Assessment of metal concentrations found within a North Sea drill cuttings pile

North Sea drill cuttings piles are a distinct anthropogenic legacy resulting from the exploration and production of North Sea oil reserves. The need to understand metal cycling within the piles becomes increasingly important with the imminent decommissioning of many North Sea platforms and the subsequent fate of associated cuttings piles. This paper presents results of the simultaneous analysis of geochemical carrier substances (Mn and Fe oxyhydroxides), along with dissolved (<0.2 microm) and total (>0.2 microm) metal (Ba, Co, Cr, Cu, Mo, Pb, V) concentrations from a North Sea cuttings pile and surrounding sediment. These data are examined in conjunction with in situ measured porewater oxygen and sulfide. Results show a rapid removal of oxygen within the top few millimeters of the cuttings pile along with elevated concentrations of total hydrocarbons and solid phase metal concentrations compared to the surrounding environment.     

Offshore macrobenthic recovery in the Murchison field following the termination of drill-cuttings discharges

The effects of discharged drilling cuttings contaminated with oil-based drilling fluids on the macrobenthos surrounding several North Sea oil-production platforms have been well documented. Areas of biological effect ranging from highly modified benthic communities, through transitional zones to undisturbed zones have been identified and characterized. Results are presented from a series of studies at the Murchison oil field which indicate partial recovery of macrofaunal communities around the production platform after cuttings discharges had ceased. Eventual rates of recovery of affected macrobenthic communities around production platforms are discussed in terms of persistence of oil in the drilling cuttings and the rates of degradation of the oil and its toxic components.     

Drill cutting accumulations in the Northern and Central North Sea: a review of environmental interactions and chemical fate

The exploration and production of North Sea oil and gas reserves has resulted in the accumulation of large quantities of drill cuttings on the seabed surrounding drill sites. This complex mixture of man-made and natural substances contains higher concentrations of certain metals (Ba, Cr, Cu, Ni, Pb, and Zn) and hydrocarbons than are observed in background sediments. With decommissioning of older platforms underway, an evaluation of the environmental interactions and chemical fate of the drill cuttings accumulations is required.This review concentrates on contaminants within drill cutting accumulations in the Northern and Central North Sea (56 degrees N-62 degrees N). Present literature reviewed reveals that hydrocarbons within the cuttings piles remain relatively unchanged with time. A considerable proportion of the associated contaminants are likely to remain within the cuttings pile unless they are disturbed which will then increase exchanges of porewater and solids back to the seabed surface resulting in pathways of exposure for organisms.     

Environmental effects of the use of oil-based drilling muds in the North Sea

The environmental effects of oil-based drilling mud cuttings have been evaluated using all the data available from monitoring around North Sea platforms. Beneath the platforms making extensive use of oil-based drilling muds the natural sediment is buried by cuttings and the hydrocarbon concentration 250 m from the platforms may be 1000 times background, but the concentration gradient is very steep and background levels are usually reached 2000–3000 m from the platform.The extent of the biological effects appear to be greater from the use of oil-based muds than from water-based muds. Beyond the area of physical smothering the effects of oil-based mud cuttings may be due to organic enrichment or to the toxicity of the aromatic fraction of the oil. Despite the large scale of inputs, in all the fields studied the major deleterious biological effects occurred within 500 m of the platform. Surrounding the area of major impact was a transition zone in which subtle biological effects could be detected as community parameters returned to normal, generally within 400–1000 m.The shape and extent of this zone varied and was largely determined by the current regime and scale of the drilling operation. Elevated hydrocarbon concentrations were detected beyond the areas of biological effects.     

