A speculation on the structure of the D″ layer: The growth of anti-crust at the core–mantle boundary through the subduction history of the Earth

The growth curve of the continental crust shows that large amounts of continental crust formed in the early part of the Earth history are missing. In order to test a hypothesis that the former crust was subducted to the deep mantle, we performed phase assemblage analysis in the systems of mid-oceanic ridge basalt (MORB), anorthosite, and tonalite–trondhjemite–granite (TTG) down to the core–mantle boundary (CMB) conditions. Results show that all these materials can be subducted to the CMB leading to the development of a compositional layering in the D″ layer. We speculate that there could be five layers of FeO-enriched melt from partial melting of MORB, MORB crust, anorthosite, TTG, and slab or mantle peridotite in ascending order. Although the polymorphic transformation of perovskite to post-perovskite in (Mg,Fe)SiO₃ may explain the seismic discontinuity at the top of the D″ layer (D″ discontinuity), the effects of solid solution on the sharpness of the transformation suggest that the compositional layering is more plausible for the origin of the D″ discontinuity. The D″ layer can be an “anti-crust” made up mostly of TTG + anorthosite derived from the former continental crust. Tectonic style of the anti-crust at the CMB is similar to that at the surface. At both places, chemically distinct layers are density stratified and are also characterized by the processes of accretion, magmatism, and metasomatism.     

High-pressure phase transitions of anorthosite crust in the Earth's deep mantle

We investigated phase relations, mineral chemistry, and density of lunar highland anorthosite at conditions up to 125 GPa and 2000 K. We used a multi-anvil apparatus and a laser-heated diamond-anvil cell for this purpose. In-situ X-ray diffraction measurements at high pressures and composition analysis of recovered samples using an analytical transmission electron microscope showed that anorthosite consists of garnet, CaAl₄Si₂O₁₁-rich phase (CAS phase), and SiO₂ phases in the upper mantle and the mantle transition zone. Under lower mantle conditions, these minerals transform to the assemblage of bridgmanite, Ca-perovskite, corundum, stishovite, and calcium ferrite-type aluminous phase through the decomposition of garnet and CAS phase at around 700 km depth. Anorthosite has a higher density than PREM and pyrolite in the upper mantle, while its density becomes comparable or lower under lower mantle conditions. Our results suggest that ancient anorthosite crust subducted down to the deep mantle was likely to have accumulated at 660–720 km in depth without coming back to the Earth's surface. Some portions of the anorthosite crust might have circulated continuously in the Earth's deep interior by mantle convection and potentially subducted to the bottom of the lower mantle when carried within layers of dense basaltic rocks.     

Granite subduction: Arc subduction, tectonic erosion and sediment subduction

Continental growth has been episodic, reflecting the episodic nature of mantle dynamics as well as surface dynamics of the Earth, the net result of which is exhibited by the present mantle with two huge reservoirs of TTG rocks, one on the surface continents and the other on the D″ layer on the Core-Mantle Boundary (CMB). During the early half of the Earth history, the felsic continental crust on the surface which formed in an intra-oceanic environment has mostly been subducted into the deep mantle, except in the rare case of parallel arc collision. The growth history of continental crust shows that with its simultaneous formation, a considerable amount must have also been subducted. Such ongoing subduction processes can be seen in the western Pacific region, through tectonic erosion, arc subduction, and sediment-trapped subduction.     

Phase transformations in descending plates and implications for mantle dynamics

The role of phase transformations in a mantle of pyrolite composition is reviewed in the light of recent experimental data. The pyroxene component of pyrolite transforms to the garnet structure at 300–350 km whilst olivine transforms to beta-Mg₂SiO₄ near 400 km. Between about 500 and 550 km, beta-Mg₂SiO₄ probably transforms to a partially inverse spinel structure whilst the CaSiO₃ component of the complex garnet solid solution exsolves and transforms to the perovskite structure. The major seismic discontinuity near 650–700 km is probably caused by disproportionation of Mg₂SiO₄ spinel into periclase plus stishovite. At a slightly greater depth, the remaining magnesian garnet transforms to the corundum or ilmenite structure. Finally, at a depth probably in the vicinity of 800–1000 km, the (Mg,Fe)SiO₃ component of the ilmenite phase transforms to a perovskite structure whilst stishovite and some of the periclase recombine to form perovskite also. The mineral assemblage so formed is about 4% denser than mixed oxides (MgO + FeO + A1₂O₃ + CaO + stishovite) isochemical with pyrolite. The above sequence of phase transformations in pyrolite provides a satisfactory general explanation of the elastic properties and density distribution in the mantle. In particular, there is no evidence requiring an increase of FeO/(FeO + MgO) ratio with depth.The depths at which major phase transformations occur in subducted lithosphere differ from those in ‘normal’ mantle. These differences are caused by two factors: (1) Temperatures within sinking plates are much lower than in surrounding mantle to depths of 700 km or more. (2) Irreversible chemical differentiation of pyrolite occurs at oceanic ridges. Lithosphere plates so formed consist of a layer of basaltic rocks underlain successively by layers of harzburgite, lherzolite, and pyrolite slightly depleted in highly incompatible elements (e.g. La, Ba, Rb, U). The phase-transformation behaviour of the first three of these layers differs from that of pyrolite.The effects of these and other factors connected with phase transformations on the dynamics of plate subsidence are discussed. It appears quite likely that plates penetrate the 650–700 km discontinuity, largely because the slope of the spinel disproportionation is probably positive, not negative as generally supposed. The former basaltic oceanic crust probably sinks deeply into the lower mantle, whilst the former harzburgite component of the plate may collect above the perovskite transition boundary. Phase transformations may thus serve as a kind of filter, leading to increased and irreversible mantle heterogeneity with time.The possible roles of phase transformations in causing deep-focus earthquakes and introducing water into the mantle in subduction zones are also briefly discussed.     

