致密油油藏空气泡沫调驱机理实验

以长庆某致密油井区取心样品、注入水与地层水、优选的空气泡沫体系等为基础,利用一维长岩心驱替实验装置开展了致密油储层基质与裂缝岩心分别注入纯泡沫液、空气与空气泡沫的注入能力实验,揭示在实际储层条件下,空气泡沫体系无法直接进入致密油基质岩心,但由于泡沫剂受到储层吸附,消泡后的纯泡沫液与气体可以顺利注入致密油基质岩心实现稳定驱替。设计并开展了基质渗透率级差为10、基质与裂缝双重发育的三管并联岩心驱替实验,明确了空气泡沫封堵裂缝调驱机理。泡沫流体主要进入裂缝岩心并有效封堵裂缝,部分泡沫消泡后形成的泡沫液与空气进入并驱替基质中的剩余油,最终空气泡沫驱残余油饱和度比水驱降低了21.12%,驱油效率提高了32.89%,改善水驱后开发效果明显;为避免暴性水淹的低效阶段,应在含水90%以前尽早转入空气泡沫驱,提高采油速度与经济效益。     

储层非均质性影响空气泡沫驱注入效果研究——以鄂尔多斯盆地甘谷驿油田长6油层组为例

空气泡沫驱是重要三采技术,为了了解该技术适用储层类型,笔者等通过文献调研、机理分析、室内实验及油藏生产动态数据分析研究其注入效果与储层非均质性关系,结果表明：该技术通过泡沫体系产生阻力提高波及系数,泡沫中包含的表面活性剂降低界面张力提高驱油效率,泡沫特性“遇油消泡,遇水不变”可有效调剖堵水并改善流度比,非均质性强的储层具有大小不一的孔喉、较大的孔喉比和较强的贾敏效应,使上述增加波及系数、驱油及堵水效果更强,从而在水驱基础上可以进一步大幅提高采收率。实验和生产动态资料都说明,储层非均质性越强,表现为渗透率级差较大,增产和堵水效果越好,因此空气泡沫驱适用于储层非均质性较强的储层。该研究成果为空气泡沫驱的推广提供借鉴。     

储层非均质性影响空气泡沫驱注入效果研究——以鄂尔多斯盆地甘谷驿油田长6油层组为例

空气泡沫驱是重要三采技术,为了了解该技术适用储层类型,笔者等通过文献调研、机理分析、室内实验及油藏生产动态数据分析研究其注入效果与储层非均质性关系,结果表明：该技术通过泡沫体系产生阻力提高波及系数,泡沫中包含的表面活性剂降低界面张力提高驱油效率,泡沫特性“遇油消泡,遇水不变”可有效调剖堵水并改善流度比,非均质性强的储层具有大小不一的孔喉、较大的孔喉比和较强的贾敏效应,使上述增加波及系数、驱油及堵水效果更强,从而在水驱基础上可以进一步大幅提高采收率。实验和生产动态资料都说明,储层非均质性越强,表现为渗透率级差较大,增产和堵水效果越好,因此空气泡沫驱适用于储层非均质性较强的储层。该研究成果为空气泡沫驱的推广提供借鉴。     

泡沫固井水泥浆密度与环空液柱压力变化规律研究

超低密度泡沫水泥浆是解决低漏失压力井固井漏失,提高固井质量的有效措施。除泡沫水泥浆体系的开发与性能优化外,掌握泡沫水泥浆在环空内产生的静液柱压力随井深的变化规律,是成功实施该工艺技术的前提。借助实际气体状态方程,考虑温度、压力变化对充入氮气的影响,建立了静液柱压力和水泥浆密度与井深之间的数学模型,以迭代法编程求解该隐函数方程,并借助VB语言实现程序运算。分析了含气量变化、井深等因素对泡沫水泥浆密度及静液柱压力的影响规律,并提出了泡沫水泥浆“防漏”与“压稳”固井浆柱结构设计思路,为该工艺平衡压力固井设计提供了一定的参考和理论依据。该设计方法经现场应用,证实其运算结果的可靠性。     

