豫西熊耳山地区槐树坪金矿岩石-土壤找矿指示元素的确定及其应用

槐树坪金矿床位于河南省洛阳市嵩县境内,是豫西熊耳山地区近年来新发现的大型金矿床。本次研究对槐树坪金矿区地表及井下不同类型的较新鲜围岩、蚀变岩和矿石以及地表1∶20000面积性土壤采样,分析29项微量元素,从岩石和土壤两种采样介质来确定槐树坪金矿床的地球化学找矿指示元素。一方面基于较新鲜围岩的元素含量特征确定每个微量元素在该区岩石中的异常下限,进而分别计算了蚀变岩和矿石中微量元素平均含量与异常下限的比值,即异常衬度。按照异常衬度大于1.4的标尺确定了蚀变岩与矿石中明显富集的微量元素组合。另一方面,基于Au与28项微量元素在较新鲜围岩、蚀变岩、矿石三种介质中含量关系散点图直观确定了指示金成矿的微量元素组合。综合二者确定出槐树坪金矿区岩石地球化学找矿的指示元素组合为Au、Ag、As、Sb、Hg、Sn、Mo、Bi、Cu、Pb、Zn、Cd、Nb计13项。针对地表1∶20000面积性土壤调查,采用上述岩石中异常衬度为1.4作为土壤异常下限绘制了槐树坪金矿区微量元素的地球化学异常剖析图,以槐树坪金矿区已探明鸡公山一带的主成矿段为模型确定了土壤地球化学找矿的指示元素组合为Au、Ag、As、Sb、Hg、Bi、Cu、Pb、Zn、Cd、B计11项。综合上述结果认为在找矿指示元素组合方面土壤对岩石具有明显的继承性。基于岩石与土壤介质中共同的10项找矿指示元素,构建了归一化的综合异常指标,以鸡公山矿段为标准对整个槐树坪矿区进行了综合评价,发现槐树坪矿区内马蹄沟、秦佛爷沟、姜疙瘩和天坪西4处具有类似鸡公山矿段的找矿潜力。     

Specific composition of native silver from the Rogovik Au–Ag deposit,Northeastern Russia

The first data on native silver from the Rogovik Au–Ag deposit in northeastern Russia are presented. The deposit is situated in central part of the Okhotsk–Chukchi Volcanic Belt (OCVB) in the territory of the Omsukchan Trough, unique in its silver resources. Native silver in the studied ore makes up finely dispersed inclusions no larger than 50 μm in size, which are hosted in quartz; fills microfractures and interstices in association with küstelite, electrum, acanthite, silver sulfosalts and selenides, argyrodite, and pyrite. It has been shown that the chemical composition of native silver, along with its typomorphic features, is a stable indication of the various stages of deposit formation and types of mineralization: gold–silver (Au–Ag), silver–base metal (Ag–Pb), and gold–silver–base metal (Au–Ag–Pb). The specificity of native silver is expressed in the amount of trace elements and their concentrations. In Au–Ag ore, the following trace elements have been established in native silver (wt %): up to 2.72 S, up to 1.86 Au, up to 1.70 Hg, up to 1.75 Sb, and up to 1.01 Se. Native silver in Ag–Pb ore is characterized by the absence of Au, high Hg concentrations (up to 12.62 wt %), and an increase in Sb, Se, and S contents; the appearance of Te, Cu, Zn, and Fe is notable. All previously established trace elements—Hg, Au, Sb, Se, Te, Cu, Zn, Fe, and S—are contained in native silver of Au–Ag–Pb ore. In addition, Pb appears, and silver and gold amalgams are widespread, as well as up to 24.61 wt % Hg and 11.02 wt % Au. Comparison of trace element concentrations in native silver at the Rogovik deposit with the literature data, based on their solubility in solid silver, shows that the content of chalcogenides (S, Se, Te) exceeds saturated concentrations. Possible mechanisms by which elevated concentrations of these elements are achieved in native silver are discussed. It is suggested that the appearance of silver amalgams, which is unusual for Au–Ag mineralization not only in the Omsukchan Trough, but also in OCVB as a whole, is caused by superposition of the younger Dogda–Erikit Hg-bearing belt on the older Ag-bearing Omsukchan Trough. In practice, the results can be used to determine the general line of prospecting and geological exploration at objects of this type.     

