Surface irrigation performance of date palms under water scarcity in arid irrigated lands

In this paper, a study on the performance of surface irrigation of date palms in a Tunisian arid area (Douz oasis) is presented. The study is conducted in 16 plots with various sizes and soil textures over a 4-year period (2012–2015). In the first step, an assessment of total water requirements of the date palms is carried out. Then, the surface irrigation performance is analyzed using three indicators, i.e., the relative water supply (RWS) indicator, the uniformity index of water distribution (D _U ), and the water application efficiency (E _a ). Finally, the irrigation management problems are identified. The results indicate that in the arid Tunisian Saharan oases, the soil texture, plot size, and farmers’ practices (especially irrigation duration) have significant effects on surface irrigation performance. The average annual net irrigation requirements of date palms are about 2400 mm. The RWS increases from 1.8 in the smaller plots (0.5 ha) to 3.6 in the largest plots (2.5 ha), implying that the increase in the plot size requires an excessive water supply. D _U decreases from 80.7 in the 0.5 ha plots to 65.4 in the 2.5 ha plots; however, no significant difference in the E _a is observed. The results show that the soil texture has no influence on the RWS and D _U , but the E _a is significantly higher in the loamy-sand soils (46.7%) compared to the sandy soils (36.3%). Overall, RWS indicator is higher than 1 (RWS?=?2.6) implying excessive irrigation supply to the system. Although D _U is relatively uniform (>?60%), E _a is relatively low (<?50%) indicating that the current irrigation management is inefficient. These findings have a paramount importance for improving irrigation water management in the Tunisian Saharan oases.     

Adsorptive removal of pharmaceuticals and personal care products from aqueous solutions by chemically treated fly ash

This study investigated the removal efficiency of pharmaceuticals from aqueous solutions supported on chemically treated fly ash. The coal fly ash was supplied by the electric power station in Krakow, Poland. There are plenty of studies showing the utilization of fly ash as a low-cost adsorbent for wastewater containing heavy metals or dyes. Adsorption and immobilization of pharmaceuticals and personal care products on fly ash is a relatively new method but it is a very promising one. In this study, the adsorptive removal of diclofenac, ketoprofen, carbamazepine, bezafibrate, bisphenol A, 17α-ethinyl estradiol and estriol by HCl- and NaOH-treated fly ash was assessed. Chemical treatment of fly ash changed structures of particles and enhanced specific surface areas. HCl-treated fly ash was characterized by the highest BET specific surface area 47.9 m² g^?1 and unburned carbon content 8.1%. Isotherms for all compounds except for 17α-ethinyl estradiol (EE2) and estriol (E3) were linear. Higher linear regression coefficients (R ²) obtained for isotherms of EE2 and E3 show that the Freundlich model better describes their sorption. Adsorption coefficients K _d varied between 109.5 (L kg^?1) for bisphenol A and 471.5 (L kg^?1) for bezafibrate. Freundlich constants (K _F) for EE2 and E3 were 62.3 and 119.9 (µg^1?1/n L^1/n kg^?1), respectively. Acid treatment of fly ash increased adsorption of diclofenac, ketoprofen, carbamazepine, bezafibrate and bisphenol A. Comparison of the octanol–water partitioning coefficients (log K _OW) with the partitioning coefficients normalized on unburned carbon content (log K _UC) revealed similarities but no strong correlation. The increasing of unburned carbon increased sorption of compounds to fly ash.     

Evaluation of bagasse ash treated lateritic soil as a potential barrier material in waste containment application

Laboratory tests were conducted on a reddish-brown lateritic soil treated with up to 12 % bagasse ash to assess its suitability in waste containment barriers applications. Soil samples were prepared using four compaction energies (i.e. reduced Proctor, standard Proctor, West African Standard or ‘intermediate’ and modified Proctor) at ?2, 0, 2 and 4 % moulding water content of the optimum moisture content (OMC). Index properties, hydraulic conductivity (k), volumetric shrinkage and unconfined compressive strength (UCS) tests were performed. Overall acceptable zones under which the material is suitable as a barrier material were obtained. Results recorded showed improved index properties; hydraulic conductivity and UCS with bagasse ash treatment up to 8 % at the OMC. Volumetric shrinkage strain increased with higher bagasse ash treatment. Based on the overall acceptable zone obtained, an 8 % optimal bagasse ash treatment of the natural lateritic soil makes it suitable for use in waste containment barrier application.     

