青海南祁连科克岩体地球化学特征及其形成时代

为探讨南祁连喀克图蒙克山科克岩体的构造属性,对南祁连喀克图蒙克山中奥陶世科克岩体进行了详细的地球化学和定年研究。研究结果表明,该岩体主体岩性为正长花岗岩,具有高SiO_2(68.41%～73.10%)、高Al_2O_3(13.03%～14.35%)的特征,亏损高场强元素Nb、P、Ti和重稀土元素,发育明显的负Eu异常,反映岩石经历了强烈的分离结晶作用,其稀土元素配分曲线类型与壳源花岗岩相似;构造成因分类图解表明,这些花岗岩属同碰撞环境的产物。LA-ICP-MS锆石U-Pb测年结果表明,岩体形成于461±2.7Ma,时代为中奥陶世,表明该岩体的源岩为壳源或壳幔混合的产物。结合区域地质特征认为,该岩体为同碰撞作用的产物,佐证了南祁连地块在奥陶纪处于挤压状态,对进一步研究南祁连造山带的演化具有重要意义。     

Methane-Bearing Fluid Inclusions as Evidence of the Collisional Nature of High-Alumina Granites,Northern Sikhote-Alin,Russian Far East

The Khungariisk high-alumina S-type granites (northern Sikhote-Alin fold system, Russian Far East) have been formed as a result of anatectic melting during collision of the Anyuy sialic block with the continental margin in the Early Cretaceous. Methane-rich fluid inclusions are characteristic of these granites. The CH₄-H₂O fluid composition is explained by the release of water and methane from the sedimentary units residing on the oceanic plate, as it was subducted beneath the sialic block. This fluid seeped into the heated and deformed metamorphic rocks of the overlying block and initiated partial fusion of the granites. A comparison of the new data with the results of fluid-inclusion studies of high-alumina collisional granites from the Pamir Mountains and Japan reveals similarities. Thus, methane-bearing fluid is probably one of the general features of this granite type, reflecting its anatectic origin.     

Timing and geochemistry of potassic magmatism in the eastern part of the Svecofennian domain,NW Ladoga Lake Region,Russian Karelia

The Puutsaari intrusion is a potassium-rich magmatic complex in the eastern part of the Svecofennian domain close to the Archaean border. The intrusion is generally undeformed in contrast to 1880–1875 Ma-old country rock tonalitic migmatites and diatectites. The main rock types are: (1) mafic rocks of a gabbro–norite–diorite–quartz monzodiorite series; (2) quartz diorite–tonalite–granodiorite; and (3) coarse-grained microcline granite. The three rock-types intruded coevally forming a peculiar three-component mingling system. The mafic rocks, enriched in K, P, Ba, Sr and LREE, have marked shoshonitic affinities (K₂O=1.97–5.40, K₂O/Na₂O=0.6–2.37). On a regional scale they demonstrate transitional geochemistry between less enriched syn-orogenic 1880 Ma-old gabbro–tonalite complexes and strongly enriched 1800 Ma post-collisional shoshonitic intrusions. The microcline granite as well as the tonalite–granodiorite rocks are geochemically similar to crustal anatectic granitoids of the NW Ladoga Lake area. The three rock groups do not form a single trend on Harker-type diagrams and are unlikely to be related by fractional crystallisation or mixing. Zircons from the Puutsaari microcline granite and from the mafic rock series have been dated by ion-microprobe (NORDSIM) at 1868.2±5.9 and 1869±7.7 Ma, respectively. Most zircons recovered from a granite sample had zoned or homogeneous cores and unzoned fractured rims. No statistically significant variation of zircon core and rim ages from the granite was established in the course of this study. Zircons from the mafic rock are unzoned. It is suggested that the mafic rocks at Puutsaari were derived from an enriched mantle shortly after the main Svecofennian collisional event and the roughly 1.88 Ga regional metamorphic culmination. The emplacement of the mafic melt caused anatectic melting of various crustal protoliths and produced coeval granitic and tonalitic compositions.     