吉林省小石人金矿区微量元素地球化学特征

以吉林省小石人金矿区内不同类型岩(矿)石微量元素测试结果为基础,从数据结构和空间结构两方面,对微量元素的地球化学特征进行探讨。统计参数表明:所观测元素在矿区内具有明显的浓集、富集特点,在不同类型岩(矿)石中元素的分布分配也不尽相同。依据分布分配特点,可将矿区内的岩(矿)石分为正常岩石、弱蚀变岩石和强蚀变/矿化岩石3类。多元统计分析成果揭示:所观测元素都参与了金的成矿活动,但行为特点有所差异。依据多元统计特征,可将微量元素分为3个组合类型:Au、As、Sb、Bi、Hg、Mn,Cu、Pb、Zn、Ag,Co、Ni、V;第一组合为成矿成晕组合,第二组合为金的多金属矿化组合,第三组合为黄铁矿化蚀变组合;元素组合也对应于不同的矿化阶段,指示金的成矿活动及特征。土壤、岩石地化剖面显示所观测的元素间存在空间相关性,但Mn与Au相异,其异常出现在矿化蚀变带的外侧。     

西藏尕尔穷铜金矿元素空间分布规律及地球化学勘查模型

尕尔穷铜金矿床是班公湖-怒江成矿带西段唯一达到详查级别的矿床,其金资源量已达大型规模.根据30个钻孔的成矿元素化学分析结果,对各成矿元素平面分布特征进行了系统分析发现,尕尔穷矿床具有较明显的与岩浆热液成矿作用有关的元素分带特征,矿体从南东→北西向、深部→浅部具有Mo→Cu(Au)→Cu+Au+Ag→Au+Cu+Ag→A...     

个旧锡矿土壤次生晕地球化学勘查的可行性分析

对个旧锡矿高松矿田不同类型地质元素地球化学特征研究表明，成矿热液活动对区内地表基岩、构造岩产生了系统性的热液活动影响，地表岩石的土 经并未造成矿化指示元素显的选择性变化，土壤样品具有与地表基岩及构造岩一样对矿化作用的指示作用，但由于主元素大量流失，微量元素得到明显富集，在土壤中矿化活动指示元素含量高于地表基岩1－2个数量级，也显高于地表构造岩，而且土壤样品随机取样在一定程度上有相对稳定性，代表一定范围内均化的效果。区域上元素含量变化系数较大，具有可以区分的变化以反映不同的地质（矿化）情况，因此，研究认为在个旧锡矿隐伏矿床找矿上土壤次生晕地示化学勘查是一种可行的地面化探方法，相对于基岩原生晕有测定技术上易于实现、取样上人为影响较小、代表性和客观性较强等优点。     

辽西排山楼金矿床微量元素地球化学特征及深部找矿预测研究

为解决危机矿山储量不足的问题,突破深部找矿瓶颈,对辽西排山楼金矿床深部的北东向矿体沿4条井下勘探线（0、6、12和16）,从标高330米到175米7个开采中段采集271件样品,运用相关分析、R型聚类分析和因子分析的方法对每件样品20个微量元素进行了多元统计分析。结果表明,排山楼金矿床最佳前缘晕指示元素组合为As—Sb,近矿晕指示元素组合为Ag—Pb—As—sb—Bi,矿上晕指示元素组合为Au±（Cu—ag）,尾晕指示元素组合为V-Mn—Co—Ti。通过对F1（尾晕）、F2（矿上晕）和F3（头晕）因子得分三维空间分布趋势图的研究,发现金矿体向南西深部侧伏,且延伸进入东西向矿带,表明东西向矿带深部也存在巨大找矿前景。在对已存两矿带正确划分的基础上,评价预测出第三矿带的存在,经勘探验证,预测矿带金矿石储量可观。     

