冻融循环对黄土渗透系数各向异性影响的试验研究

为了反映冻融循环作用对原状黄土渗透各向异性及原状、 重塑黄土渗透差异的影响, 以西安Q₃黄土为研究对象, 通过三轴固结渗透试验对比分析了冻融前后水平、 竖直向原状黄土及重塑黄土的渗透系数随初始含水率、 围压、 冻融循环次数变化的规律。结果表明： 未冻融时各级围压下竖直向原状黄土的渗透系数为2×10^-6 ~ 18×10^-6 cm?s^-1, 水平向原状黄土和重塑黄土的渗透系数为0 ~ 4×10^-6 cm?s^-1; 经历冻融循环后, 水平、 竖直向原状黄土及重塑黄土的渗透系数与初始含水率的关系曲线分别呈现逐渐上升、 抛物线形式与变化平缓的不同特征, 而三者的渗透系数均随冻融循环次数的增加呈现数量级增大的趋势; 原状黄土的竖直 - 水平渗透系数比（k_v /k_h ）由冻融前的4.38逐渐减小到0.90, 可见冻融循环作用在显著提高黄土渗透性能的同时, 可以强烈弱化其各向异性特征。通过建立围压、 渗透系数与土体孔隙率的相关关系可知, 原状、 重塑黄土的孔隙率与围压存在极强的负线性相关性, 渗透系数随围压的增大呈典型指数衰减特征, 渗透系数与孔隙率具有相似的变化趋势, 因此冻融循环过程中土体孔隙率的改变是导致其渗透性质变化的主要原因。     

辽河古裂谷东斜坡北端热流值测定

辽河盆地在大地构造位置上属冀鲁断块和胶辽断块的一部分,是在稳定地块上发育的第三纪古裂谷。选取热流值测定的红阳煤田三井田的井检23孔和944孔位于辽河古裂谷东斜坡北端(图1)。     

Seepage and consolidation of bentonite saturated with pure- or salt-water by the method of unified molecular dynamics and homogenization analysis

Bentonite clay is a micro-inhomogeneous material, which consists of clay minerals (mainly montmorillonite), macro-grains (mainly quartz), water, air and others. Properties of the saturated bentonite clay are essentially characterized by the montmorillonite and water (i.e. montmorillonite hydrate). We analyze the molecular behavior of sodium montmorillonite hydrate Na_1/3Al₂[Si_11/3Al_1/3]O₁₀(OH)₂·nH₂O by applying a molecular dynamics (MD) simulation method. And by using the MD results we calculate the swelling property of the montmorillonite hydrate, and compare with an experimental result. Next, by using the same MD procedure we treat a montmorillonite mineral with a large number of external water molecules to check the properties of the water. Here we treat pure- and salt-water. Then we calculate the diffusivity and viscosity of water molecules and Na⁺ and Cl⁻ ions.

For extending the microscopic characteristics of constituent materials to a macroscopic seepage behavior of the micro-inhomogeneous material we apply a homogenization analysis (HA). That is, starting with the Navier–Stokes equation with distributed viscosity that is calculated by the former MD procedure we determine macroscopic permeability characteristics of bentonite for both cases of pure- and salt-water. Then, by using the permeability property we calculate long-term consolidation behavior of buffering clay, which is planed to be used for high-level radioactive waste (HLRW) management. Here the deformation is treated under the well-defined Cam clay model.     

Plutonium diffusivity in compacted bentonite

Measurements on plutonium diffusivity in water-saturated compacted bentonite were carried out. Representative specimens of sodium bentonite were taken from the Tsukinuno and Kuroishi mines situated in northeast Japan. Tsukinuno bentonite was divided into three types: raw type, purified Na-type, and H-type which was prepared by treating Na-type bentonite with hydrochloric acid. Kuroishi bentonite contained chlorite as impurity. H-type bentonite was used as reference for the convenience of profile measurement in bentonite, since plutonium diffusivity in H-type bentonite was considered to be larger than that in Na-type bentonite because of low pH and low swelling pressure of H-type bentonite.

