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1.
Abstract. Peyssonnelia bed distribution on continental shelf bottoms of the Balearic Islands (Western Mediterranean) ranges from 40 to 90 m depth. Different species of Peyssonnelia dominate these bottoms and, according to multivariate techniques, two main assemblages have been distinguished: the Peyssonnelia rosa-marina beds and the Peyssonnelia sp. beds, together with some transition samples between Peyssonnelia and maërl beds. Erect red algae are always abundant. Although average yearly irradiance reaching these beds is only 6.4-0.3% of subsurface irradiance, the species richness averages 45 species per sample (1600 cm 2) and mean biomass is 2835 g dw. m -2. The high carbonate content of the living algae of these bottoms suggests that they are important contributors to the production of sediments in the Balearic continental shelf. 相似文献
2.
The influence of mesoscale physical and trophic variables on deep-sea megafauna, a scale of variation often neglected in deep-sea studies, is crucial for understanding their role in the ecosystem. Drivers of megafaunal assemblage composition and biomass distribution have been investigated in two contrasting areas of the Balearic basin in the NW Mediterranean: on the mainland slope (Catalonian coasts) and on the insular slope (North of Mallorca, Balearic Islands). An experimental bottom trawl survey was carried out during summer 2010, at stations in both sub-areas located between 450 and 2200 m water depth. Environmental data were collected simultaneously: near-bottom physical parameters, and the elemental and isotopic composition of sediments. Initially, data were analysed along the whole depth gradient, and then assemblages from the two areas were compared. Analysis of the trawls showed the existence of one group associated with the upper slope (US=450–690 m), another with the middle slope (MS=1000–1300 m) and a third with the lower slope (LS=1400–2200 m). Also, significant differences in the assemblage composition were found between mainland and insular slopes at MS. Dominance by different species was evident when the two areas were compared by SIMPER analysis. The greatest fish biomass was recorded in both areas at 1000–1300 m, a zone linked to minimum temperature and maximum O 2 concentration on the bottom. Near the mainland, fish assemblages were best explained (43% of total variance, DISTLM analysis) by prey availability (gelatinous zooplankton biomass). On the insular slope, trophic webs seemed less complex and were based on vertical input of surface primary production. Decapods, which reached their highest biomass values on the upper slope, were correlated with salinity and temperature in both the areas. However, while hydrographic conditions (temperature and salinity) seemed to be the most important variables over the insular slope, resource availability (gelatinous zooplankton and Calocaris macandreae) predominated and explained 59% of decapod assemblage variation over the mainland slope. Both fish and decapods were linked to net primary production recorded over the mainland 3 months before sampling, while the delay between the input of food from the surface and fish abundance was only 1 month on the insular slope. Our results suggest that trophic relationships over insular slopes probably involve a shorter food chain than over mainland slopes and one that is likely more efficient in terms of energy transfer. 相似文献
3.
Three small turbidite systems (Almeria, Sacratif, and Guadiaro), each tens of kilometres long, are developed in the complex morpho-structural setting of the northern Alboran Sea and have similar primary architectural elements (canyons, channel-levee systems, lobes). However, comparison reveals differences in the axial gradients of their canyons, depth/physiographic location, morphological framework, and lateral and longitudinal sedimentary shifts of turbidite deposition. The depositional architecture and sedimentary evolution from late Pliocene to Quaternary seems to be conditioned by number of submarine feeding sources (canyons), sea-level fluctuations and local tectonic (e.g. margin/canyon-channel gradients, faults). We group the Alboran turbidite systems into two models: mud/sand-rich submarine point-source and mud/sand-rich multiple submarine source ramp. 相似文献
4.
Abstract. The sponge fauna of three neighbouring submarine caves of the Island of Majorca (Balcaric Islands) is studied along a light gradient; 45 species have been recorded and systematic data are given for those showing morphological, pigmentary, or spicule differences. Adaptation to darkness and precarious trophic conditions is also discussed. 相似文献
6.