Superplume, supercontinent, and post-perovskite: Mantle dynamics and anti-plate tectonics on the Core–Mantle Boundary

The Western Pacific Triangular Zone (WPTZ) is the frontier of a future supercontinent to be formed at 250 Ma after present. The WPTZ is characterized by double-sided subduction zones to the east and south, and is a region dominated by extensive refrigeration and water supply into the mantle wedge since at least 200 Ma. Long stagnant slabs extending over 1200 km are present in the mid-Mantle Boundary Layer (MBL, 410–660 km) under the WPTZ, whereas on the Core–Mantle Boundary (CMB, 2700–2900 km depth), there is a thick high-V anomaly, presumably representing a slab graveyard. To explain the D″ layer cold anomaly, catastrophic collapse of once stagnant slabs in MBL is necessary, which could have occurred at 30–20 Ma, acting as a trigger to open a series of back-arc basins, hot regions, small ocean basins, and presumably formation of a series of microplates in both ocean and continent. These events were the result of replacement of upper mantle by hotter and more fertile materials from the lower mantle.The thermal structure of the solid Earth was estimated by the phase diagrams of Mid Oceanic Ridge Basalt (MORB) and pyrolite combined with seismic discontinuity planes at 410–660 km, thickness of the D″ layers, and distribution of the ultra-low velocity zone (ULVZ). The result clearly shows the presence of two major superplumes and one downwelling. Thermal structure of the Earth seems to be controlled by the subduction history back to 180 Ma, except in the D″ layer. The thermal structure of the D″ layer seems to be controlled by older slab-graveyards, as expected by paleogeographic reconstructions for Laurasia, Gondwana and Rodinia back to 700 Ma.Comparison of mantle tomography between the Pacific superplume and underneath the WPTZ suggests the transformation of a cold slab graveyard to a large-scale mantle upwelling with time. The Pacific superplume was born from the coldest CMB underneath the 1.0–0.75 Ga supercontinent Rodinia where huge amounts of cold slabs had accumulated through collision-amalgamation of more than 12 continents. A high velocity P-wave anomaly on a whole-mantle scale shows stagnant slabs restricted to the MBL of circum-Pacific and Tethyan regions. The high velocity zones can be clearly identified within the Pacific domain, suggesting the presence of slab graveyards formed at geological periods much older than the breakup of Rodinia. We speculate that the predominant subduction occurred through the formation period of Gondwana, presumably very active during 600 to 540 Ma period, and again from 400 to 300 Ma during the formation of the northern half of Pangea (Laurasia). We correlate the three dominant slab graveyards with three major orogenies in earth history, with the emerging picture suggesting that the present-day Pacific superplume is located at the center of the Rodinian slab graveyard.We speculate the mechanism of superplume formation through a comparison of the thermal structure of the mantle combined with seismic tomography under the Western Pacific Triangular Zone (WPTZ), Laurasia (Asia), Gondwana (Africa), and Rodinia (Pacific). The coldest mantle formed by extensive subduction to generate a supercontinent, changes with time of the order of several hundreds of million years to the hottest mantle underneath the supercontinent. The Pacific superplume is tightly defined by a steep velocity gradient on the margin, particularly well documented by S-wave velocity. The outermost region of the superplume is characterized by the Rodinia slab graveyard forming a donut-shape. We develop a petrologic model for the Pacific superplume and show how larger plumes are generated at shallower depths in the mantle. We link the mechanism of formation of the superplume to the presence of the mineral post-perovskite, the phase transformation of which to perovskite is exothermic, and thus aids in transporting core heat to mantle, and finally to planetary space by plumes.We summarize the characteristics of tectonic processes operating at the CMB to propose the existence of an “anti-crust” generated through “anti-plate tectonics” at the bottom of the mantle. The chemistry of the anti-crust markedly contrasts with that of the continental crust overlying the mantle. Both the crust and the anti-crust must have increased in volume through geologic time, in close relation with the geochemical reservoirs of the Earth. The process of formation of a new superplume closely accompanies the process of development of anti-crust at the bottom of mantle, through the production of dense melt from the partial melting of recycled MORB, observed now as the ULVZ. When CMB temperature is recovered to near 4000 K through phase transformation, the recycled MORB is partially melted imparting chemical buoyancy of the andesitic residual solid which rises up from CMB, leaving behind the dense melt to sink to CMB and thus increase the mass of anti-crust. These small-scale plumes develop to a large-scale superplume through collision and amalgamation with time. When all recycled MORBs are consumed, it is the time of demise of superplume. Immediately above the CMB, anti-plate tectonics operates to develop anti-crust through the horizontal movement of accumulated slab and their partial melting. Thus, we speculate that another continent, or even a supercontinent, has developed through geologic time at the bottom of the mantle.We also evaluate the heating vs. cooling models in relation to mantle dynamics. Rising plumes control not only the rifting of supercontinents and continents, but also the Atlantic stage as seen by anchored ridge by hotspots in the last 200 Ma in the Atlantic. Therefore, we propose that the major driving force for the mantle dynamics is the heat supplied from the high-T core, and not the slab pull force by cooling. The best analogy for this is the atmospheric circulation driven by the energy from Sun.     