泡沫泥浆钻进工艺及护壁堵漏机理研究

介绍了所研制的ＤＦ－１型泡沫剂组分及性能；对泡沫泥浆钻进的配方进行了研究，得出的最优配方应用于现场，取得了较好的效果，并对泡沫泥浆的护壁机理进行了研究。     

气体、泡沫等欠平衡钻井条件下感应测井应用分析

对气体、泡沫等欠平衡钻井条件下测井方式进行阐述,通过不同钻井液电阻率下对感应测井进行数字模拟,发现气体、泡沫等介质对感应测井影响较小。天然气介质和原油介质条件下感应测井现场实验的资料分析说明,感应测井在气体、泡沫等欠平衡钻井条件下可行。     

裂隙岩体溶质运移模型研究

核废料的地下深部贮存、垃圾填埋造成的污水下渗、海水入侵、输油管道老化引起渗漏等诸多应用领域的发展,要求从机理、试验和模型等方面发展裂隙岩体溶质运移理论。基于裂隙岩体系统溶质运移的多尺度概念模型,分析了目前描述裂隙岩体系统中溶质运移各种数学模型的适用性和优缺点,为选取合理的数学模型求解具体的问题提供了参考依据。最后提出了需要进一步研究的问题。     

Reusable nanocomposite-coated polyurethane foams for the remediation of oil spills

Cost-effective oil absorbents for the remediation of oil spills have been developed following a facile process involving the modification of polyurethane foam surfaces with mixtures of silicon oxide nanoparticles and polydimethylsiloxane. Polyurethane foams with different pore sizes and connectivity are tested, and it was found that the proposed treatment, applied by dip coating and spray coating, strongly improves the intrinsic foams’ performance in terms of selectivity and oil absorption capacity. The modified foams reach oil absorption capacities up to 60 g/g and simultaneous negligible water uptake. The treatment is stable after multiple absorption cycles, and therefore, the foams can be reused without significant decrease in their performance, being possible, after five cycles of absorption and recovery of oil, to reach overall oil absorption capacities up to 250 g/g.     

双作用水泵泡沫增压装置应用及前景分析

双作用水泵泡沫增压装置是利用双缸双作用水泵的高压能力将低压空气和泡沫液二次增压至水泵的额定压力,并混合产生泡沫.采用BWZ-1200双作用水泵泡沫增压装置在北京地区深度为1 000 m以下的地热井钻探中,成功地克服了地热井钻进中井内漏失和洗井的难题;在极度缺水的宁夏南部地区水井钻探中,采用BWZ-1100双作用水泵泡沫增压装置解决了水井孔内严重漏失和施工用水的难题.该装置可代替价格昂贵的高压空压机实现气举反循环钻探,应用于深地热井、深水井和油气井钻探.     

Challenges in adjoint-based optimization of a foam EOR process

We apply adjoint-based optimization to a surfactant-alternating gas foam process using a linear foam model introducing gradual changes in gas mobility and a nonlinear foam model giving abrupt changes in gas mobility as function of oil and water saturations and surfactant concentration. For the linear foam model, the objective function is a relatively smooth function of the switching time. For the nonlinear foam model, the objective function exhibits many small-scale fluctuations. As a result, a gradient-based optimization routine could have difficulty finding the optimal switching time. For the nonlinear foam model, extremely small time steps were required in the forward integration to converge to an accurate solution to the semi-discrete (discretized in space, continuous in time) problem. The semi-discrete solution still had strong oscillations in gridblock properties associated with the steep front moving through the reservoir. In addition, an extraordinarily tight tolerance was required in the backward integration to obtain accurate adjoints. We believe the small-scale oscillations in the objective function result from the large oscillations in gridblock properties associated with the front moving through the reservoir. Other EOR processes, including surfactant EOR and near-miscible flooding, have similar sharp changes and may present similar challenges to gradient-based optimization.     