Sampled bentonite was compacted into pellets of 20 mm in diameter and 20 mm in height. Bulk densities of these specimens were 1200–1800 kg/m³ for purified Na-type and H-type bentonite and 1600 kg/m³ for raw type bentonite.

Plutonium profiles obtained in H-type bentonite can be explained by diffusion equation with constant concentration source. Diffusivity ranges from 10^-13 to 10¹² m²/s for H-type and Kuroishi impure sodium bentonite. Diffusivity in both raw type and purified Tsukinuno bentonite was was estimated to less than 10^-14 M²/s. Diffusivity in H-type bentonite showed a tendency to decrease with increasing density. Influence of in bentonite was also studied. Quartz content up to 50% or hematite content up to 1% did not influence diffusivity significantly in H-type bentonite.

The chemical species of plutonium in pore water of Na-type and H-type were estimated Pu(OH)₃^-; and PuO₂^- , respectively.     

Crushed aggregate—bentonite mixtures as backfill material for repositories of low- and intermediate level radioactive wastes

The candidate backfill materials for the repositories of low- and intermediate-level radioactive wastes consist of three components: crushed rock aggregate, finely ground rock aggregate and bentonite. The hydraulic conductivity of mixtures with 15% of sodium bentonite is approximately 5 · 10^-9m/s based on the laboratory tests. The sweling potential for the same material varies between 20 and 60 kPa depending mainly on the salinity of the groundwater.     

东濮凹陷上古生界石千峰组致密砂岩储层特征

东濮凹陷上古生界石千峰组发育一套厚度较大且具有勘探潜力的河流-湖泊相致密砂岩。采用岩心观察、薄片鉴定、扫描电镜、阴极发光、X衍射全岩及黏土矿物分析等技术手段,对东濮凹陷上古生界石千峰组致密砂岩储层的岩石学特征、物性特征和成岩作用进行了分析。结果表明:储层岩石类型主要为岩屑长石砂岩和长石岩屑砂岩;孔隙度2%~10%,渗透率(0~1)10^-3m²,整体上表现出特低孔超低渗特点;成岩作用主要为压实、压溶、胶结、溶蚀和交代作用。样品古地温、镜质体反射率(R_o,%)和X衍射黏土矿物分析结果进一步证实研究区石千峰组砂岩储层属于中成岩阶段A期。     

黑龙江省嫩江—黑河构造混杂岩带科洛金矿床成因:来自黄铁矿化学成分及He-Ar、S、Pb同位素证据

科洛金矿床位于黑龙江省嫩江—黑河构造混杂岩带中,为一正在勘查的中型金矿床。前人研究认为该矿床为一中温、富水、低盐度的韧性剪切带型金矿床。但随着勘查工作的持续开展,新发现了大量含多金属硫化物的石英脉型矿石。为进一步明确该矿床成因,对科洛金矿床内韧性变形和浸染状-团块状两种不同产状黄铁矿进行了系统的成分标型及稳定同位素特征研究。结果表明:韧性变形黄铁矿较浸染-团块状黄铁矿的S/Fe值低,Au、Ag、Co含量高,As含量低,总体显示韧性变形黄铁矿相对贫硫;黄铁矿微量元素显示两类黄铁矿REE具有相似的地球化学特征,整体呈轻稀土富集、重稀土亏损的“右倾”式稀土配分模式。稀土元素总量为17.00×10^-6~66.95×10^-6,韧性变形黄铁矿含量明显偏低,LREE/HREE值为5.25~12.50,相对较稳定。Y/Ho值与地幔和地壳重合范围较多,Zr/Hf值、Nb/Ta值变化范围较大,显示成矿环境不稳定;黄铁矿³He含量为2.405×10^-13~10.811×10^-13,⁴He含量为3.35×10^-7~4.99×10^-7,³He-⁴He图和R/R_a-⁴⁰Ar/³⁶Ar图显示成矿流体有以地幔为主的壳幔混源特征,成矿过程应有大气降水的参与;黄铁矿δ³⁴S变化范围小,集中在+2.3‰~+7.6‰(韧性变形黄铁矿δ³⁴S平均值偏低),稍正向偏离陨石硫特征;黄铁矿的²⁰⁶Pb/²⁰⁴Pb=18.157~18.211;²⁰⁷Pb/²⁰⁴Pb=15.542~15.594;²⁰⁸Pb/²⁰⁴Pb=38.032~38.218(韧性变形黄铁矿的²⁰⁶Pb/²⁰⁴Pb、²⁰⁷Pb/²⁰⁴Pb、²⁰⁸Pb/²⁰⁴Pb平均值偏低),均显示与造山作用关系密切。利用黄铁矿化学成分特征元素Co/Ni值及Co-Ni成因判别图解认为科洛金矿有热液成因矿床特征;利用w(Fe+S)-w(As)图解和Co-Ni-As含量图解显示石英脉型矿石反映浅成低温热液型金矿特征。综合区域变质变形事件、典型矿床特征及矿区内已取得的年龄、流体包裹体等相关数据认为,科洛金矿床应存在两期矿化:三叠纪形成的韧性剪切带型金矿床和白垩纪形成的浅成低温热液型金矿床。建议在今后的矿产勘查中注意寻找真正的韧性剪切带型金矿。     

