Caleta el Cobre 022 Martian meteorite: Increasing nakhlite diversity

Caleta el Cobre (CeC) 022 is a Martian meteorite of the nakhlite group, showing an unbrecciated cumulate texture, composed mainly of clinopyroxene and olivine. Augite shows irregular core zoning, euhedral rims, and thin overgrowths enriched in Fe relative to the core. Low‐Ca pyroxene is found adjacent to olivine. Phenocrysts of Fe‐Ti oxides are titanomagnetite with exsolutions of ilmenite/ulvöspinel. Intercumulus material consists of both coarse plagioclase and fine‐grained mesostasis, comprising K‐feldspars, pyroxene, apatite, ilmenite, Fe‐Ti oxides, and silica. CeC 022 shows a high proportion of Martian aqueous alteration products (iddingsite) in olivine (45.1 vol% of olivine) and mesostasis. This meteorite is the youngest nakhlite with a distinct Sm/Nd crystallization age of 1.215 ± 0.067 Ga. Its ejection age of 11.8 ± 1.8 Ma is similar to other nakhlites. CeC 022 reveals contrasted cooling rates with similarities with faster cooled nakhlites, such as Northwest Africa (NWA) 817, NWA 5790, or Miller Range 03346 nakhlites: augite irregular cores, Fe‐rich overgrowths, fine‐grained K‐feldspars, quenched oxides, and high rare earth element content. CeC 022 also shares similarities with slower cooled nakhlites, including Nakhla and NWA 10153: pyroxene modal abundance, pyroxenes crystal size distribution, average pyroxene size, phenocryst mineral compositions, unzoned olivine, and abundant coarse plagioclase. Moreover, CeC 022 is the most magnetic nakhlite and represents an analog source lithology for the strong magnetization of the Martian crust. With its particular features, CeC 022 must originate from a previously unsampled sill or flow in the same volcanic system as the other nakhlites, increasing Martian sample diversity and our knowledge of nakhlites.     

High crustal diversity preserved in the lunar meteorite Mount DeWitt 12007 (Victoria Land,Antarctica)

The meteorite Mount DeWitt (DEW) 12007 is a polymict regolith breccia mainly consisting of glassy impact‐melt breccia particles, gabbroic clasts, feldspathic clasts, impact and volcanic glass beads, basaltic clasts, and mingled breccia clasts embedded in a matrix dominated by fine‐grained crystals; vesicular glassy veins and rare agglutinates are also present. Main minerals are plagioclase (typically An_>85) and clinopyroxene (pigeonites and augites, sometimes interspersed). The presence of tranquillityite, coupled with the petrophysical data, the O‐isotope data (Δ¹⁷O = ?0.075), and the FeO_tot/MnO ratios in olivine (91), pyroxene (65), and bulk rock (77) indicate a lunar origin for DEW 12007. Impactites consist of Al‐rich impact‐melt splashes and plagioclase‐rich meta‐melt clasts. The volcanic products belong to the very low titanium (VLT) or low titanium (LT) suites; an unusual subophitic fragment could be cryptomare‐related. Gabbroic clasts could represent part of a shallow intrusion within a volcanic complex with prevailing VLT affinity. DEW 12007 has a mingled bulk composition with relatively high incompatible element abundances and shows a high crustal diversity comprising clasts from the Moon's major terranes and rare lithologies. First‐order petrographic and chemical features suggest that DEW 12007 could be launch‐paired with other meteorites including Y 793274/981031, QUE 94281, EET 87521/96008, and NWA 4884.     

Orbit of the Murchison meteorite

Abstract— Because the path of the Murchison meteorite fortuitously intersected the Earth's path at an angle of only a few degrees, the visual observations establish the entry velocity to be within 2 km/s of 13 km/s and determine the nature of its orbit with a precision quite unusual for visually sighted falls.     

