SORPTION OF BENZOTHIOPHENE ON MARINE SEDIMENTS

ImODUcrIONBenzothiophene(acomPoundinp0lycydicarornaticsulfurheterocydespresentincrudeoilsandcoal)isaddedt0marineenvironmentfromavariCtyofsouna,andisofenvironrnentalconcernduetoitSharmfulproperties(Andefssonetal.,l992,Yang,l996).Warner(l975)obtainedsulfur-containingpetroleumcomPonentSsuchasbensothiophenefr0mrnarinesamplesandfoundthatthepolycydicarornaticsuifurheterocydesweremorercadilybioconrmtratedthansulfur-freep0lycydicaromaticcompounds.Yang(l997)foundthatbensothiophenewaspresentinallin…     

Photochemical oxidation of benzothiophene in seawater

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DISTRIBUTION AND COMPOSITION OF PAHs IN SURFACE WATERS, POREWATER AND SEDIMENTS FROM XIAMEN WESTERN BAY

Xiamen Western Bay‘s water and sedimem quality were studied by detemaining thelevels of sixteen polycyclic amrrmtic hydrocarbons PAHs in water, porewater and sediment samples from nine locations in the bay. Total PAH concentrations varied from 106 to 945 ng/1 in water, below detectionto 3548 ng/1 in porewater, and 247 to 480 ng/g dry weight in surface sediments. PAHs levels in porewaterwere higher than those in surface water, due to the preference of these hydrophobic compounds for sedimentary phase instead of water. Such a concentration gradient implies a potential flux of pollutants fromsediments to overlying water. The PAils levels in sediments were one to several orders of magnitude lowerthan those in 1993, suggesting their decreased input in recent years and possible degradation with time.     

DISTRIBUTION AND COMPOSITION OF PAHs IN SURFACE WATERS, POREWATER AND SEDIMENTS FROM XIAMEN WESTERN BAY

ＩＮＴＲＯＤＵＣＴＩＯＮＰｏｌｙｃｙｃｌｉｃＡｒｏｍａｔｉｃＨｙｄｒｏｃａｒｂｏｎｓ(ＰＡＨｓ)ｗｉｄｅｌｙｅｘｉｓｔｉｎｔｈｅｅｎｖｉｒｏｎｍｅｎｔ(ａｔｍｏｓｐｈｅｒｅ,ｗａｔｅｒｃｏｌｕｍｎ,ｓｏｉｌ,ｒｉｖｅｒ,ｌａｃｕｓｔｒｉｎｅａｎｄｍａｒｉｎｅｓｅｄｉｍｅｎｔｓ)ａｎｄａｒｅｐｒｅｓｅｎｔａｔｔｒａｃｅｍｉｘｔｕｒｅｓａｎｄｗｉｄｅｌｙｓｐｒｅａｄｆｒｏｍｓｅｖｅｒａｌ×10-9ｇｒａｄｅｓｉｎｒｅｍｏｔｅａｒｅａｓｔｏｓｅｖｅｒａｌ×10-6ｌｅｖｅｌｓｉｎｕｒｂａｎａｎｄｉｎｄｕｓｔｒｉａｌａ…     

Distribution characteristics of polychlorinated biphenyls （PCBs） in coastal areas of Okinawa Island, Japan

Surface sediment and seawater samples were collected from coastal areas around Okinawa Island from September 2001 to May 2002. The samples were analyzed for total polychlorinated biphenyl (PCB) levels and homolog composition. The results show that total PCB levels ranged from 0.32 to 128.7 ng/g (dry wt.) in sediment and 1.59 to 2.48 ng/L in seawater. The levels exceed the Environmental Quality Standard (EQS) for water pollution of Japan. The distribution of PCB homolog showed different patterns in the sediments and seawaters. Penta-chlorobiphenyls (CBs) comprised the main congener group in seawater, while hexa-CBs were more abundant homologs in the sediments. The heavily contaminated sites featured higher CBs, including penta-CBs, hexa-CBs, and hepta-CBs, than those in less contaminated sites where tri-CBs dominated. This study provides current distribution and geochemical behavior of PCBs in the coastal areas around Okinawa Island.     

