Geoelectrical method in the investigation of groundwater resource and related issues in Ophiolite and Flysch formations of Port Blair, Andaman Island, India

Geoelectrical resistivity investigation using Vertical Electrical Sounding (VES) technique was conducted at Port Blair, South Andaman Island, to locate the fractures in different formations and to decipher its groundwater potential. A total of 40 VES were carried out covering the entire study area using Schlumberger electrode configuration out of which 34 VES fall in Andaman Flysch formations and the remaining VES in Ophiolite formations. The interpreted resistivity results were integrated with nine borehole lithologs for the subsurface analysis. The combination of VES with borehole litholog data has provided a close correspondence on subsurface hydrogeological conditions. The interpreted VES data of various formations showed drastic variations in the resistivity ranging from higher in Ophiolite, moderate in Andaman Flysch and very low in valleys of Andaman Flysch formations. The study further revealed that the weathered and fractured volcanics of Ophiolite groups of rocks and sandstone that occur in the Andaman Flysch formations constitute the productive water bearing zones categorized as good groundwater potential zone. Based on the geoelectrical parameters, viz., thickness of layers and the layer resistivity values, a groundwater potential map was prepared, in which good, moderate, and poor groundwater zones were demarcated. Further, numerical, spatial and litho-geoelectric models of resistivity were analyzed in terms of groundwater potential and these models have thus enabled to prepare a comprehensive groundwater development and management plans proving its efficacy in this art of exploratory investigations.     

Paleoseismological investigations along Joggers Park Fault,Port Blair,South Andaman: Implications towards delineation of blind thrusting and related crustal deformation through ground penetrating radar (GPR) and electrical resistivity techniques (ERT and VES)

A comprehensive paleoseismological investigations was carried out along Joggers Park Fault (striking NW-SE) reveals pervasive traces of active compressional tectonics (blind thrusting) and shallow-surface recent tectonic signatures along the fault. The geometry and trends in the tectonic deformation of the blind zone (shallow-subsurface stratigraphy) were examined with GPR and electrical resistivity tomography (ERT) and vertical electrical sounding (VES), strongly demonstrates severe tectonic deformation (persistent tectonic style) from Quaternary to Holocene times in a compressive stress regime. The surface manifestation of deformation (topographic expression) along the fault can be marked as hanging wall uplift and can be visually observed in the exposed sections at nearly half kilometer distance from the table land of Joggers Park in the form of a well-defined disconnected high angle thrust fault scarp (reverse fault). The reverse fault kinematically and intimately linked with underlying fault geometry provides adduced evidence to evaluate strike displacement profiles (displacement length relationship) along the fault. In addition, deformed stacked colluvial wedge below the scarp represents a powerful basis to calibrate recent and long term slip rates of the underlying fault.     

Effectiveness of geophysical surveys for water wells relocation in overexploited aquifers (the example of Maggiore and Traversola Valleys,Northwestern Italy)

Aquifer overexploitation is a common problem in drinking water management. This will become more and more important given the general reduction of water resources. To overcome overexploitation, one of the most adopted solutions is the relocation of extraction wells. To establish the positions of new wells, a precise knowledge of the hydrogeological setting is required. Specific surveys are therefore necessary to obtain information over wide investigation zones. Geophysical methods, particularly electromagnetic and electrical, can be useful with this aim. In the present paper a case history on the combined use of Electric Resistivity Tomography and Time Domain Electromagnetic soundings is reported. Surveys have been performed within the Maggiore and Traversola Valleys, to investigate the uppermost part of the Quaternary deposits, hosting the near surface aquifer. The electromagnetic data have been inverted with a spatially constrained approach by assuming a quasi 1D model of the subsurface. Geophysical surveys allowed for depicting the depth and lateral continuity of the supposed aquifer level in the surveyed area up to a depth of about 200 m and proposing potential positions for well relocation.     

Deciphering As and Cu cycling in sediment pore waters in a large marina (Port Camargue,southern France) using a multi-tracer (Fe,Mn, U,Mo) approach

The sediments of the Port Camargue marina (South of France) are highly polluted by Cu and As (Briant et al., 2013). The dynamics of these pollutants in pore waters was investigated using redox tracers (sulfides, Fe, Mn, U, Mo) to better constrain the redox conditions.In summer, pore water profiles showed a steep redox gradient in the top 24 cm with the reduction of Fe and Mn oxy-hydroxides at the sediment water interface (SWI) and of sulfate immediately below. Below a depth of 24 cm, the Fe, Mn, Mo and U profiles in pore waters reflected Fe and Mn reducing conditions and, unlike in the overlying levels, sulfidic conditions were not observed. This unusual redox zonation was attributed to the occurrence of two distinct sediment layers: an upper layer comprising muddy organic-rich sediments underlain by a layer of relatively sandy and organic-poor sediments. The sandy sediments were in place before the building of the marina, whereas the muddy layer was deposited later. In the muddy layer, large quantities of Fe and Mo were removed in summer linked to the formation of insoluble sulfide phases. Mn, which can adsorb on Fe-sulfides or precipitate with carbonates, was also removed from pore waters. Uranium was removed probably through reduction and adsorption onto particles. In winter, in the absence of detectable pore water sulfides, removal of Mo was moderate compared to summer.Cu was released into solution at the sediment water interface but was efficiently trapped by the muddy layer, probably by precipitation with sulfides. Due to efficient trapping, today the Cu sediment profile reflects the increase in its use as a biocide in antifouling paints over the last 40 years.In the sandy layer, Fe, Mn, Mo and As were released into solution and diffused toward the top of the profile. They precipitated at the boundary between the muddy and sandy layers. This precipitation accounts for the high (75 μg g⁻¹) As concentrations measured in the sediments at a depth of 24 cm.     