Geochemical behaviour of LREE,Y and Zr in uranium mineralized and non-mineralized granite from Darshanapur area,in the Gogi-Kurlagere fault zone,Bhima basin,Yadgiri district,Karnataka

Granite core samples (n=14) from the Gogi-Kurlagere fault zone in the central part of the Bhima basin were studied in terms of LREE, Y and Zr mobility during uranium mineralization. LREE, Zr and Y along with LILE (Ba, Rb) and P show behavioral differences in the mineralised and the non-mineralised samples. Average ΣLREE in mineralised granite (240 ppm) is higher than in non-mineralised samples (157 ppm). The average Zr and Y in the mineralised granite are 193 ppm and 17 ppm, while the corresponding abundances of these elements in non-mineralised portion are 148 ppm and 11 ppm respectively. Besides enrichment of U, Th, Ba, Pb and Rb and depletion of Sr are observed in mineralized granite in comparison to non-mineralized granite. Hydrothermal alteration has led to the mobility of these elements, which again dependent on the overall geochemical behavior of the migrating fluid. REE and Y in association with uranyl [(UO₂)²⁺] ion were transported as carbonate complexes like [UO₂(CO₃)₃]^4- and [REE (CO₃)₃]^3- and were later incorporated into favourable structural loci by precipitating minerals like pitchblende and coffinite.     

On “Birthmarks” in rare-metal granites of the Losevka pluton,northern Kazakhstan

The Losevka pluton of rare-metal albite granite, which was explored as a possible source of columbite-zircon-malacon ore, is composed of quartz, sodic plagioclase, potassium feldspar, annite, protolithionite, lepidomelane, and Li-muscovite. The average chemical composition of this rock is as follows, wt %: 74.14 SiO₂, 0.04 TiO₂, 14.07 Al₂O₃, 1.05 Fe₂O₃, 0.78 FeO, 0.15 MnO, 0.09 MgO, 0.47 CaO, 4.65 Na₂O, 4.11 K₂O, and 0.03 P₂O₅. The accessory minerals are zircon, malacon, and cyrtolite (874 ppm); apatite (18 ppm); ilmenite (114 ppm); xenotime and monazite (119 ppm); and Nb-columbite (463 ppm). The black inclusions up to 15 cm in size, which are observed in this granite and called “birthmarks” by local geologists, consist of the same rock-forming minerals as the surrounding granite, but are enriched in MnO, MgO, CaO, TiO₂, and F and depleted in SiO₂ relative to the light granite. The black granite is also distinguished by much higher Sr and Ba contents and lower La, Rb, Y, Nb, REE, Cs, Ta, Th, and U contents. The black color is caused by enrichment in manganese oxides, manganoilmenite, and Mn-annite. All rock-forming minerals are pervaded by thin veinlets of Mn-oxides. In addition, bastnaesite, Y-and Th-fluorides, zircon, and malacon have been identified. Aggregates of black-colored minerals are not the products of the fractionation of the initial magma or immiscibility effects, because the structure of the albite-potassium feldspar-quartz-mica matrix is the same both in black and light granites. The percolation of a deep-sourced fluid enriched in Mn and F into a granitic melt might be a more probable origin.     

Late Triassic U-bearing and barren granites in the Miao'ershan batholith,South China: Petrogenetic discrimination and exploration significance

The Miao'ershan uranium ore district is one of the most important granite-hosted uranium producers in South China. There are several Triassic granite plutons in the Miao'ershan batholith, but uranium ore deposits mainly occur within the Douzhashan granitic body. Precise zircon U–Pb dating indicated that these Triassic granite plutons were emplaced during 204 to 215 Ma. The Douzhashan U-bearing granite lies in the central part of the Miao'ershan batholith, and has higher U contents (8.0 to 26.1 ppm, average 17.0 ppm) than the nearby Xiangcaoping granite (5.0 to 9.3 ppm, average 7.0 ppm) and the Yangqiaoling granite (6.4 to 18.3 ppm, average 11.5 ppm) in the south part of the batholith. The Douzhashan granite is composed of medium-grained two-mica granite, whereas the Xiangcaoping and Yangqiaoling granites are composed of porphyritic biotite granite. Both the Xiangcaoping and Douzhashan granites have high A/CNK ratios (> 1.10), high (⁸⁷Sr/⁸⁶Sr)_i ratios (> 0.720) and low ε_Nd(t) values (− 11.3 to − 10.4), suggesting that they belong to strongly peraluminous S-type granites. The Douzhashan granite has low CaO/Na₂O ratios, high Rb/Sr and Rb/Ba ratios, indicating a partial melting origin of clay-rich pelitic rocks. In contrast, the Xiangcaoping granite formed from clay-poor psammite-derived melt. The Yangqiaoling granite shows different geochemical characteristics with the Douzhashan and Xiangcaoping granites, indicating a different magma source. The Yangqiaoling granite has higher ε_Nd(t) of − 9.4 to − 8.3 and variable A/CNK values from 0.98 to 1.19, suggesting a mixture source of meta-sedimentary rocks and meta-igneous rocks. Crystallization fractionation is not the main mechanism for U enrichment in the Douzhashan granite. We suggest that U-rich pelitic rock sources may be the key factor to generate peraluminous U-bearing granites in South China. Searching for those granites which are reduced, strongly peraluminous and were derived from U-rich pelitic rocks, is the most effective way for exploring granite-hosted U deposits.     

