豫西南泥湖矿集区石宝沟花岗岩体的锆石U-Pb年龄、岩石地球化学及Hf同位素组成

石宝沟花岗岩体位于华北陆块南缘,主要由似斑状二长花岗岩和中细粒二长花岗岩组成,发育岩浆暗色包体。LA-ICPMS锆石U-Pb定年结果显示,似斑状二长花岗岩和中细粒二长花岗岩的成岩年龄分别为(156±1)Ma(N=15,MSWD=0.34)和(157±1)Ma(N=17,MSWD=0.10)。这些花岗岩的A/CNK=0.82～1.02,Na2O+K2O=7.61%～8.91%,K2O/Na2O=1.02～1.48,属于高钾钙碱性、准铝质-弱过铝质I型花岗岩。稀土和微量元素特征显示其富集LREE、Rb、Ba、K、Pb等大离子亲石元素,亏损HREE、P、Ti等高场强元素,具有弱的负铕异常,个别样品具有正铕异常(δEu=0.81～1.12)。似斑状二长花岗岩的锆石εHf(t)为-22.6～-8.3,tDM2为2.64～1.73Ga;中细粒二长花岗岩εHf(t)为-26.9～-12.4,tDM2为2.91～1.99Ga。岩石地球化学和锆石Hf同位素组成特征表明,石宝沟花岗岩体的源区物质以壳源物质为主,可能为太古宙太华群,但也有年轻幔源组分的参与。     

华北克拉通南缘张士英岩体大陆动力学背景:来自地球化学、锆石U-Pb年龄和Hf同位素的证据

张士英岩体位于华北克拉通南缘,岩体主要由石英正长岩组成。石英正长岩的LA-ICP-MS锆石U-Pb年龄为122.8±1.5Ma。其Si O2含量为66.04%~67.80%,Na2O+K2O=9.03%~10.97%,K2O=4.40%~6.37%,K2O/Na2O1属于钾质长英质岩石。A/CNK=1.26~1.58,A/NK=1.63~1.79属于过铝质岩石系列。石英正长岩的Mg#变化范围在12.9~39.4。富集LREE亏损HREE,轻重稀土分异明显,(La/Yb)N=15.48~21.12,Eu呈弱的负异常(δEu=0.54~0.99)。富集Rb、K、Th、U等大离子亲石元素,亏损Nb、Ta、P、Ti等高场强元素。张士英石英正长岩岩浆锆石εHf(t)集中在-17.6~-13.9,Hf两阶段模式年龄tDM2集中在1.7~1.9Ga。石英正长岩的岩浆Zr饱和温度高(936~998℃)。地球化学及同位素显示张士英石英正长岩源区主要为古老的壳源物质,并有少量年轻组分加入,这种年轻组分是幔源物质。岩体形成于拉张性构造环境下,拉张性的环境导致了幔源物质的上涌,底侵下地壳使其发生部分熔融。形成时代正好位于华北克拉通破坏峰期,张士英石英正长岩正是这一地质事件的响应。     

广西德保铜矿钦甲岩体Hf同位素特征及其对壳幔相互作用的指示

对广西德保铜矿钦甲岩体不同单元中的锆石进行了Hf同位素的研究,结果表明,钦甲岩体中锆石εHf(t)值变化范围为-17.0～+7.8,Hf同位素两阶段模式年龄(tDMC)范围为0.93～2.49Ga,峰值为1.3～1.6Ga,表明它们的岩浆源区主要以中元古代地壳物质为主,同时在成岩过程中有地幔组分的参与,属壳幔混源花岗岩,推测钦甲岩体可能形成于岩石圈伸展的壳幔混合作用环境。华南地区加里东期花岗岩中锆石Hf同位素特征,表明岩浆形成过程中具有明显的地幔物质加入,暗示华南地区在早古生代发生过强烈的壳幔相互作用。     