Analysis of petroleum hydrocarbons in mangrove sediments of Red Sea of Yemen

A field work has been carried out to identify the occurrence of oil and oil products pollution in mangrove sediment from Red Sea of Yemen. The concentration of total petroleum hydrocarbons is from 700ng/g at Kamaran Island station to 400 ng/g at Al-Hodiedah station, and the total organic carbon （TOC） in samples ranges from 0. 07% at Dhubab station to 0. 03% at Kamaran Island station. This pollution is as a result of localized oil pollution and/or heavy ship traffic in the Red Sea and Gulf of Aden.     

Analysis of petroleum hydrocarbons in mangrove sediments of Red Sea of Yemen

A field work has been carried out to identify the occurrence of oil and oil products pollution in mangrove sediment from Red Sea of Yemen. The concentration of total petroleum hydrocarbons is from 700 ng/g at Kamaran Island station to 400 ng/g at Al-Hodiedah station, and the total organic carbon ( TOC) in samples ranges from 0.07% at Dhubab station to 0.03% at Kamaran Island station. This pollution is as a result of localized oil pollution and /or heavy ship traffic in the Red Sea and Gulf of Aden.     

Sources of sediment in tidal fl ats off Zhejiang coast,southeast China

The growth of tidal fl ats off Zhejiang coasts in southwestern China has provided substantial areas for local agriculture and construction activities. To evaluate modern and future development of tidal fl ats in the region, a good understanding of sediment sources is necessary. Previous research has concluded that the Changjiang(Yangtze) River is the dominant supplier of sediments to this part of the southeast Chinese coast, despite the fact that sediment delivery from this source has been decreased markedly in the past two decades. In this study, we investigated the sources of tidal fl at sediments, and the magnetic and geochemical properties of recent tidal fl at sediments along the Zhejiang coast were compared with those discharged from rivers. Magnetic and geochemical properties of the tidal fl at samples reveal statistically distinct sediment provenance groups. The magnetic and geochemical scatter plots show that the suspended sediment samples are naturally divided into two diff erent groups, one including the Changjiang River and Qiantang River material, and the other including the Jiaojiang, Oujiang, and Feiyun Rivers that located in the central and southern parts of the study areas. At last, a binary source of tidal fl at sediments along the Zhejiang coast was determined, with the substantial majority originating from local rivers, while a much smaller proportion emanates from the Changjiang River to the north. We conclude that the sediment contribution of the Changjiang River to tidal fl at development in the region has been markedly overestimated, with important implications for management.     

The vertical distributions and sources of PAHs in sediment of Xiamen Bay

INTRODUCTIONTheindustrialdevelopmentandrisingpopulationintheXiamencoastalzonearelikelytoresultinincreasingpollutantsloadingwhichcanaffecttheoceanicecosystemsenvironmentthereandthreatenhumanhealth .PAHs ,asgoodenvironmentpollutionindicators(Aizenshat,1 973 ;Randahl,1 983 ) ,arerela tivelystableinairandwater,andarewidelydistributedintheaquaticenvironmentasaresultofhumanactivities.ProposedprimarysourcesofPAHsincludecombustionofvariousfossilfuels,nat uralfires,roadrunoff streetdustaswellas…     

MONITORING POLYNUCLEAR AROMATIC HYDROCARBONS IN SEDIMENT POREWATER BY SPMD

A new mimic biological Semi-permeable Membrane Device (SPMD) introduced for sampling organic pollutants yielded satisfactory results when it was frrst used as a passive sampler to concentrate and determine 16 kinds of polynuclear aromatic hydrocarbons (PAHs) by means of capillary GC on an HP 5890 GC-FID in coastal sediment perewater. The concentration of PAHs in sediment porewater for naphthalene(N), acenaphthlene(AL), acenaphthene (AE), fluorene (F), phenaphthene(P), anthracene(A), fluoranthene(FA), pyrene(Py), benzo[a]anthracene(B[a]A), chrysene(Chr), benzo[b] fluor- anthene(B[b]F), benzo[k]fluoranthene(B[k]F), benzo[a]pyrene(B[a]P),indeno[1,2,3,-cd]-Pyrene(I[123]P), dibenz[a,h]anthracene(D[ab]A) and benzo[g,h,i] perylene(B[ghi]P) were:50.36, under detection limits(UD), 18.19, 8.41, 8.40, 1.44, UD, 8.01, 524.15, 168.47, 50.13,123.66, 63.48, 27.40, 82.04 and 58,81 ng/L, respectively.     

