Geochemistry and pollution of shallow aquifers in the Mafraq area, North Jordan

 Chemical data are used to clarify the hydrogeological regime in the Mafraq area in northern Jordan, as well as to determine the status of water quality in the area. Groundwater from the shallow aquifer in the Mafraq area can be divided into two major groups according to geographical locations and chemical compositions. Water in the basaltic eastern part of the study area is characterized by the dominance of chloride, sulfate, sodium, and potassium, whereas waters in the limestone aquifers in the west are dominated by the same cations but have higher concentrations of bicarbonate. Stable isotopes show that the shallow aquifers contain a single water type which originated in a distinct climatic regime. This water type deviates from the Global Meteoric Water Line (MWL), as well as from the eastern Mediterranean meteoric water line. The waters are poor in tritium, and thus can be considered generally older than 50 years. Chemical mass balance models suggest that water is moving from the west towards the north of the study area. This suggests that waters from the different basins are separated from each other. Degradation of water quality can be attributed to agricultural fertilizers in most cases, although the waste-water treatment plant at Khirbet es Samra is a contributor to pollution in the southwestern part of the study area. Received: 20 August 1997 · Accepted: 3 February 1998     

Impact of agricultural activity and lithology on groundwater quality in the Merdja area, Tebessa, Algeria

This work presents results of the hydrogeological and hydrochemical studies on groundwater samples from the alluvial aquifer of Merdja in Tébessa, located in the Western part of this town. Its groundwater resources are used mainly for crop irrigation in an agriculture dominated area. Hydrochemical and water quality data obtained through a sampling period (December 2008) and analysis program indicate that nitrate pollution can be a serious problem affecting groundwater due to the use of nitrogen (N) fertilizers in agriculture. The concentration of nitrate in groundwater ranged from 19 to 281 mg/l. Considerable seasonal fluctuations in groundwater quality were observed as a consequence of agricultural practices and other factors such as annual rainfall distribution and the wadi El Kebir flow regime. The chemical composition of the water is not only influenced by agricultural practices, but also by interaction with the alluvial sediments. The dissolution of evaporites accounts for part of the Na⁺, K⁺, Cl^?, SO ₄ ^2? , Mg²⁺, and Ca²⁺, but other processes, such as calcite precipitation and dedolomitization, also contribute to groundwater chemistry.     

Hydrogeological studies for the Nubia sandstone aquifers in Garf Hussein area,Western Desert,Egypt

The lithology of the studied aquifers has an important effect on their hydrogeologic setting. Moreover, the structural patterns have their imprint on the geologic setting and consequently the hydrogeologic conditions of the area. Lake Nasser recharges the groundwater in the study area by large amount of water increasing the groundwater level. A comparison of the depth to water in the same wells at two different periods (1998 and 2014 ) shows that the depth to water increases with average rise 11.1 m during 16 years. The constructed water table map shows that the groundwater flow is mainly towards the northwest direction reflecting recharge from Lake Nasser. The hydraulic parameters of the Abu Aggag and Sabaya sandstone aquifers are determined in the present work from pumping tests. The transmissivity of the studied aquifers reflects the moderate to high potentiality. The groundwater salinity of the studied aquifers is fresh water and varies from 353 to 983 ppm (part per million) and suitable for all purposes. It increases due to the west direction coinciding with groundwater flow direction. The main result of the present study shows that the seepage water from Lake Nasser attains 17 mcm/year.     

Hydrogeochemistry of groundwaters in a semi-arid region. El Ma El Abiod aquifer, Eastern Algeria

