夏季北黄海不同性质悬浮体分布特征及其控制因素分析

为了探讨夏季不同性质悬浮体在研究区的分布特征及其控制因素,于2016年6—7月在北黄海使用LISST-100X(C)型激光粒度仪和CTD测量了悬浮体浓度和水体温度、浊度、荧光叶绿素浓度数据。结合现场水文数据对不同粒径悬浮体的分布规律进行分析。结果表明,夏季研究区悬浮体含有大量以生源颗粒为主的粗颗粒(128μm),其浓度在下层水体较低,在远岸层结水体的温跃层附近最高。粒径128μm的细颗粒浓度与浊度分布趋势一致,主要反映陆源无机颗粒的变化。其浓度整体呈近岸高远岸低、下层高上层低的分布特征;在成山头近岸海域最高,并且在鲁北沿岸浅水与远岸深水之间存在浓度锋。潮混合作用和温跃层是影响悬浮体浓度空间分布的主要控制因素。潮混合作用促使鲁北沿岸出现陆架温度锋,阻碍沿岸细颗粒物质向海输运;成山头近岸较强的潮混合作用导致当地沉积物再悬浮,使该区域细颗粒浓度最高。温跃层不仅阻碍了下层细颗粒物质向上扩散,还对上层沉降下来的颗粒有"累积"作用。此外,跃层附近丰富的浮游植物对粗颗粒浓度高值区的形成有促进作用。     

Properties of coarse particles in suspended particulate matter of the North Yellow Sea during summer

Fine particles in seawater commonly form large porous aggregates. Aggregate density and settling velocity determine the behavior of this suspended particulate matter(SPM) within the water column.However, few studies of aggregate particles over a continental shelf have been undertaken. In our case study, properties of aggregate particles, including size and composition, over the continental shelf of the North Yellow Sea were investigated. During a scienti?c cruise in July 2016, in situ ef fective particle size distributions of SPM at 10 stations were measured, while temperature and turbidity measurements and samples of water were obtained from surface, middle, and bottom layers. Dispersed and inorganic particle size distributions were determined in the laboratory. The in situ SPM was divided into(1) small particles(<32 μm),(2) medium particles(32–256 μm) and(3) large particles(>256 μm). Large particles and medium particles dominated the total volume concentrations(VCs) of in situ SPM. After dispersion, the VCs of medium particles decreased to low values(<0.1 μL/L). The VCs of large particles in the surface and middle layers also decreased markedly, although they had higher peak values(0.1–1 μL/L). This suggests that almost all in situ medium particles and some large particles were aggregated, while other large particles were single particles. Correlation analysis showed that primary particles <32 μm in?uenced the formation of these aggregates. Microscopic examination revealed that these aggregates consisted of both organic and inorganic ?ne particles, while large particles were mucus-bound organic aggregates or individual plankton.The vertical distribution of coarser particles was clearly related to water strati?cation. Generally, medium aggregate particles were dominant in SPM of the bottom layer. A thermocline blocked resuspension of?ne material into upper layers, yielding low VCs of medium-sized aggregate particles in the surface layer.Abundant large biogenic particles were present in both surface and middle layers.     

Distribution of suspended particulate matter in the North Sea as inferred from NOAA/AVHRR reflectance images and in situ observations