Multi-Parametric Approach for Earthquake Precursor Detection in Assam Valley (Eastern Himalaya,India) using Satellite and Ground Observation Data

Geotectonics - In present study soil radon (Rn-222) emanation, geomagnetic total field intensity (Btotal), and total electron content (TEC) in ionosphere prior to Mw 5.5, Kokrajhar, Assam...     

3-D Distribution of Sulphide Minerals in the Merensky Reef (Bushveld Complex, South Africa) and the J-M Reef (Stillwater Complex, USA) and their Relationship to Microstructures Using X-Ray Computed Tomography

Large mafic–ultramafic layered intrusions may containlayers enriched in platinum-group elements (PGE). In many cases,the PGE are hosted by disseminated sulphides. We have investigatedthe distribution of the sulphides in three dimensions in twooriented samples of the Merensky Reef and the J-M Reef. Theaim of the study was to test the hypothesis that the sulphidescrystallized from a base metal sulphide liquid that percolatedthrough the cumulate pile during compaction. The distributionof sulphides was quantified using: (1) X-ray computed tomography;(2) microstructural analysis of polished thin sections orientedparallel to the paleovertical; (3) measurement of dihedral anglesbetween sulphides and silicates or oxides. In the Merensky Reefand the J-M Reef, sulphides are connected in three dimensionsand fill paleovertical dilatancies formed during compaction,which facilitated the downward migration of sulphide liquidin the cumulate. In the melanorite of the Merensky Reef, thesulphide content increases from top to bottom, reaching a maximumvalue above the underlying chromitite layer. In the chromititelayers sulphide melt connectivity is negligible. Thus, the chromititemay have acted as a filter, preventing extensive migration ofsulphide melt downwards into the footwall. This could partiallyexplain the enrichment in PGE of the chromitite layer and theobserved paucity of sulphide in the footwall. KEY WORDS: X-ray computed tomography; microstructures; sulphides; Merensky Reef; J-M Reef     

Vertical distribution of As(III) and As(V) in a coastal sandy aquifer: factors controlling the concentration and speciation of arsenic in the Stuarts Point groundwater system,northern New South Wales,Australia

Arsenic species were measured in a bundled-piezometer installed in the Holocene barrier of the Stuarts Point coastal sands aquifer, northern New South Wales, Australia. Vertical distribution shows two peaks of elevated As concentration. At a depth of 10–11 m, concentrations of As^Tot, As(V) and As(III) are in the range of 52–85, 38–67 and 14–18 μg/l respectively and the ratio of As(V)/As(III) is well above 1 at 3.7–2.7. The second peak, at a depth of 25 m, shows the highest concentrations of As^Tot, As(V) and As(III) with values reaching 337, 125 and 212 μg/l, respectively. The As(V)/As(III) ratio is below 1 at 0.6–0.7. High As^Tot and As(V) concentrations at shallower depths are associated with acidic conditions and very low concentrations of all ions. Desorption of As from Al-hydroxides and As-enriched Fe-oxyhydroxides are plausible mechanisms releasing As into the groundwater system. The elevated concentration of As^Tot and As(III) at 25 m is potentially related to the leaching of the clay surfaces. Elevated HCO₃^- and alkaline pH conditions at this depth cause desorption of As which is later present as As(III) species in the reducing environment. The high concentrations of HCO₃^- further reduce the possible extent of As sorption on Fe and Mn oxyhydroxides. The identification of As in a groundwater system associated with the coastal barrier sand-dune environment raises serious questions of the suitability of human consumption of untreated groundwater, drawn from these aquifer types. Further investigation both in Australia and globally are needed to classified the extent of this hydrogeochemical occurrence near coastal communities that rely on groundwater.     