The Tianlin meteorite

Abstract Chemical data are reported for the Tianlin iron meteorite from south China. The meteorite is classified as a coarse octahedrite of group IA with complete decomposition of cohenite to ferrite and graphite.     

Near-infrared spectroscopy of 3:1 Kirkwood Gap asteroids: Mineralogical diversity and plausible meteorite parent bodies

The 3:1 Kirkwood gap asteroids are a mineralogically diverse set of asteroids located in a region that delivers meteoroids into Earth-crossing orbits. Mineralogical characterizations of asteroids in/near the 3:1 Kirkwood Gap can be used as a tool to “map” conditions and processes in the early Solar System. The chronological studies of the meteorite types provide a “clock” for the relative timing of those events and processes. By identifying the source asteroids of particular meteorite types, the “map” and “clock” can be combined to provide a much more sophisticated understanding of the history and evolution of the late solar nebula and the early Solar System.A mineralogical assessment of seven 3:1 Kirkwood Gap asteroids has been carried out using near-infrared spectral data obtained over the years 2006–2009 combined with visible spectral data (when available) to cover the spectral interval of 0.4–2.5 μm. We explore the diversity, uniqueness, and possible links between the asteroids (198) Ampella, (329) Svea, (495) Eulalia, (556) Phyllis, (623) Chimaera, (908) Buda, and (1772) Gagarin, which are located adjacent to the 3:1 resonance, and the meteorite types in the terrestrial collections.     

On meteorite orbits

The new method of calculation of meteorite orbits based on the analysis of meteorite showers scattering patterns is suggested. Elements of orbits of 14 meteorites are listed. Correlations between oribt type and petrological type of meteorite are absent.     

The nature of the Tunguska meteorite

Abstract— Arguments in favor of the cometary origin of the Tunguska meteorite are adduced along with reasons against the asteroidal hypothesis. A critical analysis is given for the hypotheses by Sekanina (1983) and Chyba et al. (1993). On the basis of the azimuth and inclination of the trajectory of the Tunguska body with plausible values of the geocentric velocity, the semimajor axis of the orbit and its inclination to the ecliptic plane are calculated for this body. It is noted that the theory of the disintegration of large bodies in the atmosphere put forward by Chyba et al. (1993) is crude. Applying more accurate theories (Grigoryan, 1979; Hills and Goda, 1993) as well as taking into account the realistic shape of the body yield for the cometary body lower disruption heights than obtained by Chyba et al. Numerical simulations carried out by Svettsov et al. agree well with the cometary hypothesis and the analytical calculations based on Grigoryan's theory. The asteroidal hypothesis is shown not to be tenable: the complete lack of stony fragments in the region of the catastrophe, cosmochemical data (in particular, the results of an isotope analysis), and some other information contradict this hypothesis. It is shown that stony fragments that would have originated in the explosive disruption of the Tunguska body would not be vaporized by the radiation of the vapor cloud nor as a result of their fall to the Earth's surface.     

The orbit of the Dhajala meteorite

Observations of the trail caused by the meteorite which fell around Dhajala, Gujarat (India), on 28 January 1976 have been used to compute the probable orbit of the meteoroid in space. The cosmic ray effects in the meteorite fragments indicate high mass ablation (?90%), suggesting a high velocity (?20 km/sec) of entry into the Earth's atmosphere. The atmospheric trajectory is reasonably well documented and its deviation from the projected ground fallout can be understood in terms of the ambient wind pattern. The apparent radiant of the trail was at a point in the sky with right ascension 165°, declination +60°. Considering the errors in estimating the radiant, we get a range of orbits with a = 2.3 ± 0.8 AU, e = 0.6 ± 0.1, and i = 28 ± 4° with the constraints of a ? 1.5 AU and V_∞ < 25 km/sec (which causes nearly complete evaporation of the meteoroid). Taking V_∞ = 21.5 lm/sec as indicated by the measured mass ablation of the meteorite, the orbital elements are deduced to be $\text{a = 1.8}\text{AU}\text{, e = 0.59, i = 27°.6, ω = 109°.1, Ω = 307°.8,}\text{and}\text{q = 0.74}$.     