Influencing factors of sediment deposition and their spatial variability in riparian zone of the Three Gorges Reservoir,China

Many factors can affect the sediment deposition and soil erosion process in riparian zone, including terrain, sediment transport and water level fluctuations. Clarifying the factors influencing sediment deposition process in the riparian zone of the Three Gorges Reservoirs is an important problem to determine the key area of sediment deposition and its trend of development in the study area. In order to reveal the influence of these environmental factors on the sediment deposition in riparian zone of the Three Gorges Reservoir, this study investigated 1) the amount of deposited sediment in different environmental conditions, 2) the potential factors affecting sediment deposition in riparian zone of the Three Gorges Reservoir, 3) the relationship between the deposited sediment amount and these factors previously mentioned using correlation analysis, and 4) the influence of human activities considered as an additional factor. This study found that 1) slope gradient, elevation, inundating duration and human activities were the main factors influencing sedimentation in riparian zone of the Three Gorges Reservoir, and 2) the impact of each factor varied with spaces. Specifically, in the upper reach from Jiangjin to Fuling, human activities such as gravel dredging, bank revetment and ports and wharfs constructing disturbed considerable amounts of deposited sediment, as a result, there was no natural law to dictate the distribution. In the middle reach from Fuling to Fengjie, slope gradient and inundating duration were the controlling factors, and the sediment deposition amount was greater in the areas with a gentler slope or lower elevation. Water flow on gentler slopes generally had lower velocity, resulting in more sediment to deposit. Sites with lower elevations would be drowned by sediment-laden flow with a longer duration resulting from hydrologic regime controlled by the operating strategy of the Three Gorges Reservoir, leading to a larger amount of sediment deposition. In the lower reach from Fengjie to Zigui, slope gradient was similar to the middle reach, performing a primary factor, while other factors showed little relationship with sediment amount.     

Influence of fine sediment on the fluidity of debris flows

Debris flows include a great diversity of grain sizes with inherent features such as inverse grading, particle size segregation, and liquefaction of fine sediment. The liquefaction of fine sediment affects the fluidity of debris flows, although the behavior and influence of fine sediment in debris flows have not been examined sufficiently. This study used flume tests to detect the effect of fine sediment on the fluidity of laboratory debris flows consisting of particles with various diameters. From the experiments, the greatest sediment concentration and flow depth were observed in the debris flows mixed with fine sediment indicating increased flow resistance. The experimental friction coefficient was then compared with the theoretical friction coefficient derived by substituting the experimental values into the constitutive equations for debris flow. The theoretical friction coefficient was obtained from two models with different fine-sediment treatments: assuming that all of the fine sediments were solid particles or that the particles consisted of a fluid phase involving pore water liquefaction. From the comparison of the friction coefficients, a fully liquefaction state was detected for the fine particle mixture. When the mixing ratio and particle size of the fine sediment were different, some other cases were considered to be in a partially liquefied transition state. These results imply that the liquefaction of fine sediment in debris flows was induced not only by the geometric conditions such as particle sizes, but also by the flow conditions.     

Dynamic hydraulic jump and retrograde sedimentation in an open channel induced by sediment supply: experimental study and SPH simulation

Mountainous torrents often carry large amounts of loose materials into the rivers, thus causing strong sediment transport. Experimentally it was found for the first time that when the intensive sediment motion occurs downstream over a gentle slope, the siltation of the riverbed is induced and the sediment particles can move upstream rapidly in the form of a retrograde sand wave, resulting in a higher water level along the river. To further study the complex mechanisms of this problem, a sediment mass model in the framework of the Smoothed Particle Hydrodynamics(SPH) method was presented to simulate the riverbed evolution, sediment particle motion, and the generation and development of dynamic hydraulic jump under the condition of sufficient sediment supply over a steep slope with varying angles. Because the sediment is not a continuous medium, the marker particle tracking approach was proposed to represent a piece of sediment with a marked sediment particle. The twophase SPH model realizes the interaction between the sediment and fluid by moving the bed boundary particles up and down, so it can reasonably treat the fluid-sediment interfaces with high CPU efficiency. The critical triggering condition of sediment motion, the propagation of the hydraulic jump and the initial siltation position were all systematically studied. The experimental and numerical results revealed the extra disastrous sediment effect in a mountainous flood. The findings will be useful references to the disaster prevention and mitigation in mountainous rivers.     

