Deciphering polymetamorphic episodes in high-grade metamorphic orogens: Constraints from PbSL, Sm/Nd and Lu/Hf garnet dating of low- to high-grade metasedimentary rocks from the Kaoko belt (Namibia)

Three dating techniques for metamorphic minerals using the Sm–Nd, Lu–Hf and Pb isotope systems are combined and interpreted in context with detailed petrologic data from crustal segments in NW Namibia. The combination of isochron ages using these different approaches is a valuable tool to testify for the validity of metamorphic mineral dating. Here, PbSL, Lu–Hf and Sm–Nd garnet ages obtained on low- to medium-grade metasedimentary rocks from the Central Kaoko Zone of the Neoproterozoic Kaoko belt (NW Namibia) indicate that these samples were metamorphosed at around 550–560 Ma. On the other hand, granulite facies metasedimentary rocks from the Western Kaoko Zone underwent two phases of high-grade metamorphism, one at ca. 660–625 Ma and another at ca. 550 Ma providing substantial evidence that the 660–625 Ma-event was indeed a major tectonothermal episode in the Kaoko belt. Our age data suggest that interpreting metamorphic ages by applying a single dating method only is not reliable enough when studying complex metamorphic systems. However, a combination of all three dating techniques used here provides a reliable basis for geochronological age interpretation.     

The Archean BIF-hosted Cuiabá Gold deposit, Quadrilátero Ferrífero, Minas Gerais, Brazil

The Cuiabá Gold Deposit is located in the northern part of the Quadrilátero Ferrífero, Minas Gerais State, Brazil. The region constitutes an Archean granite–greenstone terrane composed of a basement complex (ca. 3.2 Ga), the Rio das Velhas Supergroup greenstone sequence, and related granitoids (3.0–2.7 Ga), which are overlain by the Proterozoic supracrustal sequences of the Minas (< 2.6–2.1  Ga) and Espinhaço (1.7 Ga) supergroups.The stratigraphy of the Cuiabá area is part of the Nova Lima Group, which forms the lower part of the Rio das Velhas Supergroup. The lithological succession of the mine area comprises, from bottom to top, lower mafic metavolcanics intercalated with carbonaceous metasedimentary rocks, the gold-bearing Cuiabá-Banded Iron Formation (BIF), upper mafic metavolcanics and volcanoclastics and metasedimentary rocks. The metamorphism reached the greenschist facies. Tectonic structures of the deposit area are genetically related to deformation phases D₁, D₂, D₃, which took place under crustal compression representing one progressive deformational event (E_n).The bulk of the economic-grade gold mineralization is related to six main ore shoots, contained within the Cuiabá BIF horizon, which range in thickness between 1 and 6 m. The BIF-hosted gold orebodies (> 4 ppm Au) represent sulfide-rich segments of the Cuiabá BIF, which grade laterally into non-economic mineralized or barren iron formation. Transitions from sulfide-rich to sulfide-poor BIF are indicated by decreasing gold grades from over 60 ppm to values below the fire assay detection limit in sulfide-poor portions. The deposit is “gold-only”, and shows a characteristic association of Au with Ag, As, Sb and low base-metal contents. The gold is fine grained (up to 60 μm), and is generally associated with sulfide layers, occurring as inclusions, in fractures or along grain boundaries of pyrite, the predominant sulfide mineral (> 90 vol.%). Gold is characterized by an average fineness of 0.840 and a large range of fineness (0.759 to 0.941).The country rocks to the mineralized BIF show strong sericite, carbonate and chlorite alteration, typical of greenschist facies metamorphic conditions. Textures observed on microscopic to mine scales indicate that the mineralized Cuiabá BIF is the result of sulfidation involving pervasive replacement of Fe-carbonates (siderite–ankerite) by Fe-sulfides. Gold mineralization at Cuiabá shows various features reported for Archean gold–lode deposits including the: (1) association of gold mineralization with Fe-rich host rocks; (2) strong structural control of the gold orebodies, showing remarkable down-plunge continuity (> 3 km) relative to strike length and width (up to 20 m); (3) epigenetic nature of the mineralization, with sulfidation as the major wall–rock alteration and directly associated with gold deposition; (4) geochemical signature, with mineralization showing consistent metal associations (Au–Ag–As–Sb and low base metal), which is compatible with metamorphic fluids.     