Heave Studies on Fly Ash-Stabilised Expansive Clay Liners

Clay liners or compacted earthen barriers are important barrier materials used for preventing contaminant transport through soils. A low hydraulic conductivity (k) is a significant parameter that governs the design and construction of clay liners. Compacted expansive clays, which are montmorillonite clays, also have a very low hydraulic conductivity (k). When expansive clays are blended with fly ash, an industrial waste, the hydraulic conductivity (k) further reduces as the ash-clay blends result in increased dry densities at increased fly ash contents. Hence, fly ash-stabilised expansive clay can also be proposed as a unique clay liner material. As expansive clays undergo heave when they come into contact with water, it is necessary to study the heave behaviour of fly ash-stabilised expansive clay liners. This paper presents heave studies on fly ash-stabilised expansive clay liners. Fly ash in different contents by dry weight of the expansive clay was added to the clay, and the ash-clay blend was compacted as a liner overlying a natural field soil layer. Compacted lateritic clay was used for simulating the natural field soil into which contaminants migrate. Calcium chloride (CaCl₂) solution of varying concentration (5, 10, 20, 50, 100 and 500 mM) was used as the permeating fluid in the heave studies. The rate of heave and the amount of heave of the fly ash-stabilised expansive clay liners were monitored. Deionised water (DIW) was also used as inundating fluid for comparative study. Heave (mm) decreased with increase in solute concentration for all fly ash contents. For a given solute concentration, heave decreased up to a fly ash content of 20 % and thereafter it increased when the fly ash content was increased to 30 %. Heave of the fly ash-stabilised expansive clay liners was correlated with their permeability, liquid limit (LL) and free swell index (FSI) pertaining to the respective fly ash content and CaCl₂ concentration.     

Characterizing groundwater recharge using oxygen and hydrogen isotopes: a case study in a temperate forested region,South Korea

In the cool temperate region of South Korea, oxygen and hydrogen isotopes of groundwater, lake water, and precipitation were studied to determine the season of groundwater recharge. All the groundwater samples, irrespective of season, on δ¹⁸O–δ²H scale plotted along the summer precipitation, suggesting summer precipitation largely modulates recharge. The deuterium excess values of groundwater (d-excess) show clear seasonal difference, higher in winter (> 18‰) and lower in summer (< 10‰). And its resemblance to the summer precipitation d-excess value further suggests dominant role of summer precipitation in groundwater recharge. Based on the mass balance equation, with end-member d-excess values of seasonal precipitation and groundwater as input variables, groundwater is composed of 66% summer and 34% winter precipitation. Despite the study area being heavily forested, summer rainfall contribution higher than winter suggests that evapotranspiration effect is minimal in the region; may be due to thin sand–gravel-based porous soil overlying highly weathered granitic rock system.     

Nutrient uptake by mulberry and Chinese prickly ash associated with arbuscular mycorrhizal fungi