Exposure history of the Torino meteorite

Abstract— We determined He, Ne, Ar, ¹⁰Be, ²⁶Al, ³⁶Cl, and ¹⁴C concentrations, as well as cosmic-ray track densities and halogen concentrations in different specimens of the H6 chondrite Torino, in order to constrain its exposure history to cosmic radiation. The Torino meteoroid had a radius of ～20 cm and travelled in interplanetary space for 2.5–10 Ma. Earlier, Torino was part of a larger body. The smallest possible precursor had a radius of 55 cm and a journey through space longer than ～65 Ma. If the first-stage exposure took place in a body with a radius of >3 m or in the parent asteroid, then it lasted nearly 300 Ma. The example of Torino shows that it is easy to underestimate first-stage exposure ages when constructing two-stage histories.     

Magnetic remanence in the Murchison meteorite

Abstract— The Murchison meteorite is a carbonaceous chondrite containing a small amount of chondrules, various inclusions, and matrix with occasional porphyroblasts of olivine and/or pyroxene. It also contains amino acids that may have served as the necessary components for the origin of life. Magnetic analyses of Murchison identify an ultrasoft magnetic component due to superparamagnetism as a significant part of the magnetic remanence. The rest of the remanence may be due to electric discharge in the form of lightning bolts that may have formed the amino acids. The level of magnetic remanence does not support this possibility and points to a minimum ambient field of the remanence acquisition. We support our observation by showing that normalized mineral magnetic acquisition properties establish a calibration curve suitable for rough paleofield determination. When using this approach, 1–2% of the natural remanence left in terrestrial rocks with TRM and/or CRM determines the geomagnetic field intensity irrespective of grain size or type of magnetic mineral (with the exception of hematite). The same method is applied to the Murchison meteorite where the measured meteorite remanence determines the paleofield minimum intensity of 200–2000 nT during and/or after the formation of the parent body.     

The multiple meteorite fall of Neuschwanstein: Circumstances of the event and meteorite search campaigns

Abstract— A large meteorite fall in southern Germany on April 6, 2002 was captured by camera stations of the European Fireball Network (EN) which routinely monitors the night sky over central Europe. From analysis of the images, a prediction on the geographic location of the meteorite strewn field could be made. Following systematic ground searches in difficult high‐mountain terrain, three fragments of a rare EL6 enstatite chondrite were recovered during search campaigns in the summers of 2002 and 2003. “Neuschwanstein” is the fourth meteorite fall in history that has been photographed by fireball networks and the fragments of which have been found subsequently. It is the first time since the beginning of the EN operation in the early sixties that the photographic observations have made a meteorite recovery possible.     

The fall of the St-Robert meteorite

Abstract The St-Robert (Québec, Canada) meteorite shower occurred on 1994 June 15 at 0h02m UT accompanied by detonations audible for >200 km from the fireball endpoint. The fireball was recorded by visual observers in Vermont, New York State, New Hampshire, Québec and Ontario as well as by optical and infrared sensors in Earth-orbit. Penetration to an altitude of 36 km occurred ～60 km to the northeast of Montreal, where the bolide experienced several episodes of fragmentation. A total of 20 fragments of this H5 chondrite, comprising a total mass of 25.4 kg, were recovered in an ellipse measuring 8 × 3.5 km. One fragment of the shower partially penetrated the aluminum roof of a shed. Interpretation of the visual and satellite data suggests that the fireball traveled from south-southwest to north-northeast, with a slope from the horizontal of 55°–61°. A statistical evaluation of the likely heliocentric orbits for the body prior to collision with the Earth, coupled with theoretical modeling of the entry, suggests an entry velocity in the range of 12.7–13.3 km/s; the meteoroid had moved in a low-inclination orbit, with orbital perihelion located extremely close to the Earth's orbit. From satellite optical data, it is found that the photometric mass consumed during the largest detonation is ～1200 kg. Estimation of the amplitude of the acoustic signal detected by the most distant observer yields a source energy near 0.5 kt TNT equivalent energy, which corresponds to a mass of order 10 metric tonnes. This measure is uncertain to approximately one order of magnitude. Theoretical modeling of the entry of the object suggests a mass near 1600 kg. Cosmogenic radionuclide activities constrain the lower initial mass to be ～700 kg with an upper limit near 4000 kg. Seismic data possibly associated with the fireball suggest extremely poor coupling between the airwave and the ground. The total mass estimated to have reached the ground is ～100 kg (in material comprising >55 g fragments), while the preatmospheric mass is found to be most probably in the range of 1200–2000 kg.     