Distribution patterns of suspended particulate matter (SPM) in the surface water of the North Sea were calculated on the basis of: (1) the 1973–1993 data base of the EC MAST North West European Shelf Programme (NOWESP); and (2) composite reflectance images constructed from data that were collected by the NOAA/AVHRR satellite in 1990–1991. Three models were used for interpolating the in situ data: (1) a distance-weighted interpolation algorithm in which only the in situ data are taken into account; (2) an algorithm in which the ratios between the measured SPM concentrations and reflectances are interpolated, and the distribution of SPM is calculated from the field of interpolated ratios and the synoptic reflectance image; and (3) a distance-weighted algorithm similar to model-1, but with an additional weight factor that is based on local differences in reflectance. The models were tested for periods of 1 and 3 weeks in September 1990 and January 1991, and for the merged set consisting of all in situ data measured in September and January, respectively, between 1973 and 1993. Model-2 and -3 gave largely similar results and had a performance superior to model-1, particularly because they showed more detailed structures in the spatial distributions. Validations and cross-validations showed that the absolute concentrations of SPM predicted by the models were too low at high in situ concentrations and too high at low in situ concentrations. This shortcoming was due to the relatively high degree of smoothing that we applied in the models to account for the large variance of the in situ data. Semivariograms and correlograms indicated that the in situ data had substantial variability and were poorly correlated even at short distances. Only for the 20-year-merged data set did some correlation ( %) exist for stations km from each other. Monthly distributions of SPM were calculated with model-3 and the 20-year data set. The distributions confirm the main patterns previously found by others, such as the turbidity plume crossing the North Sea from southeast England towards the depository in the Skagerrak and the Norwegian Channel. The distributions indicate that materials from this plume may be deposited in the central North Sea in spring and summer and eroded again in autumn and winter. Areas with maximum SPM concentrations were identified off the Belgian coast and north of the Wadden Sea, particularly in winter, from which particles are entrained into the main current in a narrow strip along the continental coast to the German Bight. The results suggest that the two main fluxes of SPM in the North Sea, off England and along the continental coast, remain largely separated until they both end in the Skagerrak.     

南黄海悬浮体浓度的平面分布特征及其输运规律

重点分析和探讨了南黄海悬浮体浓度的平面分布及其水平输运,结果显示悬浮体浓度具有显著的空间区域化分布特征,其与该海域环流场的布局和季节转换存在良好的对应关系,南黄海环流是该海域悬浮体运移的主要动力和控制因素;江苏近岸海域在一年四季均为悬浮体浓度的最高值区,其悬浮体主要来源于潮流和海浪所引起的沉积物再悬浮以及苏北沿岸水的携带和输送,而且夏季悬浮体在该海域的累积还可为冬半年在黄海西部沿岸流作用下将其输运至东南海域提供很好的物源保证;长江口东北部海域在春、夏、秋三季出现东北向扩展的高值区,体现了长江冲淡水的影响;石岛外海在冬、春、秋三季也存在悬浮体浓度高值区,并具有向南黄海中部泥质区扩展的态势,这是鲁北沿岸流将现代黄河物质输运至此的结果。发现调查海域中部表底层在春秋季均存在云团状高值区,而且该海域悬浮体浓度自春季至秋季出现"双峰现象",这与春秋季水华期间浮游植物繁殖所产生的有机碎屑有关,并使作为悬浮体组成的海洋浮游生物有机质向沉积物转移,据此进一步指出这一物源可能对南黄海冷涡泥质区的形成、发育也具有一定的作用,该观点深化了对南黄海中部冷涡泥质区受上层生物活动影响以及泥质区物源的认识。     

渤海悬浮物分布的遥感研究

利用渤海湾和莱州湾现场实测的悬浮物含量和光谱数据,建立了基于555和670nm波段遥感反射率的悬浮物含量遥感反演模型。经检验,模型平均相对误差优于20%,对输入端误差不敏感。基于该模型,利用ENVISAT MERIS遥感数据,从空间分布格局、大风过程的短期扰动以及季节性差异等方面分析了渤海悬浮物的时空分布特征。(1)渤海悬浮物含量的高值区集中分布在莱州湾(尤其是黄河口和莱州湾湾底)和渤海湾沿岸,此外在辽东湾沿岸海域悬浮物含量也相对较高,而在渤海大部水体悬浮物含量较低。(2)大风过程可在短期内(约1~3d)显著改变全渤海的悬浮物空间分布格局,其中渤海湾和莱州湾响应最为强烈,辽东湾响应相对较弱,这与其各自的水深条件、底质类型和悬浮物粒径等因素有关。(3)渤海悬浮物含量总体上呈春夏低、秋冬高的分布特征;季节性差异最显著的区域是渤海湾、莱州湾和辽东湾,差异性最小的是秦皇岛近岸海域;风力等气候因素是悬浮物分布呈现季节性差异的主要原因,入海径流是另一重要因素。     