Understanding how nutrient absorption processes in plants are related to arbuscular mycorrhizal (AM) association is critical for predicting the effects of AM symbiosis on elemental cycling for plants. Both mulberry (Morus alba) and Chinese prickly ash (Zanthoxylum bungeanum) are AM-associated plants, widely distributed in southwest China. It was hypothesized that if the nutrient absorption processes were efficiently associated with AM symbiosis in both mulberry and Chinese prickly ash, foliar nutrient concentrations—especially calcium (Ca)—would be primarily determined by the soil conditions in different regions. To investigate this, AM colonization levels of soils, nutrient levels in soils and leaves, and δ¹³C values of leaves were analyzed for mulberry and Chinese prickly ash. In this study, spore density in soils with low pH was higher than that in soils with high pH. The average concentrations of sugar delivered to roots in both mulberry and Chinese prickly ash in soil with relatively low pH and soil extractable cations were higher than those in other areas. The values of foliar δ¹³C in both mulberry and Chinese prickly ash in low soil-pH and soil extractable cations were lower than those in contrast areas, indicating that water availability was impacted by soil characteristics. The efficiency in AM-mediated processes might play an important role in translocation between soil nutrients and plant tissue. The results suggest uptake and translocation of nutrients, especially Ca, in AM-associated plants may be affected by an efficiency of AM-mediated processes. Since Sr does not appear to be similarly affected, expressing Ca and other nutrient concentrations relative to Sr could be used to evaluate whether the uptake and translocation of Ca and other nutrients are affected by AM-mediated processes.     

Magnetic susceptibility as a proxy for coal ash pollution within riverbed sediments in a watershed with complex geology (southeastern USA)

A study of near surface sediments from the Dan River (southeastern USA) was conducted to assess the use of magnetic properties as proxies of coal ash after a recent spill. The watershed geology is diverse and potentially contributes magnetic minerals to riverbed sediment from diabase dikes in the Dan River Triassic Basin and from granitic gneiss outside the basin. Coal ash is heterogeneous, including aluminosilicate spheres, amorphous particles and carbonaceous rods and lacy particles. The magnetic fraction of ash from the failed storage pond is up to 17 wt% and is mostly composed of black spheres with maghemite and magnetite. Ash was detected in riverbed sediment from quiet water settings such as inside of meander bends, the confluence of tributary streams and near islands between the spill site and 20 miles downstream in the Schoolfield Reservoir, Danville, VA. The strong magnetic signal is detected above background in riverbed samples and is strongly positively correlated with total ash; elevated low field magnetic susceptibility (χ _LF) is evident in samples with ≥ 12% ash content. Anhysteretic remanent magnetization and hysteresis parameters delineate native sediment, ash-bearing sediment, and diabase dikes. Between 20 and 70 miles downstream of the spill site, ash concentrations were either buried or too low due to dilution with native sediment to be detected with χ _LF in riverbed samples.     

Hydraulic Conductivity of Fly Ash-Amended Mine Tailings

The objective of this study was to evaluate the effect of fly ash addition on hydraulic conductivity (k) of mine tailings. Mine tailings used in this study were categorized as synthetic tailings and natural tailings; two synthetic tailings were developed via blending commercially-available soils and natural tailings were collected from a garnet mine located in the U.S. Two fly ashes were used that had sufficient calcium oxide (CaO) content (17 and 18.9 %) to generate pozzolanic activity. Hydraulic conductivity was measured on pure tailings and fly ash-amended tailings in flexible-wall permeameters. Fly ash was added to mine tailings to constitute 10 % dry mass of the mixture, and specimens were cured for 7 and 28 days. The influence of fly ash-amendment on k of mine tailings was attributed to (1) molding water content and (2) plasticity of the mine tailings. Tailings that classified as low-plasticity silts with clay contents less than 15 % exhibited a decrease in k when amended with fly ash and prepared wet of optimum water content (w _opt ). Tailings that classified as low-plasticity clay exhibited a one-order magnitude increase in k with addition of fly ash for materials prepared dry or near w _opt . The decrease in k for silty tailings was attributed to formation of cementitious bonds that obstructed flow paths, whereas the increase in k for clayey tailings was attributed to agglomeration of clay particles and an overall increase in average pore size. The results also indicated that the effect of curing time on k is more pronounced during the early stages of curing (≤7 days), as there was negligible difference between k for 7 and 28-days cured specimens.     