湖南益将稀土-钪矿的石英闪长岩锆石U-Pb定年和Hf同位素特征:湘南加里东期岩浆活动的年代学证据

湖南汝城益将REE-Sc矿是中国华南重要的稀有稀土金属矿床类型,其赋矿岩石石英闪长岩的锆石SHRIMPU-Pb年龄为(424±3)Ma,代表中志留世的侵位年龄,为该区存在加里东期岩浆活动提供了同位素年代学的新证据。锆石εHf(t)值为-1.9～-7.6,锆石Hf同位素地壳模式年龄(1.5～1.9Ga)。εHf(t)值主要为负值,揭示其源区可能主要为陆壳物质或者富集地幔。部分锆石的εHf(t)值约为-1.9,说明在其形成过程中可能有一定比例亏损地幔物质的加入;源区同位素的不均一,可能是壳幔相互作用的结果,即幔源岩浆与古老地壳物质混合的结果。锆石Hf同位素数据显示古元古代—中元古代(1.5～1.9Ga)的两阶段模式年龄揭示湘南地区存在至少为古元古代的地壳增生。这些新资料为理解华南地壳演化和区域成矿提供了重要的同位素年代学和地球化学制约。     

华北地台南缘张士英岩体的锆石SHRIMP U-Pb测年、Hf同位素组成及其地质意义

张士英岩体位于华北地台南缘,岩石类型包括钾长花岗岩、似斑状花岗岩和石英斑岩脉,其中只在钾长花岗岩中发育有暗色岩石包体,在包体和寄主岩中发育反映岩浆混合作用的岩石结构。钾长花岗岩、似斑状花岗岩和石英斑岩脉的SHRIMP锆石U-Pb年龄分别为107.3±2.4Ma、106.7±2.5Ma和101±3Ma。锆石Hf同位素分析结果显示,钾长花岗岩的锆石εHf(t)为-15.96～-20.80,单阶段模式年龄(tDM1)为1396～1643Ma,两阶段模式年龄(tDM2)为1880～2018Ma;似斑状花岗岩的锆石εHf(t)为-18.97～-22.18,tDM1为1512～1640Ma,tDM2为1925～2080Ma;除了一粒年龄为2.6Ga的锆石具有εHf(t)为-0.71、tDM1为2943Ma和tDM2为3036Ma的组成,石英斑岩的锆石εHf(t)为-23.41～-27.95,tDM1为1678～1896Ma,tDM2为2144～2330Ma。这些数据暗示,除了存在少量太古宙地壳物质的贡献外,张士英岩体的物质来源可能主要为1.9～2.3Ga期间形成的新生地壳,但也不排除古老地壳与富集地幔源混合的可能。综合分析前人研究成果表明,在太平洋板块俯冲方向发生转变的过程中,先存断裂带发生拉张。张士英岩体与中国东部同期岩浆活动一起可能形成于这种受断裂带控制的伸展环境。     

华北克拉通南缘豫西下汤地区2.3 Ga岩浆作用和1.94 Ga变质作用

本文报道了华北克拉通南缘豫西鲁山下汤地区古元古代片麻状花岗岩和黑云角闪斜长片麻岩的全岩地球化学和锆石SHRIMP U-Pb年龄和Hf同位素组成。岩石呈包体形式存在于中元古代花岗岩中。片麻状花岗岩具深熔特征,岩浆锆石年龄为2.30Ga;岩石高SiO2和K2O,低ΣFeO、MgO和CaO,具稀土总量较高(ΣREE=165.8×10-6)、轻重稀土分离较强[(La/Yb)n=37.8]及弱负铕异常(Eu/Eu*=0.76)的稀土模式;εNd(t)(t=2.30Ga)=-0.75;tDM(Nd)=2.66Ga。黑云角闪斜长片麻岩变质原岩为辉长闪长岩,捕获锆石年龄为2.25Ga;岩石低SiO2和MgO,高Al2O3和P2O5,具稀土总量高(ΣREE=373.4×10-6)、轻重稀土分离不强[(La/Yb)n=9.4]及较强负铕异常(Eu/Eu*=0.44)的稀土模式;εNd(t)(t=2.25Ga)=-1.21;tDM(Nd)=2.75Ga。片麻状花岗岩和黑云角闪斜长片麻岩都记录了1.94Ga变质锆石年龄。片麻状花岗岩的岩浆锆石组成域的εHf(t)(t=2.30Ga)=-6.71～0.38,tDM1(Hf)=2627～2910Ma,tDM2(CC)(Hf)=2823～3255Ma。黑云角闪斜长片麻岩的捕获锆石组成域的εHf(t)(t=2.25Ga)=-19.58～-1.73,tDM1(Hf)=2664～3360Ma,tDM2(CC)(Hf)=2968～4011Ma。结合前人资料,得出如下结论:华北克拉通南缘豫陕晋结合部地区存在一规模较大的约2.3Ga地质体分布区;华北克拉通南缘很可能存在规模巨大的>2.7Ga基底;中部造山带与孔兹岩带具有类似的古元古代晚期构造热事件演化历史。     