In this work, we present results of the hydrogeochemical and isotopic studies on groundwater samples from the El Ma El Abiod Sandstone aquifer, in Tébessa, Algeria. Chemical and environmental isotope data are presented and discussed in order to identify the geochemical processes and their relation with groundwater quality as well as to get an insight into the hydrochemical evaluation, in space and time, of groundwater and of the origin of dissolved species. A combined hydrogeologic and isotopic investigation have been carried out using chemical and isotopic data to deduce a hydrochemical evaluation of the aquifer system based on the ionic constituents, water types, hydrochemical facies, and factors controlling groundwater quality. All of the investigated groundwaters are categorized into two chemical types: low mineralized water type and relatively high mineralized water type. Interpretation of chemical data, based on thermodynamic calculations and geochemical reaction models of selected water groups constructed using PHREEQC, suggest that the chemical evolution of groundwater is primarily controlled by water–rock interactions, involving (1) acidic weathering of aluminosilicates, (2) dissolution of secondary carbonate minerals, and (3) cation exchange of Na⁺ for Ca²⁺. However, the original composition of groundwater may have been modified by further secondary processes such as mixing of chemically different water masses. The combined use of SI and mass-balance modeling has shown to be a useful approach in interpreting groundwater hydrochemistry in an area where large uncertainties exist in the understanding of the groundwater flow system. Interpretation of ¹⁸O and ²H, suggest that the recharge of the investigated groundwaters may result from different mechanisms.     

Hydrogeochemistry and pollution assessment of quaternary–tertiary aquifer in the Liwa area,United Arab Emirates

This study presents the data on the hydrochemical characteristics and isotope chemistry of Liwa aquifer, which could be useful to clarify the hydrochemical facies and hydrogeological regime in the study area. Electric conductivity and total dissolved solid values show that the investigated water is slightly brackish, due to the effect of evaporation and the occurrences of evaporite rocks in the adjacent Sabkhas of Abu Dhabi. Major cations and anions arranged according to their decreasing concentrations are: Na⁺ > Ca⁺² > K⁺ > Mg⁺² and Cl⁻ > HCO₃ ⁻ > SO₄⁻², respectively. As sodium is the dominate cation and chloride is the prevailing anion, hydrochemically the groundwater of Liwa can be classified as Na–Cl rich, predominantly chloridic. Ion concentrations increase towards the northeast and presumably coincide with the lithological sources of ions. Factors affecting the hydrochemistry of the groundwater of the investigated area include the effect of weathering of soil and rocks, evaporation and agricultural activities. Stable isotopes of oxygen and hydrogen show that the shallow aquifers contain a single water type that originated in a distinct climatic regime. This water type deviates from the local meteoric water line, as well as from the Eastern Mediterranean Meteoric Water Line, suggesting potential evaporation of recharged water prior to infiltration. The waters are poor in tritium, and thus can be considered generally as indication for recharge prior to 1952. The degradation of groundwater quality can be attributed to evaporation and agricultural practices in most cases.     

黑河流域中游盆地地下水动态特征及其调蓄能力分析

40 多年来,我国西北地区大规模的地下水开发利用造成了部分地区地下水水位持续下降甚至泉水干涸,部分地区地下水仍能维持动态稳定,判断这类地区水资源开发利用是否具有可持续性是必须解决的重大科学问题。以黑河流域中游盆地作为研究对象,采用MK检验和连续小波分析等方法,分析长时间序列地下水水位数据的变化特点,研究区域地下水动态特征;结合区域水文地质条件,综合划分黑河流域中游盆地地下水补排平衡区与非平衡区;利用克里金插值法估算1990—2020 年盆地含水层对水资源的调节水量,并评价不同动态平衡区的调蓄能力。结果显示,黑河流域中游盆地地下水水位动态类型有:水文型、水文-开采型、开采型和蒸发-开采型4种长周期动态稳定型,过量开采型或上游过度引用地表水型2 种长周期持续下降型。黑河-梨园河倾斜平原、酒泉盆地和黑河中游下段侵蚀堆积平原的大厚度含水层是黑河流域中游盆地的地下水补排平衡区,其在1990—2001 年共输出地下水12.06×108 m3,2001—2020年共储存地下水9.06×108 m3。大厚度含水层为地下水的长周期调蓄提供了充足的空间,在合理控制开采量的前提下,该类含水层的天然调蓄能力可满足生产生活和下游生态用水需要。盆地地下水补排非平衡区,如黑河以东诸河倾斜平原、盐池盆地和榆木山山前诸小河流域等地区,目前的地下水开发利用方式和强度是不可持续的,应适当减少地下水开采量,调节盆地上游的引水量和开采量,抑制地下水资源枯竭。本研究成果可为西北干旱内陆地区水资源管理和持续开发利用提供参考。     