Groundwater potential recharge estimation in bare soil using three soil moisture accounting models: field evaluation for a semi-arid foothill region

Performances of conventional and improved soil moisture balance as well as locally calibrated empirical models were evaluated in simulating potential recharge (R) and soil moisture content for a semi-arid foothill region. Models comparison with observed values using lysimeter data during [(2011–2012), (2012–2013)] reveal poor performance of conventional soil moisture balance model, underestimating annual R values. Improved soil moisture balance model provided acceptable estimation of annual R for 2011–2012 by considering the wetting of the near surface soil storage. However, it produced the worst simulation for daily soil moisture content once rainy season was over. Sensitivity analysis revealed that the precision degree of initial soil moisture deficit value would strongly influence estimation of R by improved soil moisture balance model, which can be viewed as a limiting factor. Additionally, locally calibrated model produced the best estimation of annual R and daily soil moisture content, which is suggested for the study region.     

Spatial heterogeneity of soil moisture, microbial biomass carbon and soil respiration at stand scale of an arid scrubland

Studying the influence of plants on soil biological variables in an arid zone is important to the understanding of soil processes and relationships between above and below ground. The objective of this study was to quantify the pattern and degree of soil heterogeneity for soil moisture and its relationship with microbial biomass carbon and soil respiration using geostatistical techniques at stand scale of an arid scrubland. The experiment was conducted in a scrubland landscape using a 2 × 2 m grid within a 16 × 14 m plot in the lower reach of Sangong River watershed in Xinjiang, northwest China. The results revealed the following: (1) Soil moisture and soil microbial biomass carbon had moderate spatial variation, but soil respiration had strong variation. Spatial variability of soil moisture in the study plot decreased when soil moisture changed from wet in April to dry in June. In addition, correlations of soil moisture with microbial biomass carbon and soil respiration were positive and significant (p < 0.005). (2) Variation of soil microbial biomass carbon and soil moisture had a strong spatial autocorrelation in the study plot, mainly induced by structural factors, and the spatial autocorrelation of microbial biomass carbon and soil respiration was mainly determined by soil moisture. (3) The location of the high-value positions of soil moisture, soil microbial biomass carbon and soil respiration were clearly around the positions of scrubs in the study plot. Such information provided some insights to explain the spatial heterogeneity of soil properties at stand scale in an arid region.     

Spatial information of soil hydraulic conductivity and performance of cokriging over kriging in a semi-arid basin scale

Unlike the studies in small parcels by systematic measurements, the spatial variability of soil properties is expected to increase in those over relatively large areas or scales. Spatial variability of soil hydraulic conductivity (K _h) is of significance for the environmental processes, such as soil erosion, plant growth, transport of the plant nutrients in a soil profile and ground water levels. However, its variability is not much and sufficiently known at basin scale. A study of testing the performance of cokriging of K _h compared with that of kriging was conducted in the catchment area of Sarayköy II Irrigation Dam in Cank?r?, Turkey. A total of 300 soil surface samples (0–10 cm) were collected from the catchment with irregular intervals. Of the selected soil properties, because the water-stable aggregates (WSA) indicated the highest relationship with the hydraulic conductivity by the Pearson correlation analysis, it is used as an auxiliary variable to predict K _h by the cokriging procedure. In addition, the sampling density was reduced randomly to n = 175, n = 150, n = 75 and n = 50 for K _h to determine if the superiority of cokriging over kriging would exist. Statistically, the results showed that all reduced K _h was as good as the complete K _h when its auxiliary relations with WSA were used in cokriging. Particularly, the results of the “Relative Reduction in MSE” (RMSE) revealed that the reduced data set of n = 75 produced the most accurate map than the others. In this basin-scaled study, there was a clear superiority of the cokriging procedure by the reduction in data although a very undulating topography and topographically different aspects, two different land uses with non-uniform vegetation density, different parent materials and soil textures were present in the area. Hence, using the statistically significant auxiliary relationship between K _h and WSA might bring about a very useful data set for watershed hydrological researches.     