超压背景下中深层砂岩储集层沉积—成岩演化差异性分析: 以南海莺歌海盆地中新统黄流组为例*

南海莺歌海盆地内地层普遍发育超压,东方区和乐东区是莺歌海盆地天然气成藏有利区的核心地带。其中,东方区位于底辟带中心,超压形成时间较早(9—5 Ma),主要物源来自西部昆嵩隆起区;乐东区位于莺东斜坡带,超压形成时间较晚(5—2 Ma),主要物源区为东部海南隆起区。本研究通过铸体薄片、荧光薄片、扫描电镜、电子探针、含烃包裹体微束荧光分析、流体包裹体激光拉曼成分与均一温度、X射线衍射黏土矿物等分析测试研究方法,对东方区和乐东区超压背景下黄流组砂岩储集层的岩石学与物性特征、烃类充注与成岩作用特征进行对比分析。结果显示: (1)东方区黄流组砂岩的压实作用、胶结作用较弱,物性较好(平均孔隙度17.68%,平均渗透率11.11×10^-3 μm²),处于中成岩A期晚期;乐东区黄流组砂岩整体压实作用、胶结作用较强,物性较差(平均孔隙度8.94%,平均渗透率1.52×10^-3 μm²),处于中成岩B期。(2)研究区储集层物性主要受沉积作用、超压背景和成岩作用的控制。物源、沉积中心与沉降中心、沉积相类型,超压形成时间和烃类充注规模共同影响了储集层的成岩作用特征及成岩—孔隙演化过程。(3)超压在一定程度上抵抗了压实作用强度,抑制了胶结作用,促进了溶蚀作用。     

超压背景下中深层砂岩储集层沉积—成岩演化差异性分析: 以南海莺歌海盆地中新统黄流组为例*

南海莺歌海盆地内地层普遍发育超压,东方区和乐东区是莺歌海盆地天然气成藏有利区的核心地带。其中,东方区位于底辟带中心,超压形成时间较早(9—5 Ma),主要物源来自西部昆嵩隆起区;乐东区位于莺东斜坡带,超压形成时间较晚(5—2 Ma),主要物源区为东部海南隆起区。本研究通过铸体薄片、荧光薄片、扫描电镜、电子探针、含烃包裹体微束荧光分析、流体包裹体激光拉曼成分与均一温度、X射线衍射黏土矿物等分析测试研究方法,对东方区和乐东区超压背景下黄流组砂岩储集层的岩石学与物性特征、烃类充注与成岩作用特征进行对比分析。结果显示: (1)东方区黄流组砂岩的压实作用、胶结作用较弱,物性较好(平均孔隙度17.68%,平均渗透率11.11×10^-3 μm²),处于中成岩A期晚期;乐东区黄流组砂岩整体压实作用、胶结作用较强,物性较差(平均孔隙度8.94%,平均渗透率1.52×10^-3 μm²),处于中成岩B期。(2)研究区储集层物性主要受沉积作用、超压背景和成岩作用的控制。物源、沉积中心与沉降中心、沉积相类型,超压形成时间和烃类充注规模共同影响了储集层的成岩作用特征及成岩—孔隙演化过程。(3)超压在一定程度上抵抗了压实作用强度,抑制了胶结作用,促进了溶蚀作用。     