霍州矿区李雅庄煤矿突水机理分析与水害防治

李雅庄煤矿是霍州矿区北端的一个井田,目前主要开采2#煤层。基于矿井水文地质条件及开采以来的突水资料分析,认为矿井主要水害为上马家沟组、峰峰组与太原组岩溶裂隙承压含水层,其突水方式是承压水通过导水断层或陷落柱涌人工作面;矿井以F2断层为界,分为东西两部分,西部水位较高,为补给区;东部水位较低,其内的马家沟组、峰峰组与太原组灰岩水基本属于相对独立单元,但三者间存在局部有限导水的特征。据此提出了矿井今后的防治水工作应以查明导水通道（断层、陷落柱）,并对其进行注浆加固与封堵为主。     

淮北某矿区地下水环境质量评价

在分析淮北某矿区水文地质条件的基础上,选取S₄O2-、Cl-、矿化度、总硬度4个污染因子作为评价因子,以GB/T14848-93《地下水质量标准》为评价标准,分别运用尼梅罗指数法和模糊数学法,对该矿区各主要含水层进行了地下水环境质量评价。评价结果表明,该矿区第一含水层(组)水质较好,适合作为矿区工业用水以及生活饮用水的供水水源,而第二含水层(组)及其以下含水层地下水均需要作适当的处理才可作为饮用水源。      

河南荥巩矿区岩溶水发育规律研究

通过对矿区地层、构造以及水文地质条件的分析,认为寒武-奥陶系岩溶裂隙含水层是矿区的主要含水层。岩溶水受地层岩性、构造的作用明显,岩溶发育程度在矿区呈现出西弱东强,浅部强、深部弱的发育规律。岩溶水动态受大气降水和矿井排水的双重控制,大气降水是岩溶水的主要补给来源,矿井排水是主要排泄方式,水位动态属于降水-矿排型。在天然状态下,岩溶水主要接受南部露头区大气降水的补给,然后自南向北、自西向东径流,经过新中-三李一带的岩溶水强径流带,在三李一带以岩溶大泉的方式向外排泄。     

Characteristic of groundwater potentialities in West Nile Valley South,Minia Governorate,Egypt

The main aim of the present study is to detect the status of groundwater resources in west Mallawi area which represented one of the new reclamation lands. In order to achieve this aim, the hydrogeological and hydrogeochemical studies are carried out, based on the results of 21 pumping tests and chemical analysis of 29 water samples. Two water-bearing units are detected in the study area, namely, the Eocene fractured limestone aquifer which occupies the east portion of the studied area. The second aquifer consists of friable sediments of sand and gravel and may be related to the late Oligocene–early Miocene age and overlies the limestone rocks in the west, and this aquifer were studied for the first time in this work. Regionally, the groundwater flow in the area under study occurs toward the north and east directions. There is a hydraulic connection between both aquifers through the structural pattern affected the area. The partial recharge of the both aquifers takes place through the upward leakage from deep aquifers and the Nile water. There is a general decrease in the water salinity from west to east direction. The groundwater of both aquifers was evaluated for the different purposes and concluded that, it is considered suitable for different uses.     