福建紫金山矿田罗卜岭斑岩型铜钼矿地球化学立体探测示范

罗卜岭矿床是与晚中生代花岗闪长斑岩体有关的隐伏斑岩型铜钼矿床, 矿区位于紫金山矿田的东北部; 铜钼矿体主要产于绿泥石化-绢英岩化和(弱)钾化-绢英岩化带中, 矿石矿物组合为黄铜矿+辉钼矿; 少量过渡类型矿体产于高级泥化带中, 矿石矿物组合为蓝辉铜矿+铜蓝+辉钼矿。罗卜岭矿区的原生晕地球化学三维模型显示, 微量元素具有一定的分带特征, 低温元素Au与高温元素组合W、Sn、Bi分布于矿体上方, 中低温元素Pb、Zn、Ag分布于Cu、Mo元素之间; 元素直观垂向分带序列大致为: (As、Sb、Hg)-(W、Bi、Sn)-Ga-Au、Ba-Cu、Ag-Pb、Zn-Mn-Mo; 前缘晕的元素与氧化物组合为As、Sb、Au、Ga、Al2O3, 矿体近矿晕元素组合为Ag、Pb、Zn, 缺失尾晕元素组合; Cu、Mo可直接作为找矿指示元素, Au、Ag、Pb、Zn、As、Sb、Ga、Ba、Mn可作为间接指示元素, 矿床深部K2O正异常与Al2O3负异常可作为斑岩型铜钼矿的重要找矿标志, 这一规律对紫金山矿田深部和外围隐伏斑岩型矿体的勘查工作具有重要的参考意义。     

Seasonal variation of gold and arsenic in biogeochemical samples from a disseminated gold deposit in the Northern Cordillera

An orientation survey was conducted over the Quartz Mountain, Oregon, hot-spring type disseminated gold deposit to address three questions critical to successful exploration of the area: What is the relationship between bedrock geology and the trace-element content of trees and soils; do these relationships change seasonally; are these relationships similar in the two tree species which discontinuously blanket the area?Twig, needle and wood samples were collected four times during the year from both ponderosa pine (Pinus ponderosa) and white fir (Abies concolor). Soils were collected once. All samples were analyzed for Au and As and the wood samples were analyzed also for Sb.Arsenic was the best pathfinder element, having little analytical, spatial, or seasonal variation in the twig and needle samples. Anomalous levels were 150 μg/g (ppm) As in pine and 30 μg/g in fir. Gold showed analytical variation of 20–30%, sample duplicate variation up to 90%, spatial changes, and seasonal variation ranging from winter-summer background [10–20 ng/g (ppb) Au] to anomalies of 300–400 ng/g (ppb) Au in pine and 100 μg/g (ppb) Au in fir in the spring and fall. Antimony could not be completely evaluated as a pathfinder element because it was only determined in wood samples.Needles and twigs from both species proved to be viable sample media for exploration of the area. Wood was not a suitable medium because of low, erratic values, perhaps due in part to analytical technique. Needles had 2 to 20 times higher As concentrations than did twigs. Twigs had a slightly higher Au content [25 ng/g (ppb)] than did needles. The pine samples were higher in both elements than were the fir samples. The data, normalized by species, could be treated as one homogeneous data base.The soil Au and As data outlined the mineralization clearly with a central Au anomaly [100 ng/g (ppb) and greater] surrounded by As anomalies [100 μg/g (ppm) and greater] over a distance of 594 m. Neither spring nor fall tree Au anomalies were coincident with the soil Au anomaly. Consistent throughout the year, tree As anomalies coincided with the soil As anomalies, but covered a smaller area. Both the Au and As anomalies in trees appeared to be related to bedrock contact zones rather than to the soil the trees were growing in.     

Bryolithochemical studies in the search for and evaluation of gold-silver mineralization based on stream sediments (northeastern Russia)

The first bryolithochemical studies have been carried out within the Dukat ore field (Balygychan-Sugoi trough, northeastern Russia), in its northeast (Dukat Au-Ag deposit, Chaika site) and on its eastern flank (Au-Ag ore occurrence, Piritovyi site). Sampling was made along primary water streams draining Au-Ag ore zones, because the headstreams localized in the permafrost zone are poor in alluvial sediments or lack them, whereas the stream banks and beds are overgrown with aquatic and semiaquatic mosses. We examined samples of moss cushions with loose sediments (fine silt suspension and sand-silt material). The study has shown that moss cushions are an effective natural trap extracting finely dispersed, ultradisperse, and colloid-dispersed particles, including ore ones, from water stream suspension. The contents of major elements indicating Au-Ag mineralization (Au, Ag, Hg, Sb, As, Pb, and Zn) in the bryolithochemical and lithochemical samples were compared. The highest contents of these elements have been revealed in the bryolithochemical samples. Scintillation analysis shows a predominance of finely dispersed Au and Ag particles. The chemical composition of lithoparticles and probable species of elements indicating mineralization were studied by energy-dispersive X-ray microanalysis. It has been concluded that the bryolithochemical stream sediments are an integral part of the lithochemical ones and can also be effectively used to reveal geochemical anomalies and identify the corresponding ores. It is shown that the bryolithochemical sediment streams bear important information about the chemical composition of primary ores, as they have the same major indicator elements (Au, Ag, Hg, Sb, As, Pb, and Zn) and nearly the same mineral composition (finely dispersed gold and silver, electrum, silver sulfosalts, and simple sulfides). The proposed bryolithochemical research is promising not only for northeastern Russia but also for other areas with similar landscapes, primarily areas where lithochemical and bryolithochemical stream sediments form in the northern subarctic and arctic environments.     