超深层砂岩粘土矿物特征及其对储层物性的定量控制作用——以库车前陆冲断带白垩系巴什基奇克组为例

库车前陆冲断带超深层储层是当前天然气勘探开发的重要领域, 具有特低孔、特低渗-低渗, 裂缝-孔隙型, 测试高产储集特征。 为揭示储层中粘土矿物的特征及其对储层演化、储层性质的控制作用, 本文以大量微观实验分析（X 衍射、扫描电镜、激光共聚焦扫描、 铸体薄片、高压压汞）为依据, 研究表明：主要的粘土矿物含量为 5%～12%, 矿物类型以伊利石、伊蒙混层为主, 其次为绿泥石, 成因以成岩早期沉积水体继承性沉淀及成岩中晚期长石质次生溶蚀产物为主;砂岩中早期沉积型粘土矿物主要富集于三角洲前缘水下河道砂体的侧缘、水道砂体的顶底面附近, 其形成粘土薄膜可有效抑制超深层储层早中成岩期硅质、长石质次生加大, 保存基质孔隙, 不同期粘土杂基也可提供大量矿物晶间微孔隙, 微孔隙度可达 1%～4%, 是天然气的主要储集空间之一;粘土矿物是降低储层渗透率的主控因素, 6%～ 9%的粘土矿物含量（尤其是伊利石及伊蒙混层）可降低超深层储层渗透率 10～100 倍, 使渗透率总体为 0.01×10 ^-3 μm ² ～0.1×10 ^-3 μm ² 。 粘土矿物含量及赋存特征：早期长期（130～23 Ma）浅 埋（< 3 000 m）期储集性能保存良好, 晚期（23 Ma 左右）深埋（> 3 000 m）期基质渗透性急剧降低, 总体致密化（< 0.1×10 ^-3 μm ² ）, 这是研究区的关键因素。 粘土矿物的特征及其分布对评价砂岩储集性质, 预测超深层天然气有利储层的分布具有重要地质意义。     

松辽盆地北部中二叠统碳酸盐岩元素和稳定同位素地球化学特征与古环境

松辽盆地中二叠统哲斯组发育一套暗色泥岩、灰色砂砾岩与灰岩沉积组合,灰岩中产海相腕足类和双壳类化石。由于受钻井进尺和取心资料限制,前人对盆地覆盖区晚古生代地层及其沉积环境研究较少。对采自松辽盆地杜101井、杜103井剖面哲斯组的白云质灰岩进行了系统的稳定同位素和微量元素、稀土元素分析,首次获取了盆地覆盖区中二叠统灰岩元素地球化学资料。测试结果显示碳同位素δ¹³C_PDB值一般>0(均值为1.68‰),氧同位素δ¹⁸O_PDB值全部<-15‰(均值为-19.98‰),碳、氧稳定同位素关系图解显示二者呈正相关关系,表明白云岩化作用对灰岩同位素改造作用明显。稀土元素(REE+Y)总量为56.88×10^-6~143.72×10^-6,均值为108.92×10^-6,PAAS标准化后显示具有轻稀土相对于中稀土和重稀土亏损、δEu(均值0.94,最大值1.57)负异常、δCe(均值0.87,最大值1.06)普遍负异常和相对高的Y/Ho均值(均值34.59)等特点,与正常海相具有大体相同的稀土元素配分模式;而微量元素Ba(均值281.55×10^-6)、Zn(均值71.91×10^-6)、Y(均值17.44×10^-6)、Zr(均值117.75×10^-6)和Rb(均值66.84×10^-6)等元素含量整体较高,Sr/Ba(均值2.91)、Th/U(均值2.75)、V/Cr(均值1.45)和V/(V+Ni)(均值0.66)等比值适中,指示研究区哲斯组沉积时期主体为一种频繁受陆源碎屑混染作用影响的碳酸盐台地或滨海岸环境。     