Abundance of picoplanktonic chroococcoid marine cyanobacteria Synechococcus was monitored weekly over the year 1998 in shallow coastal waters of the northern Levantine Basin. The ambient physical, chemical and biological variables (temperature, salinity, Secchi disk depth, total suspended sediment, nitrate, phosphate, Chl a and phytoplankton) were also measured. Synechococcus was found to be more abundant during summer and early autumn and less during winter and early spring. At the surface and 15 m depth, cell concentrations were in the range 6.4 × 10 3–1.5 × 10 5 and 3.2 × 10 3–1.6 × 10 5 cells·ml −1, respectively. Based on the Pearson product–moment correlation analysis, a highly significant correlation between Synechococcus abundance and ambient temperature was observed (n = 40, r = 0.558, P < 0.01). As Synechococcus forms blooms that usually do not last more than a week, the short time‐scale survey achieved in this study was appropriate to reveal its abundance dynamics. Several factors such as rapid changes in nutrient concentration (especially nitrate), phytoplankton, light availability, temperature, salinity, freshwater input and vertical mixing played a relevant role on the abundance of Synechococcus over the year in the highly dynamic shallow coastal waters of the Levantine Basin. 相似文献
7.
With the aim of improving the knowledge of the open ocean carbon cycle, we present a budget of particulate organic carbon (POC) fluxes carried out in the deep central part of the Algero-Balearic Basin (ABB) at 2850 m water depth based on a single mooring equipped with five automated sediment traps deployed from April 2001 to May 2002 at depths of 250, 845, 1440, 2145 and 2820 m. Suspended particulate matter (SPM) and superficial sediments were also used as indicators of hydrodynamics and carbon burial, respectively. The data reveal that the fraction of primary production buried in the sediment, which finally leads to the sequestration of carbon dioxide from the atmosphere, is 0.16%, lower than the values found in the nearby continental margin regions such as the Alboran Sea (0.48–0.89%) but of the same order as recorded at other Mediterranean sites at similar depths, such as the Ionian Sea (0.11%). As they sink through the water column, the particles exhibit decreases in flux that are similar to those observed elsewhere, but also show variations that appear to correlate with hydrological features of the water masses present in the basin, as revealed by SPM concentrations and compositions. The input of the tyrrhenian deep water (TDW) into the ABB at 800–1500 m of water depth exhibits low suspended POC concentrations and low sinking POC fluxes were also observed in this depth range. Gulf of Lions water mass formation appears to also contribute to elevated suspended POC concentrations and perhaps POC accumulation in the traps and sediments by spreading of dense cold water along the whole ABB that supplied POC at depths higher than 2000 m. 相似文献
8.
The role of internal and external forcing of sedimentation in turbidite systems remains a subject of debate. Here we propose new insights from the quantitative analysis of architectural parameters of the Congo Axial Fan.Fifty-two channel-levee-lobe systems, spanning the last ca. 200 ka, are visible on the seafloor, most of them having slightly elongated lobe complexes at their termination. Volumes of lobe complexes (usually 3–196 km 3) are highly variable in time and space. The cumulative volume of the lobe complexes represents approximately 30% of the volume of the Axial Fan.The Axial Fan is sequentially divided into periods of increasing/decreasing channel lengths and basinward/landward migrations of avulsion points, representing successive prograding/retrograding architectural patterns called architectural cycles. These cycles are either symmetrical saw toothed and bell-shaped with progressive progradation and retrogradation phases, or asymmetrical, with long-lasting progradation phases and abrupt retrogradation phases that correspond to channel avulsions occurring high up on the fan.Our study points to the interplay between internal and external factors controlling the architecture of the Congo Axial Fan. The local topographic constraint is a major factor in the fan's stacking pattern. However, cyclic evolution of the architecture reveals major shifts in the deposition site that are linked to very upfan avulsion events. These events are interpreted to be driven by external factors (e.g. climate and/or eustatic sea-level change) that were able to drastically increase and/or coarsen the sediment supply to the fan. 相似文献
9.
Recently, as oil exploitation has become focused on deepwater slope areas, more multi-channel high resolution 2D and 3D seismic data were acquired in the deepwater part of the Qiongdongnan Basin, northern South China Sea. Based on 3D seismic data and coherence time slice, RMS and 3D visualization, a series of deepwater channels were recognized on the slope that probably developed in the late Quaternary period. These channels trend SW–NE to W–E and show bifurcations, levees, meander loops and avulsions. High Amplitude Reflections (HARs), typical for channel–levee complexes, are of only minor importance and were observed in one of the channel systems. Most of the detected channels are characterized by low-amplitude reflections, and so are different from the typical coarse-grained turbidite channels that had been discovered worldwide. The absence of well data in the study area made it difficult to determine the age and lithology of these channels. Using a neighboring drill hole and published data about such depositional systems worldwide, the lithology of these channels is likely to be dominated by mudstones with interbedded thin sandstones. These channels are formed by turbidity currents originated from the little scale mountain river of mid-Vietnam in SW direction and were probably accompanied by a relative sea level drop in the last glacial age. These channels discovered on the northern South China Sea slope are likely to be fine-grained, mud-dominant and low N:G deposits in a deepwater paleogeographic setting. 相似文献
10.
