Palynology in a polar desert, eastern North Greenland

A pollen diagram from a lake in a polar desert in eastern North Greenland records the regional vegetation history back to c. 7,000 years calBP (6,000 years convBP) in this extreme environment, which presents the coldest thermal regime where vascular plants can grow. The diagram shows that polar desert developed from sparse high arctic tundra at c. 4,300 years calBP (3,900 years convBP), owing to reduced summer heat. Also adjacent parts of high arctic Greenland, Canada and Svalbard suffered environmental decline, and polar deserts - presently restricted to a narrow fringe of land at the shores of the Arctic Ocean - were even more restricted before this time. Like other arctic vegetation types, polar desert is highly sensitive to summer temperatures, and its southern limit coincides with the isotherm for mean July temperatures of 3.5C. A comparison with the Northwest European ice-age pollen record shows no evidence of summers as cold as those now prevailing in the extreme north, and the results support the contention that the present Arctic and the ice-age mid-latitude environments are not identical.     

Ultraviolet radiation exposure of a high arctic lake in Svalbard during the Holocene

Long‐term fluctuations in lake‐water optical properties were examined using a Holocene sediment sequence and multi‐proxy palaeolimnological approach in Lake Einstaken, Nordaustlandet, Svalbard. UV‐absorbance of sedimentary cladoceran remains provided information on underwater UV exposure and changes in lake‐catchment coupling processes were inferred from sediment geochemistry. In addition, aquatic community succession was used as an indicator for lake‐water bio‐optical properties and a Holocene record of sun activity (sunspots) was utilized to evaluate long‐term solar forcing. The results indicated that the UV‐absorbance of cladoceran remains was highest (i.e. maximum UV‐induced pigmentation) for a short period during the early Holocene and for several millennia during the mid‐Holocene. Sun activity was high during these time intervals, probably impacting the UV intensities, but it is probable that the amount of UV‐attenuating compounds (e.g. dissolved organic carbon (DOC)) also significantly affected the underwater UV environment and were low during high UV exposure. Benthic autotrophic communities also responded to the millennial changes in lake‐water optical properties. UV‐resistant Nostoc cyanobacterial colonies were established during the mid‐Holocene, indicative of high underwater UV intensities, and Fontinalis mosses thrived during the early Holocene, indicating a highly transparent water column. The results further suggested that underwater UV exposure decreased during the late Holocene, which is probably attributable to increased DOC and decreased solar forcing. Owing to the location of Lake Einstaken and its catchment in the periglacial barren landscape of the polar desert, the fluctuations of bio‐optical lake‐water properties were apparently forced by postglacial environmental processes and Holocene climate development. These factors controlled sea shoreline proximity, water discharge, ice‐cover duration and littoral‐benthic primary production and further affected the underwater UV environment. Although the role of solar forcing cannot be underestimated, the current record emphasizes the role of climate‐mediated lake‐catchment interactions in impacting bio‐optical properties and UV exposure of high arctic aquatic systems.     

Heightened sensitivity of a poorly buffered high arctic lake to late-Holocene climatic change

A diatom-based paleolimnological investigation was conducted on late Holocene sediments from a poorly buffered lake, informally named “Rock Basin Lake”, on Ellesmere Island, Arctic Canada. The fossil diatom record is unlike any other obtained thus far from high arctic regions, exhibiting dynamic assemblage shifts over the entire 3300 yr sedimentary record. Multiple proxies (i.e., diatoms, pH reconstructions, biogenic silica, C/N ratios, total organic carbon) appear to sensitively track rapid limnological changes, which are associated with distinct climate intervals as inferred from other regional proxy records. The highly responsive nature of the diatom assemblages in Rock Basin Lake, relative to those recorded from nearby alkaline sites, appears to be related to this lake's limited ability to buffer changes in pH. The dynamic species responses suggest that the diatoms in Rock Basin Lake are faithfully tracking climatic changes, and that low-alkalinity lakes may provide the most sensitive diatom-based paleolimnological records from high arctic regions.     

