Plagioclase breakdown and regeneration reactions in Grenville kyanite eclogite at Glenelg,NW Scotland

A rare type of eclogite at Glenelg contains finegrained, white streaks about 1 mm across consisting of kyanite-oligoclase ±quartz ±Kfeldspar. Garnet and omphacite bordering the streaks are relatively enriched in grossular and jadeite components respectively. The streaks are interpreted as former plagioclase which reacted with neighbouring garnet and omphacite during a period of shearing and compression. P-T conditions during the reaction are estimated as 740° C and 17 kbar. Subsequent reaction, manifest by narrow rims of oligoclase on kyanite, new growth of garnet and resorption of omphacite, is interpreted as an effect of near-isothermal decompression by about 2 kbar. The compressive phase is attributed to dextral transpression (oblique convergence) along the Grenville Front in Scotland.     

Metamorphism of the Scourian Complex, NW Scotland

The rocks of the Scourian Complex have been intensively studied, but there is still no consensus as to the conditions of the granulite-facies metamorphism preserved in these rocks. Recent estimates of these conditions fall into two groups, one at 820-920°C and ca. 11 kbar and the second at ca. 1000°C and >12 kbar. Investigation of a variety of rocks shows that the recorded conditions vary with grain-size, with higher-grade conditions recorded by the cores of coarser ( ca. 10 mm) crystals, and lower-grade conditions recorded by the rims of coarser grains and by finer grains. This observation suggests that re-equilibration during recovery of these rocks to the surface has been important which may account for the discrepancy in estimated P-T conditions. Revised estimates of the equilibration conditions of the Scourian Complex of T > 1000°C and P > 8.5 kbar are presented. The conditions suggested for the peak of metamorphism mean that the role of anatexis in the genesis of these rocks must be considered and the nature of the fluid phase thoroughly investigated.     

A study of fluted moraines in the Torridon area,NW Scotland

A study of certain small-scale fluted moraines, all less than 4m high but up to 400m long, in the Torridon area has shown that they are subglacial features composed of a clast-rich till, and formed in the Loch Lomond Stadial beneath ice with a maximum depth of 100-200m. The evidence from lithological analysis of till samples from the fluted moraines suggests that they were formed by subglacial deformation of a pre-existing till with little in the way of net down-glacier movement of the material.     

High-temperature,high-pressure granulites (retrogressed eclogites) in the central region of the Lewisian,NW Scotland: Crustal-scale subduction in the Neoarchaean

Eclogites and associated high-pressure (HP) rocks in collisional and accretionary orogenic belts preserve a record of subduction and exhumation, and provide a key constraint on the tectonic evolution of the continents. Most eclogites that formed at high pressures but low temperatures at > 10–11 kbar and 450–650 °C can be interpreted as a result of subduction of cold oceanic lithosphere. A new class of high-temperature (HT) eclogites that formed above 900 °C and at 14 to 30 kbar occurs in the deep continental crust, but their geodynamic significance and processes of formation are poorly understood. Here we show that Neoarchaean mafic–ultramafic complexes in the central granulite facies region of the Lewisian in NW Scotland contain HP/HT garnet-bearing granulites (retrogressed eclogites), gabbros, lherzolites, and websterites, and that the HP granulites have garnets that contain inclusions of omphacite. From thermodynamic modeling and compositional isopleths we calculate that peak eclogite-facies metamorphism took place at 24–22 kbar and 1060–1040 °C. The geochemical signature of one (G-21) of the samples shows a strong depletion of Eu indicating magma fractionation at a crustal level. The Sm–Nd isochron ages of HP phases record different cooling ages of ca. 2480 and 2330 Ma. We suggest that the layered mafic–ultramafic complexes, which may have formed in an oceanic environment, were subducted to eclogite depths, and exhumed as HP garnet-bearing orogenic peridotites. The layered complexes were engulfed by widespread orthogneisses of tonalite–trondhjemite–granodiorite (TTG) composition with granulite facies assemblages. We propose two possible tectonic models: (1) the fact that the relicts of eclogitic complexes are so widespread in the Scourian can be taken as evidence that a > 90 km × 40 km-size slab of continental crust containing mafic–ultramafic complexes was subducted to at least 70 km depth in the late Archaean. During exhumation the gneiss protoliths were retrogressed to granulite facies assemblages, but the mafic–ultramafic rocks resisted retrogression. (2) The layered complexes of mafic and ultramafic rocks were subducted to eclogite-facies depths and during exhumation under crustal conditions they were intruded by the orthogneiss protoliths (TTG) that were metamorphosed in the granulite facies. Apart from poorly defined UHP metamorphic rocks in Norway, the retrogressed eclogites in the central granulite/retrogressed eclogite facies Lewisian region, NW Scotland have the highest crustal pressures so far reported for Archaean rocks, and demonstrate that lithospheric subduction was transporting crustal rocks to HP depths in the Neoarchaean.     