Seismic velocity structure of a large mafic intrusion in the crust of central Denmark from project ESTRID

The origin of regional sedimentary basins is being investigated by the ESTRID project (Explosion Seismic Transects around a Rift In Denmark). This project investigates the mechanisms of the formation of wide, regional basins and their interrelation to previous rifting processes in the Danish–Norwegian Basin in the North Sea region. In May 2004 a 143 km long refraction seismic profile was acquired along the strike direction of a suspected major mafic intrusion in the crust in central Denmark. The data confirms the presence of a body with high seismic velocity (> 6.5 km/s) extending from a depth of  10–12 km depth into the lower crust. There is a remarkable Moho relief between 27 and 34 km depth along this new along-strike profile as based on ray-tracing modelling of PmP reflections. The lack of PmP reflections at a zone of very high velocity in the lowest crust (7.3–7.5 km/s) suggests a possible location of a feeder channel to the batholith. The presence of volcanic rocks of Carboniferous–Permian age above the intrusion (mafic batholith) suggests a similar age of the intrusion. An older obliquely crossing profile and two new fan profiles deployed perpendicular to the main ESTRID profile, show that the batholith is about 30–40 km wide. The existence of this large mafic batholith supports the hypothesis that the origin of the Danish–Norwegian Basin is related to cooling and contraction after intrusion of large amounts of mafic melts into the crust during the late Carboniferous and early Permian. The data and interpretations from project ESTRID will form the basis for subsidence modelling. Tentatively, we interpret the formation of the Danish–Norwegian Basin as a thermal subsidence basin, which developed after widespread rifting of the region.     

Neoarchaean high-grade metamorphism in the Central Zone of the Limpopo Belt (South Africa): Combined petrological and geochronological evidence from the Bulai pluton

The Bulai pluton represents a calc-alkaline magmatic complex of variable deformed charnockites, enderbites and granites, and contains xenoliths of highly deformed metamorphic country rocks. Petrological investigations show that these xenoliths underwent a high-grade metamorphic overprint at peak P–T conditions of 830–860 °C/8–9 kbar followed by a pressure–temperature decrease to 750 °C/5–6 kbar. This P–T path is inferred from the application of P–T pseudosections to six rock samples of distinct bulk composition: three metapelitic garnet–biotite–sillimanite–cordierite–plagioclase–(K-feldspar)–quartz gneisses, two charnoenderbitic garnet–orthopyroxene–biotite–K-feldspar–plagioclase–quartz gneisses and an enderbitic orthopyroxene–biotite–plagioclase–quartz gneiss. The petrological data show that the metapelitic and charnoenderbitic gneisses underwent uplift, cooling and deformation before they were intruded by the Bulai Granite. This relationship is supported by geochronological results obtained by in situ LA-ICP-MS age dating. U–Pb analyses of monazite enclosed in garnet of a charnoenderbite gneiss provide evidence for a high-grade structural-metamorphic–magmatic event at 2644 ± 8 Ma. This age is significantly older than an U–Pb zircon crystallisation age of 2612 ± 7 Ma previously obtained from the surrounding, late-tectonic Bulai Granite. The new dataset indicates that parts of the Limpopo's Central Zone were affected by a Neoarchaean high-grade metamorphic overprint, which was caused by magmatic heat transfer into the lower crust in a ‘dynamic regional contact metamorphic milieu’, which perhaps took place in a magmatic arc setting.     

The Ordovician Sierras Pampeanas–Puna basin connection: Basement thinning and basin formation in the Proto-Andean back-arc

The Ordovician Sierras Pampeanas, located in a continental back-arc position at the Proto-Andean margin of southwest Gondwana, experienced substantial mantle heat transfer during the Ordovician Famatina orogeny, converting Neoproterozoic and Early Cambrian metasediments to migmatites and granites. The high-grade metamorphic basement underwent intense extensional shearing during the Early and Middle Ordovician. Contemporaneously, up to 7000 m marine sediments were deposited in extensional back-arc basins covering the pre-Ordovician basement. Extensional Ordovician tectonics were more effective in mid- and lower crustal migmatites than in higher levels of the crust. At a depth of about 13 km the separating boundary between low-strain solid upper and high-strain lower migmatitic crust evolved to an intra-crustal detachment. The detachment zone varies in thickness but does not exceed about 500 m. The formation of anatectic melt at the metamorphic peak, and the resulting drop in shear strength, initiated extensional tectonics which continued along localized ductile shear zones until the migmatitic crust cooled to amphibolite facies P–T conditions. P–T–d–t data in combination with field evidence suggest significant (ca. 52%) crustal thinning below the detachment corresponding to a thinning factor of 2.1. Ductile thinning of the upper crust is estimated to be less than that of the lower crust and might range between 25% and 44%, constituting total crustal thinning factors of 1.7–2.0. While the migmatites experienced retrograde decompression during the Ordovician, rocks along and above the detachment show isobaric cooling. This suggests that the magnitude of upper crustal extension controls the amount of space created for sediments deposited at the surface. Upper crustal extension and thinning is compensated by newly deposited sediments, maintaining constant pressure at detachment level. Thinning of the migmatitic lower crust is compensated by elevation of the crust–mantle boundary. The degree of mechanical coupling between migmatitic lower and solid upper crust across the detachment zone is the main factor controlling upper crustal extension, basin formation, and sediment thickness in the back-arc basin. The initiation of crustal extension in the back-arc, however, crucially depends on the presence of anatectic melt in the middle and lower crust. Consumption of melt and cooling of the lower crust correlate with decreasing deposition rates in the sedimentary basins and decreasing rates of crustal extension.     

