西秦岭天水地区关子镇蛇绿岩锆石LA-ICP-MSU-Pb定年

秦岭造山带商丹缝合带的西延部分在天水地区以出露的关子镇蛇绿岩为标志,该蛇绿岩的形成时代是探讨秦岭造山带构造格局与演化的关键.在室内外综合研究的基础上,从该蛇绿岩的辉长岩中精选锆石,通过锆石的CL显微图像进行锆石形态学研究,结合U、Th含量特征,证明本次用于定年的锆石为岩浆成因.辉长岩中的锆石LA-ICP-MS定年给出U-Pb年龄为471 Ma±1.4Ma(MSWD=1.03,2σ),代表了辉长岩的结晶时代,也限定了关子镇蛇绿岩的形成时代.结合已有的地质、地球化学研究成果,认为秦岭商丹古洋盆存在的时限至少可延续至470Ma.该年龄的确定为深入研究和认识秦岭造山带古生代的构造格局及其演化提供了新的证据.     

新疆东昆仑阿克苏库勒蛇绿岩地球化学特征和形成时限——来自辉长岩岩墙和枕状玄武岩的证据

康西瓦-苏巴什-鲸鱼湖混杂岩带作为昆仑造山带一条重要的混杂岩带,通常被认为是古特提斯洋的残存带,其形成时限一直受到地质界的密切关注。在该带新识别出一套蛇绿岩,采用LA-ICP-MS锆石U-Pb测年,获得该蛇绿岩铁镁质单元中辉长岩的年龄为270.3±0.7Ma(MSWD=0.65),枕状玄武岩年龄为263.4±7.4Ma(MSWD=1.5),属于晚二叠世,代表蛇绿岩的形成年龄。通过岩石地球化学特征、区域背景等分析,认为其形成于洋中脊环境,属于典型的MORB型蛇绿岩。结合主量、微量元素特征、构造环境及同位素年龄讨论,认为古特提斯洋主洋盆至少持续到晚二叠世。     

东北大兴安岭北段蛇绿岩的时空分布及与区域构造演化关系的研究

大兴安岭北段作为中亚造山带东段重要组成单元,该区域的构造背景一直悬而未决,它涉及兴安与松辽地块基底属性、额尔古纳地块亲缘性以及三者之间的拼贴位置、时限和方式等众多科学问题。蛇绿岩作为研究造山带的重要工具之一,不仅是古板块或微地块的重要边界,而且是认识地幔组成和壳幔演化的重要窗口。然而大兴安岭北段蛇绿岩却鲜有报道。根据近年来野外工作及结合前人研究成果,文章探讨了蛇绿岩形成时代及构造环境。研究表明：(1)大兴安岭北段蛇绿岩整体呈北东向展布,但时代跨越较大,主要包括新元古代、早奥陶世-志留纪、石炭纪-二叠纪;(2)大兴安岭北段蛇绿岩均有E-MORB地球化学特征,其中新元古代的蛇绿岩明显亏损高场强元素Nb、Ta,而晚古生代的蛇绿岩则相对富集高场强元素;(3)大兴安岭北段新元古代蛇绿岩可能形成于洋内岛弧环境,记录着前寒武纪陆弧碰撞信息,而早奥陶世-志留纪蛇绿岩可能与早古生代弧盆体系演化相关。尽管上述认识为大兴安岭北段古生代的地球动力学背景研究提供了新的依据,但大兴安岭北段蛇绿岩仍存在较多问题亟须解决。     

新疆东昆仑阿克苏库勒蛇绿岩地球化学特征和形成时限——来自辉长岩岩墙和枕状玄武岩的证据

康西瓦-苏巴什-鲸鱼湖混杂岩带作为昆仑造山带一条重要的混杂岩带,通常被认为是古特提斯洋的残存带,其形成时限一直受到地质界的密切关注。在该带新识别出一套蛇绿岩,采用LA-ICP-MS锆石U-Pb测年,获得该蛇绿岩铁镁质单元中辉长岩的年龄为270.3±0.7Ma（MSWD=0.65）,枕状玄武岩年龄为263.4±7.4Ma（MSWD=1.5）,属于晚二叠世,代表蛇绿岩的形成年龄。通过岩石地球化学特征、区域背景等分析,认为其形成于洋中脊环境,属于典型的MORB型蛇绿岩。结合主量、微量元素特征、构造环境及同位素年龄讨论,认为古特提斯洋主洋盆至少持续到晚二叠世。     