春、秋季黄东海海域悬浮体平面分布特征及海流对其分布的影响

利用2003年春季(4月)和秋季(9月)两次对南黄海及东海北部海域II类水体悬浮体质量浓度的调查资料,得到了本海域近期悬浮体的平面分布特征,并分析了海流对本海域悬浮体分布的影响。结果表明,本海域春季悬浮体质量浓度明显高于秋季;受黄海沿岸流、黄海暖流及台湾暖流的影响,春季苏北浅滩悬浮体呈西北-东南舌状向深海运移,秋季悬浮体以苏北浅滩高值区为中心向外海扩散;长江及杭州湾入海泥沙基本都沉降在123o30′E以西的海域内。     

Methane in the southern North Sea: Sources, spatial distribution and budgets

Measurements of methane (CH₄) so far have always shown supersaturation in the entire North Sea relative to the atmospheric partial pressure and the distribution of surface CH₄ reveals a distinct increase towards the shore. Since North Sea sediments presumably are an insignificant source for CH₄ the coastal contribution via rivers and tidal flats gains in importance.In this work, CH₄ data from the River Weser, the back barrier tidal flats of Spiekeroog Island (NW Germany), and the German Bight are presented. Results from the River Weser are compared to other rivers draining into the German Bight. Measurements in the tidal flat area of Spiekeroog Island highlight this ecosystem as an additional contributor to the overall CH₄ budget of the southern North Sea. A tidally driven CH₄ pattern is observed for the water column with maximum values during low tide. Tidal flat sediments turn out to be the dominating source because pore waters discharged during low tide are highly enriched in CH₄. In contrast, the freshwater contribution to the tidal flats by small coastal tributaries has almost no impact on water column CH₄ concentrations. The CH₄ level seems to be disturbed irregularly by wind forcing due to elevated degassing and prevention of advective flow when tidal flats remain covered by water.Based on our data, two model calculations were used to estimate the impact of tidal flats on the CH₄ budget in the German Bight. Our results demonstrate that the back barrier tidal flats of the east Frisian Wadden Sea contribute CH₄ in an order of magnitude between the Wash estuary and River Elbe and thus have to be considered in budget calculations.     

2012 年春季南海南部不同水团上层海水中悬浮体分布特征及其物源分析

为了解南海南部海域不同水团对悬浮体分布特征的影响,于2012年4~5月在南海南部海域的80个测站分层采集了悬浮体水样,并现场测量各站位200 m以浅水体剖面上的悬浮体浓度、粒径、水体浊度、叶绿素a浓度以及温度、盐度等数据。分别选取受中南半岛沿岸混合水、南部陆架水、苏禄海与本地海水的混合水、南沙中央表层水等4个水团影响的多个典型站位数据,分析各水团悬浮体组分和分布特征。结果表明,南海南部海域悬浮体含量很少,浓度较小,均值为2.96μL/L;悬浮体主要组分为生源大颗粒,其粒径多在100μm以上,另有少量无机矿物碎屑,其粒径大部分小于32μm。巽他陆架北缘浅水区受南部陆架水控制,并且受到局地上升流的影响,陆源物质和生源物质含量均较多,导致其悬浮体浓度在4个水团中最高。苏禄海与本地海水混合水中悬浮体分布主要受浮游植物的影响。中南半岛沿岸混合水中悬浮体含较多陆源物质。南沙中央表层水受陆源物质影响很小,悬浮体主要由生源物质组成,且其浓度较小。     