淮南市朱集东矿井新生界松散层地下水开采保证程度评价

利用淮南市朱集东矿井新生界松散层供水水文地质勘探成果和抽水试验资料,查明了区内新生界松散层供水含水层的供水水文地质条件,认为第一含水层埋藏浅,易受污染,水量随季节变化大,不宜作为生活饮用水供水水源,第三含水层水质较差,亦不作为生活饮用水供水水源,确定了第二含水层为矿区主要供水层位。采用解析法对第二含水层的水量进行了计算,并设计了布井方案,计算了井群水量;水位预报结果表明,开采50a后,3#、4#井中的水位最大降深为35.229m,小于其顶板埋深,说明拟建井群布置是合适的。评价结果为矿井供水设计提供了依据。     

A study of234U/238U ratios in groundwaters of Taiyuan area,Shanxi Province

Uranium contents and²³⁴U/²³⁸U ratios have been determined on 29 water samples from the Taiyuan area, Shanxi Province. The results show that the same artesian aquifer has similar uranium contents and²³⁴U/²³⁸U activity ratios, and the deeper aquifers have higher A. R. values but lower uranium contents. The A. R. values increase slightly towards groundwater flow in the artesian aquifers dominated by oxidizing ground waters. The Lancun Spring and the famous Jinci Spring belong to two different karst groundwater systems, i.e., the east and west karst groundwater systems. The recharge area of the Lancun Spring should cover the wide limestone outcrops of middle Ordovician in the northeast. The Ordovician fissure-karst ground water to the Jinci Spring is extensively mixed with fissure water in Carboniferous-Jurassic formations and seepage water from the Fenhe River.     

Geological and geophysical exploration of the groundwater aquifers of As Suqah area, Makkah district, Western Arabian Shield, Saudi Arabia

As Suqah area is a NW–SE trending wadi present in the west central part of the Arabian Shield. It comprises Precambrian–Cambrian basement rocks, Cretaceous–Tertiary sedimentary succession, Tertiary–Quaternary basaltic lava flows, and Quaternary–Recent alluvial deposits. The magnetic anomalies indicated the presence of many recent local buried faults. These affected the distribution of the clastic sedimentary succession and seem to have controlled the deep groundwater aquifers. Groundwater movement is towards the west and northwest, following in general the surface drainage system. Hydraulic gradient varies greatly from one point to another depending on the pumping rates and cross-sectional area of the aquifer in addition to its transmissivity. The detailed results of the resistivity and seismic measurements were integrated with those obtained from test holes drilled in the study area. Groundwater occurs mainly in two water-bearing horizons, the alluvial deposits and within the clastic sedimentary rocks of Haddat Ash Sham and Ash Shumaysi formations. The shallow zone is characterized with a saturated thickness of 3–20 m and water is found under confined to semi-confined conditions. Water levels were encountered at depths varying from 3 to 16 m in the alluvial wadi deposits and from 18 to 62 m in the sedimentary succession. The combinations of vertical electrical sounding, horizontal electrical profiling, and drilling led to the identification of groundwater resources in the study area. Resistivity soundings clearly identified the nature of the lithological depth and proved useful at identifying water-bearing zones. Significantly, the majority of the groundwater was found within the deep confined aquifer gravelly sandstone, rather than in the shallow unconfined aquifer.     

Behaviour of a small sedimentary volcanic aquifer receiving irrigation return flows: La Aldea,Gran Canaria,Canary Islands (Spain)

In many arid and semi-arid areas, intensive cultivation is practiced despite water commonly being a limiting factor. Often, irrigation water is from local aquifers or imported from out-of-area aquifers and surface reservoirs. Irrigation return flows become a significant local recharge source, but they may deteriorate aquifer water quality. La Aldea valley, located in the western sector of Gran Canaria Island (Atlantic Ocean), is a coastal, half-closed depression in altered, low-permeability volcanics with alluvium in the gullies and scree deposits over a large part of the area. This area is intensively cultivated. Irrigation water comes from reservoirs upstream and is supplemented (average 30 %) by local groundwater; supplementation goes up to 70 % in dry years, in which groundwater reserves are used up to exhaustion if the dry period persists. Thus, La Aldea aquifer is key to the water-supply system, whose recharge is mostly from return irrigation flows and the scarce local rainfall recharge on the scree formations, conveyed to the gully deposits. To quantify the hydrogeological conceptual model and check data coherence, a simplified numerical model has been constructed, which can be used as a tool to help in water management.     