Mountain building across a lithospheric boundary during arc construction: The Cretaceous Peninsular Ranges batholith in the Sierra San Pedro Martir of Baja California, Mexico

The Jura-Cretaceous Peninsular Ranges batholith (PRB) of Southern and Baja California contains a remarkable example of variation in crustal composition and structure across a batholith-parallel lithospheric-scale discontinuity. This lithospheric boundary between western oceanic-floored and eastern continental-floored crust influenced contractional deformation, arc magmatism, and differential exhumation of western and eastern zones in the batholith during its evolution.In the Sierra San Pedro Martir of Baja California, Mexico, a ca. 20 km wide, doubly vergent fan structure occurs across the PRB basement transition that consists of inward-dipping mylonite thrust sheets on the sides of the fan that gradually transition to a steeply-dipping tectonized zone in the center. A dramatic inverted metamorphic gradient occurs on the western side of this structure where mid-crustal amphibolite metamorphic grade rocks with peak pressures of 5–6 kbar in the center of the fan were thrust over upper-crustal sub-greenschist grade rocks (peak pressures < 2 kbar) in the western zone footwall. An inverted but smaller gradient occurs on the eastern side of the structure where rocks of the fan interior have been thrust eastwards over amphibolite to upper greenschist grade rocks (peak pressures 4–5 kbar).Gradients in cooling ages determined by ⁴⁰Ar/³⁹Ar biotite and K-feldspar and apatite fission track methods coupled with U–Pb zircon ages and Al in hornblende thermobarometry studies on plutons across this zone indicate that structures focused along the transition zone between contrasting lithosphere in the PRB accommodated nearly 15 km of the differential exhumation of western and eastern basement in the orogen. The western zone of the batholith was a major forearc depo-center for thick clastic sequences derived from the uplifting eastern PRB and remained at low average elevation during the Late Cretaceous and Paleogene. In contrast the eastern zone experienced dramatic uplift subsequent to achieving a crustal thickness in excess of 55 km by mid-Cretaceous time. This region had the isostatic potential for 4–5 km surface elevations, and likely formed a topographically high orogenic plateau. Exhumation of the fan structure initiated after 100 Ma and was largely complete by 85 Ma. Eastward-migrating unroofing of the rest of the eastern PRB continued into the Paleogene.A variety of factors were responsible for exhumation in this region. Structural thickening of the eastern zone of the orogen resulted from more than 30 million years of episodic contractional deformation in the fan structure, much of which followed island arc accretion of the western zone along this segment of the batholith. An episode of voluminous magmatism involving the intrusion of the 99–92 Ma La Posta-type magmatic suite across the eastern zone of the PRB triggered exhumation in the fan structure. Denudation in this region appears to have been solely by erosion; no evidence has been found for extensional tectonics during this time. This arc orogen demonstrates the important influence of inherited tectonic boundaries in controlling the spatial distribution of structural thickening and magmatism. It also displays the complex interrelationships among structural thickening, exhumation, and the role of magmatism in triggering exhumation episodes within orogens.     

A palaeomagnetic study of charnockites from Madras Block, Southern Granulite Terrain, India