渤海南部海域沉积物上覆海水与颗粒物中的磷与硅

研究了渤海南部海域沉积物上覆水、悬浮颗粒物中P、Si的变化特征。上覆水体PO4-P、SiO3-Si的平均含量均低于大洋底层水PO4-P、SiO3-Si的平均含量,二者具有相似的循环控制机制。悬浮颗粒物中无机磷、生源态磷(TIP、BP)的来源和循环控制机制不同,无机硅、生源态硅(TISi、BSi)有一定的相似性。稀释作用和表层沉积物中可交换态P、Si的循环控制上覆水体中P、Si的地球化学行为。颗粒物中TIP、TISi的行为受离子交换和化学吸附过程影响,其中化学吸附可能与Fe(Ⅲ)的氧化物有关;生物过程对颗粒物中生源P、Si的地球化学行为有重要影响。     

2013年夏秋季黄、渤海悬浮颗粒物及粒径分布特征研究

悬浮颗粒物及粒径是水质重要参数,其分布特征研究有助于加深对海洋生态环境的了解。利用2013年6月和2013年11月LISST-100观测数据,研究了黄、渤海区域悬浮物粒径和浓度的分布情况,浓度分布整体上呈现近岸高远岸低的状况,粒径分布呈现近岸细远岸粗的特征,季节分布特征明显;通过典型断面分析,悬浮物粒径和浓度随着水深变化明显,连续站数据分析结果表明大风对底层颗粒物的再悬浮作用显著,潮流对悬浮物的时空分布有着重要影响;水体衰减系数随着体积浓度变化明显;此外,还研究了悬浮颗粒物粒径Junge分布在黄、渤海区域的适用性。     

黄、东海边界悬浮物输运量的卫星遥感估算

利用2002—2015年的中等分辨率成像光谱仪(Moderate Resolution Imaging Spectroradiometer, MODIS)第4波段反射率产品对黄、东海边界的悬浮物输运情况进行了分析, 同时利用黄、东海2003年现场实测的悬浮物含量数据和这期间准实时的MODIS影像数据, 建立了基于MODIS第4波段遥感反射率的悬浮物含量遥感反演模型。基于该模型, 反演黄、东海表层悬浮物浓度, 并计算悬浮物扩散面积。利用反演得到的表层悬浮物浓度和悬浮物浓度垂向预测模型, 获取垂直方向上的悬浮物浓度, 同时结合水深、扩散面积数据, 计算特定时刻水体中的悬浮物含量。利用插值方法获得整个输运过程中各时刻水体中的悬浮物的含量, 计算各个时刻悬浮物含量的总和作为悬浮物的输送量。对2002年10月至2003年4月黄海向东海的悬浮输送量进行估算, 估算结果为153Mt。     

浙江近岸海域悬浮颗粒物中磷的赋存形态及分布特征研究

磷元素是海洋基础营养盐之一,其赋存形态及分布直接影响海区的初级生产力,是海洋生物地球化学循环的重要驱动力。但大河河口与近海等重要的水生关键带水动力循环过程复杂,导致悬浮颗粒物(SPM )中磷元素的赋存形态和分布特征变化多端,亟须深入研究。根据2016年春季(4−5月)、夏季(7月)和秋季(9−10月)对浙江近岸海域的调查结果,本研究分析了浙江近岸海域SPM中总磷(TPP)、无机磷(PIP)和有机磷(POP)的含量水平、空间分布特征和影响因素。结果表明,浙江近岸海域SPM中TPP含量范围为0.13～66.13 μmol/L,均值为3.35 μmol/L;PIP含量范围为0.03～34.19 μmol/L,均值为1.97 μmol/L;POP含量范围为0.06～31.94 μmol/L,均值为1.39 μmol/L。PIP是浙江近岸海域水体中TPP的主要存在形式,占52.3%。春季浙江近岸海域表层TPP含量占总磷(TP)含量的19.3%～97.7%。春、秋季的SPM中,TPP、PIP和POP含量空间分布相似,均呈现由内湾向外海逐渐降低的变化趋势。PIP、POP与SPM呈显著的正相关性,表现出高SPM含量的海区有着较高的颗粒态磷含量,说明其受陆源输入的影响。春季盐度大于28且SPM含量小于20 mg/L的外侧远海海域,POP与Chl a的相关系数和斜率均明显高于PIP与Chl a的相关系数和斜率,说明该区域浮游植物是POP的主要贡献来源。     

