Geochemical research on C-O and Sr-Nd isotopes of mantle-derived rocks from Shandong Province, China

Abstract This paper presents systematic studies on the C-O and Sr-Nd isotopic compositions for Cretaceous Badou carbonatites, Fangcheng basalts, and Jiaodong lamprophyres and Paleozoic Mengyin kimberlites in Shandong Province, China. Paleozoic kimberlites have normal and uniform C-O isotopic compositions with δ13C and δ18O in the range of-4.8‰-7.6‰ and +9.9‰-+13.2‰, respectively. However, Cretaceous three different types of mantle-derived rocks have quite different C-O isotopic compositions, indicating that the mantle sources are probably partially contaminated with organic carbon-bearing crustal materials. These Cretaceous rocks show uniform and EMII-like Sr-Nd isotopic compositions and also indicate that the mantle sources were affected by recycled crustal materials. Comparative studies of C-O and Sr-Nd isotopes reveal that the lithospheric mantle beneath the eastern North China Craton had different isotope characteristics in the Paleozoic, the early Cretaceous, and the Tertiary time. This demon     

Geochemistry and Sr-Nd-Pb isotopic characteristics of the Mugouriwang Cenozoic volcanic rocks from Tibetan Plateau:Constraints on mantle source of the underplated basic magma

The Mugouriwang Cenozoic volcanic rocks exposed in the north Qiangtang Block of Tibetan Plateau are mainly composed of basalt and andesitic-basalt,both characterized by the lower SiO2 (51%―54%),high refractory elements (i.e. Mg,Cr,Ni) as well as the moderate enrichment in light rare earth elements (LREE) relative to a slight depleted in Eu and high strength field elements (HFSE,i.e. Nb,Ta,Ti). Be-sides,the fairly low Sm/Yb value (3.07―4.35) could signify that the rocks should be derived directly from partial melting of the spinel lherzolite at the upper part of the asthenosphere. These rocks have radiogenic Sr and Pb (87Sr/86Sr = 0.705339 to 0.705667; 208Pb/204Pb = 38.8192 to 38.8937; 207Pb/204Pb = 15.6093 to 15.6245; 206Pb/204Pb = 18.6246 to 18.6383),and non-radiogenic Nd (143Nd/144Nd = 0.512604 to 0.512639; εNd = 0.02 to -0.66) in agreement with those values of the BSE mantle reservoir. The DUPAL anomaly of the rocks can be evidently attested by the △8/4Pb = 66.82 to 74.53 ,△7/4Pb = 9.88 to 11.42,△Sr>50,implying that the Mugouriwang volcanic rock is likely to be generated by partial melting of a Gondwana-bearing asthenospheric mantle ever matasomatised by the fluid from subduction zone. Depending on the previous study on the high-K calc-alkaline intermediate-felsic volcanics in the study area,this paper proposed that the fluids derived from the subducted Lhasa Block metasomatised the asthenosphere beneath the Qiangtang Block,and induced its partial melting,and then the melt under-plated the thickened Qiangtang lithosphere and caused the generation of the Cenozoic adakite-like felsic magmas in the Qiangtang region.     

Geochemistry and Ar/Ar geochronology of Miocene volcanic rocks from the Karaburun Peninsula: Implications for amphibole-bearing lithospheric mantle source,Western Anatolia

New geochemical and ⁴⁰Ar/³⁹Ar age data are presented from the Neogene volcanic units of the Karaburun Peninsula, the westernmost part of Western Anatolia. The volcanic rocks in the region are associated with Neogene lacustrine deposition and are characterized by (1) olivine-bearing basaltic-andesites to shoshonites (Karaburun volcanics), high-K calc-alkaline andesites, dacites and latites (Yaylaköy, Arma?anda? and Kocada? volcanics) of ~ 16–18 Ma, and (2) mildly-alkaline basalts (Ovac?k basalt) and rhyolites (Urla volcanics) of ~ 11–12 Ma. The first group of rocks is enriched in LILE and LREE with respect to the HREE and HFSE on N-MORB-normalised REE and multi-element spider diagrams. They are comparable geochemically with volcanic rocks in the surrounding regions such as Chios Island and other localities in Western Anatolia. The Ovac?k basalt is geochemically similar to the first stage early–middle Miocene volcanic rocks but differs from NW Anatolian late Miocene alkali basalts.     

Chemical and isotopic signatures of the basement rocks from the Campi Flegrei geothermal field (Naples, southern Italy): inferences about the origin and evolution of its hydrothermal fluids