北山月牙山蛇绿岩地球化学特征及SHRIMP定年

北山造山带是天山—兴蒙造山带的关键枢纽地带,该地区蛇绿岩系统的地质—地球化学研究,对于探讨中亚造山带的演化有着非常重要的意义。系统报道了月牙山蛇绿岩的主量元素、微量元素、Sr-Nd-Pb-Hf同位素组成及SHRIMP年代学研究成果。蛇绿岩套中斜长花岗岩的精细SHRIMP锆石U-Pb年龄为(536±7)Ma,表明该蛇绿岩形成于早寒武世晚期。月牙山蛇绿岩中蚀变橄榄岩、变基性岩系统的地球化学特征推测其应形成于与岛弧无关的构造环境。结合区域地质特征分析表明它应形成于板内深大断裂—初始裂谷演化至陆间有限小洋盆构造环境。     

北秦岭新元古代北北西向碰撞造山带存在的可能性及两侧陆块的汇聚与裂解

在北秦岭北西一北西西向显生宙造山带核部鉴别出与其斜交的北西向古构造带,可能为被改造了的北北西向新元古代造山带的残迹.强烈的区域变形(959～889Ma)和变质特别是高压变质(996～750Ma)以及S→I→A型花岗岩演化(959～725Ma)揭示,该造山带可能经历了同碰撞、晚碰撞到碰撞后伸展的碰撞造山旋回.由此推测,在该区新元古代时期可能发生了陆块的汇聚与裂解;当时造山带的原始方位及两侧汇聚陆块的边界可能是北北西向,汇聚方向可能是北东东向.     

喜马拉雅造山带东、西构造结的地质特征与对比

喜马拉雅造山带的东、西两端分别有一个构造急剧转向的地区——构造结, 这里是探讨喜马拉雅造山带构造演化的重要场所.区域地质调查资料对比显示这2个构造结有: (1)相似的地貌景观; (2)相似的地质特征和演化历史, 即都缺失喜马拉雅沉积岩(寒武纪—第三纪); (3)结晶岩系中都有高压变质岩, 且在10 Ma以来均发生过深熔与混合岩化作用; (4)25 Ma以来, 特别是10 Ma以来两地都经历了快速剥露和隆升作用; (5)印度板块-欧亚板块的碰撞时间接近, 分别为75 Ma和65 Ma, 均早于喜马拉雅造山带的其他地区.这些相似性表明: 伸展拆离和以河流作用为主的地表过程是喜马拉雅造山带的东、西构造结快速剥露的主导因素; 因强烈剥露减压所致的地壳部分熔融作用形成的岩浆向地表减压处的流动在构造结的演化过程中起着重要作用.      

内蒙古中部索伦克缝合带主要杂岩特征及其构造意义

中亚造山带是著名的增生型造山带之一,被认为大致由13个地体碰撞拼贴而成,演化时间约为750~250 Ma,而内蒙古中部索伦克缝合带的形成则代表着古亚洲洋的最终闭合。根据索伦克缝合带内一些典型杂岩的地质特征及其年代学研究成果,讨论古亚洲洋的最终闭合时间及其构造演化过程,认为古亚洲洋于晚二叠世最终消亡,通过多条近平行俯冲-增生杂岩带的相互拼贴碰撞造山,形成了兴蒙造山带,使得华北板块与南蒙古陆块发生接触。     