低温泡沫钻进技术在漠河盆地冻土井工程的试验研究

低温泡沫钻进技术除了具有岩心采取率高、钻进效率高和孔内事故少的特点之外,还具有低导热性、低热容量及对钻井孔壁的热干扰小等特点。低温泡沫系统由空压机、泡沫液罐、热交换器、泡沫发生器和参数监测系统组成。通过对泡沫液和空气制冷后,经发泡器混合后可获得低温泡沫。利用低温泡沫作为冲洗介质进行取心钻进,孔内返出的泡沫经消泡后,可再次循环利用。该技术在漠河盆地冻土井工程中进行了应用,经试验数据分析,低温泡沫对冻土层温度的影响极小,岩心采取率高,满足冻土层取心钻进工作的要求。     

数学地球科学的新进展

从下列研究方向探讨了数学地球科学的新进展,即数据分析与数据挖掘（多点地质统计学,数据同化方法,数据挖掘和展示,时间序列分析,基于不规则数据集方法,数值分析方法与新算法）、非线性科学（多重分形模型,自组织临界理论,混沌理论,系统固有的复杂性,非线性随机过程的动态建模）、遥感（差分干涉合成孔径雷达,最先进雷达遥感,新的星载和地基微波技术,与遥感相结合的地理信息系统环境建模）、建模（新的数学变形模型与方法,地下蓄水层的流动与运送的预测模型,新油气发现模型,石油采收数学模型,空间与时间建模）、资源环境定量评价（复杂储存环境的地震特性综合反演,油井与储藏动态数据的实时同化处理,不确定性评估储藏动态新方法,资源评价和风险分析的新模式,环境地球化学,定量环境地质学）等     

Mathematical models for control of resource-distribution used in drilling

System analysis can provide an efficient control of the distribution of an oil company's drilling resources. The technique presented here (using cable as an example) is applied to the construction and synthesis of a material- and technical- resources control system, and to the mathematical modeling of the man-computer interface.     

数理统计在油气层解释中的应用

数理统计原理是应实践的需要而发展起来的，并成为实际工作中的一种基本工具，特别是在地质工作中应用越来越广泛，但由于它的统计计算相当复杂，一直未能得到有效地利用，为了更好地将数理统计方法和地质理论结合起来，充分发挥计算机这一现代化设备的作用，使数理统计原理在油气层解释中见到很高的效益，更好地为地质录井服务，我们研制了数理统计软件包，本文主要介绍该统计中判别分析方法在油气层解释中的应用。     

Pore-scale mechanisms and characterization of light oil storage in shale nanopores: New method and insights

A new method is proposed to analyze the pore-scale mechanisms and characterization of light oil storage in shale nanopores, which is based on the Hydrocarbon Vapor Adsorption (HVA) and Pore Calculation Model (PCM). First, the basic principle of the HVA-PCM method is introduced, and the experimental/mathematical analysis processes are given. Then, the HVA-PCM method is applied to shale samples to analyze the mechanisms and characterization of light oil storage in shale nanopores. The results provide insights into the pore-scale oil storage mechanisms, oil storage structure, oil film thickness, oil distribution within different sized pores, and the oil storage state. Finally, the advantages and limitations of the HVA-PCM method are discussed, and suggestions for further improvement are proposed. Overall, the HVA-PCM method is a powerful tool for extracting quantitative information on the light oil storage in shale nanopores.     

空气泡沫钻进的设备选择及灌注系统设计

在实钻应用的基础上,论述了选择泡沫钻进设备、机具时应考虑的因素;介绍了适用的配套设备选择和管汇系统的设计方案.     