REE and PGE Geochemical Constraints on the Formation of Dunites in the Luobusa Ophiolite, Southern Tibet

The Luobusa ophiolite, Southern Tibet, lies in the Indus–YarlungZangbo suture zone that separates Eurasia to the north fromthe Indian continent to the south. The ophiolite contains awell-preserved mantle sequence consisting of harzburgite, clinopyroxene(cpx)-bearing harzburgite and dunite. The harzburgite containsabundant pods of chromitite, most of which have dunite envelopes,and the cpx-bearing harzburgites host numerous dunite dykes.Dunite also exists as a massive unit similar to those of themantle–crust transition zones in other ophiolites. Allof the dunites in the ophiolite have a similar mineralogy, comprisingmainly olivine with minor orthopyroxene and chromite and tracesof clinopyroxene. They also display similar chemical compositions,including U-shaped chondrite-normalized REE patterns. Mantle-normalizedPGE patterns show variable negative Pt anomalies. Detailed analysisof a chromite-bearing dunite dyke, which grades into the hostcpx-bearing harzburgite, indicates that LREE and Ir decrease,whereas HREE, Pd and Pt increase away from the dunite. Thesefeatures are consistent with formation of the dunite dykes byinteraction of MORB peridotites with boninitic melts from whichthe chromitites were formed. Because the transition-zone dunitesare mineralogically and chemically identical to those formedby such melt–rock reaction, we infer that they are ofsimilar origin. The Luobusa ultramafic rocks originally formedas MORB-source upper mantle, which was subsequently trappedas part of a mantle wedge above a subduction zone. Hydrous meltsgenerated under the influence of the subducted slab at depthmigrated upward and reacted with the cpx-bearing harzburgitesto form the dunite dykes. The modified melts ponded in smallpockets higher in the section, where they produced podiformchromitites with dunite envelopes. At the top of the mantlesection, pervasive reaction between melts and harzburgite producedthe transition-zone dunites. KEY WORDS: melt–rock interaction; REE; PGE; hydrous melt; mantle; ophiolite; Tibet     

Lithosphere structure of the Ukrainian Shield and Pripyat Trough in the region of EUROBRIDGE-97 (Ukraine and Belarus) from gravity modelling

The southern segment of the seismic profile EUROBRIDGE—EUROBRIDGE-97 (EB'97)—located in Belarus and Ukraine, crosses the suture zone between two main segments of the East European Craton—Fennoscandia and Sarmatia—as well as Sarmatia itself. At the initial stage of our study, a 3-D density model has been constructed for the crust of the study region, including the major part of the Osnitsa–Mikashevichi Igneous Belt (OMIB) superimposed by sediments of the Pripyat Trough (PT), and three domains in the Ukrainian Shield—the Volhyn Domain (VD) with the anorthosite–rapakivi Korosten Pluton (KP), the Podolian Domain (PD), and the Ros–Tikich Domain (RTD). The model comprises three layers—sediments with maximum thickness (6 km) in the PT and two heterogeneous layers in the crystalline crust separated at a depth of 15 km. 3-D calculations show the main features of the observed gravity field are caused by density heterogeneities in the upper crust. Allocation of density domains deeper than 15 km is influenced by Moho topography. Fitting the densities here reveals an increase (up to 2960 kg m⁻³) in the modelled bodies accompanied by a Moho deepening to 50 km. In contrast, a Moho uplift to a level of 35–37 km below the KP and major part of the PT is associated with domains of reduced densities. An important role for the deep Odessa–Gomel tectonic zone, dividing the crust into two regions one of basically Archean consolidation in the west (PD and RTD) and one of Proterozoic crust in the east (Kirovograd Domain)—was confirmed.2-D density modelling on the EB'97 profile shows that in the upper crust three main domains of different Precambrian evolution—the OMIB (with the superimposed PT), the VD with the KP, and the PD—can be distinguished. Deeper, in the middle and lower crust, layered structures having no connection to the surface geology are dominant features of the models. Least thickness of the crust was obtained below the KP. Greatest crustal thickness (more than 50 km) was found below the PD, characterised also by maximum deviation of velocity/density relation in the rocks from a standard one. The velocity and density models along the EB'97 profile have been interpreted together with inferred V_p/V_s ratios to estimate crustal composition in terms of SiO₂ content. In the course of the modelling, the status of the PD as a centre of Archean granulitic consolidation has been confirmed. The crustal structure of the anorthosite–rapakivi KP is complex. For the first time, a complicated structure for the lower crust and lower crust–upper mantle transition zone beneath the KP has been determined. The peculiarities of the crustal structure of the KP are quite well explained in terms of formation of rapakivi–anorthosite massifs as originating from melt chambers in the upper mantle and lower crust. An important role for the South Pripyat Fault (SPF), repeatedly activated during Proterozoic–Palaeozoic times, has been ascertained. At the subplatform stage of crustal evolution the SPF was, probably, a magma channel facilitating the granitic intrusions of the KP. In the Palaeozoic the fault was reactivated during rifting in the PT.     