火成岩构造组合与壳-幔成矿系统

讨论了火成岩构造组合,指出不能单纯地运用化学图解,强调要结合岩相学、岩石组合特征研究,要注意区分区域与局部的构造环境。指出双峰式火成岩组合的确切含义是指缺乏中性成员,而不单看化学图解的几何形态,讨论了伸展与挤压对双峰式和钙碱性火成岩组合的可能约束。指出由蛇绿岩套再造的古构造历史可能是残缺的,结合弧火成岩的厘定可在某些方面弥补这个不足,讨论了弧火成岩组成极性形成的可能原因。讨论了大陆碰撞造山带的火成岩构造组合类型及其在再造造山带的边界性质、造山带演化历史中的重要意义。指出大陆裂谷带的火成岩常呈组成对称的水平分带,而不同于弧火成岩的组成极性。讨论了岩浆构造热事件及其序列的重要意义,提出大陆碰撞造山带具类似于变质作用的顺时针演化的事件序列,而大洋俯冲造山带则具反时针演化的事件序列。最后,强调并讨论了“壳幔岩浆流体成矿系统”的科学命题,提出从壳幔这个大系统来考察成矿作用是很重要的     

东昆仑造山带不同蛇绿岩带的厘定及其构造意义

在野外填图和室内地球化学研究的基础上,对东昆仑造山带蛇绿岩重新进行了厘定,并对本区构造演化进行了探讨,把东昆仑造山带蛇绿岩划分为４个带,从南到北分别为：阿尼玛卿蛇绿岩带、塔妥蛇绿岩带、清水泉蛇绿岩带、乌妥蛇绿岩带,它们在围岩的时代、构造样式及围岩变质程度,地球化学等方面明显差异。     

Wavelength-dispersive X-ray fluorescence spectrometric determination of Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in komatiites

Komatiites are mantle-derived ultramafic volcanic rocks. Komatiites have been discovered in several States of India, notably in Karnataka. Studies on the distribution of trace-elements in the komatiites of India are very few. This paper proposes a simple, accurate, precise, rapid, and non-destructive wavelength-dispersive x-ray fluorescence (WDXRF) spectrometric technique for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in komatiites, and discusses the accuracy, precision, limits of detection, x-ray spectral-line interferences, inter-element effects, speed, advantages, and limitations of the technique. The accuracy of the technique is excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Zr, Nb, Ba, Pb, and Th and very good (within 4%) for Y. The precision is also excellent (within 3%) for Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th. The limits of detection are: 1 ppm for Sc and V; 2 ppm for Cr, Co, and Ni; 3 ppm for Cu, Zn, Rb, and Sr; 4 ppm for Y and Zr; 6 ppm for Nb; 10 ppm for Ba; 13 ppm for Pb; and 14 ppm for Th. The time taken for determining Sc, V, Cr, Co, Ni, Cu, Zn, Rb, Sr, Y, Zr, Nb, Ba, Pb, and Th in a batch of 24 samples of komatiites, for a replication of four analyses per sample, by one operator, using a manual WDXRF spectrometer, is only 60 hours.     

高压微波消解法测定醋酸纤维过滤器采集的微尘粒子中的砷镉钴铬铜铁锰镍铅钒锌

最新的流行病学研究表明,空气中较高浓度的悬浮细颗粒可能对人类的健康有不利的影响。根据该项研究显示,由于心脏病、慢性呼吸问题和肺功能指标恶化而导致死亡率的升高与细尘粒子有关。这些研究结果已经促使欧盟于1999年4月出台了限制空气中二氧化硫、二氧化氮、氧化氮、铅和颗粒物含量的法案（1999/30/EC）,对各项指标包括对可吸入PM10颗粒的浓度提出了新的限制性指标。PM10颗粒是指可以通过预分级器分离采集的气体动力学直径小于10 μm的细颗粒。目前研究的兴趣重点逐步偏向PM2.5这些更细微颗粒物,PM2.5这种颗粒物对健康有明显的不利影响。在欧盟指令2008/50/EC中,对PM10和PM2.5都提出了具体测定要求。     

Isotopic systematics of He,Ar, S,Cu, Ni,Re, Os,Pb, U,Sm, Nd,Rb, Sr,Lu, and Hf in the rocks and ores of the Norilsk deposits