Groundwater flow through Pleistocene glacial deposits in the rapidly urbanizing Rouge River–Highland Creek watershed,City of Scarborough,southern Ontario,Canada

The city of Scarborough lies on the eastern margin of the Greater Toronto Area of southern Ontario, Canada, along the northern coastline of Lake Ontario. The City has a population of 500,000 and is presently one of the fastest growing communities in Canada. The City is expanding northwards onto rural land on the south slope of the large Pleistocene glacial Oak Ridges Moraine system. The moraine system is underlain by a thick (150 m) succession of tills, sands and gravels and is a regionally-significant recharge area for three principle aquifer systems that discharge to numerous watercourses that flow to Lake Ontario. Protection of deeper aquifers from surface-generated urban contaminants is a particular concern. A groundwater flow model using Visual MODFLOW was developed for the 350-km² Rouge River–Highland Creek (RRHC) drainage basin using an extensive GIS-based collection of subsurface geological, geophysical and hydrogeological data, maps of land use and surficial geology. The RRHC model was calibrated against point water level data, known potentiometric surfaces of the principal aquifers and baseflow measurements from streamflow gauging stations and determined to be within acceptable limits. Water balance calculations indicate that 70% of the basin recharge (106,000 m³/day) enters the Upper Aquifer along the crest and immediate flanks of the Oak Ridges Moraine. To the south, Upper Aquifer water moving through fractured till aquitards accounts for more than 75% of recharge to deeper aquifers. Water quality data confirm previous observations that urban- and rural-sourced contaminants (chlorides and nitrates) present in Upper Aquifer waters are moving rapidly into deeper aquifers. Some 83% of total RRHC recharge water is ultimately discharged as baseflow to creeks draining to Lake Ontario; the remainder discharges to springs and along eroding lakeshore bluffs. Model results demonstrate that deeper aquifers are poorly protected from urban contaminants and that long-term protection of ground and surface water quality has to be a priority of municipal planners if the resource is not to be severely degraded. Electronic Publication     

Effect of the groundwater contribution, the climatic change, and the human-induced activities on the hydrological behavior of discharge playas: a case study Sidi El Hani discharge playa, Tunisian Sahel

This study is meant to provide an insight into how discharge playas, which are strongly influenced by a regional salty groundwater flow regime, such as the discharge playa of Sidi El Hani, would respond to the climatic variability and to the materials coming from the subsurface of the Sahel area. In order to choose the appropriate method, a special care was given in this paper to different methods of investigation of the groundwater contribution in water and salt budgets of saline systems. The hydrogeological map of the surrounding aquifers proved their convergence toward Sidi El Hani discharge playa. As consequence of the dominance of a salty groundwater contribution, the climate variability may be considered minor. Accordingly, the model proposed by this study showed the dominance of the salty water coming from the hydrogeology at the expense of the fresh water coming from the climatic contribution. Moreover, according to the adopted model, the effect of the human-induced activity on the hydrogeological contribution such as the installation of dams in the Tunisian center and the overexploitation of the phreatic aquifer of Kairouan was judged increasing the convergence of Kairouan aquifer towards Sidi El Hani discharge playa. On the other hand, the consumption of salt reserves from the discharge playa tends to decrease its salinization.     

The groundwater age in the Middle-Upper Devonian aquifer system, Lithuania

³H, δ¹³C and hydrochemical data were used to estimate the corrected groundwater age derived from conventional ¹⁴C age of dissolved inorganic carbon (DIC). The Middle-Upper Devonian aquifer system from the Baltic upland recharge area in eastern Lithuania towards the discharge area on the Baltic Sea coast in the west was considered. The concentration of total dissolved solids (TDS) in groundwater changes from 300 to 24,000  mg/L and increases downgradient towards the coast. The other major constituents have the same trend as the TDS. The hydrochemical facies of groundwater vary from an alkali-earth carbonates facies at the eastern upland area to an alkali-earth carbonate-sulfate and chloride facies at transit and discharge areas. Meteoric water percolating through the Quaternary and Devonian aquifers regulate the initial ¹⁴C activities of groundwater involving two main members of DIC: soil CO₂ with modern ¹⁴C activity uptake and dissolution of ¹⁴C-free aquifer carbonates. Other sources of DIC are less common. ¹⁴C activity of DIC in the groundwater ranged from 60 to 108 pMC at the shallow depths. With an increase of the aquifers depth the dolomitization of aqueous solution and leakage of the “old” groundwater from lower aquifers take place, traced by lower activities (7–30 pMC).     