2.3 Ga Magmatism and 1.94 Ga Metamorphism in the Xiatang Area,Southern Margin of the North China Craton——Evidence from Whole-rock Geochemistry and Zircon Geochronology and Hf Isotope

本文报道了华北克拉通南缘豫西鲁山下汤地区古元古代片麻状花岗岩和黑云角闪斜长片麻岩的全岩地球化学和锆石SHRIMP U-Pb年龄和Hf同位素组成.岩石呈包体形式存在于中元古代花岗岩中.片麻状花岗岩具深熔特征,岩浆锆石年龄为2.30 Ga;岩石高SiO2和K2O,低∑FeO、MgO和CaO,具稀土总量较高(∑REE=165.8×10-6)、轻重稀土分离较强[(La/Yb)n=37.8]及弱负铕异常(Eu/Eu(*)=0.76)的稀土模式;εNd(t)(t=2.30 Ga)=-0.75; tDM(Nd) =2.66 Ga.黑云角闪斜长片麻岩变质原岩为辉长闪长岩,捕获锆石年龄为2.25 Ga;岩石低SiO2 和MgO,高Al2O3和P2O5,具稀土总量高(∑REE=373.4×10-6)、轻重稀土分离不强[ (La/Yb)n=9.4]及较强负铕异常( Eu/Eu*=0.44)的稀土模式;εNd(t)(t=2.25 Ga)=-1.21;tDM(Nd) =2.75 Ga.片麻状花岗岩和黑云角闪斜长片麻岩都记录了1.94 Ga变质锆石年龄.片麻状花岗岩的岩浆锆石组成域的εHf(t)(t=2.30 Ga)=-6.71～0.38,tDMI(Hf) =2627 ～2910 Ma,tDM2(CC)(Hf)=2823 ～ 3255 Ma.黑云角闪斜长片麻岩的捕获锆石组成域的εHf(t)(t=2.25 Ga)=-19.58～ -1.73,tDM1 (Hf) =2664～3360 Ma,tDM2(CC)(Hf)=2968 ～4011 Ma.结合前人资料,得出如下结论:华北克拉通南缘豫陕晋结合部地区存在—规模较大的约2.3 Ga地质体分布区;华北克拉通南缘很可能存在规模巨大的＞2.7 Ga基底;中部造山带与孔兹岩带具有类似的古元古代晚期构造热事件演化历史.     

藏北聂荣地区早侏罗世末期的岩浆混合作用及构造意义

藏北聂荣岩体的岩浆源区性质和岩石成因还未能得到很好约束,直接限制了对班公湖-怒江缝合带早侏罗世构造岩浆演化历史的认识。为探讨这一问题,本文报道了聂荣岩体中的花岗质岩石及其闪长质包体的岩石学、全岩主量元素和微量元素地球化学、锆石U-Pb定年和Lu-Hf同位素分析结果。一件闪长质包体样品的锆石U-Pb年龄为175.0±1.3Ma,与其寄主花岗岩类样品的年龄(174.5±1.4Ma,175.9±0.4Ma)同期。聂荣岩体中～175Ma的寄主岩石均属于偏铝质到过铝质(A/CNK=1.04～1.16)钾玄岩系列的花岗闪长岩到碱性花岗岩,标准刚玉分子数为0.6%～2.1%,包括I型和S型两种成因类型,富集大离子亲石元素、轻稀土元素和Pb,锆石εHf(t)值为-9.8～-3.7,Hf同位素地壳模式年龄为1.45～1.84Ga,主要来源于成熟地壳物质的重熔;闪长质包体在成分上主要属偏铝质钾玄岩系列的二长闪长岩,锆石εHf(t)值变化范围大(-10.3～-1.2),Hf同位素亏损地幔模式年龄介于0.87～1.22Ga,其来源可能与古老岩石圈地幔物质的部分熔融有关。聂荣地区在早侏罗世末期很可能发生了来源于成熟地壳物质深熔或重熔的熔体(占大比例)和岩石圈地幔来源的幔源岩浆之间的混合作用,混合过程中幔源组分的输入使S型熔体向I型熔体转化。在～175Ma侵位的聂荣岩体很可能是这种由岩浆混合作用形成的母岩浆再经历一定程度的分离结晶作用形成的。结合碎屑锆石研究成果,本文暂时主张聂荣岩体可能是与由班公湖-怒江洋壳北向俯冲所引起的聂荣微陆块和羌塘地体间碰撞相关的产物,这可能指示班公湖-怒江洋壳沿聂荣微陆块南侧的分支,在侏罗纪早期既发生了南向俯冲(俯冲于拉萨地体之下),又发生了北向俯冲(俯冲于羌塘地体之下)等地球动力学过程。     