Signature of potassium enrichment in granite of the Chitrial area, Nalgonda district, Andhra Pradesh: Inferences using its U, Th, K2O, Na2O, Rb, Ba and Sr contents

A medium tonnage unconformity proximal uranium deposit has been established at Chitrial by the Atomic Minerals Directorate in the Srisailam sub-basin. In this type of deposits, the association of uranium with potassic alteration (illitization) is well-documented. The present study is directed towards understanding such an association in the Chitrial area for which the uranium mineralized borehole core samples were collected and analyzed. It is observed that the average concentrations of K₂O, Na₂O, Rb, Ba and Sr in the granite of the Chitrial area are 5.35%, 1.78%, 252 ppm, 564 ppm and 52 ppm, respectively, and they show average critical elemental ratios of K/Rb, Ba/Rb and Rb/Sr as 191, 2.37 and 7.13, respectively. The granites show low K/Rb, low Rb/Ba and high Rb/Sr ratios compared to that of the average crust indicating its derivation from crustal source. The samples have higher values of uranium (av. 53 ppm), thorium (av. 66 ppm) and lead (av. 41 ppm). The U/Th ratio in the granite varies from 0.07 to 20.86 with an average of 1.68. They also exhibit high K₂O/Na₂O ratio typical of post-Archaean granite and very high values suggest the possibility of later potassium enrichment.     

Mineralogy,geochemistry, and genesis of co-genetic granite-pegmatite-hosted rare metal and rare earth deposits of the Kawadgaon area,Bastar craton,Central India

Co-genetic pegmatites associated with the granite of the Kawadgaon area in the Bastar craton, Central India, contain a wide range of ore minerals of Nb, Ta, Be, Sn, Zr, Ti, and REE, including columbite-tantalite, ixiolite, pseudo-ixiolite, wodginite, tapiolite, microlite, fersmite, euxenite, aeschynite, beryl, cassiterite, monazite, xenotime, zircon, ilmenite, triplite, and magnetite. There is a distinct vertical zonation between the rare metal and tin pegmatites in apical parts of the host granite. Geochemically, these are LCT-S type, beryl-columbite-phosphate pegmatites that have notably high contents of SiO₂ (av. 73.80%), Rb (av. 381 ppm), and Nb (av. 132 ppm). The investigated granites probably were derived from the melting of older crustal rocks, as indicated by a high initial ⁸⁷Sr/⁸⁶Sr isotopic ratio, and the major-element geochemistry of the granites and pegmatites. Plots of mol. CaO/(MgO+FeO^t) vs. mol. Al₂O₃/(MgO+FeO^t) suggest that the source rock was pelitic metasediments. Based on the available data, it is postulated that the derivation of pegmatites from the parent granite occurred shortly after granite emplacement in the late Archaean-early Proterozoic (~2500 Ma). The K/Rb, Ba/Rb, and Rb/Sr ratios of the felsic bodies reveal that a substantial part of the granite formed from evolved melts, and further fractionation produced the co-genetic pegmatites and associated rare metal and rare earth deposits.     