恒河-雅鲁藏布江流域雪线场的建立及其环境意义

利用冰川编目最新数据资料,计算恒河-雅鲁藏布江冰川平均高度(H_me)与测量雪线(ELA_h)之间的回归方程,发现冰川系统越大,样本数越多,则相关性越好,从而建立大系统的回归方程计算系统内所有冰川样点的计算雪线高度(ELA_hc).对所求得的ELAhc采用10’×10’的格网覆盖区域,对格网内样点的经纬度和计算雪线高度进行算术平均,用Kriging插值生成一定间隔的雪线分布图,即雪线高度场.把所得结果与该区域已有研究对比,发现它除具有共同的基本规律外,还更能体现出西藏南部雪线场的详尽分布规律,如全流域从下游向上游按照平均雪线高度的大小可以分为4个区,不同区域的雪线分布反映了影响区域雪线分布的主导因素.此方法可应用于其它已进行冰川编目的地区,也可建立不同尺度的温度场、积累场、降水场等冰川特征值场.     

Modification of physical, mechanical and hydraulic properties of bentonite by thermo-hydraulic gradients

The conditions of the bentonite in an engineered barrier for high-level radioactive waste disposal have been simulated in a series of tests. Cylindrical cells with an inner length of 60 cm and a diameter of 7 cm have been constructed. Inside the cells, six blocks of FEBEX bentonite have been piled-up, giving rise to a total length similar to the thickness of the clay barrier in a repository according to the Spanish concept. To obtain the blocks, the clay with its hygroscopic water content has been uniaxially compacted at a dry density of 1.65 g/cm³. The bottom surface of the material was heated at 100 °C and the top surface was injected with granitic water. The duration of the tests was 6, 12 and 24 months. The temperatures inside the clay and the water intake were measured during the tests and, at the end, the cells were dismounted and the dry density, water content and some hydro-mechanical properties of the clay (permeability, swelling pressure and swelling under load) were measured at different positions. The values obtained are compared to those of the untreated FEBEX bentonite. The injection of water provokes in the vicinity of the hydration surface an increase of the water content and a decrease of the dry density due to the swelling of the clay, while heating gives rise to an increase of the dry density and a reduction of the water content in the 18 cm closest to the heater, even after 2 years of thermo-hydraulic (TH) treatment. The swelling capacity and the hydraulic conductivity after TH treatment are mainly related to the dry density and water content attained during it. No major irreversible modifications of these properties with respect to those of the untreated clay have been detected.     

The combined effect of clay and moisture content on the behavior of remolded unsaturated soils

The behavior of unsaturated clayey soil is highly influenced by the coupled interaction between water and clay content. Various aspects of the behavior of artificial clay–sand mixtures with variable water content were experimentally studied. Laboratory tests were utilized for the determination of consistency limits, the stress–strain relationship, strength parameters, hydraulic conductivity, and volume change characteristics for various combinations of water and clay content in soil mixtures.

Results presented for various clay–sand mixtures include: new normalized consistency limits; the combined effect of clay content and water content on the stress–strain relationship and on the strength parameters (c and φ); and the effect of clay content on hydraulic conductivity and swelling potential. The cohesion of clayey sand is found to increase with increasing water content to a certain limit, above which it decreases. The angle of internal friction for clayey sand is found generally to decrease with increasing water content. The degree of saturation is found to be better than the water content in explaining the strength behavior. The hydraulic conductivity sharply decreases with increasing clay content up to 40% beyond which the reduction becomes less significant. Simple empirical equations are proposed for predicting the swelling potential of clayey soils as a function of either the clay content or plasticity index.     

Effects of temperature on strength and compressibility of sand-bentonite buffer

Dense sand-bentonite buffer (γ_d = 1.67Mg/m³) has been proposed in Canada as one of several barriers for isolating nuclear fuel waste. The buffer will be required to function under conditions of high total pressures and elevated temperatures approaching 100°C. Summary results are presented from two test programs: (1) isothermal consolidated undrained triaxial (CIU¯) tests; and (2) isothermal drained constant-p′ (CID) triaxial tests. Specimens were consolidated at effective stresses up to 9.0 MPa and temperatures up to 100°C.