Aqueous alteration of the Nakhla meteorite

Abstract— Interior samples of three different Nakhla specimens contain an iron-rich silicate “rust” (which includes a tentatively identified smectite), Ca-carbonate (probably calcite), Ca-sulfate (possibly gypsum or bassanite), Mg-sulfate (possibly epsomite or kieserite), and NaCl (halite); the total abundance of these phases is estimated as <0.01 weight percent of the bulk meteorite. Rust veins are truncated and decrepitated by fusion crust and are preserved as faulted segments in partially healed olivine crystals, indicating that the rust is pre-terrestrial in origin. Because Ca-carbonate and Ca-sulfate are intergrown with the rust, they are also indicated to be of pre-terrestrial origin. Similar textural evidence regarding origins of the NaCl and Mg-sulfate is lacking. Impure and poorly crystallized sulfates and halides on the fusion crust of the meteorite suggest leaching of interior (pre-terrestrial) salts from the interior after Nakhla arrived on Earth but coincidental addition of these same salts by terrestrial contamination cannot be excluded. At least the clay-like silicate “rust,” Ca-carbonate, and Ca-sulfate were formed by precipitation from water-based solutions on the Nakhla parent planet although temperature and pressure conditions of aqueous precipitation are unconstrained by currently available data. It is possible that aqueous alteration on the parent body was responsible for the previously observed disturbance of the Rb-Sr geochronometer in Nakhla at or near 1.3 Ga.     

Atmospheric variations and meteorite production on Mars

Through a combination of aerobraking (drag deceleration) and ablation, meteoroids which enter planetary atmospheres may be slowed sufficiently to soft-land as meteorites. Results of an earlier study suggest that the current 6 mbar atmosphere of Mars is sufficient to aerobrake significant numbers of small (<10 kg) asteroidal-type meteoroids into survivable, low-velocity (<500 m s⁻¹) impacts with the planet's surface. Since rates of meteorite production depend upon the density of Mars's atmosphere, they must also change as the martian climate changes. However, to date, martian meteorite production has received relatively little attention in the literature Here we expand upon our previous work to study martian meteorite production rates and how they depend upon variations of the martian atmosphere, and to estimate the ranges of mass, velocity and entry-angle that produce meteorites. We find that even the current atmosphere of Mars is sufficient to soft-land significant fractions of incident stony and iron objects, and that these fractions increase dramatically for denser martian atmospheres. Therefore, like impact cratering, meteorite populations may preserve evidence of past martian climates.     