内蒙古武川西乌兰不浪地区早前寒武纪变质基底锆石SHRIMP定年及Hf同位素组成

本文报道了华北克拉通西部武川西乌兰不浪地区太古宙变质基底的锆石SHRIMP年龄和Hf同位素组成。一个片麻状奥长花岗岩样品的锆石具核边结构,核部岩浆锆石和边部变质锆石的207Pb/206Pb加权平均年龄分别为2692±17Ma和2528±16Ma。对9个样品进行了锆石Hf同位素分析。新太古代早期(2692～2697Ma)片麻状奥长花岗岩(2个样品)的岩浆锆石的εHf(t)、tDM1(Hf)和tDM2(Hf)分别为4.78～8.83、2646～2780Ma和2632～2845Ma;新太古代二辉麻粒岩(2个样品)中的捕获锆石的εHf(t)、tDM1(Hf)和tDM2(Hf)分别为-2.30～8.62、2543～2954Ma和2529～3189Ma;新太古代变质深成岩(4个样品)的岩浆锆石的εHf(t)、tDM1(Hf)和tDM2(Hf)分别为-2.60～8.09、2529～2880Ma和2538～3089Ma;古元古代蓝晶石榴长英质片麻岩(1个样品)的碎屑锆石的εHf(t)、tDM1(Hf)和tDM2(Hf)分别为1.52～6.59、2432～2774Ma和2498～2925Ma。结合前人研究结果,可得出如下结论和认识:1)该区存在新太古代早期片麻状奥长花岗岩,太古宙岩石在新太古代晚期普遍遭受高级变质作用影响;2)新太古代早期为该区地壳形成主要时期,新太古代晚期则主要表现为陆壳物质再循环;3)作为阴山地块的典型代表,固阳-武川地区与华北克拉通东部太古宙基底十分类似,可能表明华北克拉通在新太古代晚期已成为统一的整体。     

苏鲁造山带荣成超高压地体片麻岩锆石年龄和铪同位素组成特征

本文对苏鲁造山带内荣成超高压地体片麻岩样品进行了锆石U-Pb年龄、Hf同位素和全岩Nd同位素分析,旨于探讨片麻岩的原岩性质及成因。3个片麻岩样品的锆石SHRIMP U-Pb年龄(770Ma和710Ma之间)表明原岩形成于晚元古代,与Rodinia超大陆裂解过程的岩浆活动时间相吻合。14个片麻岩的单阶段钕模式年龄变化在1.70Ga至2.30Ga(平均～1.93Ga),表明荣成超高压地体片麻岩平均地壳存留时间为古元古代,与扬子陆块的平均地壳形成年龄相一致,暗示具有扬子陆块属性。其锆石ε_(Hf)(t)值(t=750Ma)和模式年龄值变化范围大。2个片麻岩的锆石具有非常负的ε_(Hf)(t),平均值为-16.4,铪模式年龄为2.70Ga。6个片麻岩的锆石ε_(Hf)(t)平均值为-7.7,铪模式年龄为2.15Ga。这些结果表明荣成超高压地体部分原岩主要由太古代-古元古代地壳物质在晚元古代时重熔形成的,进一步说明荣成地区可能有扬子陆块的太古代地壳残留。另有6个片麻岩的锆石ε_(Hf)(t)变化范围为-0.56至6.6之间,其中部分锆石的两阶段Hf模式年龄为0.81Ga至0.94Ga,表明片麻岩原岩晚元古代形成时,有幔源岩浆活动和新生地壳形成,可能同时存在强烈壳-幔相互作用,上侵的幔源岩浆底侵导致上覆扬子陆块太古代-古元古代地壳物质重熔,形成花岗质岩浆。     