The results indicate parallel hardening lines at systematically lower values of specific volume at elevated temperatures. In shear, increased temperatures produced lower values of maximum deviator stressq_f, and higher pore water pressure changesΔu_f. The net result is curved peak strength envelops in plots ofq_f versusp_f′ that are higher at elevated temperatures, even though the strengths,q_f of individual specimens are lower. The critical state strength envelope is curved inq, p′-planes.

The effect of drained heating on buffer to 100°C is not marked. Compressibilities, stiffnesses, strengths, and pore water pressure generation are all affected, but none of the changes are great.     

油页岩原位开采区注浆封闭浆液优化及其防渗效果实验

为提高油页岩原位转化加热效率、减少油气污染,采用注浆技术对油页岩开采区进行封闭止水。基于扶余油页岩开采区地质条件,对优化封闭浆液配方与封闭效果进行实验研究。首先基于正交试验,获得了不同指标下的优化配方,进而通过综合分析法,选出符合此封闭区要求的优化配方;为了验证优化浆液的封闭效果,对比分析了浆液充填前后油页岩试样渗透率的变化。结果表明：浆液优化配方为水灰质量比0.85,w（钠基膨润土）4.0%、w（微硅粉）6.0%、w（聚羧酸减水剂）0.5%;当围压为扶余油页岩开采区地应力时,充填浆液试样的渗透率均约为0.1×10^-3 μm²,远低于未充填的试样,优化浆液封堵试样裂缝效果较好。     

溶液和温度作用下膨润土防水毯的渗透性能

以颗粒状和粉末状膨润土防水毯(GCLs)为对象,运用GDS (global digital systems)全自动渗透仪开展渗透试验,研究CaCl_2溶液作用下GCLs渗透性能的温度效应,初步探讨其机理。试验表明:当水化液为0.05mol/L的CaCl_2溶液时,两种GCLs渗透系数随温度升高呈现增大趋势;当水化液为去离子水时,颗粒状GCL渗透系数随温度升高而减小,粉末状GCL渗透系数随温度升高而增大。去离子水情况下,膨润土吸附结合水量随温度升高而减小;CaCl_2溶液作用下,吸附结合水量较去离子水情况大幅降低。当CaCl_2溶液浓度一定时,膨润土膨胀指数随温度升高而略有增大;当温度一定时,膨润土膨胀指数随CaCl_2溶液浓度升高而显著减小。以去离子水进行试验时:颗粒状和粉末状GCLs渗透系数随温度的变化主要影响因素为凝胶态蒙脱石数量,其次为流体黏滞系数和吸附结合水量;颗粒状GCLs膨润土孔隙结构越不均匀,凝胶态蒙脱石数量的影响就越显著,导致渗透系数随温度升高而减小、固有渗透率随温度升高显著降低。以CaCl_2溶液进行试验时,两种GCLs渗透系数随温度变化的主要受流体黏滞系数和吸附结合水量的影响,而受凝胶态蒙脱石数量的影响较小。孔隙溶液性质、温度和膨润土类型均对GCLs的防渗性能具有重要影响。     

Geological characteristics and favorable areas prediction of shale gas in Wufeng-Longmaxi Formation in Zheng’an area of Northern Guizhou

In order to determine the shale gas geological characteristics of Wufeng Formation in upper Ordovician and Longmaxi Formation in Lower Silurian of Zheng'an area in Northern Guizhou, the authors used geology survey,gravity,magnetic,two dimensional seismic,geological well and test analysis methods to carry out 1:50000 shale gas basic geology survey. The distribution, depositional environment, organic geochemical, mineral composition, reservoir properties and hydrocarbon content and other characteristics of Wufeng-Longmaxi Formation rich organic shale were obtained. The results show that the rich organic shale belongs to deep water continental shelf facies, mainly distributed in Anchang, Banzhu and Nigao syncline, with a thickness of 14.5-55 m and burial depth of 0-3 200 m. The TOC content is between 1.0% and 4.0%, and the vitrinite reflectance (R_o) is between 1.82% and 2.23%, with the organic matter type mainly I kerogen. The rocks are mainly composed of quartz, feldspar and clay minerals. The brittle mineral content is high, generally more than 50%. The porosity is generally between 2.03% and 3.89%,and the permeability is generally between 0.35×10^-5 μm² and 1.86×10^-5 μm², showing the characteristics of low porosity and low permeability. The highest gas content is 2.88m³/t, showing good gas content characteristics. Three favorable target areas for the shale gas in Zheng’an area were identified through comprehensive analysis and evaluation optimization, that is Anchang,Banzhu and Nigao block respectively, which provides exploration direction for shale gas exploration and development in the study area.     