Evidence for silicate dissolution on Mars from the Nakhla meteorite

Veins containing carbonates, hydrous silicates, and sulfates that occur within and between grains of augite and olivine in the Nakhla meteorite are good evidence for the former presence of liquid water in the Martian crust. Aqueous solutions gained access to grain interiors via narrow fractures, and those fractures within olivine whose walls were oriented close to (001) were preferentially widened by etching along [001]. This orientation selective dissolution may have been due to the presence within olivine of shock‐formed [001](100) and [001]{110} screw dislocations. The duration of etching is likely to have been brief, possibly less than a year, and the solutions responsible were sufficiently cool and reducing that laihunite did not form and Fe liberated from the olivine was not immediately oxidized. The pores within olivine were mineralized in sequence by siderite, nanocrystalline smectite, a Fe‐Mg phyllosilicate, and then gypsum, whereas only the smectite occurs within augite. The nanocrystalline smectite was deposited as submicrometer thick layers on etched vein walls, and solution compositions varied substantially between and sometimes during precipitation of each layer. Together with microcrystalline gypsum the Fe‐Mg phyllosilicate crystallized as water briefly returned to some of the veins following desiccation fracturing of the smectite. These results show that etching of olivine enhanced the porosity and permeability of the nakhlite parent rock and that dissolution and secondary mineralization took place within the same near‐static aqueous system.     

Mineralogy of meteorite groups

Abstract— Approximately 275 mineral species have been identified in meteorites, reflecting diverse redox environments, and, in some cases, unusual nebular formation conditions. Anhydrous ordinary, carbonaceous and R chondrites contain major olivine, pyroxene and plagioclase; major opaque phases include metallic Fe-Ni, troilite and chromite. Primitive achondrites are mineralogically similar. The highly reduced enstatite chondrites and achondrites contain major enstatite, plagioclase, free silica and kamacite as well as nitrides, a silicide and Ca-, Mg-, Mn-, Na-, Cr-, K- and Ti-rich sulfides. Aqueously altered carbonaceous chondrites contain major amounts of hydrous phyllosilicates, complex organic compounds, magnetite, various sulfates and sulfides, and carbonates. In addition to kamacite and taenite, iron meteorites contain carbides, elemental C, nitrides, phosphates, phosphides, chromite and sulfides. Silicate inclusions in IAB/IIICD and IIE iron meteorites consist of mafic silicates, plagioclase and various sulfides, oxides and phosphates. Eucrites, howardites and diogenites have basaltic to orthopyroxenitic compositions and consist of major pyroxene and calcic plagioclase and several accessory oxides. Ureilites are made up mainly of calcic, chromian olivine and low-Ca clinopyroxene embedded in a carbonaceous matrix; accessory phases include the C polymorphs graphite, diamond, lonsdaleite and chaoite as well as metallic Fe-Ni, troilite and halides. Angrites are achondrites rich in fassaitic pyroxene (i.e., Al-Ti diopside); minor olivine with included magnesian kirschsteinite is also present. Martian meteorites comprise basalts, lherzolites, a dunite and an orthopyroxenite. Major phases include various pyroxenes and olivine; minor to accessory phases include various sulfides, magnetite, chromite and Ca-phosphates. Lunar meteorites comprise mare basalts with major augite and calcic plagioclase and anorthositic breccias with major calcic plagioclase. Several meteoritic phases were formed by shock metamorphism. Martensite (α₂-Fe,Ni) has a distorted body-centered-cubic structure and formed by a shear transformation from taenite during shock reheating and rapid cooling. The C polymorphs diamond, lonsdaleite and chaoite formed by shock from graphite. Suessite formed in the North Haig ureilite by reduction of Fe and Si (possibly from olivine) via reaction with carbonaceous matrix material. Ringwoodite, the spinel form of (Mg,Fe)₂SiO₄, and majorite, a polymorph of (Mg,Fe)SiO₃ with the garnet structure, formed inside shock veins in highly shocked ordinary chondrites. Secondary minerals in meteorite finds that formed during terrestrial weathering include oxides and hydroxides formed directly from metallic Fe-Ni by oxidation, phosphates formed by the alteration of schreibersite, and sulfates formed by alteration of troilite.     