南黄海和东海表层水两种粒级颗粒物和颗粒氮含量的分布特征

测定了南黄海和东海表层水0.7~53.0μm和〉53.0μm这2种悬浮颗粒物（SPM）、颗粒氮（PN）的含量.其结果表明,南黄海和东海表层水0.7~53.0μm粒级的SPM、PN平均含量分别为4.68 mg/dm3、18.50μg/dm3;而〉53.0μm粒级的SPM、PN平均含量分别为0.20 mg/dm3、2.65μg/dm3.0.7~53.0μm和〉53.0μm粒级的PN/SPM含量平均比值分别为0.78%、1.41%（m/m）,后者约是前者的2倍.统计分析结果表明,尽管这2种粒级的SPM、PN含量和PN/SPM含量比值的范围较大,但约80%的数据集中在较小范围内,即0.7~53.0μm和〉53.0μm粒级SPM含量分别集中在0.37~3.68、0.02~0.29 mg/dm3的范围内;0.7~53.0μm和〉53.0μm粒级PN含量分别集中在2.54~18.90、0.40~2.69μg/dm3的范围内;0.7~53.0μm和〉53.0μm粒级的PN/SPM含量比值分别集中在0.14%~1.00%和0.15%~1.95%之间.研究结果表明,研究海域0.7~53.0μm粒级SPM、PN含量有2个高值区,分别位于近岸海区和东海东北部海区.〉53.0μm粒级SPM、PN含量的分布分为2个部分：南黄海表层水SPM、PN含量分布呈从近岸向外海降低的趋势;而东海表层水SPM、PN含量分布呈断面中间高,并分别向近岸和外海降低的趋势.     

冬、夏季东海北部悬浮体分布及海流对悬浮体输运的阻隔作用

依据1987年6月、1996年12月、1997年2月和1998年7月在东海北部所取得的悬浮体、温度和盐度资料就该区冬季和夏季的悬浮体分布、影响因素和输运进行了研究,结果表明该区悬浮体分布具有明显的季节性变化,在中、外陆架区悬浮体含量冬季明显高于夏季.悬浮体的分布及输运受到东海环流、风暴和潮流等的影响,其中东海环流的季节性变化是主要影响因素.受台湾暖流的阻隔,冬季和夏季长江入海泥沙在东海基本不能越过124°00'E以东海域.黄海沿岸流携带着老黄河口水下三角洲的再悬浮沉积物向陆架东南扩散,其搬运的量和在中、外陆架区的扩散范围冬季显著大于夏季.在黄海暖流的阻隔下,陆架悬浮体冬季和夏季在32°N断面很少能扩散至126°30'E以东海域.台湾暖流和黑潮爬升水的阻隔作用使得冬季和夏季陆架悬浮体在P-N断面也基本不能扩散至陆架边缘.冬季在东海北部可有部分陆架悬浮体输送到冲绳海槽,但有区域性,其输送的可能位置是在P-N断面以北、32°N断面以南之黄海沿岸流向东南延伸的陆架边缘;夏季陆架悬浮体基本滞留在陆架区.     

海水悬浮颗粒物中不同形态磷的测定

分别采用硫酸过硫酸钾作为氧化剂进行高压消解和用浓度为1 mol/dm³盐酸浸泡提取,然后用磷钼蓝分光光度法测定海水悬浮颗粒物、沉积物中的总磷和无机磷,用差减法得到有机磷。悬浮颗粒物总磷(PTP)和无机磷(PIP)质量浓度分别为(632.4～651.7)×10^-6和(436.6～452.6)×10^-6时,其相对标准偏差小于1.44%。悬浮颗粒物总磷、无机磷和有机磷的回收率分别为97.2%～101.3%,97.8%～100.4%和97.3%～102.3%。所建立的分析方法可用于海水、河口水悬浮颗粒物及沉积物中不同形态磷的测定。     