Geochemical characteristics of the niobium-rich arfvedsonite granites, Younger Granites province of Nigeria

Arfvedsonite granites are most prevalent in the northern sector of the Nigerian anorogenic ring-complex province wherein they form the main granitic rocks at Kudaru and Fagam and are important components of Kila-Warji, Ririwai and Dutsen-Wai ring-complexes. The albitized variety of these rocks hosts pyrochlore to varying extents depending on the degree of albitization and are, therefore, important targets for niobium investigation. Geochemical data of the granites reveal that niobium has a mean concentration of 111 ppm in the arfvedsonite granite, increasing to 168 ppm in the aegirine arfvedsonite granite and reaching 1568 ppm in the albite arfvedsonite granite. Niobium is thus enriched in the albite arfvedsonite granite by a factor of 8-11 relative to its mean value in the aegirine arfvedsonite and arfvedsonite granites, respectively. Uranium contents show a sympathetic trend with niobium, being also enriched in the albite arfvedsonite granite relative to its abundance in both the aegirine arfvedsonite granite and arfvedsonite granite by a factor of 15. The uranium abundance in the albite arfvedsonite granite is more than 48 times higher than the mean background values in low-calcium granite.The REE fractionation patterns in all three arfvedsonite granite varieties are characterized by enrichment of both the light (La-Sm) and heavy (Gd-Lu) rare earth elements and a significant negative Eu anomaly. The albite arfvedsonite granite is, however, preferentially more enriched in the heavy REE relative to the aegirine arfvedsonite and the arfvedsonite granites. A plot of the ∑REE against Na₂O and niobium reveals positive correlation in the arfvedsonite granites. There is also a linear relationship and strongly positive correlation between Nb and Na₂O because the pyrochlore is most abundant in the most extensively albitized variety of the arfvedsonite granites.     

Geochemistry of the Baishitouquan Amazonite—and Topaz—bearing Granite in the Mid—Tianshan Belt,Xinjiang,China

The Baishitouquan amazonite and topaz-bearing granite is one of the typical high-rubidium and high-fluorine granites in the eastern part of the Mid-Tianshan belt. This intrusion is in sharp contact with Mid-Proterozoic schists, gneisses and marbles, and is composed of four zones transitional from the bottom upwards: leucogranite, amazonite granite, topaz-bearing amazonite granite and topaz quartz albitite. The Baishitouquan granite contains highly ordered K-feldspar, Li-rich mica, Mn-rich garnet, α-quartz and low temperature zircon and is chemically high in Si, K, Na, Al, Li, Rb, Cs and F, and low in Ti, Fe, Ca, Mg, P, Co, Ni, Cr, V, Sr and Ba, with Na₂O<K₂O. Amazonite from the amazonite granite zone contains 1867 ppm Rb. The F contents of bulk rocks are 3040 and 4597 for the amazonite granite and topaz-bearing amazonite granite zones, respectively. These two zones have δ¹⁸O values of 8.97–9.85‰ (SMOW) and show flat REE distribution patterns with strong Eu depletion. K-Ar and Rb-Sr ages of this intrusion are 226. 6 Ma and 209. 6 Ma respectively, with an initial⁸⁷Sr/⁸⁶Sr ratio of 0.987±0.213. The Baishitouquan granite is the product of crystallization of a low temperature, and water, rubidium and fluorine-rich magma, which may have been derived from partial melting of muscovite-rich crustal rocks. Consolidation of this granite involved two contrasting and successive stages: melt crystallization and hydrothermal metasomatism and precipitation. Various geological features of this granite were formed during the transition from the magmatic to the hydrothermal stage.     

内蒙古沙麦钨矿花岗岩岩石地球化学、锆石U-Pb年代学及其地质意义

沙麦钨矿床位于内蒙古东乌旗地区,是该区目前已探明的中型岩浆热液型钨矿床。矿体主要赋存在黑云母二长花岗岩和黑云母二长花岗斑岩中,对这两种花岗质岩石的岩相学、岩石地球化学和LA-ICP-MS锆石U-Pb年代学进行了研究。结果表明,黑云母二长花岗岩锆石U-Pb年龄为135.6±1.6 Ma和136.3±1.8 Ma,黑云母二长花岗斑岩锆石U-Pb年龄为138.6±1.1 Ma,二者侵位时间均为早白垩世。两种花岗质岩体具有富SiO₂(73.73%～78.23%)、高钾钠(Na₂O+K₂O)(7.56%～8.89%)、贫MgO(0.09%～0.20%)、贫CaO(0.51%～0.89%)、贫TiO₂(0.03%～0.12%)的特征,属于过铝质-高钾钙碱性系列;微量元素富集Rb、K、Th和U,相对亏损Sr、Ba、Nb、P和Ti元素,具有强烈的Eu负异常,具有较高的FeO^T含量,较高的FeO^T/MgO和FeO^T/(FeO^T+M...     