The South Indian Craton is composed of low-grade and high-grade metamorphic rocks across different tectonic blocks between the Moyar–Bhavani and Palghat–Cauvery shear zones and an elongated belt of eastern margin of the peninsular shield. The Madras Block north of the Moyar–Bhavani shear zone, which evolved throughout the Precambrian period, mainly consists of high-grade metamorphic rocks. In order to constrain the evolution of the charnockitic region of the Pallavaram area in the Madras Block we have undertaken palaeomagnetic investigation at 12 sites. ChRM directions in 61 oriented block samples were investigated by Alternating Field (AF) and Thermal demagnetization. Titanomagnetite in Cation Deficient (CD) and Multi Domain (MD) states is the remanence carrier. The samples exhibit a ChRM with reverse magnetization of D_m = 148.1, I_m = + 48.6 (K = 22.2, α₉₅ = 9.0) and a palaeomagnetic pole at 37.5 °N, 295.6 °E (dp/dm = 7.8°/11.8°). This pole plots at a late Archaean location on the Indian Apparent Polar Wander Path (APWP) suggesting an age of magnetization in the Pallavaram charnockites as 2600 Ma. The nearby St. Thomas Mount charnockites indicate a period of emplacement at 1650 Ma (Mesoproterozoic). Thus the results of Madras Block granulites also reveal crustal evolution similar to those in the Eastern Ghats Belt with identical palaeopoles from both the areas.     

Supergene and hypogene alteration in the dual-use kaolin-bearing coal deposit Angren, SE Uzbekistan

The Jurassic Angren coal–kaolin deposit, Uzbekistan, is one of the largest producers of coal and kaolin suitable for refractories and industrial ceramics in central Asia. The Major coal seam, attaining a thickness between 4 and 24 m, is encased by kaolin-bearing bedsets which have been derived from supergene pre- and hypogene post coal kaolinization. Joint clay-mineralogical and coal petrographic analyses formed the basis of the environment analysis of this coal–kaolin series and constrained the physico-chemical conditions existing during the Triassic through Jurassic period of time. Massive kaolin I underneath the coal seam is a typical residual kaolin or underclay with arsenic Fe-disulfides and siderite indicative of a reducing swampy depositional environment developing under moderately hot climatic conditions. Towards the top, kaolin I became reworked fluvial by processes. The Major coal seam developed in swamps interfingering with a fluvial drainage system of suspended to mixed-load deposits. The maximum temperature for the post-depositional alteration of the carbonaceous material is 70 °C. Post-coal kaolinization (kaolin II) affecting trachyandesites and trachytes is of low-temperature origin and low-sulphidation-type. The temperature of formation was well below 200 °C, deduced from the absence of dickite in the clay mineral assemblage. Basaltic dykes intersected the coal–kaolin series and account for contact metamorphic reactions in the proximal parts of the aluminum-bearing wall rocks reaching sanidinite-facies conditions with temperatures around 1000 °C.     

Large P–T gap between Ballantrae blueschist/garnet pyroxenite and surrounding ophiolite, southern Scotland, UK: Diapiric exhumation of a Caledonian serpentinite mélange

The Ballantrae ophiolite in southern Scotland includes a NEE–SWW-trending serpentinite mélange that contains blocks of mafic blueschist and high-pressure, granulite facies, metapyroxenite (Sm–Nd metamorphic age: 576 ± 32 and 505 ± 11 Ma). Tectonic blocks of mafic schist are less than 3 × 3 m in size, and have greenschist, blueschist or epidote amphibolite facies assemblages corresponding to the high-pressure intermediate-type metamorphic facies series.Adjacent rocks of the serpentinite mélange are hydrothermally-altered MORB-like ophiolitic basalt (prehnite–pumpellyite facies), dolerite (actinolite–oligoclase sub-facies) and gabbro (amphibolite facies), all with assemblages that are diagnostic of the low-pressure metamorphic facies series.The difference in metamorphic facies series and parageneses of minerals between the high-pressure mafic blocks and the adjacent, low-pressure ophiolitic meta-basic rocks suggests that the former were exhumed from > 25 km depth within a cold subducted slab, and were juxtaposed with the latter, the bottom of a MORB-like ophiolite in the hanging wall of a trench. An ENE–WSW-trending, 501 ± 12 Ma volcanic arc belt extends for 3 km south of the serpentinite mélange. We suggest that ridge subduction associated with a slab window created arc-related gabbro (483 ± 4 Ma) at Byne Hill and within-plate gabbro (487 ± 8 Ma) at Millenderdale. Final continental collision created the duplex structure of the Ballantrae complex that includes the HP blocks and serpentinite mélange. These relations define diapiric exhumation in the Caledonian orogen of SW Scotland.     

