Trace Metals in Selected Benthic Invertebrates from Belgian Coastal Waters (1981–1996)

Mercury, cadmium, lead, copper, zinc and chromium were assessed in brown shrimp (Crangon crangon), swimming crab (Liocarcinus holsatus), hermit crab (Pagurus bernhardus), starfish (Asterias rubens) and cut trough shell (Spisula subtruncata) from ten sampling stations off the Belgian coast, including three dredge spoils disposal sites. Calculations of time trends indicated that on the whole concentrations of trace metals had significantly decreased since 1981, also on dredged material dumping sites. Starfish and hermit crab were found to be the most promising benthic indicator species for metal contamination. Globally, the location of the sites, including the dredge spoils disposal zones, showed to be of little influence on the concentrations of trace metals.     

Preliminary studies of man-made litter in the Firth of Forth,Scotland

Short-term studies on man-made litter deposited on the beaches of the Edinburgh coastline of the Firth of Forth, Scotland, have demonstrated that containers of all kinds, plastic bags, plastic sheeting and clothing, comprise the main and dominant components of the nineteen categories of litter analysed. Most of the litter is of local origin either deposited in situ or washed ashore from neighbouring water's-edge tips. Very little evidence was found of litter washed ashore being of foreign origin or having been tipped overboard from ships at sea. Much of the smaller items of litter are discarded by visitors to the beach. The solution to the problem is seen as one of education at all levels rather than ineffective punitive measures.     

Trends and shifts in streamflow in Hawai‘i, 1913–2008

This study addresses a need to document changes in streamflow and base flow (groundwater discharge to streams) in Hawai‘i during the past century. Statistically significant long‐term (1913–2008) downward trends were detected (using the nonparametric Mann–Kendall test) in low‐streamflow and base‐flow records. These long‐term downward trends are likely related to a statistically significant downward shift around 1943 detected (using the nonparametric Pettitt test) in index records of streamflow and base flow. The downward shift corresponds to a decrease of 22% in median streamflow and a decrease of 23% in median base flow between the periods 1913–1943 and 1943–2008. The shift coincides with other local and regional factors, including a change from a positive to a negative phase in the Pacific Decadal Oscillation, shifts in the direction of the trade winds over Hawai‘i, and a reforestation programme. The detected shift and long‐term trends reflect region‐wide changes in climatic and land‐cover factors. A weak pattern of downward trends in base flows during the period 1943–2008 may indicate a continued decrease in base flows after the 1943 shift. Downward trends were detected more commonly in base‐flow records than in high‐streamflow, peak‐flow, and rainfall records. The decrease in base flow is likely related to a decrease in groundwater storage and recharge and therefore is a valuable indicator of decreasing water availability and watershed vulnerability to hydrologic changes. Whether the downward trends will continue is largely uncertain given the uncertainty in climate‐change projections and watershed responses to changes. Copyright © 2012 John Wiley & Sons, Ltd.     

East Greenland freshwater runoff to the Greenland‐Iceland‐Norwegian Seas 1999–2004 and 2071–2100

In this paper, we quantify the terrestrial flux of freshwater runoff from East Greenland to the Greenland‐Iceland‐Norwegian (GIN) Seas for the periods 1999–2004 and 2071–2100. Our analysis includes separate calculations of runoff from the Greenland Ice Sheet (GrIS) and the land strip area between the GrIS and the ocean. This study is based on validation and calibration of SnowModel with in situ data from the only two long‐term permanent automatic meteorological and hydrometric monitoring catchments in East Greenland: the Mittivakkat Glacier catchment (65°N) in SE Greenland, and the Zackenberg Glacier catchment (74°N) in NE Greenland. SnowModel was then used to estimate runoff from all of East Greenland to the ocean. Modelled glacier recession in both catchments for the period 1999–2004 was in accordance with observations, and dominates the annual catchment runoff by 30–90%. Average runoff from Mittivakkat, ～3·7 × 10^?2 km³ y^?1, and Zackenberg, ～21·9 × 10^?2 km³ y^?1, was dominated by the percentage of catchment glacier cover. Modelled East Greenland freshwater input to the North Atlantic Ocean was ～440 km³ y^?1 (1999–2004), dominated by contributions of ～40% from the land strip area and ～60% from the GrIS. East Greenland runoff contributes ～10% of the total annual freshwater export from the Arctic Ocean to the Greenland Sea. The future (2071–2100) climate impact assessment based on the Intergovernmental Panel on Climate Change (IPCC) A2 and B2 scenarios indicates an increase of mean annual East Greenland air temperature by 2·7 °C from today's values. For 2071–2100, the mean annual freshwater input to the North Atlantic Ocean is modelled to be ～650 km³ y^?1: ～30% from the land strip area and ～70% from the GrIS. This is an increase of approximately ～50% from today's values. The freshwater runoff from the GrIS is more than double from today's values, based largely on increasing air temperature rather than from changes in net precipitation. Copyright © 2008 John Wiley & Sons, Ltd.     