Strongly peraluminous leucogranite (Ebrahim-Attar granite) as evidence for extensional tectonic regime in the Cretaceous,Sanandaj Sirjan zone,northwest Iran

The Ebrahim-Attar (EBAT) leucogranite body is intruded within the Jurassic metamorphic complex of the Ghorveh area, located in the northern part of the Sanandaj Sirjan zone (SaSZ) of northwest Iran. The granite comprises alkali feldspar, quartz, Na-rich plagioclase and to a lesser extent, muscovite and biotite. Garnet and beryl are also observed as accessory minerals. Additionally, high SiO₂ (71.4–81.0wt %) and Rb (145–440 ppm) content; low MgO (<0.12wt %), Fe₂O₃ (< 0.68 wt.%), Sr (mainly < 20 ppm), Ba (<57 ppm), Zr (10–53 ppm) and rare earth elements (REEs) low content (3.88–94.9 ppm with an average = 21.2 ppm); and flat REE patterns with a negative Eu anomaly characterize these rocks. The chemical composition and mineral paragenesis indicate that the rocks were formed by the partial melting of siliciclastic to pelitic rocks and can be classified as per-aluminous leucogranite or strongly per-aluminous (SP) granite. The Rb-Sr whole rock and mineral isochrons confirm that crystallization of the body occurred at 102.5 ± 6.1 Ma in Albian. The ⁸⁷Sr/⁸⁶Sr(i) and ¹⁴³Nd/¹⁴⁴Nd(i) ratios are 0.7081 ± 0.009 and 0.51220 ± 0.00005, respectively, and ε_Nd(t) values range from −5.8 to −1.6. These values verify that the source of this body is continental crust. The Nd model ages (T_DM2) vary between 1.0 and 1.3 Ga and are more consistent with the juvenile basement of Pan African crust. Based on these results, we suggest that the upwelling of the hot asthenospheric mantle in the SaSZ (likely during the Neo-Tethys rollback activity) occurred after the late Cimmerian orogeny. Consequently, we suggest that this process was responsible for a thinning and heating of the continental crust, from which the SP granite was produced by the partial melting of muscovite rich in pelitic or felsic-metapelitic rocks in the northern SaSZ.     

滇西梁河勐养花岗闪长岩LA-ICP-MS锆石U-Pb年龄、地球化学特征及其构造意义

勐养花岗闪长岩体位于滇西腾冲地块梁河县南勐养镇一带。用LA-ICP-MS技术测得花岗闪长岩锆石U-Pb年龄为115.2±1.0Ma,该年龄被解释为花岗闪长岩的形成年龄,表明该区花岗闪长岩体的形成时代为早白垩世。岩石地球化学特征表明,花岗闪长岩中SiO_2含量为62.39%~67.97%,Na_2O+K_2O为6.26%~7.80%,K_2O为1.98%~4.11%,具有贫钾(K_2O/Na_2O值为0.45~1.11)、低P2O5(0.09%~0.38%)的特征;MgO为1.78%~1.98%,Mg~#为34.90~48.40,属于准铝质-弱过铝质钙碱性系列。微量元素具有相对富集大离子亲石元素(U、Th、Rb、Ba)、亏损高场强元素(Tb、Nb、Zr、Hf)的特点。该花岗闪长岩具有I型花岗岩的特征,同时兼有S型花岗岩之特点,具有明显的岩浆混合作用特征。岩石具有岛弧或活动陆缘岩系的微量元素分布特征。地球化学特征和微量元素构造判别图解揭示,勐养早白垩世花岗闪长岩形成于碰撞后岩浆弧环境。花岗闪长岩为幔源岩浆与高黎贡山群古老地壳部分熔融的岩浆混合的产物。该区早白垩世花岗闪长岩是腾冲地块早白垩世侵入岩与班公湖-怒江-泸水-瑞丽洋盆的闭合、洋壳向南西俯冲及板块间的碰撞造山作用的产物。     