Occurrence and significance of pyrochlorins in a lake sediment

The occurrence of pyrochlorophyll a and pyrophaeophytins a and b in the bottom sediments of a small eutrophic lake (Priest Pot, Cumbria, U.K.) is reported on the basis of HPLC coinjection with standards. Assignment of pyrophaeophytins a and b was confirmed by FAB mass spectrometric and nuclear magnetic resonance studies of the isolated components and comparison with standards. The co-occurrence of pyrochlorins with their non-pyro counterparts, even in a surface sediment, shows that decarbomethoxylation can occur at the very earliest stages of the Treibs diagenetic pathway linking the chlorophylls and sedimentary porphyrins.     

Revision of the early Holocene lake sediment based chronology and event stratigraphy on Hochstetter Forland, NE Greenland

The previously established and often debated lake sediment based chronology and event stratigraphy from Hochstetter Forland, NE Greenland, has been re-examined. These new studies show that the last deglaciation of the coastal area is several thousand years younger than previously described. The main reason behind the difference is the fact that the older chronology was based on ¹⁴C datings of bulk sediment samples, which are now shown to contain enough coal fragments to produce erroneous ages. The re-examination was performed on sediments from two lakes located within the Nanok moraine system: one is situated at or slightly above the marine limit around 65 m. the other at 21–22 m a.s.l. The combined stratigraphy from the two lakes shows that the area was deglaciated before 9000 BP, after which followed deposition of glaciomarine sediments, fining upwards. The first vegetation seems to have been dominated by grasses, Lycopodium and Polypodiaceae. At c . 8000 BP the limnic production increased significantly and a pioneer vegetation characterized the area. At this time the 'Artemisia' grains appear. A short but distinct climatic cooling occurs at c . 7500 BP causing a significant drop in lake productivity and possibly also producing coarser sediments in the (glacio)marine environment. About 200 years later the lake productivity again increased, very rapidly, and the marine sediments became finer and more rich in molluscs, as a response to the beginning of the climatic optimum. Because of the time-lag between climate and vegetation response it took another 300 years before Betulci nana immigrated, at the same time as the 'Artemisia' grains disappeared, and another several hundred years before a real dwarf-shrub vegetation developed in these parts of Hochstetter Forland. Before the lower lake was isolated from the sea at c . 6000 BP, coarse wave-washed sediments, followed by a typical isolation sequence, were deposited in it.     

folding and slumping in a layered gabbro

The layered gabbroic intrusion of Sarqata qaqa, Ubekendt Ejland, West Greenland contains numerous xenoliths of thermally metamorphosed picrite-basalt. Folding and slumping of the layering occurs adjacent to some of these blocks. It is postulated that the structures were formed by sloped lava xenoliths hitting the unconsolidated layers of crystals forming the floor of the magma chamber during the cooling history of the intrusion. The settling velocities of the xenoliths, and thickness and viscosity of the crystal mush are estimated and discussed.     

Subglacial to proglacial sediment transition in a shallow ice-contact lake

A complete subglacial to glacial-lacustrine facies transition is described from a temporary exposure in the Lake Michigan bluffs of southeastern Wisconsin. This transition occurs where a Late Woodfordian terminal moraine intersects the bluff line and grades from basal meltout till to chaotic diamicton to rhythmites over an abrupt 90 m lateral distance. The boundary of the subglacial meltout deposits is marked by an abrupt increase in pebbles and cobbles, which cluster at specific horizons, producing an incipient stratification. Thereafter, the diamicton develops contorted flow structures with progressive segregation into coarse and fine-grained fractions, ultimately into well-stratified rhythmites.     