Numerical simulation on the process of saltwater intrusion and its impact on the suspended sediment concentration in the Changjiang (Yangtze) estuary

To study the relationship between sediment transportation and saltwater intrusion in the Changjiang (Yangtze) estuary, a three-dimensional numerical model for temperature, salinity, velocity field, and suspended sediment concentration was established based on the ECOMSED model. Using this model, sediment transportation in the flood season of 2005 was simulated for the Changjiang estuary. A comparison between simulated results and observation data for the tidal level, flow velocity and direction, salinity and suspended sediment concentration indicated that they were consistent in overall. Based on model verification, the simulation of saltwater intrusion and its effect on sediment in the Changjiang estuary was analyzed in detail. The saltwater intrusion in the estuary including the formation, evolution, and disappearance of saltwater wedge and the induced vertical circulation were reproduced, and the crucial impact of the wedge on cohesive and non-cohesive suspended sediment distribution and transportation were successfully simulated. The result shows that near the salinity front, the simulated concentrations of both cohesive and non-cohesive suspended sediment at the surface layer had a strong relationship with the simulated velocity, especially when considering a 1-hour lag. However, in the bottom layer, there was no obvious correlation between them, because the saltwater wedge and its inducing vertical circulation may have resuspended loose sediment on the bed, thus forming a high-concentration area near the bottom even if the velocity near the bottom was very low during the transition phase from flood to ebb.     

Residues of organochlorine pesticides in intertidal flat surface sediments from coastal zone of Jiangsu Province,China

Sixteen surface sediment samples were collected and analysed to evaluate the residues of organochlorine pesticides(OCPs) from intertidal flat in Jiangsu Province. Overall, 22 OCPs were detected with total concentrations of OCPs ranging widely from 0.96 to 12.14 ng/g(dry wt). Total hexachlorocyclohexane(HCH) and total dichlorodiphenyltrichloroethane(DDT) levels varied from 0.01 to 0.67 ng/g and from 0.23 to 4.85 ng/g, respectively. DDTs were the predominant compounds. The dominance of β-HCH indicated a history of HCH pollution. According to the ratios of( p, p'-DDD+ p, p'-DDE)/ p, p '-DDT and o, p ′-DDT/ p, p ′-DDT, new input of DDTs did not occur in most sites, and the main sources were historical usage of technical DDTs. OCPs such as dieldrin, endrin, p, p ′-DDD, and p, p ′-DDT exceeded the effects range low, showing adverse biological effects that would occasionally occur at some sites of the study area.     

Ecological study on protozoa in the sediment of the Three-Gorges Area of the Changjiang River

This paper reports on the study on the protozoan community structure of the immersed sediment in the Three-Gorges Area of the Changjiang River. Protozoa observed included 7 phytoflagellates, 12 zooflagellates, 49 amoebae and 16 ciliates. Sarcodina dominated in sediment, ciliates in water. Analysis of species and horizontal density distribution of protozoan in sediment in 28 sampling points reflected the pollution degree of water quality at every site. It was shown that heavy metal contamination in sediment has some effects on the distribution of protozoan species in the Changjiang River. This study was supported by Chinese National Nature Science Fund No. 386-0595     

澳门附近海域沉积物污染状况及特征分析

掌握澳门附近海域沉积物的污染状况及特征,对于合理安排澳门海洋海岸工程疏浚泥的海洋倾倒,防止造成海洋污染有十分重要的意义。根据1997—1999年连续三年对澳门附近主要区域的海洋沉积物采样测定结果,通过分析认为澳门附近海域沉积物污染具有下列特征:1)沉积物中重金属和油类含量普遍较高,除了总Hg外均高于珠江口海区的其他港口;2)沉积物中污染物的分布受人类活动的影响明显,澳门内港受船只排污、码头作业、陆地工业和生活污水排放的影响,是澳门附近海域沉积物污染最为严重区域;3)受水质交换的影响明显,澳门外港、路环岛东北等区域受珠江径流影响水质交换较快,沉积物中污染物的含量较低,而内港由于水质交换较差,沉积物中污染物的含量相对较高;4)与沉积物的成分组成(吸附)有关,大部分污染物与沉积物中粉砂有较好的相关性,表明粉砂对污染物质有较广泛性的吸附能力,尤其是Cu、Zn、Cd、油类、有机质。     

Distribution and generic composition of culturable marine actinomycetes from the sediments of Indian continental slope of Bay of Bengal