Lateglacial to early Holocene multiproxy record from Loch Assynt,NW Scotland

A core, recovered from a water depth of 53 m in Loch Assynt, North-West Scotland, has yielded a 9 m sequence comprising two distinct units, an upper, organic-rich unit (Unit I, ca. 6 m) overlying a sequence of laminated clays, silts and sands (Unit II, ca. 3 m). The upper unit is essentially Holocene in age based upon three bulk AMS radiocarbon dates while a fourth radiocarbon date from Unit II confirms a late-glacial age for that interval and supports a broadly linear age–depth relationship. Distinct variations in the magnetic susceptibility record of the lower unit can be visually correlated to major changes in the Greenland ice core (GISP2), this together with pollen evidence supports the radiocarbon dating suggesting an age of approximately 11,000 to around 17,000 cal. BP for Unit II, with evidence for the Younger Dryas (Loch Lomond) stadial and the Bolling–Allerød climatic phases. Variations in the magnetic susceptibility record of the late-glacial sediments are thought to relate to climatically driven changes in soil cover and erosion rates. The multiproxy record from Loch Assynt indicates relatively continuous, sub-aqueous sedimentation during the last ～17,000 years, providing an approximate age for the initiation of modern Loch Assynt and supporting recent dates of moraine retreat lines in the Loanan Valley from about 14–15 ka BP. Pollen and chironomid sampling provides further insights to the history of this relatively deep water body and compliment existing high-resolution palaeo-precipitation records for the mid to late Holocene interval from speleothem archives within the loch catchment.     

A clinoenstatite-bearing cumulate Olivine Pyroxenite from Howqua,Victoria

The Howqua Olivine Pyroxenite of eastern Victoria, Australia, intrudes a metamorphosed sequence of Cambrian high-Mg lavas. It crystallized an unusual mineral assemblage: Cr-rich magnesiochromite, olivine (Fo₉₄), and protoenstatite (now inverted to polysynthetically-twinned clinoenstatite). Residual liquid crystallized strongly-zoned interstitial pyroxenes followed by pargasite. Pargasite, often showing quench habit, crystallized in interstitial glass which is now altered to serpentine.The extremely refractory nature of the cumulus phases indicates a very high temperature of crystallization for liquidus olivine and chromite from a high-MgO, low-Al₂O₃ parent liquid similar in some respects to Archaean peridotitic komatiites. The suggested origin by hydrous melting of depleted mantle peridotite, plus other compositional and mineralogical similarities (especially the olivine-liquid reaction producing protoenstatite) indicate that the parent magma of the Howqua Olivine Pyroxenite had many features in common with the high-SiO₂, high-MgO clinoenstatite-bearing boninitic lavas of the Western Pacific. It is interpreted as a more extreme melt with affinities to boninite and it demonstrates that ultramafic magmas existed in the Cambrian.     

Microstructural and fabric studies from the rocks of the Moine Nappe,Eriboll, NW Scotland

Microstructures and quartz c-axis fabric diagrams from mylonites and psammitic Moine schists, collected in traverses across the lower levels of the Moine Nappe in the Eriboll area, are presented. On approaching the Moine Thrust from the Kyle of Tongue, the following microstructural sequence is encountered: interlayered coarse grained biotite psammitic and schistose tectonites being in part mylonitic with two platy slide zones, one containing biotite and the other only muscovite and chlorite and both showing quartz microstructures indicative of post-tectonic relaxation; these pass into more mylonitic rocks nearer the thrust zone which in turn passes into the main chlorite-grade mylonite belt and finally, adjacent to the Moine Thrust, into reworked lower chlorite grade mylonites. Although there is some local variation, the overall quartz c-axis fabric is an incomplete asymmetric type I girdle. The main variation is the development of type II girdles in the reworked, ultrafine grained mylonites. The extent of the mylonitization is more extensive than previously reported. Studies of folds within the mylonite belt have revealed eye structures and small-scale folds; many are sheath folds. They cannot be unequivocally correlated with large-scale recumbent folds within the Moine Nappe. The results presented indicate that mylonitization is not limited to a single phase, and raises the possibility that there may be earlier Caledonian or possibly Precambrian structural elements present in the Eriboll region Moines prior to much of the mylonitization.     