Distribution and its mechanism of suspended particulate matters in the southern Huanghai Sea and the East China Sea in summer

Water temperature,turbidity,chlorophyll-a and suspended sediment concentration (SSC) were investigated at 61 stations of eight sections in the southern Huanghai Sea (HS) and the East China Sea (ECS) during the summer (28 June to 15 July) of 2006.The horizontal distribution of suspended parti culate matter (SPM) displayed a high concentration inshore and a low value offshore.The maximum value can reach 10.4 mg/dm 3,which can be found at the Changjiang River mouth.For the same site,the SSC was generally higher at the bottom than on the surface.In the vertical direction,distribution characteristics of turbidity can be divided into two types:in the southern HS high values at the bottom while low values on the surface,and in the ECS high values inshore with low values offshore.The thermocline in the HS and the Taiwan Warm Current in the ECS could be important factors preventing the SPM from diffusing upward and seaward.Even the typhoon Ewiniar was not able to work on the major sediment transport under the thermocline during the observation.     

渤海及北黄海河流悬浮颗粒碳氮同位素时空分布及源解析

选择流入渤海和北黄海的36条主要河流为研究对象,对比了平水期、丰水期和枯水期水体中悬浮颗粒物和河流表层沉积物的碳和氮稳定同位素的地球化学特征,并对颗粒物有机质碳和氮来源进行分析。结果表明,水体悬浮有机质碳同位素总体上表现为δ13C平水期δ13C丰水期δ13C枯水期的特点,δ15N值呈δ15N丰水期δ15N平水期δ15N枯水期的特点。渤海和北黄海的主要入海河流悬浮颗粒物有机质的来源具有明显的季节性差异,悬浮颗粒有机质碳平水期(春秋季)来源以C3植物、土壤有机质和水生藻类为主,丰水期(夏季)碳的各来源中浮游植物的贡献率明显增大,枯水期(冬季)则表现为陆源C3植物分解和水源性有机质的混合来源;悬浮颗粒态氮的来源与季节性降水量、生活污水、合成化肥及河流内源性水生植物密切相关。     

悬浮颗粒物粒径分布的幂律模型研究——以黄渤海为例

为了准确地描述悬浮颗粒物粒径的分布特征,探索高精度的悬浮颗粒物粒径分布模拟,本文基于2014年11月黄、渤海的现场悬浮颗粒物粒径数据,研究了幂律模型在黄、渤海的适用性;同时,参考粒径作为幂律模型的重要参数,影响着幂律模型的斜率(颗粒粒径分布斜率)和模拟精度,因此对不同参考粒径下幂律模型的斜率变化情况以及模型模拟精度也进行了分析。结果显示:黄、渤海区域颗粒粒径分布斜率在0.46~7.53(均值:4.09),其中84.2%的斜率在3.2~4.5范围内;当参考粒径小于7.33μm时,颗粒粒径分布斜率变化大(均值为5.60±1.09),颗粒粒径分布模拟误差大,平均相对误差绝对值在20%~85%范围内,平均相对误差绝对值的平均值为48.2%;当参考粒径为7.33~19.8μm时,颗粒粒径分布斜率为4.08±0.29,颗粒粒径分布模拟的平均相对误差绝对值在5%~25%范围内,平均相对误差绝对值的平均值为9.8%;当参考粒径大于19.8μm时,颗粒粒径分布斜率为3.87±0.25,颗粒粒径分布模拟的平均相对误差绝对值在2%~10%范围内,平均相对误差绝对值的平均值为6.0%。误差分析表明:参考粒径取值大于19.8μm,幂律模型对颗粒粒径分布的模拟效果较好,最优参考粒径可选为122.0μm,此时模拟误差最小(平均相对误差绝对值的平均值为4.79%±1.78%)。