The occurrence of the cold-water coral Lophelia pertusa (Scleractinia) on oil and gas platforms in the North Sea: colony growth, recruitment and environmental controls on distribution

This study reports a newly established sub-population of Lophelia pertusa, the dominant reef-framework forming coral species in the north-east Atlantic, on oil and gas platforms in the northern North Sea. L. pertusa was positively identified on 13 of 14 platforms examined using existing oil and gas industry visual inspections. Two platforms were inspected in more detail to examine depth and colony size distributions. We recorded 947 colonies occurring between 59 and 132 m depth that coincides with cold Atlantic water at depths below the summer thermocline in the northern North Sea. We suggest that these colonies provide evidence for a planktonic larval stage of L. pertusa with recruits initially originating from populations in the north-east Atlantic and now self recruiting to the platforms. Size class distribution showed a continuous range of size classes, but with few outlying large colonies. The break between the largest colonies and the rest of the population is considered as the point when colonies began self recruiting to the platforms, resulting in greater colonization success. We present the first documented in situ colony growth rate estimate (26 +/- 5 mm yr(-1)) for L. pertusa based on 15 colonies from the Tern Alpha platform with evidence for yearly recruitment events starting the year the platform was installed. Evidence of contamination from drill muds and cuttings was observed on the Heather platform but appeared limited to regions close to drilling discharge points, where colonies experience partial as well as whole colony mortality.     

Impact of oil on the marine environment: Policy of the Paris commission on operational discharges from the offshore industry

Environmental impacts occur at all stages of oil and gas production. They are the result of prospecting activities, of the physical impact due to the installation of rigs, of the operational discharges when production starts and of accidental spills. The input of oil to the North Sea due to the offshore industry has been estimated at 29% of the total input of oil. The operational discharges consist of production water and drilling cuttings. An overview of statistics collected over the last 10 years shows that although the amount of oil discharged via production water is increasing as platforms are getting older, cuttings still account for 75% of the oil entering the sea as a result of normal operations. Spills represent a relatively small source of oil. The effects on the marine environment of discharges of production water and of discarded oily cuttings have been extensively studied, by national authorities as well as by the industry. Although it has not always been possible to reach consensus about the significance of the observed effects, a number of ‘agreed facts’ have led to establishment of regulations in the framework of the Paris Commission. The ‘decisions’ and ‘recommendations’ adopted by the Commission are regularly reviewed in the light of new developments.     

Environmental effects of North Sea oil operations

To appreciate the impact of large-scale industrial operations on the marine environment requires a range of scientific studies which ideally should include physical, chemical and biological surveys of the various environmental compartments likely to be contaminated, linked with experiments designed to detect and quantify effects. More finely focused studies can then provide an evaluation of the impact. In relation to North Sea oil activities, this type of approach suggests that at present significant offshore contamination is found only in the sediments close to platforms using oil-based drilling muds.     

Effects of drilling cuttings on the behaviour of the Norway lobster Nephrops norvegicus

Small quantities of drilling cuttings (100 g/250 cm²) were found to affect both the survival and general behaviour of Nephrops norvegicus held in experimental aquaria. In one experiment volatile hydrocarbons released from the cuttings caused a significant decrease (p < 0.05) in the beat of the exopodite on the third maxilliped. Flicking rates of the antennule and the time taken to identify and capture food introduced into the tanks were unaffected by exposure to cuttings. When the water flow through the tanks was interrupted for 12 h, 58% of animals died after exposure to the highest concentration of cuttings but those at the lower concentrations survived. After the water flow was restored the remaining survivors showed disorientated behaviour and uncoordinated movements which lasted for about 36 h. In this condition animals will be more vulnerable to predators. This unnatural behaviour may have serious implications for natural populations exposed to cuttings discharge in the close vicinity of offshore drilling platforms.     

Water column monitoring near oil installations in the North Sea 2001-2004

Fisheries have been vital to coastal communities around the North Sea for centuries, but this semi-enclosed sea also receives large amounts of waste. It is therefore important to monitor and control inputs of contaminants into the North Sea. Inputs of effluents from offshore oil and gas production platforms (produced water) in the Norwegian sector have been monitored through an integrated chemical and biological effects programme since 2001. The programme has used caged Atlantic cod and blue mussels. PAH tissue residues in blue mussels and PAH bile metabolites in cod have confirmed exposure to effluents, but there was variation between years. Results for a range of biological effects methods reflected exposure gradients and indicated that exposure levels were low and caused minor environmental impact at the deployment locations. There is a need to develop methods that are sufficiently sensitive to components in produced water at levels found in marine ecosystems.     

