利用粉煤灰制备多孔氧化硅的实验

利用相分离原理,以粉煤灰经硅铝分离后所得的硅酸凝胶为原料,选用聚乙烯醇为造孔剂,硝酸为催化剂,成功地制备了多孔氧化硅。实验结果表明:制备的多孔氧化硅的孔道发育良好,含有三级孔道。扫描电镜分析显示:大孔孔径为1～2 μm,比表面积为12.03 m²/g,这与实际应用的硅藻土助滤剂制品大致相当。对实验制品在啤酒液中的稳定性实验结果显示:多孔氧化硅制品在浸泡于啤酒过程中几乎没有Ca²⁺、Fe³⁺离子溶出,浸泡后的啤酒液的pH值基本不变。上述结果表明:实验制备的多孔氧化硅制品作为硅藻土助滤剂的替代品具有良好的实际应用前景。     

硅藻土在一些高附加值产品中的应用及其基础研究

硅藻土是重要的非金属矿物材料。本文综述了它在具有高附加值的功能材料领域,包括助滤剂、吸附剂、载体中的应用,并从这些产品对原料的要求的角度,探讨了有关硅藻土的成分、结构、表面酸性、羟基结构、界面反应性,以及提纯处理的研究现状。     

Environmental and depositional characteristics of diatomite deposit, Alayunt Neogene Basin (Kutahya), West Anatolia, Turkey

This paper describes the geological-depositional and environmental characteristics of diatomite. The diatomite deposit is situated in the southern part of the Alayunt (Kutahya) Basin. Samples of 18 diatomites and 12 host rocks were collected from four sedimentary profiles in the spring season. Basement rocks are Paleozoic-aged metamorphic rocks (schist, phyllite, quartzite, etc.) and Mesozoic-aged ophiolitic and complex rocks. Host rocks are rhyodacitic–rhyolitic tuffite, volcanic glass. Diatomite is composed of Upper Miocene–Upper Pliocene-aged diatom species. Diatomite shows layer morphology and lies on volcanic glass layer. XRD characteristic peaks of diatomite show that it comprises dominantly of Opal-A silica, whereas volcanic glass has Opal-CT constituent. SEM and NPM photomicrographs indicate that diatomites are dominantly composed of benthic freshwater diatom species, such as Pinnularia microstauron, Pinnularia lundii, Pinnularia subrostrata, Pinnularia brevicostata, Pinnularia tenuis, Pinnularia sp., Navicula eligensis, Fragilaria construens, Mastogloia braunii Grunow, Melosira varians Agardh, Surirella capronii Brébisson, Cymbella lanceoloata, Amphora venata, Gomphonema germainii, Gomphonema angustatum and Rhapalodia gibba. These species are general indicators of shallow paleolake environment and cool climate conditions. Due to the fluvial currents and climatic conditions; lake water levels, temperature and nutrient content fluctuated through the time. Chemical data obtained from 18 diatomite samples show that while silica is the bodybuilding material for diatomite (over 89 % SiO₂), Al, Mg and Fe contents of diatomite samples might be derived from clastic materials. The concentration of Al, Mg and Fe decreases toward the lake center. Diatom genera, sedimentary profile sections and mineralogic data suggest that diatomite deposited in lacustrine-type freshwater shallow lake is associated with Upper Miocene-aged extension tectonics. Physical and filtration tests along with environmental characteristics of diatomite suggest that calcined diatomite can be used for waste treatment processes in the filter aid industry.     

吉林省白山市硅藻土矿产资源形势分析

随着社会经济的快速发展,我国对各种资源的需求日益增大,硅藻土就是很重要的一种矿产资源,作为生物成因的硅质沉积岩,其用途十分广泛,主要作助滤剂和功能填料。吉林省白山市的硅藻土矿产资源无论是在规模上还是在质量上都位于世界前列,文章从白山市的硅藻土资源的现状入手,阐述并分析其存在问题,并对硅藻土矿产勘查和开发提出建议,在此基...     

Effects of Zeolitization of Diatomite on Benzene Adsorption

Diatomite, a type of biogenic mineral, is sourced from deposition and accumulation of diatom shell. Diatom shells are mainly composed of amorphous hydrated silica, which is categorized as non-crystalline opal-A according to the mineralogical classification. Diatomite has a characteristic macro/mesoporous structure and unique physical and chemical capabilities, such as high thermal stability, strong acid resistance, and high adsorption capacity, and thus is widely used as the filter aid, catalytic support, and adsorbent. However, the low surface area of diatomite shows disadvantage in adsorption. Moreover, the hydrophilic surface which contains abundant silanols is usually covered by adsorbed water, resulting in that the adsorption sites of diatomite were occupied and the adsorption capacity of hydrophobic guests decreased. In previous reports, zeolitization was employed to increase the specific surface area (SBET) and porosity of diatomite. However, the hydrophilic property of diatomite was not changed after zeolitization. It is due to that the zeolite formed on the surface area of diatomite contained some aluminum in its structure, which was highly hydrophilic. Therefore, it is significantly interesting to prepare the zeolitized diatomite with both large SBET and high hydrophobicity.     