地气测量在戈壁覆盖区210金矿的试验

在新疆哈密和甘肃安西县交界地带的金窝子210隐伏金矿上方,运用泡塑捕集器和液态捕集液进行大比例尺地气测量,深入研究地气测量方法在野外的应用。试验结果显示,隐伏金矿体上方出现了较为明显的Au地球化学异常,并伴随Cu、Pb、Fe等成矿伴生元素的地球化学异常,异常与覆盖层厚度、矿体产状、构造等因素相关。地气法捕集的微量物质的稀土配分模式与210金矿矿石样品的稀土配分模式相似,证明了捕集的微量物质来源于深层隐伏矿体,体现了地球化学深穿透方法在戈壁地区隐伏矿产勘查中具有良好的应用前景。     

招远大尹格庄金矿床微量元素特征及其意义

该文以山东招远大尹格庄金矿床中微量元素为研究对象,通过对矿床围岩、矿石等微量元素的研究,表明大尹格庄金矿围岩中微量元素以富含 Bi,Au,Pb,W,Ag,Sn 为特点,矿体和矿化体中元素组合为 Au,Ag,As,Sb,Hg,B, Cu,Zn,Bi,Mo,Mn,Co,Ni,W。在5个成矿阶段中,第二阶段与第三阶段微量元素的富集程度较明显,表现为 Au, Ag,As,Co,Bi,Cu,Pb,Zn 等的富集,成矿元素可分为2个分带序列,主成矿元素为 Au Ag Cu Pb Zn Bi 组合、头晕元素 As Sb Hg 组合和尾晕元素 Co Ni 组合。     

新疆土屋铜矿床某些成矿地球化学特征探讨

在分析土屋铜矿床I号矿体中部主要围岩和矿(化)体的硅酸盐、稀土元素、微量元素及成矿元素含量的基础上,借助MVSP等专业软件系统统计对比了上述示踪元素在各类围岩和矿(化)体中的分布分配规律.根据矿区的斑岩体与矿(化)体在多种元素组合特征上的相似性判断,二者有物质上的亲缘关系.而成矿元素表现出的某些地球化学行为则说明初步聚集了成矿元素Cu、Au、Ag、Sb、(Mo)的斑岩体,经热液蚀变使其中的成矿物质活化迁移,并富集在有利的构造和岩相部位,在后期复合成因热液所携矿质的多期次叠加下,形成大型斑岩-热液型铜矿床.     

西秦岭拉尔玛金矿床微量元素地球化学演化分析

本文扼要地总结了拉尔玛金矿床赋矿岩石和矿石中微量元素的分配特点,指出元素的沉积初始富集是成矿的基础,而后期叠加改造强度则是元素工业富集的关键。进一步通过元素组合的相关分析,详细地剖析金、铀矿化及其伴生元素系列的演化特征。     