Fate of drilling waste discharges and ecological risk assessment in the Egyptian Red Sea: an aquivalence-based fuzzy analysis

Egypt is located in the Northeast of Africa where oil and gas (O&G) are produced offshore from the Gulf of Suez and the Southeast part of the Mediterranean. The O&G production in Egypt is distributed as follows: 70% from Gulf of Suez, 16% from Western desert, 8% from the Sinai Peninsula and 6% from Eastern desert. Past O&G activities, refining and transport have resulted in chronic pollution in Egyptian offshore and numerous environmental programs have been initiated to protect new development areas from the environmental impacts. The offshore drilling process uses drilling fluids (mud) and generates waste fluids and cuttings, which could be the largest discharges going into the receiving water bodies. There are several options to manage offshore drilling wastes: offshore discharge, offshore down-hole injection and onshore disposal. Water-based drilling fluids (WBF) are commonly employed for drilling in Egyptian offshore because of their expected environmental benign behavior. The main objective of this paper is to develop a methodology to determine the fate of heavy metals associated with WBF drilling waste in the marine environment and estimate the associated ecological risks. Proposed contaminant fate model is based on an aquivalence approach, which has been integrated with fuzzy-based analysis to study the uncertainties. This research concluded that the impacts of heavy metals associated with the drilling waste discharges in the receiving waters are minimal.     

Sedimentation on the cold-water coral Lophelia pertusa: cleaning efficiency from natural sediments and drill cuttings

Anthropogenic threats to cold-water coral reefs are trawling and hydrocarbon drilling, with both activities causing increased levels of suspended particles. The efficiency of Lophelia pertusa in rejecting local sediments and drill cuttings from the coral surface was evaluated and found not to differ between sediment types. Further results showed that the coral efficiently removed deposited material even after repeated exposures, indicating an efficient cleaning mechanism. In an experiment focusing on burial, fine-fraction drill cuttings were deposited on corals over time. Drill cutting covered coral area increased with repeated depositions, with accumulation mainly occurring on and adjacent to regions of the coral skeleton lacking tissue cover. Tissue was smothered and polyp mortality occurred where polyps became wholly covered by material. Burial of coral by drill cuttings to the current threshold level used in environmental risk assessment models by the offshore industry (6.3 mm) may result in damage to L. pertusa colonies.     

The influence of drill cuttings on physical characteristics of phytodetritus

Sinking of aggregated phytoplankton cells is a crucial mechanism for transporting carbon to the seafloor and benthic ecosystem, with such aggregates often scavenging particulate material from the water column as they sink. In the vicinity of drilling rigs used by the oil and gas industry, the concentration of particulate matter in the water column may at times be enriched as a result of the discharge of ‘drill cuttings’ - drilling waste material. This investigation exposed laboratory produced phytoplankton aggregates to drill cuttings of various composition (those containing no hydrocarbons from reservoir rocks and those with a <1% hydrocarbon content) and assessed the change in aggregate size, settling rate and resuspension behavior of these using resuspension chambers and settling cylinders. Results indicate that both settling velocity and seabed stress required to resuspend the aggregates are greater in aggregates exposed to drill cuttings, with these increases most significant in aggregates exposed to hydrocarbon containing drill cuttings.     