The composition of suprabenthic crustacean assemblages, their diversity, production (P) and production/biomass (P/B) ratios, were analyzed at species level along two transects situated to the north (N) and south (S) of Mallorca (Balearic Islands, western Mediterranean) at depths between 134 m and 760 m, based on a ca. bi-monthly sampling performed between August 2003 and June 2004. Differences with depth and season in assemblage composition and diversity were analyzed as a function of the contrasting environmental features (e.g. water mass dynamics) of the two areas. We identified 187 species (18 decapods, 5 euphausiids, 16 mysids, 76 gammaridean amphipods, 13 hyperiids, 1 caprellid, 21 isopods and 37 cumaceans). Substantial mesoscale variability in the deep-sea suprabenthic assemblages coupled with diversity trends between the N and S transects were found. Seasonality was the most important gradient influencing the dynamics of suprabenthos over the upper (350 m) and middle (650–750 m) slope in the N area. Conversely, the S area appeared to be more stable temporally with depth as the main gradient inducing assemblage differences. Different depth-related patterns were observed both for diversity and P/B. To the north diversity was very low at the shelf-break, increasing on the upper-slope ( H′ > 3.00) and then decreasing again on the middle-slope. To the south diversity increased smoothly downward, reaching the highest values on the middle-slope. Regarding productivity, P/B was highest at intermediate depths to the north (over ca. 450–500 m), while to the south highest P/Bs were found deeper (over ca. 600–650 m). The higher P/B at intermediate depths found along N are likely due to higher % of organic matter (OM) in sediments, a product of oceanographic frontal systems. In particular, P/B was higher along N among omnivores and detritus feeders (e.g. Andaniexis mimonectes, Lepechinella manco and combined cumaceans), coupled to enriched OM in sediments, while along S mesoplanktonic carnivores ( Rhachotropis spp.) had higher P/Bs. We conclude that on the north slope the influence of frontal systems and more active flow dynamics of different water masses (WIW and LIW) increases natural disturbance in the area, increasing productivity and diversity of suprabenthic peracarids in the Benthic Boundary Layer. Also, species showed a displacement of their average distributions (their Centres of Gravity, CoG) to shallower depths along N, which is another indicator of more favorable habitat conditions for suprabenthos in the 400–500 m range at N. 相似文献
11.
The objective of this study is to propose a simple methodological approach, based on the Limits of Acceptable Change process, to support the formulation of management measures for recreational boating in bays. Management measures have been determined using statistical and geospatial analyses of data of biophysical characteristics, use, and user perceptions in a bay on the island of Mallorca. The results suggest that the optimal use level of the study site is being surpassed and a range of potential management options is provided. This methodology is applicable to additional management scenarios where balancing social and environmental needs is necessary and should be implemented as part of a broader Integrated Coastal Zone Management framework. 相似文献
12.
Palaeo-bottom current strength of the West Spitsbergen Current (WSC) and the influence of the Svalbard-Barents Sea Ice Sheet (SBIS) on the depositional environment along the northern Svalbard margins are poorly known. Two gravity cores from the southern Yermak Plateau and the upper slope north of Nordaustlandet, covering marine isotope stage (MIS) 1 to MIS 5, are investigated. Five lithofacies, based on grain size distribution, silt/clay ratio, content and mean of sortable silt (SS), are distinguished to characterise the contourite-dominated sedimentary environments. In addition, depositional environments are described using total organic carbon (TOC), total sulphur (TS) and calcium carbonate (CaCO 3) contents of sediments. Facies A, containing coarse SS, suggests strong bottom current activity and good bottom water ventilation conditions as inferred from low TOC content. This facies was deposited during the glacial periods MIS 4, MIS 2 and during the late Holocene. Facies B is dominated by fine SS indicating weak bottom current and poor ventilation (cf. high TOC content of 1.2–1.6%), and correlates with the MIS 4/3 and MIS 2/1 transition periods. With an equal amount of clay and sand, fine SS and high content of TOC, facies C indicates reduced bottom current strength for intervals with sediment supply from proximal sources such as icebergs, sea ice or meltwater discharge. This facies was deposited during the last glacial maximum. Facies D represents mass-flow deposits on the northern Svalbard margin attributed to the SBIS advance at or near the shelf edge. Facies E sediments indicating moderate bottom current strength were deposited during MIS 5 and MIS 3, and during parts of MIS 2. This first late Quaternary proxy record of the WSC flow and sedimentation history from the northern Svalbard margin suggests that the oceanographic conditions and ice sheet processes have exerted first-order control on sediment properties. 相似文献
13.