Quartz microfabric of the Laxfordian Canisp Shear Zone,NW Scotland

The Canisp Shear Zone transects layered Lewisian gneisses near Lochinver, NW Scotland. It is a vertical ductile shear zone with a dextral shear sense, formed during Laxfordian amphibolite facies metamorphism, transposing the layering to new foliation and linear structures. Minerals in the layered gneisses show little or no shape fabric, while a strong shape fabric defines the foliation. For quartz, this shape fabric is accompanied by development of a preferred crystal orientation with fabric patterns reflecting the geometry of the shear deformation. The quartz fabric shows a pole-free area around the lineation with the c-axes concentrated in an asymmetric cross-girdle or a point maximum perpendicular to the shear plane, and a monoclinic symmetry consistent with the shear sense.     

Garnet-pyroxene thermometry and barometry in the Scourie granulites,NW Scotland

Garnets and pyroxenes from granulites ranging in composition from trondhjemitic to ultramafic were analysed with the electron probe in order to test current geothermometric and geobarometric models. A consistent pressure and temperature estimate based on garnet-pyroxene equilibria shows that the peak of metamorphism was at $\text{820±50°}\text{C}$ and 11 kb and implies a minimum crustal thickness of 30 km and a maximum geothermal gradient of 25–28°C, km^?1, at 2700 Ma in the Scourie area. These results are in contrast to earlier more extreme P-T estimates of $\text{1150±100°}\text{C and}\text{15±3}\text{kb}$.     

Recent research developments on the Isle of Rum,NW Scotland

The appearance in 1997 of the British Geological Survey's memoir on Rum was followed by a period of intense research, leading to upwards of 35 papers, books and other articles. The scope of these publications, and the research progress over the last 15 years since publication of the memoir, is reviewed here. Igneous activity on Rum was short lived, possibly only ca. 500 ka, and, at about 60.5 Ma. The Rum central complex thus pre‐dates the nearby Skye central complex. The earliest, acidic and mixed acidic/basic magmatism on Rum involved both shallow intrusions and ignimbrite eruptions into a collapsing caldera bound by the Main Ring Fault, a structure which probably also exercised a structural influence on subsequent mafic and ultrabasic magmatism. Subsequent emplacement of gabbros and ultrabasic rocks caused only limited thermal metamorphism of the surrounding Torridonian sandstones, contrasting markedly with the intense alteration of uplifted masses of Lewisian gneiss within the ring fault. Detailed textural studies on the gabbroic and ultrabasic rocks allow distinction between intrusive peridotites and peridotite that formed as part of the classic layered units of Rum and, furthermore, this work and that on the chromite seams and veins in these rocks shows that movements of trapped magma and magma derived from later intrusions, may produce textures and structures hitherto regarded as primary features of cumulate rocks. Rare picritic dykes provide an indication of likely parent magma for the mafic and ultrabasic rocks, but these and other magmatic rocks on Rum have all undergone varying degrees of crustal contamination, involving both Lewisian granulite and amphibolite crust but, notably, not Moine rocks as at Ardnamurchan. Sulphides in the chromite seams and ultrabasic rocks show possible influences from assimilated Jurassic sediments. From recent apatite fission track studies it seems likely that Rum, in common with other Palaeogene centres, underwent a brief, but significantly younger (Mesozoic) heating event.     

Paleomagnetism of granites from the Angara-Kan basement inlier,Siberian craton

We report a new paleomagnetic determination of Paleoproterozoic rocks from the Siberian craton which showed a positive baked contact test and a stable age of the high-temperature NRM component. The mean paleomagnetic pole of Siberia for ～1730 Ma located at 42.9° S, 109.6° E (α95 = 5.3°) is compatible with the pole positions obtained recently for the middle and late Early Proterozoic.     

An archaean granulite-grade tonalite-trondhjemite-granite suite from scourie,NW Scotland: Geochemistry and origin

The Lewisian complex of the Scourie-Badcall area is composed predominantly of banded tonalitic gneiss which intrudes layered gabbro-ultramafic complexes. Intrusive into both gabbro and tonalitic gneiss are homogeneous acid sheets which are trondhjemitic to granitic in composition. All rocks were subjected to granulite facies metamorphism. Smooth continuous trends on chemical variation diagrams suggest that the evolution of these rocks was dominated by fractional crystallisation. A scheme is proposed whereby a tonalitic melt was parental to trondhjemite and granite. Variation within tonalites was a function of the fractional crystallisation of hornblende and plagioclase, and trondhjemite was derived from tonalite by the fractional crystallisation of hornblende and/or plagioclase. Granite and granodiorite represent residual liquids which evolved along the quartz-feldspar cotectic surface; they were derived by the fractional crystallisation of plagioclase from a trondhjemite liquid. Some trondhjemitic sheets are quartz-plagioclase residues from which a granitic melt was removed. The associated gabbros and ultramafic rocks are not directly related to the proposed fractional crystallisation scheme and are not crystal residues removed from the tonalitic melt. Tonalites were probably derived from a basaltic source by partial melting or fractional crystallisation with either hornblende and/or garnet as residual phases.     