On-going orogeny in the outer-arc of the Timor–Tanimbar region, eastern Indonesia

The Timor–Tanimbar islands of eastern Indonesia form a non-volcanic arc in front of a 7 km deep fore-arc basin that separates it from a volcanic inner arc. The Timor–Tanimbar Islands expose one of the youngest high P/T metamorphic belts in the world, providing us with an excellent opportunity to study the inception of orogenic processes, undisturbed by later tectonic events.Structural and petrological studies of the high P/T metamorphic belt show that both deformation and metamorphic grade increase towards the centre of the 1 km thick crystalline belt. Kinematic indicators exhibit top-to-the-north sense of shear along the subhorizontal upper boundaries and top-to-the-south sense in the bottom boundaries of the high P/T metamorphic belt. Overall configuration suggests that the high P/T metamorphic rocks extruded as a thin sheet into a space between overlying ophiolites and underlying continental shelf sediments. Petrological study further illustrates that the central crystalline unit underwent a Barrovian-type overprint of the original high P/T metamorphic assemblages during wedge extrusion, and the metamorphic grade ranged from pumpellyite-actinolite to upper amphibolite facies.Quaternary uplift, marked by elevation of recent reefs, was estimated to be about 1260 m in Timor in the west and decreases toward Tanimbar in the east. In contrast, radiometric ages for the high P/T metamorphic rocks suggest that the exhumation of the high P/T metamorphic belt started in western Timor in Late Miocene time and migrated toward the east. Thus, the tectonic evolution of this region is diachronous and youngs to the east. We conclude that the deep-seated high P/T metamorphic belt extrudes into shallow crustal levels as a first step, followed by doming at a later stage. The so-called ‘mountain building’ process is restricted to the second stage. We attribute this Quaternary rapid uplift to rebound of the subducting Australian continental crust beneath Timor after it achieved positive buoyancy, due to break-off of the oceanic slab fringing the continental crust. In contrast, Tanimbar in the east has not yet been affected by later doming. A wide spectrum of processes, starting from extrusion of the high P/T metamorphic rocks and ending with the later doming due to slab break-off, can be observed in the Timor–Tanimbar region.     

Thermal maturity of a fold–thrust belt based on vitrinite reflectance analysis in the Western Foothills complex, western Taiwan

Burial depth, cumulative displacement, and peak temperature of frictional heat of a fault system are estimated by thermal analysis in the fold–thrust belt of the Western Foothills complex, western Taiwan based on the vitrinite reflectance technique. The regional thermal structure across the complex reveals that the rocks were exposed to maximum temperatures ranging from 100 °C to 180 °C, which corresponds to a burial depth of 3.7–6.7 km. A large thermal difference of 90 °C were observed at the Shuilikeng fault which make the eastern boundary of the fold–thrust belt where it is in contact with metamorphic rock of Hsuehshan Range. The large thermal difference corresponds to cumulative displacements on the Shuilikeng fault estimated to be in the range of 5.2–6.9 km. However, thermal differences in across the Shuangtung and Chelungpu faults cannot be determined apparently due to small vertical offsets. The large displacement observed across the Shuilikeng fault is absent at the other faults which are interpreted to be younger faults within the piggyback thrust system. Localized high temperatures adjacent to fault zones were observed in core samples penetrating the Chelungpu fault. Three major fracture zones were observed at core lengths of 225 m, 330 m, and 405 m and the two lower zones which comprise dark gray narrow shear zones. A value of vitrinite reflectance of 1.8%, higher than the background value of 0.8%, is limited at a narrow shear zone of 1 cm thickness at the fracture zone at 330 m. The estimated peak temperature in the range of 550–680 °C in the shear zone is far higher than the background temperature of 130 °C, and it is interpreted as due to frictional heating during seismic faulting.     

SHRIMP U–Pb zircon geochronology and geochemistry of metavolcanic and metasedimentary rocks in Northwestern Fujian, Cathaysia block, China: Tectonic implications and the need to redefine lithostratigraphic units

Northwestern Fujian Province is one of the most important Pre-Palaeozoic areas in the Cathaysia Block of South China. Metavolcano-sedimentary and metasedimentary rocks of different types, ages and metamorphic grades (granulite to upper greenschist facies) are present, and previously were divided into several Formations and Groups. Tectonic contacts occur between some units, whereas (deformed) unconformities have been reported between others. New SHRIMP U–Pb zircon ages presented here indicate that the original lithostratigraphy and the old “Group” and “Formation” terminology should be abandoned. Thus the “Tianjingping Formation” was not formed in the Archaean or Palaeoproterozoic, as previously considered, but must be younger than its youngest detrital zircons (1790 Ma) but older than regional metamorphism (460 Ma). Besides magmatic zircon ages of 807 Ma obtained from metavolcano-sedimentary rocks of the “Nanshan Formation” and 751–728 Ma for the “Mamianshan Group”, many inherited and detrital zircons with ages ranging from 1.0 to 0.8 Ga were also found in them. These ages indicate that the geological evolution of the study area may be related to the assembly and subsequent break-up of the Rodinia supercontinent. The new zircon results poorly constrain the age of the “Mayuan Group” as Neoproterozoic to early Palaeozoic (728–458 Ma), and not Palaeoproterozoic as previously thought. Many older inherited and detrital zircons with ages of 3.6, 2.8, 2.7, 2.6–2.5, 2.0–1.8 and 1.6 Ga were found in this study. A 3.6 Ga detrital grain is the oldest one so far identified in northwestern Fujian Province as well as throughout the Cathaysia Block. Nd isotope t_DM values of eight volcano-sedimentary and clastic sedimentary rock samples centre on 2.73–1.68 Ga, being much older than the formation ages of their protoliths and thus showing that the recycling of older crust played an important role in their formation. These rocks underwent high grade metamorphism in the early Palaeozoic (458–425 Ma) during an important tectono-thermal event in the Cathaysia Block.     