便携式X射线荧光光谱仪在岩石样品分析中的应用研究

便携式X射线荧光光谱仪(PXRF)因具有快速、无损检测元素含量的能力,通常被用于野外或实验室地质样品的元素含量检测工作中,对于大多数地质样品,在2 min内就能够获得几十种元素的半定量-定量分析结果。但在实际应用中,被测样品的表面平整度、样品中物质的均一性和施测时间等因素都会影响元素分析结果。为了进一步了解样品类型和分析测试方法等因素对元素分析的具体影响,本文对比了PXRF与实验室分析结果、岩石和粉末样品PXRF分析结果、不同检测时间所得PXRF分析结果的关系,在不损失过多分析精度的前提下提出了通过PXRF降低勘查成本、提高工作效率的方案。结果表明:用PXRF直接分析岩石样品时,大多数元素的分析结果可靠性较差,尤其是成矿预测工作中常用的Cu、Pb、Zn、As和Ni等元素;粉末样品的PXRF分析结果与实验室分析结果具有较好的相关性,表明对岩石样品进行粉碎处理能够明显改善PXRF分析质量;元素种类不同,岩石和粉末样品PXRF测量结果的相关性也不同。因此,在实际工作中可以根据感兴趣的目标元素确定是否需要对岩石样品进行粉碎制样处理;检测时间对元素含量分析结果没有明显影响,对于特定元素,如果能够在较短时间内获得其含量信息,则无需增加检测时间。     

新疆和田团结峰铅锌矿床勘查模型初论

新疆和田县团结峰铅锌矿床是西昆仑地区新发现的一处重要MVT型铅锌矿床,铅锌规模达中型,伴生银。在勘查工作实践及综合研究矿床模型基础上,总结了矿床的成矿地质条件、地球物理勘查模型、地球化学勘查模型和地质找矿标志。研究表明:赋矿地层为中侏罗统龙山组二段灰岩,次级NW向断裂控制了铅锌矿体的分布,硅钙面之上的层间构造是矿体的赋存部位。1∶50万水系沉积物测量勘查模型显示:矿区及周边主要异常元素有Au,Ag,Pb,Zn,Mn,Hg,Sb,Cu,Co等,矿区为Ag-Zn-Cu-Pb-Au-As-Sn-Cr-Fe-F异常范围内,元素异常套合较好。1∶5万水系物测量勘查模型显示:成矿元素Ag,Zn,Cu,As,Sn,Sb,Pb浓度分带明显,异常套合好,有明显的浓集区;1∶1万瞬变电磁测量勘查模型显示:矿区内主要岩层的电阻率差异很大,含铅锌矿化地层电阻率为4 660～6 030Ω·m,可形成中高阻异常;遥感蚀变信息勘查模型显示:矿区遥感异常以羟基为主,铁染零星,异常与构造套合较好。除了物化遥异常标志外,铁帽、次级NW向断裂、围岩蚀变也是重要的找矿标志。     

Trace Element Analysis of Natural Gold by Laser Ablation ICP-MS: A Combined External/Internal Standardisation Approach

For the trace element analysis of gold by laser ablation ICP-MS, external calibration samples of differing matrix composition have been used in previous studies. Data presented here suggest that even for calibration samples and unknowns with closely-matched matrices, discrepancies arise due to variations in the coupling behaviour of the laser with the sample at different power deliveries, and can lead to erroneous trace element determinations. Internal standardisation for gold is complicated because Au and Ag, the most common major elements, do not have minor isotopes that can be used as internal standards. This problem was overcome for natural gold samples by using an external calibration sample only for the major elements Au and Ag, then defocussing the ion path and using ¹⁰⁷Ag in each sample as an internal standard against which μg g^-1 levels of Te, Sb, Hg, Bi, and Cu were determined. The results suggest that trace elements can occupy lattice sites in gold rather than occurring only as micro-inclusions of other phases. The analytical approach taken here may be used in trace element analysis where adequate external calibration samples are not readily available.     

陕西陈耳金矿床不同构造－岩相带微量元素地球化学特征及构造控矿机理

通过对陈耳金矿床两类不同构造-岩相带微量元素分布特征分析,发现元素特别是成矿元素Au的含量从片理化带→破碎蚀变带→石英脉逐渐增强。构造-岩相带内变形岩石的石英Rf/φ法有限应变测量表明,片理化带应变强度最大,破碎蚀变带应变强度小,应变集中在韧性剪切带边部的片理化带内。R型聚类分析表明Au与Ag、Cu、Pb及Zn的相关系数远大于Au与Ni、Co元素的相关系数,甚至接近于1。研究认为:破碎蚀变带内由于应变软化导致脆性裂隙大量发育,易于成矿流体的迁入与淀积而强富集;片理化带由于应变集中,造成成矿流体的迁出而弱富集。韧性剪切带脆-韧性变形转换不仅控制了矿体就位空间,同时也决定着元素迁移的方向。     