Bathymetric, 9.5-kHz long-range sidescan sonar (OKEAN), seismic reflection and sediment-core data are used in the analysis
of two tectonic troughs south of Crete, Eastern Mediterranean Sea. Here, up to 1.2 s two-way travel time (TWTT) of strata
have accumulated since the Middle Miocene in association with extension in the South Aegean region. The study area comprises
>100-km- long by >25-km-wide basins filled by sediments subdivided into two seismic units: (1) an upper Unit 1 deposited in
sub-basins which follow the present-day configuration of the southern Cretan margin; (2) a basal Unit 2, more than 500 ms
(TWTT) thick, accumulated in deeper half-graben/grabens distinct from the present-day depocentres. Both units overlap a locally
stratified Unit 3 comprising the pre-Neogene core complex of Crete and Gavdos. In this work, the interpreted seismic units
are correlated with the onshore stratigraphy, demonstrating that denudation processes occurring on Crete and Gavdos in response
to major tectonic events have been responsible for high sedimentation rates along the proximal southern Cretan margin. Consequently,
topographically confined sedimentary units have been deposited south of Crete in the last 12 Ma, including turbidites and
other mass-flow deposits fed by evolving transverse and axial channel systems. Surface processes controlling facies distribution
include the direct inflow of sediment from alluvial-fan systems and incising mountain rivers onto the Cretan slope, where
significant sediment instability processes occur at present. In this setting, seismic profiles reveal eight different types
of stratigraphic contacts on basin-margin highs, and basinal areas show evidence of halokinesis and/or fluid escape. The acquired
data also show that significant changes to the margin’s configuration occurred in association with the post-Alpine tectonic
and eustatic episodes affecting the Eastern Mediterranean. 相似文献
14.
The island of Menorca, one of the Balearic Islands (Spain) located in the western Mediterranean, is characterised by a contrasting geology and landscape with two major geographic domains: (1) a southern region called Migjorn, comprised of Late Miocene calcarenites and limestones, and (2) a northern region known as Tramuntana, which is composed of folded and faulted Palaeozoic, Mesozoic and Tertiary (Oligocene) siliceous and calcareous rocks. Both domains are lined by numerous pocket beaches exhibiting a high variety of surficial sediment assemblages. Grain-size and compositional analyses revealed that cliff erosion and nearshore Posidonia oceanica meadows are the main sources of sediments consisting mostly of medium- to coarse-grained carbonate sands of marine biogenic origin, with variable amounts of terrigenous rock fragments and quartz. Based on distinctly different contributions of bioclastic material, biogenic carbonates and quartz, 320 sediment samples from 64 beaches were grouped into different facies associations dominated by either (1) biogenic sands, (2) biogenic sands with terrigenous contributions or (3) terrigenous sands with quartz. Nevertheless, there is a marked regional variability in sediment texture and composition. Thus, variable mixtures of carbonate and siliciclastic sediments characterise the beaches of the northern region, whereas the beaches of the southern region are composed mostly of carbonate sands of marine biogenic origin. An exception is the central sector of the south coast, which is enriched in quartz sand (~10 %); this can be related to outcrops of quartz-rich basement rock and also to rocks exposed in some northern drainage basins captured by southern streams since the Plio-Quaternary. 相似文献
15.
Based on analysis of well and drilling data, cores, sediment grains and 3D seismic data, four types of turbidites–slope fan, channelized, laminated and sublacustrine fan turbidite–are identified in Members 1 and 2 of the Qingshankou Formation in northern Songliao Basin. The slope fan turbidite is located in Members 1 and 2 of the Qingshankou Formation. It is dominated by silt and fine sand and is distributed in an SN-trending ribbon zone along the slope break at delta front in the western part of the basin. The channelized turbidite is located at the bottom of Member 1 of the Qingshankou Formation. It is dominated by silt and fine sand and is distributed in an SN-trending strip-shaped zone along the Qijia-Gulong sag, with funnel-shaped sublacustrine fans at the end. The laminated turbidite body is located in Member 2 of the Qingshankou Formation. It is dominated by siltstone and argillaceous siltstone and is distributed continuously in a tongue-shaped zone along the northern delta front towards the lacustrine region, with belt-like distributaries at the central part and sublacustrine fans at the end. Low-permeability and low-yield lithologic reservoirs are formed near the delta front within the slope fan turbidite and channelized turbidite. There are “sweet spots” in local regions, where reservoir reform techniques are required to attain high industrial yields. Laminated turbidite and sublacustrine fans can form unconventional and continuous reservoirs that generally have no natural productivity; industrial production is impossible until horizontal drilling and multistage volume fracturing are employed. Therefore, the research results are important to the exploration of unconventional oil and gas reservoirs in northern Songliao Basin. 相似文献
16.