Role of tonalite-trodhjemite-granite (TTG) crust subduction on the mechanism of supercontinent breakup

The tonalite-trondhjemite-granite (TTG) crust has been considered to be buoyant and hence impossible to be subducted into the deep mantle. However, recent studies on the juvenile arc in the western Pacific region indicate that immature island arcs subduct into the deep mantle in most cases, except in the case of parallel arc collision. Moreover, sediment trapped subduction and tectonic erosion are also common. This has important implications in evaluating the role of TTG crust in the deep mantle and probably on the bottom of the mantle. Because the TTG crust is enriched in K, U and Th, ca. 20 times more than that of CI chondrite, the accumulated TTG on the Core Mantle Boundary (CMB) would have played a critical role to initiate plumes or superplumes radiating from the thermal boundary layer, particularly after 2.0 Ga, related to the origin of superplume-supercontinent cycle. This is because selective subduction of oceanic lithosphere including sediment-trapped subduction, tectonic erosion and arc- and microcontinent-subduction proceeded under the supercontinent before the final amalgamation ca. 200-300 million years after the formation of the nuclei. We speculate the mechanism of superplume evolution through the subduction of TTG-crust and propose that this process might have played a dominant role in supercontinent breakup.     

Stagnant lids and mantle overturns:Implications for Archaean tectonics,magmagenesis,crustal growth,mantle evolution,and the start of plate tectonics

The lower plate is the dominant agent in modern convergent margins characterized by active subduction,as negatively buoyant oceanic lithosphere sinks into the asthenosphere under its own weight.This is a strong plate-driving force because the slab-pull force is transmitted through the stiff sub-oceanic lithospheric mantle.As geological and geochemical data seem inconsistent with the existence of modernstyle ridges and arcs in the Archaean,a periodically-destabilized stagnant-lid crust system is proposed instead.Stagnant-lid intervals may correspond to periods of layered mantle convection where efficient cooling was restricted to the upper mantle,perturbing Earth's heat generation/loss balance,eventually triggering mantle overturns.Archaean basalts were derived from fertile mantle in overturn upwelling zones(OUZOs),which were larger and longer-lived than post-Archaean plumes.Early cratons/continents probably formed above OUZOs as large volumes of basalt and komatiite were delivered for protracted periods,allowing basal crustal cannibalism,garnetiferous crustal restite delamination,and coupled development of continental crust and sub-continental lithospheric mantle.Periodic mixing and rehomogenization during overturns retarded development of isotopically depleted MORB(mid-ocean ridge basalt)mantle.Only after the start of true subduction did sequestration of subducted slabs at the coremantle boundary lead to the development of the depleted MORB mantle source.During Archaean mantle overturns,pre-existing continents located above OUZOs would be strongly reworked;whereas OUZOdistal continents would drift in response to mantle currents.The leading edge of drifting Archaean continents would be convergent margins characterized by terrane accretion,imbrication,subcretion and anatexis of unsubductable oceanic lithosphere.As Earth cooled and the background oceanic lithosphere became denser and stiffer,there would be an increasing probability that oceanic crustal segments could founder in an organized way,producing a gradual evolution of pre-subduction convergent margins into modern-style active subduction systems around 2.5 Ga.Plate tectonics today is constituted of:(1)a continental drift system that started in the Early Archaean,driven by deep mantle currents pressing against the Archaean-age sub-continental lithospheric mantle keels that underlie Archaean cratons;(2)a subduction-driven system that started near the end of the Archaean.     