This paper reports the first results of a study of 11 isotope systems (³He/⁴He, ⁴⁰Ar/³⁶Ar, ³⁴S/³²S, ⁶⁵Cu/⁶³Cu, ⁶²Ni/⁶⁰Ni, ⁸⁷Sr/⁸⁶Sr, ¹⁴³Nd/¹⁴⁴Nd, ^206–208Pb/²⁰⁴Pb, Hf–Nd, U–Pb, and Re–Os) in the rocks and ores of the Cu–Ni–PGE deposits of the Norilsk ore district. Almost all the results were obtained at the Center of Isotopic Research of the Karpinskii All-Russia Research Institute of Geology. The use of a number of independent genetic isotopic signatures and comprehensive isotopic knowledge provided a methodic basis for the interpretation of approximately 5000 isotopic analyses of various elements. The presence of materials from two sources, crust and mantle, was detected in the composition of the rocks and ores. The contribution of the crustal source is especially significant in the paleofluids (gas–liquid microinclusions) of the ore-forming medium. Crustal solutions were probably a transport medium during ore formation. Air argon is dominant in the ores, which indicates a connection between the paleofluids and the atmosphere. This suggests intense groundwater circulation during the crystallization of ore minerals. The age of the rocks and ores of the Norilsk deposits was determined. The stage of orebody formation is restricted to a narrow age interval of 250 ± 10 Ma. An isotopic criterion was proposed for the ore-bearing potential of mafic intrusions in the Norilsk–Taimyr region. It includes several interrelated isotopic ratios of various elements: He, Ar, S, and others.     

硅酸盐中铁、锰、钛、钙、钾、磷、硅、铝、镁、钠、锶、铷、钡的X-射线荧光光谱定量测定

本文介绍样品经四硼酸锂熔融制成玻璃小饼。采用Lachance模式和理论a系数来校正元素间的效应,由3080E型X-射线荧光谱仪和DF-350B数据处理系统完成硅酸盐中十三个项目的测定。     

硅酸盐类样品中硅、铁、铝、钛、锰、钙、镁、钾、钠和磷的x射线荧光光谱测定

本文拟定了一种以熔融法制备样片,用X射线荧光光谱测定硅酸盐类样品中Si、Fe、Al、Tj、Mn、Ca、Mg、K、Na、P等元素的分析方法。在对不同靶材X光管和分光晶体实验对比的基础上,选择了最佳的测量条件。该法具有快速、准确,测量范围广,检测限低,价格便宜等优点。经过近百个各种类型标样或管理样品的分析对比表明,本法不仅适用于硅酸盐类岩石样品的分析,还适用于铁矿、铝土矿、碳酸盐类岩矿样品以及水泥、耐火材料等样品的分析。     

Viscous, cohesive, non-Newtonian, depositing, radial slurry flow

Mining induced subsidence can significantly affect mining costs where major surface facilities and natural environment need to be protected. Overburden grout injection is a technology used to control coal mine subsidence by injecting the mine waste material extracted from the coal back into the inter-burden rock during longwall mining. The flowing slurry is here categorised as a nonlinear viscous cohesive (Bingham plastic) fluid. During longwall mining the grout slurry is pumped into the separated beds of the rock mass through a central vertical borehole, which is drilled deep into the inter-burden rock strata above the coal seam. However, a blockage can occur in the injection system when the slurry velocity falls below a certain critical threshold velocity, indicating a material phase change from cohesive-viscous to cohesive-frictional. In situ field injection tests through boreholes have been simulated at a smaller scale at the CSIRO laboratory in Brisbane by pumping the slurry through a radial disk (gap = 4 mm) from its centre. Laboratory experiments indicate a general, nonlinear, cohesive, viscous, frictional model for shear behaviour of the slurry, in which the material shear parameters are functions of the disk radial distance. Complete dimensional and dimensionless analytical solutions have been developed based on an approach related to Bingham–Herschel–Bulkley fluid mechanics. The derived formulae include relations for minimum pump pressure, local pressure and pressure gradient, wall shear stress, volume rate, velocity and velocity gradient. The theoretical results match the experimental measurements. The experiments covered slurries with maximum particle sizes of 0.5 to 2 mm with about 50% being larger than 100 µm. The viscosities at the various solids concentrations were measured with a standard torsion viscometer. This study differs from the previous research in several distinct aspects, namely, consideration of the variable shear parameters rather than fixed values, inclusion of total nonlinear behaviour, and implementation of a friction function to mimic behaviour of the deposited and consolidating stiff slurry, which can cause a significant pressure rise as a result of the increased shear resistance.     