Particulate biogenic barium (bio-Ba) fluxes obtained from three instrumented arrays moored in the Alboran Sea, the westernmost basin in the Mediterranean Sea, are presented in this study. The mooring lines were deployed over almost 1 year, from July 1997 to May 1998, and were equipped with sediment traps at 500–700 m depth, 1000–1200 m depth and 30 m above the seafloor (1000–2200 m). The results obtained support the growing body of evidence that the relationship between particulate bio-Ba and Corg throughout the water column in margin systems is clearly different from this relation in the open ocean. In the Alboran Sea, the annual averaged bio-Ba fluxes range from 0.39 to 1.07 μmol m −2 day −1, with mean concentrations of 1.31–1.69 μmol g −1 and bio-Ba/Corg ratios lower than in the open ocean. The low bio-Ba values obtained also indicate that calculating bio-Ba is extremely sensitive to the detrital Ba/Al ratio of each sample. The lithogenic Ba fraction in the Alboran Sea continental margin area contributes between 24% and 85% of the total Ba. Increased bio-Ba export efficiency was observed after periods of high primary productivity and suggests that the processes limiting the bio-Ba formation in the study area relate to settling dynamics of organic matter aggregates. Furthermore, the ballasting effect of the abundant lithogenic and carbonate particles may limit decomposition of organic matter aggregates and enhance the transfer of particles rich in Corg and relatively poor in bio-Ba to the deep seafloor. Lateral input of freshly sedimented biogenic material, including particulate bio-Ba, has been observed on the lower continental slope in the western Alboran Sea. These observations emphasize that the use of the bio-Ba as a proxy of export productivity from the surface ocean must be used cautiously in highly dynamic environments such as those in the Alboran Sea. 相似文献
17.
The Barcelona continental shelf is part of a 6–20 km wide canyon-bounded shelf located off the city of Barcelona (NE Spain). This study integrates newly acquired high-resolution single channel seismic reflection profiles and available lithological information of the Barcelona shelf to describe its late Quaternary architecture and the role of global glacio-eustatic fluctuations and local factors in its development. Four major sequence boundaries are identified throughout the seismic dataset. They are tentatively correlated with the four last 4th order (100–120 ka) high-amplitude late Quaternary glacio-eustatic lowstands. Most of the stratigraphic record is formed by falling stage systems tracts with forced-regressive deposits, which confers a general progradational vertical stacking pattern. Transgressive systems tracts are represented by continuous units confined directly off river sources and on previously eroded surfaces. Stillstand deposits are difficult to recognize in the available dataset. The uppermost seismic unit corresponds to the Holocene shore-parallel Besos and Llobregat joint prodelta affected by the prevailing south-westward circulation. The general architecture of the late Quaternary Barcelona shelf deposits is determined by global glacio-eustatic cycles. However, the lateral variability of the seismic units depends largely on local factors such as (i) the position of sediment sources (essentially the Llobregat River); (ii) differential subsidence and, especially, sediment compaction; (iii) erosive processes such as canyon incision, mass wasting or wave base dynamics; and (iv) underlying geomorphic restrictions. 相似文献
18.
The stratigraphy of Quaternary marine sediments in Corsica is summarised: Holocene (Versilian) deposits occur at 2–5m and last interglacial sediments (Tyrrhenian Stage) from 2 to 10–15m altitude. Locally, two older deposits, up to 30–40m above present sea-level, indicate the first transgressive phase of the last interglacial stage, and the penultimate interglacial stage.Sections are described where Quaternary hydrodynamic conditions were different from present ones in the same locality. At some sites which are high energy at present, sand deposits and sandstones provide evidence of low or medium energy conditions during the last interglacial and the penultimate interglacial stages. These variations correlate with sea-level changes, particularly at Cala d'Ancone, where sedimentation occurred during the transgressive phase of the interglacial stage, and where cementation terminated during the subsequent regressive phase.The occurrence of pebbles in localities where low energy conditions prevail at present, probably represent fluvial material reworked by wave action, during the last as well as the penultimate interglacial stages.Local variations in hydrodynamic intensity correlate with sea-level changes along the western Corsican shore, although general energy conditions remained constant throughout the interglacial stages. 相似文献
19.