Estimating groundwater evapotranspiration rates using diurnal water-table fluctuations in a semi-arid riparian zone

In semi-arid climates, phreatophytes draw on shallow aquifers, and groundwater evapotranspiration (ET_G) is a principal component of groundwater budgets. Diurnal water table fluctuations, which often are a product of ET_G, were monitored in the riparian zone of Red Canyon Creek, Wyoming, USA. These fluctuations were higher in a riparian wetland (2–36 mm) than a grass-covered meadow (1–6 mm). The onset and cessation of water-table fluctuations correspond to daily temperatures relative to freezing. Spatial differences were due to vegetation type and specific yield, while temporal changes were due to vegetation dormancy. Ratios of ET_G to potential evapotranspiration (PET), K _c,GW, were similar to ratios of actual evapotranspiration (ET) to PET, K _c, in semi-arid rangelands. Before vegetation senescence, K _c,GW increased between precipitation events, suggesting phreatophytes pull more water from the saturated zone as soil moisture decreases. In contrast, K _c decreases with soil moisture following precipitation events as ET becomes increasingly water-limited. Error in ET_G is primarily from estimates of specific yield (S _y), which is difficult to quantify in heterogeneous sediments. ET_G values may be more reliable because the range of acceptable S _y is smaller than K _c and S _y does not change with vegetation type or soil moisture.     

A geoenvironmental application of burned wastewater sludge ash in soil stabilization

This paper studied the use of burned sludge ash as a soil stabilizing agent. The sludge ash was obtained from a public wastewater treatment plant, and it was burned at 550 °C. Different percentages of burned sludge ash were mixed with three different types of clayey soil. A laboratory study consisting of Atterberg’s limits test, unconfined compressive strength test, standard proctor density test, and swelling pressure test were carried out on samples treated with burned sludge at different percentages by dry weight of the clayey soils. The results show that the addition of 7.5 % of the burned sludge ash by the dry weight of the soil will increase the unconfined compressive strength and maximum dry density and also decrease the swelling pressure and the swell potential of the soil. The addition of percentage higher than 7.5 % by dry weight of the soil decreases both the maximum dry density and the unconfined compressive strength; as a result it showed less effectiveness in stabilizing the soil. The conclusion of this research revealed that the burned sludge ash can be used as a promising material for soil stabilization.     

Exploration of empirical relationship between surface soil temperature and surface soil moisture over two catchments of contrasting climates and land covers

Soil moisture plays a very important role in hydrological processes. It has been found in many studies that the surface soil moisture (SSM) is highly related to the diurnal change of the surface soil temperature (?SST) at the same soil depth. However, some studies contradict this common belief with findings of a much stronger correlation between the SSM and the SST. In order to investigate this further, we have carried out for the first time a comparative assessment of the in-situ measured SST and ΔSST for SSM estimations, over two catchments with contrasting climate types and land uses (i.e. one in the UK and the other in Australia). In both catchments, the time point for the highest relationship between the SST and the SSM is explored. As a result, it is found the SST is more suitable to monitor the variability of the SSM than the ΔSST in both catchments. Moreover the proposed seasonal-based classification method further improves the SSM simulation results in both catchments, with a superior performance observed in the UK catchment (NSE = 0.900 and RMSE = 0.030). In the Australian catchment, a relatively weaker correlation is observed and some potential reasons are explained. The potential applications of the findings for remote sensing soil moisture retrievals are also discussed.     

Factors controlling the changes and spatial variability of <Emphasis Type="Italic">Junipers phoenicea</Emphasis> in Jabal Al Akhdar,Libya, using remote sensing and GIS