The Campi Flegrei (Naples, Campanian Plain, southern Italy) geothermal system is hosted by Quaternary volcanic rocks erupted before, during and after the formation of the caldera that represents one of the major structural features in the Neapolitan area. The volcanic products rest on a Mesozoic carbonate basement, cropping out north, east and south of the area. Chemical (major, minor and trace elements) and stable isotope (C, H, O) analyses were conducted on drill-core samples recovered from geothermal wells MF-1, MF-5, SV-1 and SV-3, at depths of ˜ 1100 to 2900 m. The study was complemented by petrographic and SEM examination of thin sections. The water which feeds the system is both marine and meteoric in origin. Mineral zonation typical of a high-temperature geothermal system exists in all the geothermal wells; measured temperatures in wells are as high as ˜ 400 °C. The chemical composition of the waters suggests the existence of two reservoirs: a shallow reservoir (depth < 2000 m) fed by seawater that boiled at 320 °C and became progressively diluted by steam-heated local meteoric water during its ascent; and a deeper reservoir (depth > 2000 m) of hypersaline water. The drill-cores are mainly hydrothermally altered volcanics of trachy-latitic affinity, but some altered pelites and limestones are also present. Published Na, Mg and K concentrations of selected geothermal waters indicate that the hydrothermal fluids are in equilibrium with their host rocks, with respect to K-feldspar, albite, sericite and chlorite. The measured δ¹⁸O_(SMOW) values of rocks range from +4.3 to + 16.5%. The measured δD_(SMOW) values range from − 79 to − 46%. The calculated isotopic composition of the fluids at equilibrium with the samples vary from + 1 to + 8.3%. δ¹⁸O and from − 52 to + 1%. δD. The estimated isotopic composition of the waters at equilibrium with the studied samples confirmed the existence of two distinct fluid types circulating in the geothermal system. The shallower has a marine water signature, while the deeper water has a signature consistent both with magmatic and meteoric origins. In the latter case, the recharge of this aquifer likely occurs at the outcrop of the Mesozoic Limestones surrounding the Campanian Plain; after infiltration, the water percolates through evaporitic layers, becoming hypersaline and D-depleted.     

南海重磁异常特征及火成岩分布(英文)

南海火成岩油气藏具有广阔的勘探前景,综合利用地球物理方法圈划与识别火成岩体、研究火成岩分布是火成岩油气藏研究的基础。针对南海重磁场特征,采用低纬度、变倾角化极技术进行了磁异常化极处理,利用优选延拓方法实现重磁异常分离并提取南海海域浅部火成岩重磁异常信息,利用磁异常三维相关成像给出南海火成岩的三维空间等效分布,在重磁梯度突出局部异常边界信息的基础上,通过梯度加权的重磁相关分析勾画不同类型火成岩的平面展布,火成岩的分布特征显示出受地壳深部结构及断裂构造的控制与影响。     

Rb–Sr and Sm–Nd isotopic studies of mafic igneous rocks from the Ryoke plutono-metamorphic belt in the Setouchi area, Southwest Japan: implications for the genesis and thermal history

Abstract Rb–Sr and Sm–Nd isochron ages were determined for whole rocks and mineral separates of hornblende‐gabbros and related metadiabases and quartz‐diorite from Shodoshima, Awashima and Kajishima islands in the Ryoke plutono‐metamorphic belt of the Setouchi area, Southwest Japan. The Rb–Sr and Sm–Nd whole‐rock‐mineral isochron ages for six samples range from 75 to 110 Ma and 200–220 Ma, respectively. The former ages are comparable with the Rb–Sr whole‐rock isochron ages reported from neighboring Ryoke granitic rocks and are thus due to thermal metamorphism caused by the granitic intrusions. On the contrary, the older ages suggest the time of formation of the gabbroic and related rocks. The initial ⁸⁷Sr/⁸⁶Sr and ¹⁴³Nd/¹⁴⁴Nd ratios of the gabbroic rocks (0.7070–0.7078 and 0.51217–0.51231 at 210 Ma, respectively) are comparable with those of neighboring late Cretaceous granites and lower crustal granulite xenoliths from Cenozoic andesites in this region. Because the gabbroic rocks are considered to be fragments of the lower crustal materials interlayered in the granulitic lower crust, their isotopic signature has been inherited from an enriched mantle source or, less likely, acquired through interaction with the lower crustal materials. The Sr and Nd isotopic and petrologic evidence leads to a plausible conclusion that the gabbroic rocks have formed as cumulates from hydrous mafic magmas of light rare earth element‐rich (Sm/Nd < 0.233) and enriched isotopic (?_Sr > 0 and ?_Nd < 0) signature, which possibly generated around 220–200 Ma by partial melting of an upper mantle. We further conclude that they are fragments of refractory material from the lower crust caught up as xenoblocks by granitic magmas, the latter having been generated by partial melting of granulitic lower crustal material around 100 Ma.     

Pertrogenesis and tectonic implications of the late Jurassic basic rocks from the northern Shi‐Hang zone,Southeast China

The tectonic setting of the late mesozoic of South China is in a debate between two schools of thought: an intra‐continental rift zone along a passive continental margin or active rifting associated with subduction of the paleo‐Pacific Plate. In this study, we present new sensitive high‐resolution ion microprobe (SHRIMP) U‐Pb zircon ages, along with geochemical data of three basic dikes that cross‐cut the Dexing porphyry copper deposit. The deposit is the largest of its kind in eastern China and part of large scale mineralization associated with Mesozoic magmatic activity in the area. Our results indicate that the dikes were emplaced in the Late Jurassic with an average U‐Pb age of 153.5 ± 2.4 Ma. The intrusions have bulk ε_Nd(t) of ca +0.7 and zircon ε_Hf(t) value of +1.54 to +6.92. Based on relatively enriched light rare earth elements (LREE) and depleted high‐field‐strength elements (HFSE) abundances with pronounced negative Ta–Nb, Hf–Zr and Ti anomalies in multi‐element diagrams, we propose that these dikes were derived from a subduction‐modified lithospheric mantle source. The variability in Hf isotopes identifies some degree of crustal contaminations. Our data support a scenario with a back‐arc extensional setting or an intra‐arc rift environment associated with the westward subduction of the paleo‐Pacific Plate at or prior to the late Jurassic as the most likely cause for these subduction signatures.     