Constancy of Nb/U in the mantle revisited

It has long been proposed that MORB and OIB have constant supra-primitive mantle (PM) Nb/U values identical to each other. This fact together with complementary sub-PM values for the continental crust (CC), are taken as fundamental evidence, linking the mantle sources of MORB and OIB to the formation of the CC. Given that plate subduction at convergent margins is the major known process that dramatically fractionates Nb from U, and consequently that subducted oceanic slabs are the main primary carriers of supra-PM Nb/U, a constant supra-PM Nb/U in MORB mantle implies that the mixing of subducted oceanic crust is essentially finished or the newly recycled oceanic crust has Nb/U close to that of the mantle. The similarity between Nb and U as well as the constancy of Nb/U in MORB are revisited here based on MORB glass data obtained using laser ablation ICP-MS. The result shows that Nb/U is not correlated with Nb/Hf, supporting that Nb and U are similarly incompatible. Further investigation shows that Nb is not perfectly identical to, but is faintly more incompatible than U as indicated by the good correlation between log(U) and log(Nb) with a slope of 0.954, very close to 1. Nonetheless, the similarity between Nb and U is high enough, such that the average Nb/U value of MORB glasses should be very close to that of the MORB mantle. By contrast, the difference between Ce and Pb is more obvious. Ce is more incompatible than Pb with a slope of 1.13 in a log(Pb) versus log(Ce) diagram. Therefore, the Ce/Pb of MORB should be a little bit higher than that of the mantle source. The Nb/U value is not as uniform as expected for the similar incompatibility in studied MORB glasses, but varies by a factor of ∼2, suggesting that MORB mantle source is not yet homogenized in term of Nb/U. This indicates that the mixing back of subducted oceanic crust is still an ongoing process, i.e., subducted oceanic crust is recycling back after staying in the lower mantle for billions of years.     

地幔底层及其在全球物质演化中的意义

在核幔界面之上的下地幔一侧,地震波速分布极不均匀,厚度在50~300 km范围内变化的一层物质称为地幔底层。地幔底层由具有高地震波速和高密度的D″区和超低速带(ULVZ)组成。地幔底层是地核热能向地幔传播的必经之路,也是地幔中温度和温度梯度最高的地区。地幔底层既是俯冲板块的最终归宿,又是热柱和超级热柱的源区。因此,地幔底层既是全地幔对流的起点,又是全地幔对流的终点。在地幔底层可能发生地幔物质(包括俯冲板块物质在内)的部分熔融作用,也可能存在外核液态铁与地幔硅酸盐的化学反应。所以地幔底层在全球物质演化中占有重要的地位。     

大陆的起源

太阳系固体星球都有类似的核-幔-壳结构,但唯独人类居住的地球具有长英质组成的大陆壳.太古宙大陆克拉通主要由英云闪长岩(Tonalite)-奥长花岗岩(Trondhjemite)-花岗闪长岩(Granodiorite)为主的TTG深成侵入体变质而成的正片麻岩和由基性-超基性酸性火山岩及少量沉积岩变质的表壳岩(绿岩)组成....     

A catalytic delamination-driven model for coupled genesis of Archaean crust and sub-continental lithospheric mantle