Development of oil hydrocarbon fingerprinting and identification techniques

Oil, refined product, and pyrogenic hydrocarbons are the most frequently discovered contaminants in the environment. To effectively determine the fate of spilled oil in the environment and to successfully identify source(s) of spilled oil and petroleum products is, therefore, extremely important in many oil-related environmental studies and liability cases. This article briefly reviews the recent development of chemical analysis methodologies which are most frequently used in oil spill characterization and identification studies and environmental forensic investigations. The fingerprinting and data interpretation techniques discussed include oil spill identification protocol, tiered analytical approach, generic features and chemical composition of oils, effects of weathering on hydrocarbon fingerprinting, recognition of distribution patterns of petroleum hydrocarbons, oil type screening and differentiation, analysis of “source-specific marker” compounds, determination of diagnostic ratios of specific oil constituents, stable isotopic analysis, application of various statistical and numerical analysis tools, and application of other analytical techniques. The issue of how biogenic and pyrogenic hydrocarbons are distinguished from petrogenic hydrocarbons is also addressed.     

Prevention of oil spill from shipping by modelling of dynamic risk

This paper presents a new dynamic environmental risk model, with intended use within a new, dynamical approach for risk based ship traffic prioritisation. The philosophy behind this newly developed approach is that shipping risk can be reduced by directing efforts towards ships and areas that have been identified as high priority (high risk), prior to a potential accident. The risk model proposed in this paper separates itself from previous models by drawing on available information on dynamic factors and by focusing on the ship's surroundings. The model estimates the environmental risk of drift grounding accidents for oil tankers in real time and in forecast mode, combining the probability of grounding with oil spill impact on the coastline. Results show that the inherent dynamic risk introduced by an oil tanker sailing along the North Norwegian coast depends, not surprisingly, significantly upon wind and ocean currents, as well as tug position and cargo oil type. Results of this study indicate that the risk model is well suited for real time risk assessment, and effectively separates low risk and high risk situations. The model is well suited as a tool to prioritise oil tankers and coastal segments. This enables dynamic risk based positioning of tugs, using both real-time and projected risk, for effective support in case of a drifting ship situation.     

Measuring Concentrations of Dissolved Methane and Ethane and the 13C of Methane in Shale and Till

Baseline characterization of concentrations and isotopic values of dissolved natural gases is needed to identify contamination caused by the leakage of fugitive gases from oil and gas activities. Methods to collect and analyze baseline concentration‐depth profiles of dissolved CH₄ and C₂H₆ and δ¹³C‐CH₄ in shales and Quaternary clayey tills were assessed at two sites in the Williston Basin, Canada. Core and cuttings samples were stored in Isojars^® in a low O₂ headspace prior to analysis. Measurements and multiphase diffusion modeling show that the gas concentrations in core samples yield well‐defined and reproducible depth profiles after 31‐d equilibration. No measurable oxidative loss or production during core sample storage was observed. Concentrations from cuttings and mud gas logging (including IsoTubes^®) were much lower than from cores, but correlated well. Simulations suggest the lower concentrations from cuttings can be attributed to drilling time, and therefore their use to define gas concentration profiles may have inherent limitations. Calculations based on mud gas logging show the method can provide estimates of core concentrations if operational parameters for the mud gas capture cylinder are quantified. The δ¹³C‐CH₄ measured from mud gas, IsoTubes^®, cuttings, and core samples are consistent, exhibiting slight variations that should not alter the implications of the results in identifying the sources of the gases. This study shows core and mud gas techniques and, to a lesser extent, cuttings, can generate high‐resolution depth profiles of dissolved hydrocarbon gas concentrations and their isotopes.     

The impact of drilling fluid and well cuttings on polychaete feeding guilds from the US northeastern continental shelf

The effect of recent drilling operations (fluid and well cuttings) on polychaete feeding guilds from the continental shelf off Atlantic City, New Jersey, was examined. Although there were some adverse effects on macrobenthos from 2160 metric tons of cuttings and mud solids discharged into the marine environment, the composition of polychaete feeding guilds remained essentially unchanged. This key trophic relationship between polychaetes and the changing environment due to the drilling operation was apparently uninterrupted. This relationship remains to be examined in other natural and perturbed habitats.     