Geochemistry and origin of Archean volcanic rocks from the Upper Keewatin assemblage (ca 2.7 Ga), Lake of the Woods Greenstone Belt, Western Wabigoon Subprovince, Superior Province, Canada

Abstract   Volcanic rocks from the Upper Keewatin assemblage ( ca 2720 Ma) were geochemically classified into five groups; komatiites, tholeiitic rocks having near-flat primitive mantle-normalized abundance patterns, Nb-enriched basalts and andesites (NEBA) plus normal calc-alkaline (NCA) rocks, adakites and shoshonites. The adakites having [La/Yb]_N >30 and <30 were probably derived from felsic magmas formed by partial melting of a subducted slab at relatively greater and smaller depths, respectively. Ascending adakite magmas, by interaction with the overlying mantle wedge, decreased in Al₂O₃ / Y ratio and selectively lost high-field strength elements, thereby forming mantle sources for both NEBA + NCA and shoshonite magmas. Under the influence of a mantle plume, the source of komatiites, the NEBA + NCA magmas were generated from that part of the mantle wedge metasomatized by adakite magmas having [La / Yb]_N <30, and tholeiitic magmas from unmetasomatized part of the same mantle wedge. Magmas of both adakites having [La / Yb]_N >30 and shoshonites were generated in a normal Archean Arc system setting.     

Rapid cooling and geospeedometry of granitic rocks exhumation within a volcanic arc: A case study from the Central Slovakian Neovolcanic Field (Western Carpathians)

U–Pb Sensitive High‐Resolution Ion MicroProbe (SHRIMP) dating of zircon in combination with (U–Th)/He dating of zircon and apatite is applied to constrain the emplacement and exhumation history of the youngest granitic rocks in the Western Carpathians collected in the Central Slovakian Neovolcanic Field. Two samples of diorite from the locality Banky, and granodiorite from Banská Hodru?a yield the U–Pb zircon concordia ages of 15.21 ±0.19 Ma and 12.92 ±0.27 Ma, respectively, recording the time of zircon crystallization and the intrusions’ emplacement. Zircon (U–Th)/He ages of 14.70 ±0.94 (Banky) and 12.65 ±0.61 Ma (Banská Hodru?a), and apatite (U–Th)/He ages of 14.45 ±0.70 Ma (diorite) and 12.26 ±0.77 Ma (granodiorite) are less than 1 Myr younger than the corresponding zircon U–Pb ages. For both diorite and granodiorite rocks their chronological data thus document a simple cooling process from magmatic crystallization/solidification temperatures to near‐surface temperatures in the Middle Miocene, without subsequent reheating. Geospeedometry data suggest for rapid cooling at an average rate of 678 ±158 °C/Myr, and the exhumation rate of 5 mm/year corresponding to active tectonic‐forced exhumation. The quick cooling is interpreted to record the exhumation of the studied granitic rocks complex that closely followed its emplacement, and was likely accompanied by a drop in the paleo‐geothermal gradient due to cessation of volcanic activity in the area.     

Pb, Nd, and Sr isotopic constraints on the origin of Miocene basaltic rocks from northeast Hokkaido, Japan: Implications for opening of the Kurile back-arc basin

Late Miocene (7–9 Ma) basaltic rocks from the Monbetsu‐Kamishihoro graben in northeast Hokkaido have chemical affinities to certain back‐arc basin basalts (referred to herein as Hokkaido BABB). Pb‐, Nd‐ and Sr‐isotopic compositions of the Hokkaido BABB and arc‐type volcanic rocks (11–13 Ma and 4–4.5 Ma) from the nearby region indicate mixing between the depleted mantle and an EM II‐like enriched component (e.g. subducted pelagic sediment) in the magma generation. At a given ⁸⁷Sr/⁸⁶Sr, Hokkaido BABB have slightly lower ¹⁴³Nd/¹⁴⁴Nd and slightly less radiogenic ²⁰⁶Pb/²⁰⁴Pb compared with associated arc‐type lavas, but both these suites are difficult to distinguish solely on the basis of isotopic compositions. These isotopic data indicate that while generation of the Hokkaido BABB involves smaller amounts of the EM II‐like enriched component than do associated arc lavas, Hokkaido BABB are isotopically distinct from basalts produced at normal back‐arc basin spreading centers. Instead, northeast Hokkaido BABB are more similar to basalts erupted during the initial rifting stage of back‐arc basins. The Monbetsu‐Kamishihoro graben may have developed in association with extension that formed the Kurile Basin, suggesting that opening of the basin continued until late Miocene (7–9 Ma).