There is no consensus on the processes responsible for near-coeval formation of Archaean continental crust (dominantly tonalite-trondhjemite-granodiorite: TTG), greenstone belts dominated by komatiitic to tholeiitic lavas (KT), and sub-continental lithospheric mantle (SCLM). The Douglas Harbour domain (2.7-2.9 Ga) of the Minto Block, northeastern Superior Province, has two TTG suites, the western and eastern Faribault-Thury (WFT and EFT), with embedded KT greenstones. Tonalites of both suites have high light/heavy rare-earth element ratios (L/HREE), high large ion lithophile element (U-Th-Rb-Cs-La: LILE) contents, positive Sr-Pb anomalies, and negative Nb-Ta-Ti anomalies. Such typical Archaean TTG signatures are commonly explained by melting of subducted oceanic crust, but could also originate by melting the base of thick basaltic plateaux formed above mantle upwellings (plumes), leaving behind restites containing pyroxene, garnet, and rutile. Field relationships (in situ segregation veins), phase equilibria (hornblende stabilized at lower crustal pressure), petrography (corroded epidote and muscovite phenocrysts, rare plagioclase phenocrysts), and trace element models, all imply that FT tonalite to trondhjemite evolution reflects hornblende-dominated fractional crystallization, not partial melting of subducted crust. The geochemistry of parental FT tonalites can be modeled by 15-30% melting of FT tholeiitic metabasalts, with residues of eclogite, garnet-websterite, or hornblende-garnet websterite. A minor residual Ti-phase such as rutile is also needed to generate negative Ti-Nb-Ta troughs in the TTGs. However, large volumes of eclogitic restites complementary to TTG are not observed either at the base of Archaean crustal sections, or in the SCLM. Additional problems with slab-melting models include: (a) the rarity of lithologies and associations characteristic of active margins (ophiolites, andesites, blueschists, accretionary mélanges, molasse, flysch, high-pressure belts, and thrust-and-fold belts); (b) the need to deliver plume-derived KT melt through the slab; and (c) extracting enough TTG melt from a subducting slab in the time available (200-300 my). In the plateau-melting model, heat for crustal anatexis is supplied by ongoing KT magma derived from mantle upwellings. However, SCLM rocks differ from predicted 1-stage mantle melting residua; and the voluminous residual eclogites complementary to TTG generation somehow need to be removed. These two problems might solve one another if the dense crustal restites disaggregated and mixed into the underlying depleted mantle. Mantle melting slows upon exhaustion of Ca-Al-rich phases, with large temperature increases needed to extract more melt from harzburgite residua. Physical addition of delaminated crustal restites would refertilize the refractory mantle, allowing extraction of additional melt increments, and might explain the ultra-depleted and orthopyroxene-rich nature of the SCLM. A hybrid source composed of 10% eclogitic restite of EFT tonalite generation, mixed with harzburgitic residues from 25% melting of primitive mantle, yields model melts with trace element signatures resembling typical Munro komatiites. Variations in the mineralogy and geochemistry of the delaminated component might account for the diversity of komatiite types. Degassing of hornblende-rich delaminated restites would transfer LILE to surrounding depleted mantle and could generate boninites. Fusion of undepleted metabasalt sandwiched among denser restites could generate sanukitoids. Mantle melt pulses generated by catastrophic delamination events would underplate nascent TTG crust and trigger renewed crustal melting, followed by delamination of newly formed eclogitic restites, triggering additional mantle melting, and so on. I posit that delamination of crustal restites catalyzed multi-stage melting of the SCLM and maturation of the Archaean continental crust. Thus, Archaean crust and SCLM are genetically inter-linked, and both form above major mantle upwellings.     

The subducted oceanic crust within continental-type UHP metamorphic belt in the North Qaidam, NW China: Evidence from petrology, geochemistry and geochronology

Three types of eclogite, together with a serpentinized harzburgite, coexist as blocks within granitic and pelitic gneisses along the Shaliuhe cross section, the eastern part of the North Qaidam continental-type ultrahigh-pressure (UHP) metamorphic belt, NW China. The olivine (Ol¹) and orthopyroxene in the harzburgite are compositionally similar to present-day abyssal peridotites. The kyanite–eclogite is derived from a troctolitic protolith, whereas the epidote–eclogite from a gabbroic protolith, both having distinct positive Eu anomalies, low TiO₂, and high Al₂O₃ and MgO. The kyanite–eclogite shows inherited cumulate layering. The phengite–eclogite has high TiO₂, low Al₂O₃ and MgO with incompatible trace elements resembling enriched-type MORB. Sr–Nd isotope data indicate that the protoliths of both kyanite–eclogite and epidote–eclogite ([⁸⁷Sr/⁸⁶Sr]_i ~ 0.703–0.704; ε_Nd(T) ~ 5.9–8.0) are of mantle origin (e.g., ocean crust signatures). On the other hand, while the lower ε_Nd(T) value (1.4–4.1) of phengite–eclogite is more or less consistent with an enriched MORB protolith, their high [⁸⁷Sr/⁸⁶Sr]_i ratio (0.705–0.716) points to an additional enrichment in their history, probably in an subduction-zone environment. Field relations and geochemical analyses suggest that the serpentinized harzburgite and the three types of eclogite constitute the oceanic lithological section of an ophiolitic sequence from mantle peridotite, to cumulate, and to upper basaltic rocks. The presence of coesite pseudomorphs and quartz exsolution in omphacite plus thermobarometric calculations suggests that the eclogites have undergone ultrahigh pressure metamorphism (i.e., peak P ≥ 2.7 GPa). The harzburgite may also have experienced the same metamorphism, but the lack of garnet suggests that the pressure conditions of ≤ 3.0 GPa. Zircon U–Pb SHRIMP dating shows that the eclogites have a protolith age of 516 ± 8 Ma and a metamorphic age of 445 ± 7 Ma. These data indicate the presence of a Paleo-Qilian Ocean between Qaidam and Qilian blocks before the early Ordovician. The ophiolitic assemblage may be the relics of subducted oceanic crust prior to the subduction of continental materials during Ordovician–Silurian times and ultimate continent collision. These rocks, altogether, record a complete history of ocean crust subduction, to continental subduction, and to continental collision.     