Environmental monitoring in a gas production area on the northwestern Black-Sea shelf

The results of long-term seasonal oceanographic observations conducted by YugNIRO from 1955 to 1991 in standard cross-sections on the northwestern shelf of the Black Sea and data obtained by monitoring oil and chemical pollution of the marine environment from 1987 to 1993 in the area of gas deposit development are systematized and statistically treated. The oceanographic conditions of pollution field formation in this region are studied. The dynamics and distribution of total concentrations of oil products and microelements (Hg, Cu, Pb, Cd, and Cr) in water and bottom sediments are examined in the areas in Karkinitskii Bay where permanent offshore platforms are operated. The obtained results are compared with data on the background environmental pollution of the Black Sea and World Ocean. A hypothesis is offered to elucidate the possible causes and mechanisms through which offshore gas production affects the hydrochemical conditions on the shelf. The monitoring data are said to be a necessary information basis for the prediction of pollution dynamics in Karkinitskii Bay with the use of a box-type hydroecological model of petroleum hydrocarbon biotransformations in water, and approaches for the use of these data for this purpose are outlined.     

Potential Impact of Production Chemicals on the Toxicity of Produced Water Discharges from North Sea Oil Platforms

Production chemicals are used on offshore oil production platforms to prevent corrosion and scale formation, and to assist oil–water separation. A proportion of these chemicals may enter the marine environment via the produced water discharge. This study investigated the potential impact of 11 oilfield production chemicals on the toxicity of the produced water discharge. The Microtox® system was used for toxicity assessment of the chemicals, both directly in aqueous preparations and following their partitioning between oil (crude and low toxicity mineral base oil) and North Sea brine. For the majority of the chemicals tested, the toxicity of the aqueous phase to the test organism following partitioning against crude oil, was not significantly altered by the presence of process chemicals when used in their normal field dosage concentrations. However, there was evidence that certain chemicals could increase the partitioning of oil components into the aqueous phase by an order of magnitude, when applied at high dosage concentrations.     

Comparison of numerical hindcasted severe waves with Doppler radar measurements in the North Sea

Severe sea states in the North Sea present a challenge to wave forecasting systems and a threat to offshore installations such as oil and gas platforms and offshore wind farms. Here, we study the ability of a third-generation spectral wave model to reproduce winter sea states in the North Sea. Measured and modeled time series of integral wave parameters and directional wave spectra are compared for a 12-day period in the winter of 2013–2014 when successive severe storms moved across the North Atlantic and the North Sea. Records were obtained from a Doppler radar and wave buoys. The hindcast was performed with the WAVEWATCH III model (Tolman 2014) with high spectral resolution both in frequency and direction. A good general agreement was obtained for integrated parameters, but discrepancies were found to occur in spectral shapes.     

A multibiomarker approach in barramundi (Lates calcarifer) to measure exposure to contaminants in estuaries of tropical North Queensland

A suite of biomarkers were measured in barramundi (Lates calcarifer) from five North Queensland estuaries along a perceived pollution gradient. The biomarkers selected were 7-ethoxyresorufin-O-deethylase (EROD), cytochrome P450, fluorescent aromatic compounds (FACs), DNA integrity, RNA:DNA ratio, cholinesterase activity (ChE), condition factor and hepatosomatic index. The resulting database was subjected to uni- and multi-variate analyses in order to assess the most suitable biomarkers to assess pollution in North Queensland estuaries and to classify the environmental quality of the sites. Principal components analysis (PCA) on the biochemical markers revealed that EROD, EROD/P450, DNA damage and to a lesser extent ChE and FACs were found to be responsive to contaminants in the environment while cytochrome P450, condition factor and the hepatosomatic index were found to be less responsive biomarkers. This study has demonstrated the utility of applying a multibiomarker approach in conjunction with traditional analysis of contaminants in providing valuable information in environmental risk assessment.