Coarse-grained sediment gravity flow facies in a large supraglacial lake

Near Williams Lake, in the central interior of British Columbia, the Fraser River exposes long sections of late Pleistocene glaciolacustrine sediments selectively preserved within a bedrock trough. The dominant facies types are thick, normally graded gravels and sands that occupy steeply dipping multistorey channels up to 300 m wide and several tens of metres deep. Channels appear to have been simultaneously cut and filled by high density turbidity currents in a glacial lake floored by stagnant ice. Fining upward sediment gravity flow sequences up to 50 m thick may be the product of quasi-continuous ‘surging’ turbidity flows triggered by catastrophic meltwater discharges into the trough or retrogressive failure of ice-cored sediments. Large-scale post-depositional deformation structures, such as synclinal folds, normal faults, sedimentary dyke swarms and dewatering structures, record gravitational foundering of sediment and pore-water expulsion caused by the melt of underlying glacier ice. Melting of buried ice masses along the floor of the trough appears to have controlled the flow paths of turbidity currents by producing sub-basins within the overlying sediment pile. An idealized model of ‘supraglacial’ lacustrine sedimentation is developed that may be applicable to other glaciated areas with similar bedrock topography.     

Diamictic sediments within high Arctic lake sediment cores: evidence for lake ice rafting along the lateral glacial margin

Sediment cores from six small lake basins in the Canadian high Arctic reveal a gravel‐rich (≤30% by weight) to gravel‐poor (≥2%) diamict facies underlying massive, post‐glacial, clayey silt. Ten other lakes contain a second diamict facies within what are interpreted to be glaciolacustrine sedimentary assemblages. The sedimentology, clast fabrics and fossil remains (diatoms, ostracodes and chironomid head capsules) within both diamict facies suggest that these deposits are not tills. Clast fabrics yielded low S₁ (0·41–0·57) and high S₃ (0·09–0·22) eigenvalues, placing them within the range of ice‐rafted diamictons and glacigenic sediment flows. The high percentage of clast dip angles >45° (15–61%), random clast azimuth and lower diamict contacts conformable to underlying current‐bedded sediment favours an origin as a rain‐out or settling deposit. Samples of the matrix and scrapings of clasts from the diamicts revealed a diatom assemblage dominated by littoral and planktonic forms, such as are found in the littoral regions of the lakes today. This contrasts sharply with the assemblages within the overlying clayey silt, in which benthic forms predominate. Clasts are thus interpreted to have been rafted from the littoral areas of the lake. The process proposed to explain this is rafting by the lake ice cover in a glacial‐marginal environment. Early season meltwater, impounded along the lateral margin of retreating cold‐based glaciers, would buoyantly lift the lake ice cover and any adfrozen lake sediment. Higher lake levels and increased areal extent of seasonal freeze‐on between the lake ice cover and the lake bed would allow the redeposition of littoral sediments to the benthic regions through greater lateral shifting of the ice cover as it broke up. Incision by meltwater streams into the lateral glacial margins would later isolate the lake, allowing seasonal warming of lake water, enough to support the growth and maturation of the ostracode and chironomid species found as fossils within the diamicts.     

Early diagenetic influences on iron transformations in a freshwater lake sediment

Iron transformations in a calcium carbonate rich fresh-water sediment were studied by analyzing the relevant constituents of both interstitial water and solid matter. Analysis of interstitial water shows that the observed redox sequence NO⁻₃/NH⁺₄, MnO₂/Mn(II), FeOOH/Fe(II), SO²⁻₄/S(−II) is roughly in agreement with that predicted by the Gibbs Free Energy for the corresponding reactions. In contrast to marine sediments, these redox transitions occur in the uppermost sediments, i.e., at depths of 0–4 cm.

Deeper in the sedimentary sequence, the depth profile for dissolved iron exhibits a steady non-linear increase up to 400 μmol dm⁻³. In this anoxic zone, according to thermodynamic predictions, iron (II)-minerals such as iron sulfide, siderite, and vivianite should precipitate while Fe(III) oxides should be completely dissolved. However, microscopic analysis showed that Fe(III) oxides were present throughout the studied sediment. Furthermore, scanning electron microscope/energy dispersive spectroscopy analysis suggests the presence of iron sulfide could be verified but not that of siderite or vivianite. These observations indicate kinetic control of iron transformations.