Actinomycetes population from continental slope sediment of the Bay of Bengal was studied. Samples were collected during two voyages of FORV Sagar Sampada in 2004 （May-June） and 2005 （July） respectively from 11 transects （each transect had ca. 200 m, 500 m, and 1 000 m depth stations）. The physicochemical parameters of overlying water, and sediment samples were also recorded. The actinomycete population ranged from 5.17 to 51.94 CFU/g dry sediment weight and 9.38 to 45.22 CFU/g dry sediment weight during the two cruises respectively. No actinomycete colony was isolated from stations in 1 000 m depth. Two-way analysis of variance showed significant variation among stations （ANOVA two-way, P〈0.05）, but no significance was found between the two cruises （ANOVA two-way, P〈0.05）. Populations in stations in 500 m depth in both cruises were higher than that of 200 m depth stations with statistically insignificant difference （ANOVA two-way, P〉0.05）. Three actinomycetes genera were identified. Streptomyces was found to be the dominating one in both the cruises, followed by Micromonospora, and Actinomyces. The spore of Streptomyces isolates showed the abundance in spiral spore chain. Spore surface was smooth. Multiple regression analysis revealed that the influencing physico-chemical factors were sediment pH, sediment temperature, TOC, porosity, salinity, and pressure. The media used in the present study was prepared with seawater. Thus, they may represent an autochthonous marine flora and deny the theory of land runoff carriage into the sea for adaptation to the salinity of the seawater and sediments.     

Distribution characteristics of lipids in hadal sediment in the Yap Trench

In this study, cored sediment samples collected by the Jiaolong Submersible at 6 779 m depth from the hadal zone of the Yap Trench in May 2016 were sliced in 1-cm interval from top to bottom, and lipids in each sediment layer were quantitatively and qualitatively analyzed. The vertical distribution profiles of the lipids in the sediment sample, their main existing forms, and their possible sources were investigated. The results show that the concentration of lipid in the surface sediment was the highest with the carbon number from 12 to 27, dominated by medium and short-chain lipids. The total concentration of fatty acids in surface sediment was much higher than those in the offshore and deep-sea areas, being up to 325.77 μg/g due to the funnel effect caused by the “V” terrain of the trench. Fatty acid 18.0 was the most abundant lipids in the sediment sample. Abnormal high concentrations of fatty acid 18.ω7 and alkanes indicated the existence of hydrothermal fluids in the study area. In addition, saturated fatty acids and monounsaturated fatty acids existed mainly in free form, and polyunsaturated fatty acids existed mainly in bound form. Most of the alkanes were in bound form, and their major source was autochthounous input. The carbon number of alcohols in the sediment sample ranged from 12 to 20, mainly existed in bound form. The source of fatty acids was mainly autochthonous input, and the neutral lipids had both marine and terrestrial origin. This is the first study of lipids in hadal sediment of the Yap Trench. The results will promote deeper understanding of organic carbon cycle in marine environment.     

Shifts of sediment bacterial community and respiration along a successional gradient in a typical karst plateau lake wetland(China)

Bacteria are important regulators of carbon cycling in lakes and are central to sediment ecosystem processes. However, the sediment microbial communities and their respiratory responses to the lake wetland succession are poorly understood. In this study, we collected sediment samples from four different succession points(the Potamogeton lucens zone, the Scirpus tabernaemontani zone, the Scirpus triqueter zone, and the Juncus effusus zone) in the Caohai Wetland of the Guizhou Plateau(China). The bacterial communities at these succession points were studied using a high-throughput sequencing approach. The sediment microbial respiration(SR) was measured using static chambers in the field and basal respiration(BR) was determined in the laboratory. The results show that the dominant bacterial taxa in the sediment was Proteobacteria(34.7%), Chloroflexi(17.8%), Bacteroidetes(7.3%), Acidobacteria(6.6%), and Cyanobacteria(6.1%). Principal coordinate analysis showed that the microbial community structure differs significantly at different sampling points along the successional gradient, indicating that the bacterial community structure is sensitive to the lake wetland succession. Different hydrological regimes and soil characteristics such as NH_4~+-N, Fe~(2+), Mn~(2+), and sediment organic carbon(SOC) content may be important factors responsible for the differences in the sediment microbial characteristics of the different successional stages in the Caohai wetland. Additionally, it was found that the SR increased significantly from the P. lucens zone to the J. effusus zone, but BR had the opposite response. The shifts in the bacterial community structure along the successional gradient may be the main reason for the observed differences in sediment respiration.