Experimental petrology constraints on the recycling of mafic cumulate: a focus on Cr-spinel from the Rum Eastern Layered Intrusion,Scotland

The ¹⁷⁶Lu–¹⁷⁶Hf and ¹⁴⁷Sm–¹⁴³Nd decay systems are routinely used to determine garnet (Grt)–whole-rock (WR) ages; however, the ¹⁷⁶Lu–¹⁷⁶Hf age of garnet is typically older than the ¹⁴⁷Sm–¹⁴³Nd age determined from the same aliquots. Here we present experimental data for Lu³⁺ and Hf⁴⁺ diffusion in garnet as functions of temperature, pressure and oxygen fugacity and show that the diffusivity of Hf⁴⁺ in almandine/spessartine garnet is significantly slower than that of Lu³⁺. The diffusive closure temperature (T _C) of Hf⁴⁺ is significantly higher than that of Nd³⁺, and although this property is partly responsible for the observed ¹⁷⁶Lu–¹⁷⁶Hf and ¹⁴⁷Sm–¹⁴³Nd Grt–WR age discrepancies, the difference between the T _C-s of Lu³⁺ and Hf⁴⁺ could lead to apparent Grt–WR ¹⁷⁶Lu–¹⁷⁶Hf ages that are skewed from the age of Hf⁴⁺ closure in garnet. In addition, the slow diffusivity of Hf⁴⁺ indicates that the bulk of metamorphic garnets retain a substantial fraction of prograde radiogenic ¹⁷⁶Hf throughout peak metamorphic conditions, a phenomenon that further complicates the interpretation of ¹⁷⁶Lu–¹⁷⁶Hf garnet ages and invalidates the use of analytical T _C expressions. We argue that the diffusion of trivalent rare earth elements in garnet becomes much faster when their concentration level falls below a few hundred ppm, as in the experiments of Tirone et al. (Geochim Cosmochim Acta 69: 2385–2398, 2005), and further argue that this low-concentration mechanism is appropriate for modeling the susceptibility of ¹⁴⁷Sm–¹⁴³Nd garnet ages to diffusive resetting.     

Metasomatism and the crystallization of zircon megacrysts in Archaean peridotites from the Lewisian complex,NW Scotland

Zircon megacrysts are locally abundant in 1–40 cm-thick orthopyroxenite veins within peridotite host rocks in the Archaean Lewisian gneiss complex from NW Scotland. The veins formed by metasomatic interaction between the ultramafic host and Si-rich melts are derived from partial melting of the adjacent granulite-facies orthogneisses. The interaction produced abundant orthopyroxene and, within the thicker veins, phlogopite, pargasite and feldspathic bearing assemblages. Two generations of zircon are present with up to 1 cm megacrystic zircon and a later smaller equant population located around the megacryst margins. Patterns of zoning, rare earth element abundance and oxygen isotopic compositions indicate that the megacrysts crystallized from crustal melts, whereas the equant zircon represents new neocryst growth and partial replacement of the megacryst zircon within the ultramafic host. Both zircon types have U–Pb ages of ca. 2464 Ma, broadly contemporaneous with granulite-facies events in the adjacent gneisses. Zircon megacrysts locally form?>?10% of the assemblage and may be associated to zones of localized nucleation or physically concentrated during movement of the siliceous melts. Their unusual size is linked to the suppression of zircon nucleation and increased Zr solubility in the Si-undersaturated melts. The metasomatism between crustal melts and peridotite may represent an analog for processes in the mantle wedge above subducting slabs. As such, the crystallization of abundant zircon in ultramafic host rocks has implications for geochemistry of melts generated in the mantle and the widely reported depletion of high field strength elements in arc magmas.     

A structural analysis of the Moine Thrust Zone between Loch Eriboll and Foinaven,NW Scotland

The northern part of the Moine Thrust Zone as exposed around the valley of Srath Beag, Sutherland was developed by thrusts propagating in the tectonic transport direction. Deformation on any particular thrust surface evolved from dominantly ductile to dominantly brittle with time.The foreland has been progressively accreted onto the overriding Moine thrust sheet by duplex formation, a process which has continuously folded the roof thrust and the rocks above its hanging-wall. Fold culminations and depression can be related to lateral ramps which may give the rocks above the hanging-wall a complex history of extensional and compressional strains normal to the transport direction.Folds within the thrust zone are laterally independent because they are controlled by short lived variations in deformation style on an evolving thrust footwall topography. Therefore there may be no correlation between structures across or along the thrust zone. This variation limits the construction of balanced cross sections as structure cannot be projected onto particular section lines.     

