Three-dimensional modelling also allowed tracing of horizontal irregularities of the basin shape as well as variations of the Moho depth not only along profiles, but also between them. The slice between P2 and P4 profiles shows about 10-km variations of the Moho over a 100-km interval. The crustal thickness varies from about 30 km in SW, beneath the Palaeozoic platform, to about 42 km beneath East European Craton in NE. High seismic velocities of about 6.6 km/s were found in the depth range 2–10 km, which coincides with K trzyn anorthosite massif. The results of this 3-D seismic modelling of the POLONAISE'97 data will ultimately be supplemented by inversion of seismic data from previous experiments.     

基于Surpac的铜陵新桥矿床露天开采境界优化

矿床的境界优化就是要设计一个最为接近理想状态的模型,使矿山企业利润最大化,在满足经济和边坡角几何约束的条件下,设计一个最终开采境界.基于三维地质矿业软件,可以将三维可视化技术与矿床的后期开采、生产进度编排进行紧密的结合,完成矿体形态与工程实体的衔接,其不同于传统境界优化的方法,可以在三维空间内进行境界优化的应用和研究.本研究选取SURPAC三维地质矿业软件系统,结合铜陵新桥矿床的实际需求,基于三维数字矿山模型,使用L-G算法规范的数学逻辑结构对露天采场进行境界优化.其结果可以为扩大经济效益提供详实的数据基础,并为新桥矿床开展更为合理的开采生产安排提出合理化建议.     

功能性Fe3O4磁纳米粒子的合成

本研究以PNIPAM(聚N-异丙基丙烯酰胺)为单体,先制备出来Fe3O4@SiO2纳米颗粒,再与DMP(十二烷基三硫代碳酸酯)链转移剂进行酯化反应,制备的产物作为新的链转移剂,在偶氮二异丁腈为引发剂的条件下,利用可逆加成-断裂链转移自由基聚合(RAFT)活性聚合法制备温度响应性磁纳米粒子。通过红外光谱法、核磁共振法对聚合物的结构进行表征,谱图表明成功地合成出所需的产物。通过扫描电镜对其进行分析,所得到的Fe3O4@SiO2-PNIPAM聚合物纳米颗粒分布比较均匀。     

A spatially-explicit approach for estimating carrying capacity: An application for the Atlantic menhaden (Brevoortia tyrannus) in Chesapeake Bay

A spatially-explicit methodology was developed for estimating system carrying capacities of fish stocks, and used to estimate the seasonal and spatial patterns of carrying capacity of Chesapeake Bay for Atlantic menhaden (Brevoortia tyrannus). We used a spatially-explicit three-dimensional (3-D) model that divided the heterogeneous habitat of Chesapeake Bay into over 4,000 cubes. Each cube represented a volume of water that was characterized by a specific set of environmental variables (phytoplankton biomass, temperature, and dissolved oxygen) driven by the 3-D water quality model. Foraging and bioenergetics models transformed the environmental variables into measures of potential growth rates of menhaden. Potential carrying capacity of menhaden was estimated as a function of phytoplankton production, menhaden consumption rate, and potential growth rate, combining phytoplankton production, thermal habitat, and menhaden physiology into one ecological value that is a measure of habitat quality from the perspective of the fish. Seasonal analysis of the Chesapeake Bay carrying capacity for Atlantic menhaden suggested two bottleneck periods: one in early June and a second during the fall. The bottleneck in carrying capacity was at about 10 billion age-0 fish. Annual recruitment of age-0 menhaden for the entire Atlantic coast of the U.S. ranged from 1.2–18.6 billion fish between 1955 and 1986. It appears that carrying capacity of, Chesapeake Bay does not limit the coastwide production of young menhaden. Any conditions such as nutrient reduction strategies, further eutrophication, or global climatic warming, that may influence the carrying capacity during the fall or early June periods, may ultimately alter coastwide abundance of menhaden through changes in Chesapeake Bay carrying capacity.     

微凝胶颗粒水分散液体系在多孔介质中的驱替机理

储层孔隙结构的非均质性导致水驱不均,不同大小孔隙（喉）之间形成优势渗流流动.在水驱开发中后期,剩余油高度分散在储层孔渗系统中难以启动,如何对孔隙尺度的水驱优势流动进行抑制的同时又确保不堵塞油流通道,使剩余油被高效采出,是当前提高石油采收率技术基础研究的主要方向.制作微观仿真储层孔隙结构与尺度的非均质性物理模型,开展了连续相驱替流体（聚合物溶液、交联聚合物凝胶）和微纳米柔性微凝胶颗粒水分散体系驱油机理的对比实验.实验表明,作为连续相的传统聚合物溶液依靠粘度无区分地增加大小孔隙中的流动阻力,从而赋予低渗层区小孔隙中的剩余油以驱动力,将这些剩余油携带采出,当粘度过大时,甚至难以启动剩余油;微凝胶颗粒分散液作为低粘水分散流体,其中的凝胶颗粒优先进入大孔隙,暂堵在喉道处并抑制相对大孔隙中的流动,同时注入水转向进入相对小的孔隙,将其中的剩余油活塞式推出,该过程在空间和时间上是不断重复的.本文从流度调整的角度对实验结果进行了分析,结果表明传统的连续相驱替流体是依靠提升注入水的粘度实现流度的调整,而微凝胶颗粒水分散体系是通过降低注入水的相对渗透率,并相对提高油相渗透率,从而实现对流度的高效调整.