Assessing soil water content spatio-temporal variability at the hillslope scale in a headwater catchment using a multi variable interpolation model based on EMI surveys (Draix,South Alps,France)

To improve flood prediction in headwater catchments, hydrologists need to know initial soil moisture conditions that precede rain events. In torrential hydrology, soil moisture mapping provides a valuable tool for investigating surface runoff generation processes. In these mountainous environments, soil moisture prediction is challenging because of highly heterogeneous land cover and soil properties. This survey propose a methodology to study spatial soil moisture variations in the mountainous and torrential environment of the Draix Bléone experimental site—Laval 0.86 km². This approach associates water content measurements at the plot scale with spatialized soil bulk electrical conductivity (EC_a) measurements combined in a multivariate statistical analysis based on topographical parameters. Between the summer of 2015 and winter of 2016, four geophysical surveys were conducted under various moisture conditions and along the same pathway, using the Slingram electromagnetic induction (EMI) technique (EM31 device) in horizontal dipole to identify changes in soil properties to a depth of 3 m. These results were analyzed to determine water dynamics in this mountainous catchment. Temporal variations of EC_a vary among land cover types (forest, grassland, and black marl). A significant relationship was observed between EC_a and soil water content (SWC) measured with capacitive sensors in forest and grassland. A multiple linear regression produced using the spatial interpolation code LISDQS shows a significant correlation between EC_a and landform units depicted on a high-resolution DEM. EC_a variations decrease with distance to talwegs. Riparian zones appear as potential hydrological contributing areas with patterns varying according to moisture status. This study shows that multiple linear regression analysis and EMI make it possible to fill gaps between SWC plot measurements, over wide areas that are steep and that present numerous obstacles due to vegetation cover.     

Hydrogeochemical characterization and appraisal of groundwater quality for industrial purpose using a novel industrial water quality index (IndWQI) in the Guanzhong Basin,China

Life and the sustainable growth of socioeconomic sectors such as agriculture and industry depend on groundwater, particularly in arid and semi-arid regions where surface water resources are limited. The objectives of the current study are to characterize groundwater chemistry and assess its suitability for industrial usage in the Guanzhong Basin located in the semi-arid region of northwest China. To better understand the hydrogeochemistry in the study area, statistical analysis, ionic plots and Pearson's correlation analysis were conjunctively used. Finally, a novel industrial water quality index (IndWQI) model was developed in this paper to determine the overall industrial water quality based on scaling, corrosion, and foaming coefficients as well as some physicochemical parameters. The contribution of each parameter to the overall industrial water quality was determined using multivariate statistical analysis approaches. The findings reveal that dissolution of minerals such as calcite, dolomite, anhydrite and gypsum regulate the groundwater geochemistry in the study area. In addition, human activities influence the groundwater quality in the study area. According to the novel IndWQI approach, 78.95 % of the confined water samples and 74.51 % of the phreatic water samples have excellent or good quality, and can be safely used for industrial boilers. The geospatial analysis shows that the most contaminated groundwater samples are mainly located in northeast Xi'an and the northeast region of the Guanzhong Basin. The IndWQI model is trustworthy, as it can combine several water quality indices and give an instantaneous impression of the whole groundwater quality for industrial uses. It can serve as a benchmark for other areas across the world with a comparable climate.     

Understanding groundwater sources and movement using water chemistry and tracers in a low matrix permeability terrain: the Cretaceous (Chalk) Ulster White Limestone Formation,Northern Ireland

The Cretaceous Chalk [Ulster White Limestone Formation (UWLF)] in Northern Ireland has been diagenetically altered to a hard, low porosity, low matrix-permeability rock. It subcrops extensive beneath thick horizontal Tertiary Basalt lavas, but has a restricted strip of outcrop (approximately 80 km²) around the periphery of the overlying igneous rock. Despite its nature and location, numerous springs issue from the Chalk and are used for public and local supply, although little is known about the origin of the groundwater or the type of flow within the Chalk. We have addressed these unknowns using hydrogeochemical data from both rock types and surface stream waters, and fluorescent dye tracing. We have demonstrated that leakage recharge from the basalt to the Chalk accounts for less than 20% of the total water issuing from the Chalk springs using geochemical mass balance of conservative species and discharge data. The majority of the discharge derives from streams coming off the basalt and entering sink holes in the Chalk aquifer. Field and water tracing evidence shows that groundwater flow in the Chalk is dominated by conduit and fissure flow near to the outcrop areas. Karstification has been widespread near outcrop but has not ocurred in the sub-basalt region. Beneath the basalts, the Chalk exhibits different hydraulic properties due to the reduced recharge and dissolution potential that has prevented extensive development of fissure permeability in the UWLF. The Chalk aquifer thus appears to be strongly zoned in terms of the source of water, flow regime and recharge rate.     

离子色谱法测定水样中S2-、SO2-3、SO2-4、S2O2-3

该种方法利用离子色谱仪的电导检测器与电化学检测器串联,十几分钟即可连续完成水中S2-、SO2-3、SO2-4、S2O2-3的测定,方法具有快速、高效、方便、灵敏、选择性好等特点.方法的检出限分别为S2-12.5μg/L;SO2-3 22.4μg/L;SO2-4 5.0μg/L;S2O2-3 5.0μg/L.相对标准偏差在1.5%～6.9%之间,能够满足水中S2-、SO2-3、SO2-4、S2O2-3四种阴离子分析测试的需要.