Observations and simulations of an unsteady island wake in the Firth of Forth, Scotland

Beamer Rock, a 50-m-wide island in the Firth of Forth, produces a distinctive von Kármán vortex street wake, the characteristics of which depend on the speed and direction of the tidal flow. ADCP (acoustic Doppler current profiler), CTD (conductivity–temperature–depth) and aerial photograph data were collected from the region during flood and ebb tidal flow under neap and spring conditions. Good agreement was found between the observations and the results from a fixed-grid depth-averaged numerical tidal model. The island wake parameter correctly predicted the unsteady nature of the wake, and the Strouhal number (defined in terms of flow past a circular cylinder) was found to give excellent predictions of the wake wavelength when scaled on the island width. Contrary to published results, the study shows that it is possible to accurately simulate an unsteady island wake using a relatively coarse fixed-grid numerical model.Responsible Editor: Jens Kappenberg     

Trace Elements in Sediments and Mussels – Spatial Distribution,Chemical Partitioning,and Risk Assessment

Sediment samples were collected from 30 different locations in Abu Qir Bay (Mediterranean Sea), East Alexandria, Egypt and analyzed for trace elements. The highest concentrations of most of the elements were observed in the nearshore stations in the vicinity of the major anthropogenic activities as industrial settlements, wastewater discharges, and agricultural drainage. In addition, mussel samples of Mactra corallina and Tapes decussata were collected corresponding to the sediment samples. Concentrations of As, Cd, Cr, Mn, and Zn in the mussel tissues were higher than concentrations in sediments, thus indicating their relatively high bioavailability. Sequential extraction procedure was performed on selected sediment samples. Significant correlations were observed between the concentrations of Cu, Mn, Pb, and Zn in the exchangeable fraction of the sediments and the corresponding tissues of M. corallina. The output of the risk assessment applied on the sediments revealed that adverse ecological effects to benthic species could occur and that a higher level of risk is expected from the exposure to Cd, Cr, Hg, and Zn. No adverse carcinogenic or non‐carcinogenic human health effects are expected from the consumption of the two mussel species from Abu Qir Bay.     

Trends in rainfall and temperature in the Peruvian Amazon–Andes basin over the last 40 years (1965–2007)

The hydroclimatology of the Peruvian Amazon–Andes basin (PAB) which surface corresponding to 7% of the Amazon basin is still poorly documented. We propose here an extended and original analysis of the temporal evolution of monthly rainfall, mean temperature (T_mean), maximum temperature (T_max) and minimum temperature (T_min) time series over two PABs (Huallaga and Ucayali) over the last 40 years. This analysis is based on a new and more complete database that includes 77 weather stations over the 1965–2007 period, and we focus our attention on both annual and seasonal meteorological time series. A positive significant trend in mean temperature of 0.09 °C per decade is detected over the region with similar values in the Andes and rainforest when considering average data. However, a high percentage of stations with significant T_mean positive trends are located over the Andes region. Finally, changes in the mean values occurred earlier in T_max (during the 1970s) than in T_min (during the 1980s). In the PAB, there is neither trend nor mean change in rainfall during the 1965–2007 period. However, annual, summer and autumn rainfall in the southern Andes presents an important interannual variability that is associated with the sea surface temperature in the tropical Atlantic Ocean while there are limited relationships between rainfall and El Niño‐Southern Oscillation (ENSO) events. On the contrary, the interannual temperature variability is mainly related to ENSO events. Copyright © 2012 John Wiley & Sons, Ltd.     

