On the Red Rectangle optical emission bands

We have observed the Red Rectangle nebula with the Multi-Object Spectrograph on the WIYN telescope. Moderate-resolution spectra (Δ λ =0.4 Å) in the region of 5800 Å were obtained in 3-arcsec apertures at over 50 positions in the nebula. Accurate and precise wavelength calibrations were obtained against a thorium–argon lamp and the sodium lines in the sky and nebula. The peak position and full width at half-maximum of the 5800-Å Red Rectangle band (RRB) were measured to beyond 15 arcsec from the star. The shortest wavelength of the band is found to be 5799.10±0.15 Å in the rest frame of the nebula. None of the emission bands has intensity coincident with the wavelength of the diffuse interstellar band (DIB) at 5797.11±0.05 Å. The 2-Å offset cannot be explained by an instrumental, spectroscopic or photophysical effect. The hypothesis that the same molecule may be the carrier of the RRB and the DIB is contradicted by these observations. As a further test of the hypothesis, absorption has been sought that would be due to a potential DIB carrier in the nebula. Tentative evidence for absorption is found in the RRB spectra taken within 9 arcsec of the star; but any absorption has a peak position essentially coincident in wavelength with the band maximum of the emission band.     

The 3.3-μm PAH emission band of the Red Rectangle

A new analysis of long-slit CGS4 United Kingdom Infrared Telescope spectra of the 3.3-μm feature of the Red Rectangle and its evolution with offset along the NW whisker of the nebula is presented. The results support a proposed two-component interpretation for the 3.3-μm feature with peak wavelengths near 3.28 and 3.30 μm. Both components exhibit a small shift to shorter wavelength with increasing offset from the central star which, by comparison with laboratory studies, is consistent with a decrease in the temperature of the carriers with distance from HD 44179. The two-component approach is also applied to 3.3-μm data for the Red Rectangle, Orion Bar D2 and Orion Bar H2S1 from Infrared Space Observatory Short Wavelength Spectrometer (SWS) studies.     

Optical emission at 5800 Å in the Red Rectangle and the 5797-Å diffuse interstellar band

An analysis of the intensity and spatial distribution of the discrete 5800-Å emission band in the spectrum of the Red Rectangle has been used to constrain the abundance and physical properties of the carrier of this emission. An origin in a large (>30 C atom) molecule is indicated. This molecule is formed in situ in the Red Rectangle, but is also a component of the diffuse interstellar medium. The UV photodissociation probability for this molecule is ≲10⁻⁵ per absorbed photon, and the luminescence efficiency is in the range 10⁻²–10⁻³. This molecule may be a product of the dissociation of carbonaceous dust.     

Molecular hydrogen line emission from the reflection nebula Parsamyan 18

The newly commissioned University of New South Wales Infrared Fabry–Perot (UNSWIRF) has been used to image molecular hydrogen emission at 2.12 and 2.25 μm in the reflection nebula Parsamyan 18. P 18 is known to exhibit low values of the (1–0)/(2–1) S(1) ratio, suggestive of UV-pumped fluorescence rather than thermal excitation by shocks. Our line ratio mapping reveals the full extent of this fluorescent emission from extended arc-like features, as well as a more concentrated thermal component in regions closer to the central exciting star. We show that the emission morphology, line fluxes and gas density are consistent with the predictions of photodissociation region (PDR) theory. Those regions with the highest intrinsic 1–0 S(1) intensities also tend to show the highest (1–0)/(2–1) S(1) line ratios. Furthermore, variations in the line ratio can be attributed to intrinsic fluctuations in the incident radiation field and/or the gas density, through the self-shielding action of H₂. An isolated knot of emission discovered just outside P 18, and having both an unusually high (1–0)/(2–1) S(1) ratio and relative velocity, provides additional evidence for an outflow source associated with P 18.     

H2 emission from shocks in molecular outflows: the significance of departures from a stationary state

We have computed the time dependence of the H₂ rovibrational emission spectrum from molecular outflows. This emission arises in shock waves generated by the impact of jets, associated with low-mass star formation, on molecular gas. The shocks are unlikely to have attained a state of equilibrium, and so their structure will exhibit both C- and J-type characteristics. The rotational excitation diagram is found to provide a measure of the age of the shock; in the case of the outflow observed in Cepheus A West by the ISO satellite, the shock age is found to be approximately 1.5×10³ yr. Emission by other species, such as NH₃ and SiO, is also considered, as are the intensities of the fine-structure transitions of atoms and ions.     