Seismic microzonation study in Doon valley, northwest Himalaya, India

Fundamental frequency map of site amplification at different sites in Doon valley, Uttarakhand, India is prepared from microtremor (ground ambient noise) using Horizontal to Vertical Spectral Ratio (HVSR) technique. The fan deposited alluvium filled synclinal valley of Doon lies between Main Boundary Thrust (MFT) and Himalayan Frontal Thrust (HFT) in the Himalayan active seismic belt and experienced many earthquakes in the past. The HVSR at different sites in the Doon valley ranges between the predominant frequencies 0.13 and 12.77 Hz. The HVSR in lower frequencies indicates that the site has either thick sediment covers or less compact rocks with fractures. Based on information on fundamental frequency and soft soil thickness, site classification map is generated. Results indicate that degree of compactness of rock types and presences of sediments vary significantly, which may play a major role in seismic hazard. The use of microtremor, therefore, constitutes an effective and inexpensive approach to site response and soft soil thickness estimation for preliminary microzonation.     

The thermal evolution of Corsica as recorded by zircon fission-tracks

New zircon fission-track (ZFT) ages from Corsica record multiple thermal events that can be tied to the structural evolution of the western Mediterranean region. The Corsican zircons have a wide scatter of ZFT grain ages (243–14 Ma), which together define several age domains. Western Corsica consists largely of stable Hercynian basement characterized by ZFT ages in the range 161–114 Ma. We interpret these ages (Late Jurassic–Early Cretaceous) as the product of a long-lived Tethyan thermal event related to continental rifting and subsequent drifting during the separation of the European and African plates and the formation of the Liguro–Piemontese ocean basin. In contrast to Hercynian Corsica, Alpine Corsica (northeast Corsica) experienced widespread deformation and metamorphism in Late Cretaceous(?)–Tertiary time. Dated samples from Alpine Corsica range in age from 112 to 19 Ma and all are reset or partially reset by one or more Alpine thermal events. The youngest ZFT grain ages are from the northernmost Alpine Corsica and define an age population at  24 Ma that indicates cooling after Tertiary thermal events associated with the Alpine metamorphism and the opening of the Liguro–Provençal basin. A less well-defined ZFT age population at  72 Ma is present in both Alpine Corsica and Hercynian basement rocks. The thermal history of these rocks is not clear. One interpretation is that the ZFT population at  72 Ma reflects resetting during a Late Cretaceous event broadly synchronous with the early Alpine metamorphism. Another interpretation is that this peak is related to variable fission-track annealing and partial resetting during the Tertiary Alpine metamorphic event across central to north-eastern Corsica. This partial age resetting supports the presence of a fossil ZFT partial annealing zone and limits the peak temperature in this area below 300 °C, for both the affected pre-Alpine and Alpine units.     

Lithostratigraphy, basin development, base metal deposits, and regional correlations of the Neoproterozoic Nguba and Kundelungu rock successions, central African Copperbelt

The Neoproterozoic Katangan Supergroup comprises a thick sedimentary rock succession subdivided into the Roan, Nguba, and Kundelungu Groups, from bottom to top. Deposition of both Nguba and Kundelungu Groups began with diamictites, the Mwale/Grand Conglomérat and Kyandamu/Petit Conglomérat Formations, respectively, correlated with the 750 Ma Sturtian and (supposedly) 620 Ma Marinoan/Varanger glacial events. The Kaponda, Kakontwe, Kipushi and Lusele Formations are interpreted as cap-carbonates overlying the diamictites. Petrographical features of the Nguba and Kundelungu siliciclastic rocks indicate a proximal facies in the northern areas and a basin open to the south. The carbonate deposits increase southward in the Nguba basin. In the southern region, the Kyandamu Formation contains clasts from the underlying rocks, indicating an exhumation and erosion of these rocks to the south of the basin. It is inferred that this formation deposited in a foreland basin, dating the inversion from extensional to compressional tectonics, and the northward thrusting. Sampwe and Biano sedimentary rocks were deposited in the northernmost foreland basin at the end of the thrusting. The Zn–Pb–Cu and Cu–Ag–Au epigenetic, hypogene deposits occurring in Nguba carbonates and Kundelungu clastic rocks probably originate from hydrothermal resetting and remobilization of pre-existing stratiform base metal mineralisations in the Roan Group.     