Mountains,nations, parks,and conservation

Between 1985 and 1991, two new mountain protected areas (MTNPA) covering more than 35,000 km² and based on participatory management models — the Makalu-Barun National Park and Conservation Area, Nepal, and Qomolangma Nature Preserve, Tibet Autonomous Region — were successfully established through the collaborative efforts of Woodlands Mountain Institute and conservationists in China and Nepal. Characteristics common to both projects include the importance of establishing (1) effective rationales, (2) local support constituencies, (3) a senior advisory group, (4) a task force, (5) linkages between conservation and development, and (6) fund raising mechanisms. The lessons derived from the experiences of Woodlands Mountain Institute are of significant value to others in preserving MTNPA. Increased collaboration and communication between all interested in conservation, however, will remain a critical component for expanding mountain protected area coverage to throughout the world.     

Regional distribution of Al,B, Ba,Ca, K,La, Mg,Mn, Na,P, Rb,Si, Sr,Th, U and Y in terrestrial moss within a 188,000 km2 area of the central Barents region: influence of geology,seaspray and human activity

Five hundred and ninety-eight samples of terrestrial moss (Hylocomium splendens and Pleurozium schreberi) collected from a 188,000 km² area of the central Barents region (NE Norway, N Finland, NW Russia) were analysed by ICP-AES and ICP-MS. Analytical results for Al, B, Ba, Ca, K, La, Mg, Mn, Na, P, Rb, Si, Sr, Th, U and Y concentrations are reported here. Graphical methods of data analysis, such as geochemical maps, cumulative frequency diagrams, boxplots and scatterplots, are used to interpret the origin of the patterns for these elements. None of the elements reported here are emitted in significant amounts from the smelting industry on the Kola Peninsula. Despite the conventional view that moss chemistry reflects atmospheric element input, the nature of the underlying mineral substrate (regolith or bedrock) is found to have a considerable influence on moss composition for several elements. This influence of the chemistry of the mineral substrate can take place in a variety of ways. (1) It can be completely natural, reflecting the ability of higher plants to take up elements from deep soil horizons and shed them with litterfall onto the surface. (2) It can result from naturally increased soil dust input where vegetation is scarce due to harsh climatic conditions for instance. Alternatively, substrate influence can be enhanced by human activity, such as open-cast mining, creation of ‘technogenic deserts’, or handling, transport and storage of ore and ore products, all of which magnify the natural elemental flux from bedrock to ground vegetation. Seaspray is another natural process affecting moss composition in the area (Mg, Na), and this is most visible in the Norwegian part of the study area. Presence or absence of some plant species, e.g., lichens, seems to influence moss chemistry. This is shown by the low concentrations of B or K in moss on the Finnish and Norwegian side of the (fenced) border with Russia, contrasting with high concentrations on the other side (intensive reindeer husbandry west of the border has selectively depleted the lichen population).     

NEW SET OF LOW CONCENTRATION STANDARDS FOR LA, CE, SM, YB, LU, Y, SC, V, NB AND TA IN SILICATES

We have developed a set of four synthetic standards for the rare earth and high field strength elements designed for use in the determination of those elements in silicates. The base material is a glass nominally at the eutectic of the MgO-Al₂O₃-SiO₂ ternary system. The nominal doping level was 2 wt% of the elements as oxides. To avoid problems associated with peak interference, the elements were doped in four separate glasses.