Chemically driven desorption of CO from icy grains in dark clouds

The chemical desorption of an adsorbed CO molecule in the vicinity of H₂-forming sites on cosmic dust grains in cold dense clouds is investigated theoretically, mainly using a model based on a classical molecular dynamics computational simulation. As a model surface for icy mantles of dust grains, an amorphous water ice slab is generated at 10 K, and the first and the second H atoms are thrown on to the model surface to reproduce the recombination process of the two H atoms, H+H→H₂. Then, the time and space dependence of the local temperature increase of icy mantles caused by the release of H₂ formation energy in the vicinity of H₂-forming sites is examined. It is found that icy mantles are heated locally up to about 30 K in the surface region at R 4 Å and about 20 K at 4 R 6 Å, where R is the distance from the H₂-forming site. The critical temperature of CO desorption is estimated to be about 20–30 K under conditions in typical dense clouds, which might be seen to be comparable to the above result. However, the lifetime of local heating of icy mantles is found to be too short, compared with the time-scale of CO desorption (10¹³ s) and that for H₂ forming in the vicinity of an adsorbed CO molecule (more than 2×10¹³ s). Thus, it is found that the efficiency of chemical desorption of CO on a large dust grain is negligible. On the other hand, chemical desorption can occur on a small dust grain with size less than 20 Å.     

Near-infrared polarimetry of the Red Rectangle

Imaging polarimetry through J and H broad-band filters and a 3.4 μm narrow-band filter is used to highlight the regions of scattered light in the Red Rectangle. We find that the scattered light identifies the circumbinary dust component of the molecular disc seen in CO emission. This region also appears to be the origin of the recently discovered Blue Luminescence. We find that the degrees of polarization are consistent with the amorphous carbon dust model invoked by Men'shchikov. Spectropolarimetry from 1.4 to 2.5 μm confirms that the degree of polarization in the central arcsecond region is very low. This suggests that the central bicone seen in the near-infrared is predominantly due to emission from hot dust and/or from stochastically heated nanoparticles, rather than due to scattering by large grains.     

The effect of grain size distribution on H2 formation rate in the interstellar medium

The formation of molecular hydrogen  (H₂)  in the interstellar medium takes place on the surfaces of dust grains. Hydrogen molecules play a role in gas-phase reactions that produce other molecules, some of which serve as coolants during gravitational collapse and star formation. Thus, the evaluation of the production rate of hydrogen molecules and its dependence on the physical conditions in the cloud are of great importance. Interstellar dust grains exhibit a broad size distribution in which the small grains capture most of the surface area. Recent studies have shown that the production efficiency strongly depends on the grain composition and temperature as well as on its size. In this paper, we present a formula that provides the total production rate of  H₂  per unit volume in the cloud, taking into account the grain composition and temperature as well as the grain size distribution. The formula agrees very well with the master equation results. It shows that for a physically relevant range of grain temperatures, the production rate of  H₂  is significantly enhanced due to their broad size distribution.     

The possibility of nitrogen isotopic fractionation in interstellar clouds

The possibility of nitrogen isotopic fractionation owing to ion–molecule exchange reactions involving the most abundant N-containing species in dense interstellar clouds has been explored. We find that exchange reactions between N atoms and N-containing ions have most influence on the fractionation, although the extent of fractionation is too small to be readily detectable.     

The C/CO ratio in B335 and the decaying dark matter neutrino hypothesis

C¹⁸O J  = 2–1, C¹⁷O J  = 2–1 and [C  I ] ³P₁–³P₀ emission from the dense cold cloud B335 has been observed and modelled in order to determine the C/CO ratio. The observed ratio is compared with a prediction by Tarafdar who assumes a mechanism in which the CO dissociation is caused by photons of energy ∼ 13.8 eV. These were postulated by Sciama to result from the decay of dark matter neutrinos. Our value for the C/CO ratio sets an upper limit to the strength of the neutrino decay dissociation process, thus providing a significant datum for interstellar chemistry theory.     

NCCN in TMC-1 and IRC+10216

We employ quantum chemical calculations using the CBS-RAD ('Complete Basis Set – Radicals') technique on the C₂N₂H potential energy surface to show that the reaction of HNC with CN is a viable and plausible route to NCCN in cold astrophysical environments. We use detailed chemical kinetic models to predict the abundance of NCCN in TMC-1 and IRC+10216. Radio-astronomical detection of NCCN is precluded by its lack of a dipole moment. We discuss other prospects for its observation in interstellar and circumstellar environments, by space-borne infrared spectroscopy, indirectly by detection of the NCCNH⁺ ion, or inferentially by detection of its higher-energy, polar isomer CNCN.     

Desorption processes and the deuterium fractionation in molecular clouds

Several processes have been suggested as ways of returning accreted grain mantles to the gas, thus preventing the total removal of molecules from the gas phase in dark quiescent clouds. We attempt to distinguish between them by considering not only the calculated gas-phase abundances, but also the ratio of the abundances of deuterated species to non-deuterated species. We find that the D/H ratio in molecules is relatively model-independent, but that desorption due to the formation of H₂ on grains gives the best overall agreement with the observations.