The Junipers phoenicea, which covers 70 % of the Jabal Al Akhdar (Green Mountain) in Cyrene on the northeast coast of Libya, has deteriorated over large scales. To deal with this problem, the images of the Landsat 7 Enhanced Thematic Mapper Plus (ETM+) and Landsat 8 Operational Land Imager (OLI) in conjunction with the Shuttle Radar Topography Mission (SRTM) digital elevation model (DEM) were used to map factors controlling the J. phoenicea mortality using a set of automated algorithms and tools. These factors include altitude, slope, aspect, curvature, drainage pattern, seawater intrusion, and land cover. As a first step, changes of J. phoenicea and land cover during the period from the year 2000 to 2015 were mapped. The results showed a sharp decline in J. phoenicea covering an area of 396 km² (22 %) of the total area. The result also showed that areas at a lower elevation with steep slope and faced to the south and southeast directions have a higher probability of J. phoenicea distribution. The spatial analysis showed a positive correlation between wetness and the intensity of J. phoenicea mortality. The results also show that altitude and slope have the most influencing power on the J. phoenicea morality. This study is of great help for decision makers and agriculture engineers and permits a better understanding of ecological and biomass changes in the Jabal Al Akhdar, Libya, over a regional scale.     

Diffusion of municipal waste contaminants in compacted lateritic soil treated with bagasse ash

Compacted clay can minimize infiltration of liquid into waste or control the release of contaminated liquids to the surrounding soils and groundwater. Compacted lateritic soil treated with up to 12 % bagasse ash and municipal solid waste (MSW) leachate sourced from a domestic waste land fill were used in diffusion test studies to access the diffusion characteristics of some inorganic species present in the municipal solid waste leachate. Diffusion set-up were prepared containing 0, 4, 8 and 12 % bagasse ash—soil mixes compacted at 2 % wet of optimum using the modified proctor effort. The set up was saturated with water for 30 days before the introduction of MSW leachate and initiation of diffusion test for another 90 days. After diffusion testing, water content within the soil column showed a decrease with depth. Diffusion test results generally showed that diffusion is an active means of transport of chemical species even at very low flow rates in the compacted soil-bagasse ash mixes, and the effective diffusion coefficient is affected by bagasse ash. The pore fluid concentration profile for the various chemical species tested showed that the compacted soil-bagasse ash mix has the capacity to attenuate Ca²⁺, Pb²⁺ and Cr³⁺ ions.     

The human impact on the transformation of juniper forest landscape in the western part of the Pamir-Alay range (Tajikistan)

Detailed analyses were conducted of human impact on juniper forest landscapes occurring within the Zarafshan Range (Pamir-Alay). Juniperus seravschanica and J. semiglobosa belong to forest-forming species in Central Asia. At present, juniper forests all over Tajikistan are seriously threatened as a result of excessive logging and cattle grazing. The aim of this paper is to present juniper forest transformation as a result of human activities as well as the diversity of soil properties in the organic and humus horizons in the altitudinal system of soil zonation. Three groups of phytocoenoses were distinguished: those with a dominant share of Juniperus seravschanica; those with a dominant share of J. semiglobosa; and mixed. Associations with Juniperus seravschanica and J. semiglobosa feature several variants of phytocoenoses with dominant species: Artemisia lehmanniana, A. dracunculus, Eremurus olgae, Festuca sulcata, Ligularia thomsonii, Stipa turkestanica, Thymus seravschanicus, and Ziziphora pamiroalaica. The collected soil samples differ in their granulometric composition. Gravelly cobble fractions >2 mm are dominant; the share of sandy particles <2 mm is much lower (about 10–20%). Fraction 0.5–0.05 attains 35% on average. The Corg content of the soil varied from 0.26 to 11.40% in the humus horizon (A) and from 4.3 to 25% in the organic (O). Similar relationships were reported in the case of Ntot concentration. A clear relationship can be observed between concentrations of Corg and Ntot. Soil pH varied, ranging from very low acidic (pH 5.5) to neutral (pH 8.5). The content of available P varied; high concentrations were noted in organic (O) (40.46–211 mg kg^?1) and mixed horizons (OA) (2.61–119 mg kg^?1). Maximum accumulations of Pavail (1739.6 mg kg^?1) and Ptot (9696 mg kg^?1) were observed at a site heavily affected by intense grazing. Concentrations of Mgavail varied from 116 to 964 mg kg^?1. Most of the analysed soil profiles lacked an organic horizon; only thin humus occurred.     