We have investigated the importance of kinetic control of iron distribution in anoxic sediments using a diagenetic model for dissolved iron(II). A rough estimate of time scales for dissolution and precipitation rates was made by imposing limiting boundary conditions. Using the calculated rate constant, we established that more than 1000 years would be required for the complete dissolution of Fe(III) oxides, which is agreement with our observations and experimental data from the literature. Calculated precipitation rates of Fe(II) for a given mineral phase such as siderite yield a maximum value of 3 μg_(FeCO3) g⁻¹_{(dry sediment)} yr⁻¹. Such low rates would explain the absence of siderite and vivianite.

Finally, it can be inferred from the Mn_T/Fe_T ratio in the sediments that this ratio depends on the redox conditions of the sediment-water interface at the time of deposition. Thus, this ratio can be used as “paleo-redox indicator” in lacustrine sediments.     

Anthropogenic versus climatic control in a high-resolution 1500-year chironomid stratigraphy from a southwestern Greenland lake

We performed a high-resolution study of chironomid assemblages in a sediment core retrieved from Lake Igaliku in southern Greenland. The well-dated core is located within the former Norse Eastern Settlement and covered the last 1500 yr. The comparison of chironomid stratigraphy (PCA axis scores) with instrumental temperature data, land use history and organic matter in the sediment over the last 140 yr suggested that the primary changes in chironomid fauna in 1988 ± 2 yr were driven by the shift to modern agriculture in the catchment. This unprecedented change in chironomid fauna was most likely triggered by a shift in in-lake processes. Within the instrumental period, subtle variations in the chironomid assemblages that occurred before 1988 ± 2 yr were significantly correlated with summer temperatures even in times of traditional extensive sheep farming in the catchment. The relevance of the chironomid-derived climate signal over the last 1500 yr was supported by its good concordance with previous studies in west Greenland and in the Arctic. The chironomid assemblage therefore appeared to be a valuable proxy for climate changes within the Norse colony area. Synchronous changes in Norse diet and chironomid-reconstructed climate give new insights into the interplay of Norse society with climate.     

Holocene climate changes in southern Greenland: evidence from lake sediments

A Holocene lake sediment record is presented from Lake N14 situated on Angissoq Island 15 km off the main coast of southern Greenland. The palaeoclimatic development has been interpreted on the basis of flux and percentage content of biogenic silica, clastic material, organic material and sulphur as well as sedimentation rate, moss content and magnetic susceptibility. A total of 43 radiocarbon dates has ensured a reliable chronology. It is argued that varying sediment composition mainly reflects changing precipitation. By analogy with the present meteorological conditions in southern Greenland, Holocene climate development is inferred. Between 11 550 and 9300 cal. yr BP temperature and precipitation increase markedly, but this period is climatically unstable. From 9300 yr BP conditions become more stable and a Holocene climatic optimum, characterised by warm and humid conditions, is observed from 8000 to 5000 cal. yr BP. From 4700 cal. yr BP the first signs of a climatic deterioration are observed, and from 3700 cal. yr BP the climate has become more dry and cold. Superimposed on the climatic long‐term trend is climate variability on a centennial time‐scale that increases in amplitude after 3700 cal. yr BP. A climatic scenario related to the strength and position of the Greenland high‐pressure cell and the Iceland low‐pressure cell is proposed to explain the Holocene centennial climate variability. A comparison of the Lake N14 record with a terrestrial as well as a marine record from the eastern North Atlantic Ocean suggests that the centennial climate variability was uniform over large areas at certain times. Copyright © 2004 John Wiley & Sons, Ltd.     