Trace Element Levels in the Groundwater of Mediterranean Coastal Plains – The Case of Silifke,Turkey

The Silifke plain is located near the coast of the Mediterranean Sea in Turkey. The delta in the plain is a highly fertile land that supports the agriculture of more than twenty types of crop. Some trace element content of the groundwater samples taken from the existing wells in this area are analyzed using inductively coupled plasma optical emission spectrometry (ICP‐OES). The mean levels (ppm) of boron (B), barium (Ba), iron (Fe), manganese (Mn), lead (Pb), zinc (Zn), total chromium (TCr), cadmium (Cd), copper (Cu), aluminum (Al), and nickel (Ni) were obtained for the sampling points in the area for four seasons. Groundwater samples taken in the study area don't exhibit significantly elevated levels of these elements during a period of twelve months between December 2007 and November 2008. Furthermore, all of the elements exhibit values lower than 0.005 ppm, with the exception of B, Ba, and Fe. The results demonstrate that although these three elements produce the highest values, most are found to be appropriate for activities such as irrigation and human consumption in terms of trace elements.     

Assessment of the aesthetic quality of a selection of beaches in the Firth of Forth,Scotland

The aesthetic quality of fourteen beaches in the Firth of Forth, Scotland was surveyed between May and July 2002 using a protocol designed by the UK's National Aquatic Litter Group (NALG). Local authority beach cleaning regimes influence the amount of litter found on beaches. Frequent and thorough beach cleaning is necessary to maintain high aesthetic standards. Bathing and amenity beaches achieved higher aesthetic quality than non-bathing and non-amenity beaches. The aesthetic quality of rural and urban beaches was very similar. The NALG protocol appears more complicated to use than other beach litter surveys. However, the classification system generates results that are easily interpreted by the general public. Furthermore, the NALG protocol could be combined with coastal zone management plans as a useful environmental performance indicator.     

Trends in rainfall and runoff in the Blue Nile Basin: 1964–2003

Most of the water from the Nile originates in Ethiopia but there is no agreement on how land degradation or climate change affects the future flow in downstream countries. The objective of this paper is to improve the understanding of future conditions by analysing historical trends. During the period 1964–2003, the average monthly basin‐wide precipitation and monthly discharge data were collected and analysed statistically for two stations in the upper 30% of the Blue Nile Basin and monthly and 10‐day discharge data of one station at the Sudan–Ethiopia border. A rainfall–runoff model examined the causes for observed trends. The results show that, while there was no significant trend in the seasonal and annual basin‐wide average rainfall, significant increases in discharge during the long rainy season (June to September) were observed at all three stations. In the upper Blue Nile, the short rainy season flow (March to May) increased, while the dry season flow (October to February) stayed the same. At the Sudan border, the dry season flow decreased significantly with no change in the short rainy season flow. The difference in response was likely due to the construction of weir in the 1990s at the Lake Tana outlet that affected the upper Blue Nile discharge significantly but affected less than 10% of the discharge at the Sudan border. The rainfall–runoff model reproduced the observed trends, assuming that an additional 10% of the hillsides were eroded in the 40‐year time span and generated overland flow instead of interflow and base flow. Models concerning future trends in the Nile cannot assume that the landscape runoff processes will remain static. Copyright © 2010 John Wiley & Sons, Ltd.     

Extended Sediment Quality Rating for Trace Elements in Urban Waters – Case Study Klinke,Germany

The European Water Framework Directive (WFD) commits European Union member states to achieving good ecological status in all water bodies by 2015. For sediments the definition of good chemical status is based on numerical sediment quality guidelines. The aqua regia fraction is thus used for the evaluation of heavy metal concentrations in sediments. The chemical constituents in sediments responsible for mobility and toxicity are not considered generally. This article presents the combining of the sequential BCR procedure, for determining the chemical species of relevant elements, with the geoaccumulation index principle a numerical classification method for sediment quality guidelines. Using the BCR method it can be demonstrated that changes in element speciation can lead to more highly mobile species of trace elements which may affect the hazardous potential of sediments despite the “good chemical status” classification for aqua regia digestions. The Klinke stream is an urban surface water body located in Magdeburg, the state capital of Saxony‐Anhalt, Germany. Using this stream as an example it is shown that this additional information helps to describe the dynamics and discharge of the trace elements Al, Ti, V, Cr, Mn, Fe, Co, Ni, Cu, Zn, As, Rb, Sr, Mo, Pd, Cd, Sb, Ba, Pb, Bi, and U into the Elbe River from urban water bodies.     