Filtration and Clogging Behavior of Geotextiles with Roorkee Soils

Geotextile filters are rapidly replacing graded granular filters as the standard of practice in geotechnical design. The objective of the present study is to predict the behavior of the geotextile filter for the locally (Roorkee—India) available soils using three different geotextiles (two nonwoven and one woven). Nonwoven geotextiles are commonly used in filtration applications. This paper evaluates the long-term performance of two needle-punched nonwoven geotextiles and one woven geotextile. Filtration tests on soil–geotextile filter systems were conducted in the laboratory in order to evaluate the filtration and clogging behavior. Laboratory test program, include evaluation of performance of two different nonwoven and one woven geotextile filters in combination with locally available Solani River Sand and Clayey Soil. The paper describes the concept and details of the Fine Fraction Filtration (F³) test and presents data on three different geotextiles, which were evaluated using three different soil types. It is deduced that in all filtration applications, the non-woven geotextile would perform better than the woven geotextile.     

白色硅藻土微观结构特征定量研究

硅藻土常常呈现白色、黄色、黑色等颜色,其中以白色硅藻土较为特殊,遇水后其强度明显降低.为了掌握白色硅藻土的工程特性,必须研究白色硅藻土的微观结构特征.本文以白色硅藻土为研究对象,通过扫描电镜试验,以数值化的形式展现其孔隙特征,从微观角度分析白色硅藻土的整体形貌,同时对白色硅藻土的微观结构进行量化分析,通过二值化处理以及...     

通用助滤剂及其开发研究现状

助滤剂通常是以非金属为基本原料加工制成的粉末状产品。在工业生产过滤过程中,它是一种用来帮助被滤液体提高滤速、改善澄清度的助滤材料,广泛用于酒类、食品、化工、炼油、医药、环保、污水处理等工业部门。许多物质经加工后可以用助滤剂,如硅藻土、珍珠岩、纤维素、石棉纤维、碳粉、活性炭、滤棉、细粒硅胶、细砂和粉状离子交换树脂等。其中,硅藻土和珍珠岩助滤剂的用途最为广泛,用量也最大,是常见的通用助滤剂;纤维素、石棉、活性碳等也有它们特殊性能,为常见的辅助用助滤剂。１　硅藻土助滤剂近年来,硅藻土助滤剂的消耗量一直…     

硅藻土的矿物组合和电子顺磁共振研究

该文主要论述不同硅藻土矿床的矿物组合和电子顺磁共振测试结果,并探讨硅藻土中铁的存在形式和硅藻土的加热相变。     

重塑硅藻土抗剪强度的环剪试验研究

硅藻土是一种强结构性土,具有密度小、孔隙大、干燥土块吸水率高等特点。天然硅藻土的抗剪强度大,但在外界扰动或风化后,结构性强度丧失,易发生滑坡等斜坡变形破坏现象,因此,研究其在大变形下的力学性质很有必要。利用环剪仪可以研究土体在较大剪切位移条件下抗剪强度变化规律,对重塑硅藻土进行环剪试验研究,得到了不同竖向压力下的应力-位移曲线,认为重塑硅藻土为典型的应变软化型土;根据测试结果得到了重塑硅藻土的抗剪强度和残余强度,并从物质组成和微观结构特征方面对重塑硅藻土的力学性质进行了分析,为硅藻土滑坡的成因分析和灾害防治提供了依据。     

Discrete numerical modeling of particle transport in granular filters

Granular filters are an essential component in earth dams to protect the dam core from seepage erosion. This paper uses the particle flow method (PFM) to study the mechanism of particle transport in a base soil–filter system. The distributions of the eroded base-soil particles in different filters are traced and analyzed. The eroded mass and intruding depth of the eroded particles into the filters are obtained under different times and hydraulic gradients. The simulation results show that the eroded mass and intruding depth of the base-soil particles into the filter are related to the representative particle size ratio of the base soil to the filter, hydraulic gradient and erosion time. The numerical predictions are also compared with the empirical filter design criterion. The results show that the particle flow model provides an effective approach for studying the filtration micro-property and the erosion mechanism in a base soil–filter system, which is useful for filter design.     