Characterization of hydrogeologic properties of the Tabriz plain multilayer aquifer system,NW Iran

A detailed hydrogeological investigation was carried out in the Tabriz plain in Iran using conventional hydrogeological field investigations and hydrochemistry. The study was carried out because the aquifers are of particular importance as they are more or less the only source of water supply available to the rural population and for agricultural and industrial activities. Analytical and numerical methods were applied to the constant rate pumping test data from the Tabriz airport and the Tabriz Power Station well fields. Two types of aquifers of different water quality were identified in the study area: an unconfined aquifer that extends over the plain and confined aquifers that are found in the deeper layers of the multilayered sediment terraces of the Aji-Chay River course. Therefore, the central part of the Tabriz plain contains both unconfined and confined aquifers, while close to the highlands, there is only an unconfined aquifer. There was evidence of minor leakage in the confined aquifers when the numerical method was used for analysis. The groundwater in the area can be identified by three main geochemical facies: Na-Cl, Ca-HCO₃, and mixed Ca-Mg-Cl-SO₄. The processes responsible for the hydrochemical evolution in the area fall into five categories: dissolution of evaporate minerals, precipitation of carbonate minerals, evaporation, ion exchange, and anthropogenic activity.     

Micropaleontological study (foraminifera, ostracods) and characterization of the paleoenvironment of middle Cretaceous deposits (Djebel Chemla area, north-eastern Algeria)

The Djebel Chemla section is situated in the north-east of Algeria, close to the town of Tébessa and just a few kilometers from the Tunisian border. This section is composed mainly of a sequence of marl and marly limestone levels, alternating with recurring oyster levels which range in age from Vraconnian to the Early Turonian. Firstly, the micropaleontological study of the content (counting of foraminifera and ostracods, thin sections) allows the subdivision of the section into four biozones, with Rotalipora appenninica, Rotalipora globotruncanoides, Rotalipora cushmani, and Whiteinella archaeocretacea as bio-indicators; and, secondly, it provides the opportunity to specify the paleoenvironment. The supposed depositional environment is rather calm and deep, of an external platform type, with a maximum depth of 200 m. Bottom waters seem to be commonly poorly oxygenated. The end-Cenomanian anoxic crisis was also characterized by the presence of Bahloul facies levels, rich in TOC, in filaments and of globulous planktic foraminifera, including a considerable proportion of Heterohelix. The genus Rotalipora has disappeared a few levels lower down.     

Geochemical characterization of groundwater from northeastern part of Nagpur urban,Central India

Hydrogeochemical investigations are carried out in the northeastern part of Nagpur urban to assess the quality of groundwater for its suitability for drinking and irrigation purposes. Groundwater samples are collected from both shallow and deep aquifers to monitor the hydrochemistry of various ions. The groundwater quality of the area is adversely affected by urbanization as indicated by distribution of EC and nitrate. In the groundwater of study area, Ca²⁺ is the most dominant cation and Cl⁻ and HCO₃ ⁻ are the dominant anions. Majority of the samples have total dissolved solids values above desirable limit and most of them belong to very hard type. As compared to deep aquifers, shallow aquifer groundwaters are more polluted and have high concentration of NO₃ ⁻. The analytical results reveal that most of the samples containing high nitrate also have high chloride. Major hydrochemical facies were identified using Piper trilinear diagram. Alkaline earth exceeds alkalis and weak acids exceed strong acids. Shoeller index values reveal that base-exchange reaction exists all over the area. Based on US salinity diagram most of samples belong to high salinity-low sodium type. A comparison of groundwater quality in relation to drinking water standards showed that most of the water samples are not suitable for drinking purpose.