北秦岭超高压地体折返过程中的多期次部分熔融

本文对丹凤地区秦岭岩群含柯石英超高压变质地体长英质片麻岩中的混合岩化长英质浅色体和含石榴子石暗色包体的花岗质脉体进行了详细的矿物学、地球化学和锆石U-Pb年代学以及Lu-Hf同位素研究。其中,长英质浅色体显示了近原位熔融的高硅、富钾的过铝质花岗岩地球化学特征;锆石的CL图像呈灰黑色,均匀无结构或云雾状内部结构,Th/U比值0. 008,并含有钾长石、斜长石、石英和磷灰石等包裹体,显示深熔锆石的特征;花岗质脉体暗色包体中的石榴子石显示核-边成分环带,其中核部成分与秦岭岩群长英质片麻岩中石榴子石成分一致,边部Sps含量升高,显示熔体改造或退变质扩散特征,寄主花岗质脉体显示重稀土强烈亏损的与石榴子石平衡的熔体特征,指示它们是秦岭岩群含石榴子石长英质片麻岩部分熔融的产物。锆石LA-ICP-MS定年得到长英质浅色体和花岗质脉体的结晶年龄分别为445±4Ma和420±1Ma,明显晚于本区的超高压变质时代,而与折返过程中麻粒岩相和角闪岩相退变质叠加的时代基本一致。结合区域地质和前人的研究成果,提出秦岭岩群在深俯冲板块的折返过程中,分别在445Ma和420Ma发生了两期部分熔融作用。     

Petrogenesis of the Yangchang Mo‐bearing granite in the Xilamulun metallogenic belt,NE China: geochemistry,zircon U–Pb ages and Sr–Nd–Pb isotopes

The Yangchang granite‐hosted Mo deposit is typical of the Xilamulun metallogenic belt, which is one of the important Mo–Pb–Zn–Ag producers in China. A combination of major and trace element, Sr, Nd and Pb isotope, and zircon U–Pb age data are reported for the Yangchang batholith to constrain its petrogenesis and Mo mineralization. Zircon LA‐ICPMS U–Pb dating yields mean ages of 138 ± 2 and 132 ± 2 Ma for monzogranite and granite porphyry, respectively. The monzogranites and granite porphyries are calc‐alkaline with K₂O/Na₂O ratios of 0.75–0.92 and 1.75–4.42, respectively. They are all enriched in large‐ion lithophile elements (LILEs) and depleted in high‐field‐strength elements (HFSEs) with negative Nb and Ta anomalies in primitive‐mantle‐normalized trace element diagrams. The monzogranites have relatively high Sr (380–499 ppm) and Y (14–18 ppm) concentrations, and the granite porphyries have lower Sr (31–71 ppm) and Y (5–11 ppm) concentrations than those of monzogranites. The monzogranites and granite porphyries have relatively low initial Sr isotope ratios of 0.704573–0.705627 and 0.704281, respectively, and similar ²⁰⁶Pb/²⁰⁴Pb ratios of 18.75–18.98 and 18.48–18.71, respectively. In contrast, the ε_Nd(t) value (−3.7) of granite porphyry is lower than those of monzogranites (−1.5 to −2.7) with Nd model ages of about 1.0 Ga. These geochemical features suggest that the monzogranite and granite porphyries were derived from juvenile crustal rocks related to subduction of the Paleo‐Pacific plate under east China. Copyright © 2013 John Wiley & Sons, Ltd.     

川西松林口岩体锆石U-Pb定年及其地球化学特征

松林口岩体位于松潘—甘孜造山带中东部,为确定岩体的侵位时代和地球化学特征,通过镜下薄片观察、主微量元素分析以及锆石U-Pb测年,对松林口岩体进行了研究。结果表明,松林口岩体由二长花岗岩体和花岗闪长岩体组成,花岗闪长岩锆石²⁰⁶Pb/²³⁸U年龄加权平均值为（212.4±0.9） Ma （MSWD=0.66）,二长花岗岩锆石²⁰⁶Pb/²³⁸U年龄加权平均值为（222.4±1.1） Ma （MSWD=0.39）,形成于晚三叠世,由两期次岩浆作用形成;岩石的SiO₂含量56.56%~61.97%;铝饱和指数A/CNK=0.93~1.05,全碱含量3.78~5.38,K₂O/Na₂O=1.02~1.68,里特曼指数σ=1.194~1.612,样品属于准铝质中—高钾钙碱性岩系列。岩石轻重稀土比值LREE/HREE=5.22~7.13,La_N/Yb_N比值为6.93~8.96,轻、重稀土分异较明显,具较强的负Eu异常。岩石Mg^#值较高（50.97~61.27）,w（Rb）/w（Sr）为0.12~0.25,Rb-（Y+Nb）图解显示为后碰撞环境。因此,松林口二长花岗岩—花岗闪长岩属后碰撞准铝质中—高钾钙碱性I型花岗岩类。     