New insights into the origin of O–Hf–Os isotope signatures in arc lavas from Tonga–Kermadec

O, Hf and Os isotope data are presented for lavas from the highly depleted Tonga–Kermadec arc. O isotope values overlap with those of MORB limiting the amount of interaction with the arc crust. δ¹⁸O does not increase northwards as would be expected from the ~ 4 fold increase in subduction rate if slab-derived fluids had high ¹⁸O/¹⁶O ratios. Thus, the overall northward decrease in HFSE concentrations likely reflects depletion due to prior melt extraction, not increasing extents of melting. Hf isotopes are strongly negatively correlated with Be isotopes consistent with mixing of subducted pelagic sediment into the mantle wedge and do not require Hf to be fluid mobile. With the exception of a boninite from the north Tongan trench, the northern Tonga lavas do not overlap the Hf isotope composition of either the Samoan plume or the subducting Louisville volcaniclastic sediments. Thus, the Pb isotope signatures in these lavas must have been added by fluids and sediment melts derived from the Louisville volcaniclastics with minimal mobilisation of Hf. This suggests conservative behaviour for this element due to the formation of residual zircon during partial melting of the subducted sediments. ¹⁸⁷Os/¹⁸⁸Os ranges from 0.1275 to 0.4731 and the higher Os isotope ratios reflect the sensitivity of this system to even minor interaction with altered arc crust. Conversely, the lowest Os ratios are subchondritic and indicate that transfer of radiogenic Os from the slab is not all pervasive and provide an important constraint on the composition of the mantle wedge. Remarkably, the least radiogenic sample is a dacite demonstrating that evolved magmas can develop by fractionation from mantle-derived magmas with minimal interaction with the arc crust.     

俯冲带部分熔融

俯冲带是地幔对流环的下沉翼,是地球内部的重要物理与化学系统。俯冲带具有比周围地幔更低的温度,因此,一般认为俯冲板片并不会发生部分熔融,而是脱水导致上覆地幔楔发生部分熔融。但是,也有研究认为,在水化的洋壳俯冲过程中可以发生部分熔融。特别是在下列情况下,俯冲洋壳的部分熔融是俯冲带岩浆作用的重要方式。年轻的大洋岩石圈发生低角度缓慢俯冲时,洋壳物质可以发生饱和水或脱水熔融,基性岩部分熔融形成埃达克岩。太古代的俯冲带很可能具有与年轻大洋岩石圈俯冲带类似的热结构,俯冲的洋壳板片部分熔融可以形成英云闪长岩-奥长花岗岩-花岗闪长岩。平俯冲大洋高原中的基性岩可以发生部分熔融产生埃达克岩。扩张洋中脊俯冲可以导致板片窗边缘的洋壳部分熔融形成埃达克岩。与俯冲洋壳相比,俯冲的大陆地壳具有很低的水含量,较难发生部分熔融,但在超高压变质陆壳岩石的折返过程中可以经历广泛的脱水熔融。超高压变质岩在地幔深部熔融形成的熔体与地幔相互作用是碰撞造山带富钾岩浆岩的可能成因机制。碰撞造山带的加厚下地壳可经历长期的高温与高压变质和脱水熔融,形成S型花岗岩和埃达克质岩石。     

Mantle petrology and mineralogy of the Thetford Mines Ophiolite Complex

The Ordovician Thetford Mines ophiolite complex (TMOC) formed by boninite-fed seafloor-spreading, probably in a fore-arc environment. The mantle section is dominated by foliated harzburgite (≤ 5–6% clinopyroxene), cut by dunitic (± chromitite cores) and orthopyroxenitic veins and dykes. Contrasting structures, textures and mineral compositions allow us to subdivide the mantle. The granular-textured rocks of the Duck Lake Block (DLB) have two steeply-dipping foliations. The older foliation strikes NW, is sub-perpendicular to the Moho, and is interpreted to have resulted from upflow of the asthenosphere beneath the spreading ridge. This fabric is overprinted by a 2nd ductile foliation striking ENE, oriented sub-parallel to the Moho, which we interpreted as having formed by crust–mantle shear as the lithosphere migrated away from the spreading ridge. The DLB mantle has a limited range of spinel Cr# (100Cr / (Cr + Al) = 51–71). Comparison with experimentally determined residual spinel compositions (equilibrium melting) implies a maximum loss of 27–38% melt if the protolith had a fertile MORB mantle composition. However, interstitial-textured clinopyroxene may have high TiO₂ (< 0.04wt.%) and Na₂O (< 0.27wt.%), and some interstitial spinel has higher TiO₂ (< 0.09wt.%), suggesting interaction with (or crystallization from) an “impregnating” melt. Interstitial tremolitic amphibole also indicates the passage of late hydrous fluids. The harzburgite in the Caribou Mountain Block (CMB) has a porphyroclastic texture, with a strong, locally mylonitic foliation striking roughly N–S, parallel to the orientation of seafloor-spreading related paleo-normal faults in the crust. These fabrics and textures imply a colder, lithospheric deformation, possibly related to tectonic denudation (oceanic core complex). This would explain problematic lava/mantle contacts, favour infiltration of seawater, serpentinization, and reduced fO₂ conditions. The CMB mantle shows a wider range of mineral compositions than the DLB, with spinel Cr# (28–86) implying ≤ 15–45% of equilibrium melting. Locally higher TiO₂ in spinel (< 0.05wt.%) and clinopyroxene (< 0.11wt.%), a local rimward decrease in spinel Cr#, clinopyroxene Cr#, and olivine Fo-content, and traces of interstitial amphibole, are attributed to the circulation of an evolved hydrous melt during peridotite deformation. This suggests that the lower limit to the extent of melting inferred for the CMB (15%), established on the basis of Al-rich spinel rims and neoblasts, is probably too low. On the other hand, the higher inferred degree of depletion of the CMB is probably unaffected by the metasomatic overprint and is a more robust conclusion.     