黔北正安地区五峰组—龙马溪组页岩气地质特征及有利区预测

为明确黔北正安地区上奥陶统五峰组至下志留统龙马溪组的页岩气地质特征,充分应用页岩气地质调查、重磁电、二维地震、地质调查井及测试分析等工作方法,开展黔北正安地区1:5万页岩气基础地质调查,对五峰组至龙马溪组富有机质页岩的分布、沉积环境、有机地球化学、岩石矿物、储集性能及含气性等特征进行分析研究,结果表明: 研究区五峰组—龙马溪组富有机质页岩为深水陆棚相沉积,主要分布有安场向斜、斑竹向斜和泥高向斜,厚度14.5~55 m,埋深0~3 200 m; 有机碳(TOC)含量1.0%~4.0%,有机质镜质体反射率(R_o)为1.82%~2.23%,有机质类型以Ⅰ型干酪根为主; 岩石主要由石英、长石和黏土矿物组成,脆性矿物含量高,一般大于50%; 孔隙度为2.03%~3.89%,渗透率为0.35×10^-5~1.86×10^-5μm²,表现为低孔、特低渗的特征; 最高含气量为2.88 m³/t,显示出较好的含气性特征。综合分析和评价圈出3个页岩气聚集有利区,分别为安场区块、斑竹区块和泥高区块,这为研究区页岩气进一步勘探开发指明了方向。     

稀有金属矿物溶解度对花岗伟晶岩成矿作用的制约

花岗伟晶岩型矿床是稀有金属矿床重要的类型之一。在花岗伟晶岩中,稀有金属元素Li、Be、Nb和Ta主要以独立矿物的形式存在,前人对稀有金属独立矿物在硅酸盐熔体中的溶解度及其影响因素展开了系统研究。本文综合分析了已有的实验数据,其结果表明,影响稀有金属独立矿物溶解度最为重要的2个参数是温度(T)和铝饱和指数(ASI)。因此本文建立了稀有金属独立矿物,尤其是铌锰矿和钽锰矿溶解度,与温度(T)和铝饱和指数(ASI)之间的定量关系: lg [w(Li)/10^-6]=-0.37×[1 000/(T/K)]+4.56,R²=0.44 lg [w(BeO)/10^-6]=-4.21×[1 000/(T/K)]+6.86,R²=0.91 lg [K_sp(Nb)/(mg²·kg^-2)]=-(2.86±0.14)×ASI_(Mn+Li)-(4.95±0.31)×[1 000/(T/K)]+(4.20+0.28),R²=0.86 lg [K_sp(Ta)/(mg²·kg^-2)]=-(2.46±0.11)×ASI_(Mn+Li)-(4.86±0.30)×[1 000/(T/K)]+(4.00+0.30),R²=0.80 式中,温度T为热力学温度,ASI_(Mn+Li)(ASI=Al₂O₃/(CaO+Na₂O+K₂O+Li₂O+MnO),摩尔分数比)和T的适用范围分别为0.6~1.2和1 073~1 373 K的范围内。上述公式为估算硅酸盐熔体中稀有金属含量提供了便利,为量化花岗伟晶岩成矿模型提供了基础。 稀有金属独立矿物溶解度随温度降低和铝饱和指数的增加而急剧降低,因此,在岩浆演化过程中,由岩浆侵位、分离结晶以及流体作用等因素引起的岩浆温度降低和铝饱和指数的增加,是导致稀有金属独立矿物结晶的主要机制。