A HFSE- and REE-enriched ferrodiorite suite from the Bolangir Anorthosite Complex, Eastern Ghats Belt, India

The massif-type anorthosite complex at Bolangir in the northern part of the Eastern Ghats belt occurs in a milieu of predominantly supracrustal granulite-grade rocks. The massif is separated from the host gneisses by coarse-grained garnetiferous granitoid gneisses which are interpreted as coeval crustallyderived melts. Melanocratic ferrodiorite rocks occur at the immediate contact with the anorthosite massif which they intrude in cross-cutting dikes and sheets. The emplacement age of the anorthosite diapir and the associated igneous suites is deemed to be pre-D₂. Recrystallization of the igneous assemblages of the ferrodiorite suite (750–800°C, 7–8kbar, ) during a period of near-isobaric cooling from the igneous crystallization stage to the regionalP-T regime led to extensive development of coronitic garnet at the interface of plagioclase phenocrysts with the mafic matrix assemblage (opx + fay + cpx + ilm ± amph, bio). Abundant accessory phases are zircon, apatite and thorite. The mafic phases have extremely ferrous compositions (X_Fe gar: 0.93-0.87, fay: 0.90-0.87, opx: 0.80-0.60, cpx: 0.70-0.47, amph: 0.81-0.71) reflecting the low Mg-number (16-8) of the rocks. Compared to worldwide occurrences of similar rocks, the Bolangir ferrodiorites (SiO₂ 36–58 wt.%, FeO*: 39-10 wt.%) are characterized by exceptionally high concentrations of HFSE and REE (TiO₂: 4.8-1.0 wt.%, P₂O₅: 1.7-0.5 wt.%, Zr: 5900-1300 ppm, Y: 240-80 ppm, La: 540-100 ppm, Ce: 1100-200 ppm, Yb: 22-10 ppm, Th: 195-65 ppm). Well defined linear variation trends for major and trace elements reflect progressive plagioclase accumulation towards the felsic members of the suite. The ferrodiorites are interpreted to represent residual liquids of anorthosite crystallization which after segregation and extraction from the ascending diapir became enriched in HFSE and REE through selective assimilation of accessory phases (zircon, monazite, apatite) from crustal felsic melts. Ferromonzodioritic rock presumably formed through hybridization between the ferrodiorite and overlying felsic melts.     

Ore geochemistry,zircon mineralogy,and genesis of the Sakharjok Y-Zr deposit,Kola Peninsula,Russia

The Sakharjok Y-Zr deposit in Kola Peninsula is related to the fissure alkaline intrusion of the same name. The intrusion ∼7 km in extent and 4–5 km² in area of its exposed part is composed of Neoarchean (2.68–2.61 Ma) alkali and nepheline syenites, which cut through the Archean alkali granite and gneissic granodiorite. Mineralization is localized in the nepheline syenite body as linear zones 200–1350 m in extent and 3–30 m in thickness, which strike conformably to primary magmatic banding and trachytoid texture of nepheline syenite. The ore is similar to the host rocks in petrography and chemistry and only differs from them in enrichment in zircon, britholite-(Y), and pyrochlore. Judging from geochemical attributes (high HSFE and some incompatible element contents (1000–5000 ppm Zr, 200–600 ppm Nb, 100–500 ppm Y, 0.1–0.3 wt % REE, 400–900 ppm Rb), REE pattern, Th/U, Y/Nb, and Yb/Ta ratios), nepheline syenite was derived from an enriched mantle source similar to that of contemporary OIB and was formed as an evolved product of long-term fractional crystallization of primary alkali basaltic melt. The ore concentrations are caused by unique composition of nepheline syenite magma (high Zr, Y, REE, Nb contents), which underwent subsequent intrachamber fractionation. Mineralogical features of zircon-the main ore mineral—demonstrate its long multistage crystallization. The inner zones of prismatic crystals with high ZrO₂/HfO₂ ratio (90, on average) grew during early magmatic stage at a temperature of 900–850°C. The inner zones of dipyramidal crystals with average ZrO₂/HfO₂ = 63 formed during late magmatic stage at a temperature of ∼500°C. The zircon pertaining to the postmagmatic hydrothermal stage is distinguished by the lowest ZrO₂/HfO₂ ratio (29, on average), porous fabric, abundant inclusions, and crystallization temperature below 500°C. The progressive decrease in ZrO₂/HfO₂ ratio was caused by evolution of melt and postmagmatic solution. The metamorphic zircon rims relics of earlier crystals and occurs as individual rhythmically zoned grains with an averaged ZrO₂/HfO₂ ratio (45, on average) similar to that of the bulk ore composition. The metamorphic zircon is depleted in uranium in comparison with magmatic zircon, owing to selective removal of U by aqueous metamorphic solutions. Zircon from the Sakharjok deposit is characterized by low concentrations of detrimental impurities, in particular, contains only 10–90 ppm U and 10–80 ppm Th, and thus can be used in various fields of application.     