The Basin of Mexico and its metropolitan area: water abstraction and related environmental problems

The Basin of Mexico is a closed basin of lacustrine character, with an average elevation of 2200 m above sea level. The watershed covers a vast extension in five states. Mexico City and its metropolitan area are located within this basin. The aquifer system is the main source of water supply for more than 20 million people. Water consumption is about 60 m³/s. The aquifer supplies about 43 m³/s from around 1000 wells at 70–200 m depth. Pumping policies have generated subsidence and degradation of the ground water quality in the Basin of Mexico The lacustrian clay layers play an important role in the local hydrogeology, protecting the aquifer from pollution, but the transition and piedmont areas are highly vulnerable to surface pollutants.     

Analysis of airborne magnetic and gravity anomalies of peninsular shield, India integrated with seismic and magnetotelluric results and gravity anomalies of Madagascar, Sri Lanka and East Antarctica

Modelling of gravity and airborne magnetic data integrated with seismic studies suggest that the linear gravity and magnetic anomalies associated with Moyar Bhavani Shear Zone (MBSZ) and Palghat Cauvery Shear Zone (PCSZ) are caused by high density and high susceptibility rocks in upper crust which may represent mafic lower crustal rocks. This along with thick crust (44–45 km) under the Southern Granulite Terrain (SGT) indicates collision of Dharwar craton towards north and SGT towards south with N–S directed compression during 2.6–2.5 Ga. This collision may be related to contemporary collision northwards between Eastern Madagascar–Western Dharwar Craton (WDC) and Eastern Dharwar Craton (EDC). Arcuate shaped N and S-verging thrusts, MBSZ-Mettur Shear and PCSZ-Gangavalli Shear, respectively across Cauvery Shear zone system (CSZ) in SGT also suggest that the WDC, EDC and SGT might have collided almost simultaneously during 2.6–2.5 Ga due to NW–SE directed compressional forces with CSZ as central core complex in plate tectonics paradigm preserving rocks of oceanic affinity. Gravity anomalies of schist belts of WDC suggest marginal and intra arc basin setting.The gravity highs of EGFB along east coast of India and regional gravity low over East Antarctica are attributed to thrusted high-density lower crustal/upper mantle rocks at a depth of 5–6 km along W-verging thrust, which is supported by high seismic velocity and crustal thickening, respectively. It may represent a collision zone at about 1.0 Ga between India and East Antarctica. Paired gravity anomalies in the central part of Sri Lanka related to high density intrusives under western margin of Highland Complex and crustal thickening (40 km) along eastern margin of Highland Complex with several arc type magmatic rocks of about 1.0 Ga in Vijayan Complex towards the east may represent collision between them with W-verging thrust as in case of EGFB. The gravity high of Sri Lanka in the central part falls in line with that of EGFB, in case it is fitted in Gulf of Mannar and may represent the extension of this orogeny in Sri Lanka.     

Permian bimodal dyke of Tarim Basin, NW China: Geochemical characteristics and tectonic implications

This study reports for the first time the occurrence of bimodal dyke in the Shuigongtuan area of Bachu County, Tarim Basin, NW China. Here, quartz syenite porphyry and diabase dykes occur in direct contact showing bimodal feature. The quartz syenitic porphyry is metaluminous, enriched in K₂O + Na₂O (10–11 wt.%) and total rare earth elements (REE), with low Mg/(Mg + Fe) ratios, high LREE/HREE, and negative Eu anomalies. The chemical characteristics and tectonic discriminative diagrams show that the rocks have geochemical affinity with A-type granites. The diabase dyke shows 45–52 wt.% SiO₂ and Mg/(Mg + Fe) ratio in the range of, with high total REE, high LREE/HREE ratios and lack of Eu anomalies, broadly corresponding to tholeiitic composition. Based on low Y/Nb (as low as 0.4, and less than 1.2), enrichment in LILE and HFSE, and uniform Nb-enrichment patterns in spider diagram for the quartz syenitic porphyry, together with the geochemical patterns of the diabases, this biomodal association is interpreted to be derived from a mantle source and formed under typical within-plate environment. The quartz syenitic porphyry and diabase have Daly gap of 46 wt.%–67 wt.% in SiO₂, which is explained through formation under bimodal rifting. The quartz syenitic dyke probably formed during Early Permian (277 Ma) and has geochemical affinity with the Xiaohaizi syenitic body. We propose that magmas sourced from the mantle intruded into middle–upper crust and were emplaced as dykes, which indicate large-scale extension during the Permian in Tarim Basin. The bimodal dyke has genetic affinity with the huge volume of Permian basalts and igneous rocks (248–292 Ma) that occur in the Tarim Basin. The magmatism manifests the culmination of the major thermal event in the Tarim Basin.     