A Mathematical Calculation Model Using Biomarkers to Quantitatively Determine the Relative Source Proportion of Mixed Oils

It is difficult to identify the source（s） of mixed oils from multiple source rocks, and in particular the relative contribution of each source rock. Artificial mixing experiments using typical crude oils and ratios of different biomarkers show that the relative contribution changes are non-linear when two oils with different concentrations of biomarkers mix with each other. This may result in an incorrect conclusion if ratios of biomarkers and a simple binary linear equation are used to calculate the contribution proportion of each end-member to the mixed oil. The changes of biomarker ratios with the mixing proportion of end-member oils in the trinal mixing model are more complex than in the binary mixing model. When four or more oils mix, the contribution proportion of each end-member oil to the mixed oil cannot be calculated using biomarker ratios and a simple formula. Artificial mixing experiments on typical oils reveal that the absolute concentrations of biomarkers in the mixed oil cause a linear change with mixing proportion of each end-member. Mathematical inferences verify such linear changes. Some of the mathematical calculation methods using the absolute concentrations or ratios of biomarkers to quantitatively determine the proportion of each end-member in the mixed oils are deduced from the results of artificial experiments and by theoretical inference. Ratio of two biomarker compounds changes as a hyperbola with the mixing proportion in the binary mixing model, as a hyperboloid in the trinal mixing model, and as a hypersurface when mixing more than three end- members. The mixing proportion of each end-member can be quantitatively determined with these mathematical models, using the absolute concentrations and the ratios of biomarkers. The mathematical calculation model is more economical, convenient, accurate and reliable than conventional artificial mixing methods.     

用生物标志物定量计算混合原油油源的数学模型

多烃源层叠合盆地混源油油源的定量计算是十分困难的问题.典型原油的人工混合配比实验显示,当两个生物标志物浓度不同的原油相混合时,各类生物标志物的比值参数随端元原油混入量呈非线性变化,以生物标志物比值参数和简单的二元线性关系方程定量计算混源油的混合比例将导致错误的结论.三个或者三个以上原油相混合时,各类生物标志物比值参数的变化更加复杂,各端元原油的贡献更加难以判识.但是,人工混合模拟实验表明混合油中生物标志物绝对含量与端元油的混入量呈线性关系,数学推导证明了这种线性关系,由此推导出相应的数学计算模型,其中:二元混合时比值参数与混入量呈双曲线关系,三元混合呈双曲面关系,四元及其以上的多元混合呈多维曲面,可以矩阵的方式定量计算各端元油的比例.依据这些数学模型,应用生物标志物的绝对含量和(或)生物标志物比值参数均可以定量计算出混源原油中各类原油的贡献比例.数学模型比通常的人工模拟实验方法更加经济、方便、精确和可靠.     

Effect of oil pollution on fresh groundwater in Kuwait

Massive oil fires in Kuwait were the aftermath of the Gulf War. This resulted in the pollution of air, water, and soil, the magnitude of which is unparalleled in the history of mankind. Oil fires damaged several oil well heads, resulting in the flow of oil, forming large oil lakes. Products of combustion from oil well fires deposited over large areas. Infiltrating rainwater, leaching out contaminants from oil lakes and products of combustion at ground surface, can reach the water table and contaminate the groundwater. Field investigations, supported by laboratory studies and mathematical models, show that infiltration of oil from oil lakes will be limited to a depth of about 2 m from ground surface. Preliminary mathematical models showed that contaminated rainwater can infiltrate and reach the water table within a period of three to four days, particularly at the Raudhatain and Umm Al-Aish regions. These are the only regions in Kuwait where fresh groundwater exists. After reaching the water table, the lateral movement of contaminants is expected to be very slow under prevailing hydraulic gradients. Groundwater monitoring at the above regions during 1992 showed minor levels of vanadium, nickel, and total hydrocarbons at certain wells. Since average annual rainfall in the region is only 120 mm/yr, groundwater contamination due to the infiltration of contaminated rainwater is expected to be a long-term one.     

煤田泡沫绳钻应用与问题探讨

采用国产设备及自行设计配套的灌排系统首次在国内进行了金刚石泡沫绳钻试验,达到了217.74m的最大应用孔深;分析了试验中获得的钻进时效、纯钻进时间率两项主要效果指标;探讨了影响压降的几个关系问题;基本明确了煤田泡沫金刚石绳钻风量、气压等关键参数的变化规律和泡沫稳定运行的重要性。