湘中基底-盖层W-Au-Sb热液系统的金属分异机制综述

湘中盆地锑矿床闻名于世,成矿元素在垂直空间上呈现出上锑(泥盆系)、中金锑(震旦系)、下金钨或金锑钨(板溪群),盆地中锑、边缘锑(金/钨)的成矿分布特征。通过系统的成矿地质条件、成矿元素地球化学研究,以及矿物流包裹体地球化学数据分析表明,湘中盆地及其基底的成矿元素分带是成矿流体性质和元素地球化学行为差异等因素相互耦合的结果。湘中地区基底-盖层成矿系统:构造-岩浆岩+盆地-流体作用,基底成矿元素在流体的作用下被萃取迁移到不同部位(基底→盖层不断演化);成矿元素锑的沉淀主要受流体的温度和pH值影响,金的沉淀主要受硫逸度或总硫溶度的控制,钨的沉淀主要受流体的盐度控制,且因物化条件的变化和元素地球化学行为的控制而呈现不同元素组合沉淀成矿。     

青海果洛龙洼金矿床矿化元素组合特征及找矿意义

青海果洛龙洼金矿床位于东昆仑造山带东段沟里地区,具有多元素共生特征,这些共生元素不仅具有综合利用价值,也是重要的找矿指示元素。文章依据工作中系统采集的81件样品的11种元素(Au、Hg、V、Mo、Ni、Cu、As、Co、Ag、W、Pb)测试数据,进行了元素的相关分析、聚类分析和因子分析,并分块段将各因子得分与矿体Au品位进行了对比研究,结合矿区地质情况进行了解译。结果表明,主成矿元素Au与Ag、Pb、Cu、Mo显著正相关,与Hg、W、As弱正相关。伴生元素中As与Hg、Pb与Ag为强正相关,Pb与Cu、Cu与Ag、W与Mo为正相关,Ni、Co与V元素呈弱正相关。因子分析结果显示,11种元素可分为四个因子组Au-Cu-Ag-Pb(F1)、W-Mo(F2)、Hg-As(F3)和Ni-Co-V(F4)。F1因子为中温多金属硫化物元素组合,在矿床主成矿阶段形成,该因子得分情况在矿区西部区域与矿体Au品位变化规律完全一致,因此,Au-Cu-Ag-Pb组合异常对矿区西部区域找矿具有指示意义。F2因子属高温岩浆热液元素组合,该因子上Au有一定载荷,推测矿区华力西-印支期花岗闪长岩对Au成矿具有重要意义。F3为低温热液元素组合,矿区自西往东分段统计结果显示,该因子得分变化情况与矿体Au品位变化规律具一致性,可运用As-Hg组合异常进行成矿预测。F4因子与地层中的基性火山组分有关,与其它元素具有不同的地球化学演化过程。因子得分统计结果显示,矿区中部是与Au相关多元素富集中心,该区段为多种成矿因素复合叠加的中心,应加强该处的勘查工作。     

黔西南泥堡金矿围岩与矿石的对比及其成矿机制研究

泥堡金矿的矿体主要赋存在构造蚀变体及逆冲断层破碎带中,受地层和断裂的双重控制。本文在岩相学研究的基础上应用X射线粉晶衍射分析(XRD)结合电子探针分析(EMPA)确定和量化了围岩和矿石的蚀变矿物及载金砷黄铁矿,对比了围岩和矿石的特点,并利用主微量元素分析矿化过程中围岩与矿石之间的元素带入带出通量,探讨了泥堡金矿蚀变矿物与成矿的关系及成矿机制问题。分析结果表明,黄铁矿(主要的载金矿物)与石英呈负相关,与伊利石呈正相关;矿石发生了去碳酸盐化作用,矿石中的黄铁矿大多具有环带结构,部分围岩也发生了去碳酸盐化作用,而围岩中的黄铁矿一般不具有环带结构;Au明显加入到构造蚀变体的矿石中,而CaO、MgO、S、Ba、Be等从其围岩中带出;Au、Sc、As和Fe_2O_3明显加入到逆冲断层破碎的矿石中,SiO_2、CaO、Sr、W、Be等则显示从其围岩中带出。综合分析认为,去碳酸盐化和硫化作用是泥堡金矿的主要成矿机制。在矿化前,去碳酸盐化作用为成矿提供了有利的环境;在成矿过程中,矿化通过硫化作用形成了黄铁矿的载金含砷边缘。