Geochronology of metarhyolites from the Kangbutiebao Formation in the Kelang basin, Altay Mountains, Xinjiang: Implications for the tectonic evolution and metallogeny

The Altay orogenic belt (AOB), situated in the middle part of the Central Asian Orogenic Belt (CAOB), is one of the most important metallogenic belts in China. The Kangbutiebao Formation is a Late Paleozoic stratigraphic unit that hosts many important iron and Pb–Zn deposits. The Kangbutiebao Formation consists of intercalated volcanic and sedimentary rocks that have undergone regional greenschist to lower amphibolite facies metamorphism, and mainly outcrops in three NW-trending fault-bounded volcano–sedimentary basins, including the Maizi, Kelang, and Chonghuer basins. SHRIMP analyses of zircons from three metarhyolites of the Kangbutiebao Fm. in the Kelang Basin yield weighted mean ²⁰⁶Pb/²³⁸U ages of 412.6 ± 3.5 Ma, 408.7 ± 5.3 Ma and 406.7 ± 4.3 Ma, respectively, which can be interpreted as the eruption age of the Kangbutiebao silicic volcanic rocks in the Kelang Basin. These ages indicate that the Kangbutiebao Formation was formed during the Late Silurian to Early Devonian. They also demonstrate that the deposits hosted in the Kangbutiebao Formation were formed after 412–407 Ma. They play a key role in understanding the Paleozoic tectonic evolution and metallogenesis of the southern margin of the Chinese AOB.     

The Paleoproterozoic North Hebei Orogen: North China craton's collisional suture with the Columbia supercontinent

Understanding the geologic history and position of the North China craton in the Paleoproterozoic Columbia supercontinent has proven elusive. Paleoproterozoic orogenic episodes (2.00–1.85 Ga) are temporally associated with ultimate stabilization of the North China craton (NCC), followed by the development of extensive craton-wide rift systems at 1.85–1.80 Ga. The age difference between the sedimentary cover and the metamorphic basement is up to 500–700 Ma, suggesting that uplift and doming of cratonic basement occurred in the latest Paleoproterozoic. Mafic dike swarms (1.80–1.77 Ga) and anorogenic magmatism (1.80–1.70 Ga) record the extensional breakup and dispersal of the North China craton during this stage. The late Paleoproterozoic tectonic framework and geological events documented provide important constraints for reconstruction of the NCC within the Late Paleoproterozoic supercontinent of Columbia.An east-west striking thousand kilometer long belt of khondalites (granulite facies metapelites) stretches along the northern margin of the North China craton, on the cratonward side of the Northern Hebei orogenic belt. This granulite belt includes Mg–Al (sapphirine bearing) granulites that reached ultrahigh-temperature “peak” metamorphic conditions of  1000 °C at 10 kbars at 1927 ± 11 Ma. Following peak ultrahigh-temperature conditions, the rocks underwent initial isobaric cooling and subsequent isothermal decompression, and these trajectories are interpreted to be part of an overall anti-clockwise P-T evolution indicating that the northern margin of the craton experienced continental collision at 1.93–1.92 Ga. The position of the khondalite belt south of the Northern Hebei orogenic belt makes it analogous to Tibet, a continental collision-related plateau characterized by double crustal thicknesses and granulite facies metamorphism at depth. We suggest that the tectonic evolution of the NCC during this period was closely related to the assembly and break-up of the Columbia supercontinent, and that the NCC was adjacent to the Baltic and Amazonian cratons in the period 2.00–1.70 Ga. Craton-wide extension occurred within 100–150 Ma of collision along the northern margin of the craton at 1.93–1.92 Ga. It is concluded that mantle upwellings are chiefly responsible for the breakup of the NCC from the Paleoproterozoic supercontinent.