Spatio-temporal variation of feeding intensity and diet in the red shrimp Aristeus antennatus was studied at two locations around the island of Mallorca (Balearic Islands, Western Mediterraean) in August, September, and November 2003, and in February, April and June 2004 at depths between 550 and 750 m. The two areas, with different oceanographic conditions, were respectively located in the northwest (Sóller) and the south (Cabrera) of Mallorca. Off Sóller, feeding intensity of A. antennatus showed a significant increase from February to April and June 2004 in all the three size-classes studied (small shrimps: CL < 30 mm; medium: CL between 30 and 40 mm; large: CL ? 40 mm). Off Cabrera, the highest fullness was recorded in November 2003 among small and medium shrimp, while only large specimens showed patterns similar to that found off Sóller. Off Sóller, the diet of both small (CL < 34 mm) and large (CL ? 34 mm) A. antennatus was mainly influenced by season, with three dietary groups corresponding to August-September 2003, to November 2003/February 2004, and to hauls from April to June 2004. Off Cabrera, hauls (representing diets) were grouped by depth, never by season. The most remarkable seasonal shift in the diet of A. antennatus off Sóller was the increase of mesopelagic prey in April-June relative to other months. In all size categories there was an increase off Sóller in the energy intake of prey ingested from February to June 2004, an increase not found off Cabrera. Degree of digestion of mesopelagic prey indicated nocturnal feeding on mesopelagic fauna. These prey probably have a shallower depth distribution at night than found in our daylight sampling, and possible migratory movements among prey and A. antennatus at night would explain the lack of correlation between prey abundance in guts and in the environment found during daylight periods for most micronekton mesopelagic prey (euphausiids, myctophids and sergestids). Off Sóller, fullness and diet were significantly linked to temporal changes in water column productivity (e.g., Chl a readings, fluorescence) and to changes in the shrimp biology (lipid content of hepatopancreas, Gonado-somatic Index, GSI). Off Cabrera, we found a higher dependence of fullness and diet with T and S, both variables in turn related to depth. The increase of stomach fullness and dietary energy intake in pre-reproductive females from February to April-June 2004 found off Sóller, coupled with the consumption of mesopelagic prey, was parallel to a significant increase of the gonad weight (GSI, fecundity) in June. Most individuals attain gonad development in the period May-June, after two months of the peak of primary production at the surface. The strong link found between pelagic resources and reproductive processes in a deep-sea species such as the shrimp Aristeus antennatus, situated near the top of the trophic web, suggests a rapid energy flow via mesopelagic fauna between surface primary production and bathyal megabenthic communities at oligotrophic insular areas. In contrast to mainland areas off the Catalan coasts submitted to the influence of submarine canyons, around the island of Mallorca the empoverishment of benthos biomass may enhance consumption of micronektonic prey and a possible accumulation of pre-reproductive females of A. antennatus in areas (e.g., steep slopes and persistent frontal systems found off Sóller) with high zooplankton aggregations. 相似文献
20.
Humic compounds were determined in sediments collected in an area of the Adriatic sea receiving fresh waters from the river Po. Sediment cores (10 cm) were sectioned into four layers which were analysed separately for redox potential (Eh), total phosphorus (TP), total organic carbon (TOC), humic (HA) and fulvic acid (FA) content. The structure of HA and FA was also investigated. The results showed that the TOC and TP content decreased from the coast to the open-sea stations. Humic and fulvic acid concentrations were also inversely correlated to the distance from the coast. Moreover, the humic and fulvic acids were closely correlated to the total organic content and to the total phosphorus content. The correlations found between humic substances (HS) and TOC and TP, respectively, could be explained both by an in situ formation due to the high content of nutrients and organic matter, and by a common source of HS, TOC and TP, namely the River Po discharge. The predominant presence of aliphatic carbon in the humic structures, the low degree of substitution and the high nitrogen content suggest that primarily humified compounds were formed in situ. Nevertheless, the River Po can act both as supplier of organic matter of which decomposition products lead to the formation of humic compound and as carrier of humified compounds. 相似文献
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