岩质边坡生态防护客土持水性与渗透性耦合作用试验研究

对于岩质边坡而言,生态边坡防护技术的关键在于植被的形成。为保证植物的生长,客土应同时具备良好的持水性 与渗透性。文章通过室内渗透实验以及蒸发实验研究了不同黄土、硅藻土、秸秆配比条件下渗透性及持水性的耦合关系。 结果表明硅藻土与秸秆的添加能有效降低混合土密度,有利于减小混合物的自重应力、提高边坡稳定性。硅藻土和秸秆单 独掺入时混合土的渗透系数呈指数形式增加,在同等材料用量时,硅藻土对于渗透系数的提高更有效,但当硅藻土和秸秆 以相近的比例掺入时,彼此之间没有形成相互增益,而是此消彼长。硅藻土及秸秆的添加均能增加混合土的持水性,但总 体上使用硅藻土的效果优于秸秆。添加硅藻土、秸秆能够延长土壤的定常蒸发阶段,极大提高了黄土的抗旱能力。     

岩质边坡生态防护客土持水性与渗透性耦合作用试验研究

对于岩质边坡而言，生态边坡防护技术的关键在于植被的形成。为保证植物的生长，客土应同时具备良好的持水性 与渗透性。文章通过室内渗透实验以及蒸发实验研究了不同黄土、硅藻土、秸秆配比条件下渗透性及持水性的耦合关系。 结果表明硅藻土与秸秆的添加能有效降低混合土密度，有利于减小混合物的自重应力、提高边坡稳定性。硅藻土和秸秆单 独掺入时混合土的渗透系数呈指数形式增加，在同等材料用量时，硅藻土对于渗透系数的提高更有效，但当硅藻土和秸秆 以相近的比例掺入时，彼此之间没有形成相互增益，而是此消彼长。硅藻土及秸秆的添加均能增加混合土的持水性，但总 体上使用硅藻土的效果优于秸秆。添加硅藻土、秸秆能够延长土壤的定常蒸发阶段，极大提高了黄土的抗旱能力。     

A critical review on granular dam filter behaviour – from particle sizes to constriction-based design criteria

Over emphasis on tests results involving base soils with increasing coefficient of uniformity (C_u ) makes the reliability of an empirical particle-based criterion for effective filters questionable. Extra measures such as regrading of base soil are then necessary in order to capture the effectiveness of filter constriction sizes in trapping eroding fines. Recent studies which focused on the role of the sizes of filter voids on overall filtration behaviour have deployed constriction size approaches that were shown to be equally acceptable methods for distinguishing between effective and ineffective filters. This paper examines the evolution of this approach, starting from past empirical and mathematical investigations and proceeding to the eventual development of geometric-probabilistic methods with special reference to embankment dams. Models based on dominant and controlling constriction sizes are introduced, and subsequently the constriction-based retention criteria for granular filters are presented. The proposed retention criteria were verified based on extensive experimental data taken from small- and large-scale filtration tests carried out by various authors. The integration of filter compaction, porosity and C_u , together with the incorporation of analytical principles, provides alternative and rigorous design approaches that remove most limitations of the conventional particle-based criteria, thus making the models essentially more comprehensive and quantifiable.     

硅藻土-无定形碳-氧化铁三元复合体系降解三硝基甲苯的研究

煤系共伴生非金属矿产开发及综合利用难度大。本文针对先锋褐煤共伴生硅藻土高有机质、高铁的特点,提出硅藻土原矿经提纯处理后,在N2作为保护气氛下,高温煅烧形成硅藻土-无定形碳-氧化铁三元复合材料,在类Fenton体系下,去除TNT污染物的开发利用技术路线。本文考察了硅藻土处理条件、反应时间、H2O2浓度、三元复合硅藻土投加量、pH值等因素对TNT降解效能的影响。研究表明三元复合硅藻土对TNT吸附降解的最佳工艺条件为:硅藻土用量为2 g/L,H2O2(30%)4 m L/L,pH值1,反应时间2.5 h。该工艺条件下,50 mg/L TNT去除率为98%。     

极限保土状态下的反滤机制试验研究

提出了反滤系统极限保土状态的概念,分别采用4种不同孔径的钢丝编织网进行粉土反滤试验,研究反滤系统的极限保土状态。试验表明,当滤网孔径O和粉土特征粒径d85的比值等于12时,反滤系统才达到极限保土状态。极限保土状态下的反滤系统,在淹没式出流条件下,经往复水流作用26 h后改为单向水流,水力梯度从3.8逐渐增加到9.1,并在9.1的水力梯度下持续渗透453.25 h,反滤系统仍保持稳定,未发生失稳破坏;在非淹没式出流条件下,水力梯度从5.3逐渐增加到12.7期间,反滤系统保持稳定,但在维持12.7的水力梯度下持续渗透261.83 h后,反滤系统发生失稳破坏。对极限保土状态的研究有助于工程设计中更加合理地确定织物滤层孔径上限,减少淤堵。     