Iron in a post-glacial lake sediment core; a Mössbauer effect study

The distribution of iron in a 6-m core of post-glacial sediment from an oligotrophic lake (Connistonwater, England) was determined, principally by Mossbauer spectroscopy on dried samples. The immediate post-glacial deposits contain 4.8 wt. % of iron, with a Fe²⁺; Fe³⁺ ratio ～- 4. The iron there is predominantly in the form of chlorite, but there are small amounts in hematite and illite. The distribution of iron is different, and very variable in the recent sediments (~ < 13,000 BP), which contain 25–35 per cent organic matter and 5.2 wt. % of iron relative to the inorganic fraction. Typically half the iron is present there as chlorite, and the rest is ferric, mostly in the form of an amorphous gel which is also present in undried samples. To explain the observed ferrous:ferric profile, it is proposed that the latter includes iron which was once mobile, having been leached from the Fe²⁺-bearing clays under reducing conditions in the soils of the drainage basin, or in the sediment itself. It was subsequently precipitated as ferric hydroxide on contact with the oxic lake water. In contrast, the ferrous iron in the sediments is immobile iron, which remained locked in the chlorite phase of the clay particles as they were carried from soil to sediment intact.All the sediments are rather inhomogeneous. Chlorite, and especially hematite, are mechanically concentrated in pink varves in the immediate post-glacial deposits. In the partly inorganic sediments, the concentration of ferrous iron (chlorite) is approximately uniform, but the ferric content may differ by a factor of five between regions only a few millimeters apart.     

Organic matter mineralization in sediment of a coastal freshwater lake and response to salinization

Solid phase and pore water chemical data collected in a sediment of the Haringvliet Lake are interpreted using a multi-component reactive transport model. This freshwater lake, which was formed as the result of a river impoundment along the southwestern coast of the Netherlands, is currently targeted for restoration of estuarine conditions. The model is used to assess the present-day biogeochemical dynamics in the sediment, and to forecast possible changes in organic carbon mineralization pathways and associated redox reactions upon salinization of the bottom waters. Model results indicate that oxic degradation (55%), denitrification (21%), and sulfate reduction (17%) are currently the main organic carbon degradation pathways in the upper 30 cm of sediment. Unlike in many other freshwater sediments, methanogenesis is a relatively minor carbon mineralization pathway (5%), because of significant supply of soluble electron acceptors from the well-mixed bottom waters. Although ascorbate-reducible Fe(III) mineral phases are present throughout the upper 30 cm of sediment, the contribution of dissimilatory iron reduction to overall sediment metabolism is negligible. Sensitivity analyses show that bioirrigation and bioturbation are important processes controlling the distribution of organic carbon degradation over the different pathways. Model simulations indicate that sulfate reduction would rapidly suppress methanogenesis upon seawater intrusion in the Haringvliet, and could lead to significant changes in the sediment’s solid-state iron speciation. The changes in Fe speciation would take place on time-scales of 20-100 years.     

Evidence of climatic change from oxygen and carbon isotope variations in sediments of a small arctic lake,Canada

Radiocarbon dating of the organic-rich sediments of Lake Illisarvik in the outer Mackenzie Delta indicates that formation of the lake occurred approximately 9500yr BP, with maximum expansion around 6000 yr BP. Sedimentation rates have remained relatively constant at an average of 0.3mm/yr. ¹³C results on biogenic and inorganic carbonates and organics indicate a change from dominantly terrestrial organics (?27 to ?28%₀) to submerged aquatic vegetation or plankton (?18 to ?23%₀) upon formation of the lake (9500yr BP), and a dramatic return to dominantly terrestrial organics at 5800yr BP (δ¹³C = ?27 to ?30%₀). This latter shift is accompanied by a drastic reduction in the macroflora and fauna populations. ¹⁸O results suggest that a warmer climate than today existed prior to the shift at 5800yr BP.     

Perylene dominance in sediments from a subtropical high mountain lake

Perylene formation in sediments of water bodies has been a topic of continual discussion and debate. We report the concentration and age (ca. 660 yr) profiles of perylene and other polycyclic aromatic hydrocarbons (PAHs) in a sediment core from Emerald Peak Lake, the largest high mountain lake in Taiwan. Perylene is dominant at all depths of the sediment (ranging from 60% to 98% of total PAHs), a feature not commonly found in other sediments. The concentration profile of perylene with sediment age fits a first order kinetic model, which might be an indication of a steady sedimentary environment.