Aspects of the magmatic geochemistry of bismuth

Bismuth has been determined in 74 rocks from a differentiated tholeiitic dolerite, two calc-alkaline batholith suites and in 66 mineral separates from one of the batholiths. Average bismuth contents, weighted for rock type, of the Great Lake (Tasmania) dolerite, the Southern California batholith and the Idaho batholith are, 32, 50 and 70 ppb respectively. All three bodies demonstrate an enrichment of bismuth in residual magmas with magmatic differentiation. Bismuth is greatly enriched (relative to the host rock) in the calcium-rich accessory minerals, apatite and sphene, but other mineral analyses show that a Bi-Ca association is of little significance to the magmatic geochemistry of bismuth. Most of the bismuth, in the Southern California batholith at least, occurs in a trace mineral phase (possibly sulfides) present as inclusions in the rock-forming minerals.     

On the ore-deposition and geochemistry of manganese

The distribution of manganese in eruptive rocks has been elaborated together with A. Berger (1965). There are systematically higher MnO-values in intrusive rocks than in the corresponding extrusives with the same SiO₂-content. Thus, negative values of potential ore metal are characteristic for manganese. Therefore, Mn is strongly concentrated in magmatic residual solutions, contrary to chromium and titanium which have positive values of potential ore metal, and which are concentrated in the very early products of fractional crystallization of basaltic magmas. Under fresh water conditions with low ionconcentrations, small asbolan deposits may be formed on peridotite-serpentinites (New Caledonia Type). Rich ore concentrations may be formed in connection with lateritic weathering, above all on the southern continents (old Gondwana Shield) on the basis of primarily poor protores. Special reaction processes of two groundwater masses may lead to the Lindener Mark Type in the southern part of the Rheinisches Schiefergebirge as well as to the big ore bodies of Postmasburg in South Africa. Under marine conditions with the development of a carbonic-acid-zone, manganese may be dissolved in solutions with much higher pH- and more positive Eh-values. Thus, the separation of Mn and Fe and of both from the main mass of Si-Al-components can take place. Pure manganese ore deposits of the Tschiaturi/Nikopol Type in an expanded Black Sea could thus be built up. On the other side, the volcanic-sedimentary type with shale-chert-spilite-manganese ore formation is strictly bound to residual solutions of basaltic provenance in an eugeosynclinal realm. The different genetic types are schematically demonstrated in Fig. 2. The physicochemical conditions for the separation of Mn and Fe are elucidated in Fig. 9.

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Zusammenfassung Auf der Grundlage einer umfassenden Untersuchung von A. Berger (1965) über die Lagerstättenkunde und Geochemie des Mangans werden die natürlichen Prozesse, welche von der geochemischen Verdünnung zu Konzentrationen und Lagerstättenbildungen führen können, kritisch untersucht. Der Vergleich der MnO-Gehalte der verschiedensten Typen von Eruptivgesteinen (von den ultrabasischen bis zu den sauersten) zeigt, daß die Ergußgesteine stets höhere Mangangehalte aufweisen, verglichen mit den Tiefengesteinen gleichen SiO₂-Gehalts. Daher ergeben die Differenzen stets positive Werte des potentiellen Lagerstättenmetalls, was gleichzeitig für die starke Anreicherung des Mangans in hydrothermalen Restlösungen charakteristisch ist. Im Mittelpunkt der Gesamtuntersuchung steht das lagerstättenkundlich besonders wichtige Verhalten des Mangans — verglichen mit dem Fe — in kontinentalen Verwitterungslösungen und im marinen Bereich.