Migration and accumulation of ultra-depleted subduction-related melts in the Massif du Sud ophiolite (New Caledonia)

The Massif du Sud is a large ophiolitic complex that crops out in the southern region of New Caledonia (SW Pacific). It is dominated by harzburgite tectonite that locally shows a transitional gradation to massive dunite up section. Clinopyroxene, orthopyroxene and plagioclase progressively appear in dunite up to the transition to layered wehrlite and orthopyroxene–gabbro. The dunite–wehrlite and wehrlite–gabbro contacts are parallel and the latter defines the paleo-Moho.Highly depleted modal, mineral and bulk rock compositions indicate that harzburgites are residues after high degrees (20–30%) of partial melting mainly in the spinel-stability field. Their relative enrichment in HFSE, LREE and MREE is due to re-equilibration of melting residues with percolating melts. Dunite formed in the Moho transition zone by reaction between residual mantle harzburgite and olivine-saturated melts that led to pyroxene dissolution and olivine precipitation. Rare clinopyroxene and plagioclase crystallized in interstitial melt pores of dunite from primitive, low-TiO₂, ultra-depleted liquids with a geochemical signature transitional between those of island arc tholeiites and boninites.Ascending batches of relatively high-SiO₂, ultra-depleted melts migrated through the Moho transition zone and generated wehrlite by olivine dissolution and crystallization of clinopyroxene, orthopyroxene and plagioclase in variable amounts. These liquids were more evolved and were produced by higher degrees of melting or from a more depleted source compared with melts that locally crystallized clinopyroxene in dunite. Ultra-depleted magmas, non-cogenetic with those that formed the Moho transition zone, ascended to the lower crust and generated gabbroic cumulates with subduction-related affinity. Thus, the ultramafic and mafic rocks in the Moho transition zone and lower crust of the Massif du Sud ophiolite are not products of fractional crystallization from a single magma-type but are the result of migration and accumulation of different melts in a multi-stage evolution.The record of high partial melting in the mantle section, and migration and accumulation of ultra-depleted subduction-related melts in the Moho transition zone and lower crust support that the Massif du Sud ophiolite is a portion of forearc lithosphere generated in an extensional regime during the early phases of the subduction zone evolution. Our results show the existence of different types of ultra-depleted melt compositions arriving at the Moho transition zone and lower crust of an infant intraoceanic paleo-arc. Ultra-depleted melts may thus be a significant component of the melt budget generated in oceanic spreading forearcs prior to aggregation and mixing of a large range of melt compositions in the crust.     

洞错盆地蛇绿岩地球化学特征及大地构造意义

本文以改则的洞错盆地蛇绿岩为研究对象,开展了洞错盆地蛇绿岩的岩石学、岩相学及地球化学方面的研究工作。结果表明：地幔橄榄岩以方辉橄榄岩为主,为烟斗型稀土元素配分型式;形成于熔融程度较高的地幔残余物质,具有Nb、Ta负异常。辉绿岩稀土元素配分型式与N-MORB类似,其稀土元素来自亏损的软流圈地幔;Ta、Ti、Y等高场强元素分布特征与N-MORB相似;辉绿岩既有MORB特征又有IAT特征,在洋内弧后盆地扩张环境中形成。辉长岩稀土配分曲线与N-MORB的类似;微量元素中K、Rb、Ba等富集,Nb、Ta亏损,有岛弧火山岩的特征,与典型的N-MORB特征有区别;既有MORB特征,也显示了俯冲带物质的参与,为消减带上弧后盆地次级扩张产生的新洋壳。因此,洞错蛇绿岩为SSZ型蛇绿岩。     

西藏雅鲁藏布江蛇绿岩带罗布莎地幔橄榄岩的成因

广泛分布在雅鲁藏布江蛇绿岩带的地幔橄榄岩是没有蛇纹石化的新鲜岩石,因而通过显微镜下观察和全岩化学分布探索其成因和地幔活动,是十分有利和简便的。最近几年来,利用岩石化学资料揭示远洋橄榄岩,认为它不是原始地幔岩经分或分离熔化作用萃取出玄武岩熔体后的直接残余物。罗布落蛇绿岩橄的镜下观察和岩石化学资料也证明,它不是原始地幔岩经局部熔化后的残余物,而且由来自更深层的地幔过渡带的硅酸盐超高压矿物底辟上升经熔取