Amino acids in the Tagish Lake meteorite

Abstract— High‐performance liquid chromatography (HPLC) based amino acid analysis of a Tagish Lake meteorite sample recovered 3 months after the meteorite fell to Earth have revealed that the amino acid composition of Tagish Lake is strikingly different from that of the CM and CI carbonaceous chondrites. We found that the Tagish Lake meteorite contains only trace levels of amino acids (total abundance = 880 ppb), which is much lower than the total abundance of amino acids in the CI Orgueil (4100 ppb) and the CM Murchison (16 900 ppb). Because most of the same amino acids found in the Tagish Lake meteorite are also present in the Tagish Lake ice melt water, we conclude that the amino acids detected in the meteorite are terrestrial contamination. We found that the exposure of a sample of Murchison to cold water lead to a substantial reduction over a period of several weeks in the amount of amino acids that are not strongly bound to the meteorite matrix. However, strongly bound amino acids that are extracted by direct HCl hydrolysis are not affected by the leaching process. Thus even if there had been leaching of amino acids from our Tagish Lake meteorite sample during its 3 month residence in Tagish Lake ice and melt water, a Murchison type abundance of endogenous amino acids in the meteorite would have still been readily detectable. The low amino acid content of Tagish Lake indicates that this meteorite originated from a different type of parent body than the CM and CI chondrites. The parent body was apparently devoid of the reagents such as aldehyldes/ketones, HCN and ammonia needed for the effective abiotic synthesis of amino acids. Based on reflectance spectral measurements, Tagish Lake has been associated with P‐ or D‐type asteroids. If the Tagish Lake meteorite was indeed derived from these types of parent bodies, our understanding of these primitive asteroids needs to be reevaluated with respect to their potential inventory of biologically important organic compounds.     

The Mbale meteorite shower

Abstract— On 1992 August 14 at 12:40 UTC, an ordinary chondrite of type L5/6 entered the atmosphere over Mbale, Uganda, broke up, and caused a strewn field of size 3 × 7 km. Shortly after the fall, an expedition gathered eye witness accounts and located the position of 48 impacts of masses between 0.1 g and 27.4 kg. Short-lived radionuclide data were measured for two specimens, one of which was only 12 days after the fall. Subsequent recoveries of fragements has resulted in a total of 863 mass estimates by 1993 October. The surfaces of all fragments contain fusion crust. The meteorite shower caused some minor inconveniences. Most remarkably, a young boy was hit on the head by a small specimen. The data are interpreted as to indicate that the meteorite had an initial mass between 400–1000 kg (most likely ～1000 kg) and approached Mbale from Az = 185 ± 15, H = 55 ± 15, and V_∞ = 13.5 ± 1.5/s. Orbital elements are given. Fragmentation of the initial mass started probably above 25 km altitude, but the final catastrophic breakup occurred at an altitude of 10–14 km. An estimated 190 ± 40 kg reached the Earth's surface minutes after the final breakup of which 150 kg of material has been recovered.     

Stony meteorite thermal properties and their relationship with meteorite chemical and physical states

Abstract– In our ongoing survey of meteorite physical properties, we have to date measured the thermal conductivity for seventeen stony meteorites at temperatures ranging from 5 K to 300 K. Here, we report new results for nine ordinary chondrites, one enstatite chondrite, and the basaltic achondrites Frankfort (howardite) and Los Angeles (shergottite). We find that thermal conductivity is significantly lower than would be expected from averaging the laboratory conductivities of their constituent minerals, with a dependence on temperature different from the expected conductivity of pure minerals. In addition, we find a linear relationship between the inverse of the porosity of the samples measured and their thermal conductivity, regardless of meteorite composition or type. We conclude that thermal conductivity is controlled by the presence of shock‐induced microcracks within the meteorites, which provide a barrier to the transmission of thermal energy via phonons. In contrast to conductivity, our first measurement of heat capacity as a function of temperature (on Los Angeles) suggests that heat capacity is primarily a function of oxide composition and is not strongly affected by the physical state of the sample.