An investigation on dewatering kinetics of ultrafine coal

Ultrafine coal dewatering is of great importance to the coal industry due to its impacts on the handling and utilization characteristics of coal products. Commercially available filtration techniques are either ineffective or costly for dewatering of ultrafine coal to the desired moisture level of about 20%. Considerable efforts have been devoted to understanding the dewatering process and developing new technologies for applications in the coal industry. Most of the previous work on ultrafine coal filtration was focused on the final filter cake moisture and few studies have been conducted to investigate the filtration kinetics. The present investigation was undertaken to better understand the kinetics of vacuum filtration of ultrafine coal under various conditions. The filtrate weight was continuously monitored using a precise load cell during the entire filtration process. Operating parameters such as vacuum pressure and reagent conditioning time were examined for their impacts on filtration kinetics. Use of cationic and anionic flocculants showed significant improvement in filtration kinetics. Kinetic data obtained from the study were used to determine the fundamental parameters of filtration such as cake permeability, specific cake resistance, and filter medium resistance using the integrated form of the Darcy's law.     

Anoxic events during sedimentation of a Palaeogene diatomite in Denmark

A diatomite, about 60 m thick, of late Palaeocene-early Eocene age crops out in northern Jutland, Denmark. The diatomite is locally termed ‘Moler’. Frustules of marine diatoms constitute c. 65% (by weight) of the diatomite, and clay minerals, chiefly montmorillonite, make up the remainder. Slight variations in the relative supply of diatom frustules and clay minerals are preserved undisturbed in laminated diatomite, while lamination is partly destroyed by burrowing organisms in weakly laminated diatomite and obliterated by total bioturbation in structureless diatomite; these three facies alternate throughout the sequence. The presence or absence of infaunal burrowing organisms is interpreted as a record of the content of dissolved oxygen in the water above the sediment-water interface and hence of the position of the redox potential discontinuity. Interspaced in the diatomite are 179 identifiable layers of volcanic ash. These ash layers provide a means of precise lateral correlation. They show that levels of laminated diatomite may be followed throughout the basin and therefore that changes between anoxic and oxic conditions occurred simultaneously across the area. The laminated diatomites may consequently be interpreted as representing short-term anoxic events, of which twelve have been recognized.     

Micro-properties of coal aggregates: Implications on hyperbaric filtration performance for coal dewatering

The recovery of ultrafine coal can be enhanced significantly by flocculating the particles prior to dewatering. It is thus crucial to be able to quantify the effects of aggregated particles on the separation efficiency, of which they are still not fully understood. This study focused on the relationship between the micro-properties (size, structure, and strength) of flocculated coal particles and the characteristics of filter cakes obtained through hyperbaric filtration. Tools such as small angle light scattering and confocal scanning laser microscopy were used to determine the aggregate structure. The comparative bond strength of aggregates generated under different flocculation conditions was measured through a non-dimensional approach. The effects of these properties on specific cake resistance, saturation, and moisture content, as indicative of the filtration performance, were observed. It was found that flocs generated using a moderate amount of flocculant dosage (60–100 g of polymer/tonne of coal) for this ultrafine coal (97% < 35 μm) optimised the properties of dewatered filter cakes. Although cakes composed of larger and stronger aggregates with more flocculant were found to have higher porosity, the effects on specific cake resistance and cake saturation were detrimental, possibly due to the increasing proportion of intra-aggregate pores that were harder to dewater. The trend was less noticeable at low filtration pressures where most of the dewatering occurred within the larger capillaries of the inter-aggregate zones. In addition, the presence of polymer molecules was responsible in absorbing residual moisture that could not be removed through mechanical means. Through a series of tests using pre-formed filter cakes, the amount of moisture retained by the flocculant was quantified to be approximately 10.2 mg of water for every addition of 1 g of polymer/tonne of coal, calculated per 100 g of filter cake produced from hyperbaric filtration in this case.     

高速铁路硅藻土路基工程现场综合试验研究

以新建杭绍台铁路通过浙江嵊州及新昌硅藻土地区为研究背景,基于单桩静载、边坡降雨、复合地基承载性能、基床原位激振等现场试验,研究了不同桩型加固硅藻土地基的适宜性、降雨条件下硅藻土边坡变形特性和防护措施、硅藻土桩筏复合地基特性以及基床动力特性。结果表明：CFG桩、素混凝土桩及钢筋混凝土桩适用于硅藻土地基加固,而螺杆桩由于存在挤土效应、高压旋喷桩成桩效果较差不适用;干湿循环作用下硅藻土自然边坡易形成网状裂隙导致浅层稳定性不足,拱形骨架对硅藻土边坡有较好的防护效果,而锚杆框架梁由于钻孔施工易导致硅藻土软化,不适用于硅藻土边坡防护;CFG和素混凝土桩复合地基能够满足硅藻土路基变形控制要求,且素混凝土桩筏结构整体性更好;基床结构中设置毛细防排水板具有良好的防排水效果,保证了水份能够及时排出,避免对基床和硅藻土地基不利影响。