     

Subduction zone geochemistry

Crustal recycling at convergent plate boundaries is essential to mantle heterogeneity.However,crustal signatures in the mantle source of basaltic rocks above subduction zones were primarily incorporated in the form of liquid rather than solid phases.The physicochemical property of liquid phases is determined by the dehydration behavior of crustal rocks at the slab-mantle interface in subduction channels.Because of the significant fractionation in incompatible trace elements but the full inheritance in radiogenic isotopes relative to their crustal sources,the production of liquid phases is crucial to the geochemical transfer from the subducting crust into the mantle.In this process,the stability of specific minerals in subducting crustal rocks exerts a primary control on the enrichment of given trace elements in the liquid phases.For this reason,geochemically enriched oceanic basalts can be categorized into two types in terms of their trace element distribution patterns in the primitive mantle-normalized diagram.One is island arc basalts(IAB),showing enrichment in LILE,Pb and LREE but depletion in HFSE such as Nb and Ta relative to HREE,The other is ocean island basalts(OIB),exhibiting enrichment in LILE and LREE,enrichment or non-depletion in HFSE but depletion in Pb relative to HREE.In either types,these basalts show the enhanced enrichment of LILE and LREE with increasing their incompatibility relative to normal mid-ocean ridge basalts(MORB).The thermal regime of subduction zones can be categorized into two stages in both time and space,The first stage is characterized by compressional tectonism at low thermal gradients.As a consequence,metamorphic dehydration of the subducting crust prevails at forearc to subarc depths due to the breakdown of hydrous minerals such as mica and amphibole in the stability field of garnet and rutile,resulting in the liberation of aqueous solutions with the trace element composition that is considerably enriched in LILE,Pb and LREE but depleted in HFSE and HREE relative to normal MORB.This provides the crustal signature for the mantle sources of IAB.The second stage is indicated by extensional tectonism at high thermal gradients,leading to the partial melting of metamorphically dehydrated crustal rocks at subarc to postarc depths.This involves not only the breakdown of hydrous minerals such as amphibole,phengite and allanite in the stability field of garnet but also the dissolution of rutile into hydrous melts.As such,the hydrous melts can acquire the trace element composition that is significantly enriched in LILE,HFSE and LREE but depleted in Pb and HREE relative to normal MORB,providing the crustal signature for the mantle sources of OIB.In either case,these liquid phases would metasomatize the overlying mantle wedge peridotite at different depths,generating ultramafic metasomatites such as serpentinized and chloritized peridotites,and olivine-poor pyroxenites and hornblendites.As a consequence,the crustal signatures are transferred by the liquid phases from the subducting slab into the mantle.     

Environmental geochemistry at the global scale

Land degradation and pollution caused by population pressure and economic development pose a threat to the sustainability of the earth's surface, especially in tropical regions where a long history of chemical weathering has made the surface environment particularly fragile. Systematic baseline geochemical data provide a means of monitoring the state of the environment and identifying problem areas. Regional surveys have already been carried out in some countries, and with increased national and international funding they can be extended to cover the rest of the land surface of the globe. Preparations have been made, under the auspices of the International Union of Geological Surveys (IUGS) and the International Association of Geochemistry and Cosmochemistry (IAGC) for the establishment of just such an integrated global database.     

The geochemistry of strontium

The geochemistry of strontium has been investigated, using an emission spectrographic technique checked by isotope dilution analyses described elsewhere ( et al., in press). Hence the determinations are claimed to have good accuracy as well as precision.

Approximately 700 analyses have been made on silicate rocks and over 300 on carbonate materials (a detailed analysis of the latter appearing in other papers). An attempt was made at a representative sampling of the crust of the earth.

The difference in behaviour of strontium relative to calcium in granitic rocks as compared to basaltic rocks is striking. For granitic rocks there is an increase of strontium content with an increase in calcium not only for samples from a single batholith but also when extended to a universal sampling. On the other hand, though some differentiated basaltic bodies show a covariance of strontium and calcium, it is always with the strontium content increasing as the calcium content decreases. On a worldwide basis, however, this relationship is destroyed because marked regional variations subdue any differentiation effects that might be present locally.

The crustal abundance of strontium in basaltic rocks may be estimated without difficulty by taking a simple average, but a similar procedure for granitic rocks is ruled out because of the dependence of strontium content on rock-type. The table below summarizes the abundances of strontium in the various phases of the earth's crust.     

The geochemistry of indium

A double-arc spectrochemical procedure was used to analyse numerous minerals and rocks for indium. The method had sensitivity of the order of 0.02 ppm In with precision of ±20%.