Trace element content of seagrasses in the Leschenault Estuary,Western Australia

Estuarine environments are particularly vulnerable to human impacts. In this study, trace elements in Ruppia megacarpa, Halophila ovalis, sediment and porewater were analysed to assess the potential contamination of the Leschenault Estuary, Western Australia, from a primarily agricultural drain. Sediment concentrations of Cd, Cu, Mn, and Ni and were highest nearest the drain while Al, As, Cr, Fe and Zn and were highest further from the drain. H. ovalis showed greater accumulation of Fe, Al, and As than R. megacarpa. Concentrations of Fe, Al, As, and Ni were generally higher in below-ground plant parts than above, suggesting uptake of these trace elements via the sediment-route pathway. This study suggested that the drain was a source of Cu and Mn, with these elements entering the estuary through water inflows. As and Fe, were highest furthest from the drain suggesting input of trace elements from sources other than the drain under study.     

Erratum: Trace Elements in Sediments and Mussels – Spatial Distribution,Chemical Partitioning,and Risk Assessment

Sediment samples were collected from 30 different locations in Abu Qir Bay (Mediterranean Sea), East Alexandria, Egypt and analyzed for trace elements. The highest concentrations of most of the elements were observed in the nearshore stations in the vicinity of the major anthropogenic activities as industrial settlements, wastewater discharges, and agricultural drainage. In addition, mussel samples of Mactra corallina and Tapes decussata were collected corresponding to the sediment samples. Concentrations of As, Cd, Cr, Mn, and Zn in the mussel tissues were higher than concentrations in sediments, thus indicating their relatively high bioavailability. Sequential extraction procedure was performed on selected sediment samples. Significant correlations were observed between the concentrations of Cu, Mn, Pb, and Zn in the exchangeable fraction of the sediments and the corresponding tissues of M. corallina. The output of the risk assessment applied on the sediments revealed that adverse ecological effects to benthic species could occur and that a higher level of risk is expected from the exposure to Cd, Cr, Hg, and Zn. No adverse carcinogenic or non‐carcinogenic human health effects are expected from the consumption of the two mussel species from Abu Qir Bay.     

Trace organic contamination in the Americas: An overview of the US National Status & Trends and the International ‘Mussel Watch’ programmes

The National Status & Trends (NS&T, 1986–1993) and the International Mussel Watch (IMW, 1991–1992) programmes provide a good coverage of a broad range of environmental conditions along the North, Central and South American coasts. Total concentrations of DDTs, chlordane-related compounds, PCBs and PAHs present fairly homogeneous distributions along the northern Gulf of Mexico coast, with very few sites showing extremely high or low concentrations. In contrast, a larger variability in the geographical distribution of some of these organic contaminants was observed for IMW sites. For example, high concentrations of DDT and its metabolites, DDD and DDE, were generally found in tropical and subtropical areas as compared to more temperate zones of South America. ‘Industrial’ contaminants, such as PCBs and PAHs, have similar distributions with the highest concentrations encountered generally along the southern South Atlantic coast. An overall comparison of the concentrations of these organic contaminants measured at NS&T and IMW sites indicates that contamination is significantly higher along the northern coast of the Gulf of Mexico.     

Perspectives on monitoring resistivity changes with telluric signals at Parkfield, California: 1988–1999

An array designed to detect changes of resistivity in the upper 10 km of the crust has been in continuous operation since 1988. Long period (T=300–7200 s) telluric signals are recorded digitally on 5–16 km long dipoles. Telluric transfer functions are computed between field dipoles and two reference dipoles and then decomposed to examine daily fluctuations of those functions. Based on analysis of these daily fluctuations, stabilities of 0.1–0.3% are achieved. No intermediate term resistivity changes are seen associated with any of the 5 M_b>4.0 earthquakes that have occurred since 1989. Short term fluctuations are seen associated with most of these earthquakes, however. Minimum bounds on resistivity changes that could have caused the fluctuations in the telluric responses range from 1.7 to 13.0%. While these are within the ranges seen in other field studies, the statistical significance of these fluctuations is low because they also occur at many times that cannot be correlated to earthquakes. Comparison of the one potential resistivity change associated with a strain change results in a strain sensitivity that is unrealistically high. This possible resistivity change coincides spatially with a temporary variation in seismic travel time in May–June 1989, however. It is likely that many of the fluctuations in the telluric responses are random variations except for the one in 1989, and recording through the next M6 earthquake will be needed in order to detect a statistically significant resistivity change.