Geochemistry and origin of granitic rocks,Scourian Complex,NW Scotland

Concordant granite sheets from the granulite facies Scourian Complex, N.W. Scotland exhibit the following features:

1. a common planar fabric with their host pyroxene granulites;
2. the presence of an exsolved ternary feldspar phase;
3. a low-pressure, water-saturated minimum composition;
4. K/Rb ratios (450–1,350) distinctly higher than most upper crustal granites but similar to the surrounding granulites;
5. low absolute concentrations of the rare earth elements (REEs), light REE enrichment, and large positive Eu anomalies.

It is proposed that the granite sheets have originated by anatexis of gneisses undergoing granulite facies metamorphism — gneisses that were already essentially dry and depleted in incompatible elements. Their unusual trace element chemistry may be explained by either disequilibrium melting and/or sub-solidus reequilibration of the granite sheets with the surrounding gneisses. Isotopic and trace element data suggest that cross-cutting, potash-rich pegmatites represent reworking of the granite sheets during a later amphibolitization.     

Petrogenesis of the anorthosite-chromitite association: crystal-chemical and petrological insights from the Rum Layered Suite, NW Scotland

Thirteen Cr-bearing spinels from major horizons of magma replenishment in the open-system Rum Layered Suite have been analysed by X-ray single crystal diffraction and electron microprobe analyses. On the basis of the structural parameters and the chemistry of these spinels the so-called Rum trend, in which Al-content increases at the expense of Cr and Fe³⁺, has been easily recognised. In addition, natural spinels with Fe³⁺ content similar to synthetic spinels on the MgCr₂O₄?CMgFe₂O₄ join have been analysed for the first time. Layers of chromitite, anorthosite and peridotite situated within several cm of one another have yielded different intracrystalline exchange temperatures using an intercrystalline spinel-olivine thermometer. The Rum anorthosite Cr-spinels are interpreted as having crystallised within the cumulus pile following rejuvenation of the crystal mush. Their low Al-content is a function of simultaneous plagioclase crystallisation, reducing the amount of Al³⁺ present for the Cr-spinel. By contrast, Cr-spinels in well-known Archean anorthosites (e.g. Ujaragssuit nunat and Fisken?sset, western Greenland) and Sittampundi (southern India) are very aluminous in composition, attributed to crystallisation of Cr-spinel from high-alumina basalts in lower crustal magma chambers and linked to the control exerted by plagioclase crystallisation on Al content of the melt, in the absence of clinopyroxene crystallisation. The compositional differences between the Rum anorthosite Cr-spinels and the Fisken?sset and Sittampundi Cr-spinels suggest that postcumulus reaction of Cr-spinel and melt to low (800?C900°C) temperatures, as invoked for the Rum crystals, may not have been as important a process in the Archean anorthosites.     

High pressure metamorphism in the Scourian of NW Scotland: Evidence from garnet granulites

Ultramafic and mafic granulites from Archaean gneisses in N.W. Scotland (the Scourian) show evidence of two periods of granulite facies mineral growth. The first produced a high pressure clinopyroxene +garnet±plagioclase assemblage at an estimatedP-T of 12–15 kb and 1,000° C. Uplift of the complex caused partial breakdown of the garnet by reaction with clinopyroxene to produce orthopyroxene +plagioclase ±spinel±amphibole symplectites, at an estimatedP-T of 10–14 kb and 800°–900° C. Garnet stability is shown to depend on both whole-rock Fe/Mg ratios and onP-T conditions. The pressures imply crustal thicknesses in the Archaean of least 35–45 km.     

Selective elemental depletion during metamorphism of archaean granulites,scourie, NW Scotland

The low abundances of large ion lithophile elements (LIL), K, Rb, U, Th, Cs, and high K/Rb ratio in rocks varying in composition from gabbro to granite in the Scourian complex, NW Scotland, are interpreted as due to depletion during granulite facies metamorphism. Depletion was controlled by the mineralogy of the rock, the composition of the associated fluid phase and its volume relative to the volume of the rock. K-feldspar granites and granodiorites were not depleted in K and only moderately in Rb, but tonalites and trondhjemites were strongly depleted in both K and Rb. Published mineral-fluid partition coefficients for LIL in aqueous systems indicate that between 0.075 and 2.0 rock volumes of fluid phase passed through the host rock in order to achieve the observed selective elemental depletion.