Mechanical Properties and Deformation and Failure Characteristics of Surrounding Rocks of Tunnels Excavated in Soft Rocks

As soft rocks are likely to soften, slime and swell while contacting water, the existence of soft rocks is harmful for stability of surrounding rocks and supporting structures of tunnels. Through uniaxial and triaxial tests under dry condition and triaxial test with different moisture contents, the mechanical properties and failure modes of soft rocks were studied under conditions that the schistosity plane of the rock samples was vertical to, presented an oblique angle with, and paralleled to the loading direction. The results showed that peak strengths in natural and water-bearing states increased with increasing confining pressures, while those in water-bearing state were 40% lower than those in natural state. The samples were mainly subjected to ductile failure in both natural and water-bearing states while the samples in natural state exhibited a certain brittle failure characteristic in post-peak phase. With the increase of confining pressures, the post-peak curve gradually became gentle after certain brittle failure while the post-peak stresses had an insignificant change. In comparison, the samples in water-bearing state showed significant post-peak disparity, that is, exhibited strong ductile failure characteristic. Moreover, the fitting relationship between triaxial compressive strength and moisture of soft rocks can be expresses as σ ₁ = Aω + B (A < 0, B > 0) while that between elasticity modulus and moisture can be expresses as E = Aω + B (A < 0, B > 0).     

Effects of alkaline-activated fly ash and Portland cement on soft soil stabilisation

This paper studies the effects of sodium-based alkaline activators and class F fly ash on soil stabilisation. Using the unconfined compressive strength test (UCS), the effectiveness of this binder is compared with that of a common cement-based binder. Influence of the activator/ash ratio, sodium oxide/ash ratio and sodium hydroxide concentration was also analysed. Sodium hydroxide concentrations of 10, 12.5 and 15 molal were used for the alkaline-activated specimens (AA), with activator/ash ratios between 1 and 2.5 and ash percentages of 20, 30 and 40 %, relatively to the total solids (soil + ash). UCS was determined at curing periods of 7, 28, 90 and 365 days, and the most effective mixtures were analysed for mineralogy with XRD. The results showed a clear increase in strength with decreasing activator/ash ratio (up to a maximum of 43.4 MPa), which is a positive result since the activator is the most expensive component in the mixture. Finally, UCS results of the cement and AA samples, at 28 days curing, were very similar. However, AA results proved to be just between 20 and 40 % of the maximum UCS obtained at 1 year curing, while cement results at 28 days are expected to be between 80 and 90 % of its maximum.     

Fish Predation on Juvenile Penaeid Shrimp: Examining Relative Predator Impact and Size-Selective Predation

Predation is likely the primary source of mortality for juvenile penaeid shrimp and, therefore, a key factor driving their population dynamics. We sampled juvenile penaeids and their potential predators in a salt marsh from July to August 2012 to examine the impact of these predators and possible size-selective predation on the shrimp population. We quantified predator impact using the frequency of occurrence (FO) index and a relative predation index (RPI) that accounts for predator abundance and the number of shrimp consumed per individual predator. Size selectivity was assessed by comparing the size distribution of shrimp in the study area to the size distribution of shrimp removed from predator stomachs. Two penaeid species, white shrimp Litopenaeus setiferus and brown shrimp Farfantepenaeus aztecus, were collected, and most (86%) were juvenile white shrimp ≤?12 mm carapace length. Spotted seatrout Cynoscion nebulosus, which consumed relatively large shrimp, was the most important predator based on the FO index. Bay whiff Citharichthys spilopterus, which ate the smallest shrimp, was the most important predator based on the RPI. The size distribution of shrimp removed from predator stomachs differed from those collected in the study area; the smallest shrimp were disproportionally more abundant in predator stomachs. Using the RPI, we identified some potentially important predators (e.g., bay whiff) that may impact shrimp populations by consuming the smallest shrimp in estuarine nurseries. Our approach could be useful for examining predator impacts on other populations of juvenile penaeids and more generally for any prey consumed by fish predators.