原地-半原地深熔花岗岩特征:以华北克拉通北缘包头地区石榴花岗岩为例

在华北克拉通北缘大青山地区,广泛的深熔作用导致新太古代晚期石榴花岗岩发育.石榴花岗岩空间上与新太古代晚期大青山表壳岩(主要为石榴黑云母片麻岩)共生,渐变过渡.宏观上岩性具有不均一性,在包头哈德门沟一条实测地质剖面上可以观察到石榴混合闪长岩、石榴混合石英闪长岩和石榴混合花岗闪长岩等不同岩石类型.岩相学研究表明,石榴花岗岩...     

Chemical composition,volatile components,and trace elements in the magmatic melt of the Kurama mining district,Middle Tien Shan: Evidence from the investigation of inclusions in quartz

Melt and fluid inclusions were investigated in six quartz phenocryst samples from the igneous rocks of the extrusive (ignimbrites and rhyolites) and subvolcanic (granite porphyries) facies of the Lashkerek Depression in the Kurama mining district, Middle Tien Shan. The method of inclusion homogenization was used, and glasses from more than 40 inclusions were analyzed on electron and ion microprobes. The chemical characteristics of these inclusions are typical of silicic magmatic melts. The average composition is the following (wt %): 72.4 SiO₂, 0.06 TiO₂, 13.3 Al₂O₃, 0.95 FeO, 0.03 MnO, 0.01 MgO, 0.46 CaO, 3.33 Na₂O, 5.16K₂O, 0.32 F, and 0.21 Cl. Potassium strongly prevails over sodium in all of the inclusions (K₂O/Na₂O averages 1.60). The average total of components in melt inclusions from five samples is 95.3 wt %, which indicates a possible average water content in the melt of no less than 3–4 wt %. Water contents of 2.0 wt % and 6.6 wt % were determined in melt inclusions from two samples using an ion microprobe. The analyses of ore elements in the melt inclusions revealed high contents of Sn (up to 970 ppm), Th (19–62 ppm, 47 ppm on average), and U (9–26 ppm, 18 ppm on average), but very low Eu contents (0.01 ppm). Melt inclusions of two different compositions were detected in quartz from a granite porphyry sample: silicate and chloride, the latter being more abundant. In addition to Na and K chlorides, the salt inclusions usually contain one or several anisotropic crystals and an opaque phase. The homogenization temperatures of the salt inclusions are rather high, from 680 to 820°C. In addition to silicate inclusions with homogenization temperatures of 820–850°C, a primary fluid inclusion of aqueous solution with a concentration of 3.7 wt % NaCl eq. and a very high density of 0.93 g/cm³ was found in quartz from the ignimbrite. High fluid pressure values of 6.5–8.3 kbar were calculated for the temperature of quartz formation. These estimates are comparable with values obtained by us previously for other regions of the world: 2.6–4.3 kbar for Italy, 3.7 kbar for Mongolia, 3.3–8.7 kbar for central Slovakia, and 3.3–9.6 kbar for eastern Slovakia. Unusual melt inclusions were investigated in quartz from another ignimbrite sample. In addition to a gas phase and transparent glass, they contain spherical Feoxide globules (81.2 wt % FeO) with high content of SiO₂ (9.9 wt %). The globules were dissolved in the silicate melt within a narrow temperature range of 1050–1100°C, and the complete homogenization of the inclusions was observed at temperatures of 1140°C or higher. The combined analysis of the results of the investigation of these inclusions allowed us to conclude that immiscible liquids were formed in the high-temperature silicic magma with the separation of iron oxide-dominated droplets.