Geochemistry of natural chromium occurrence in a sandstone aquifer in Bauru Basin, São Paulo State, Brazil

Anomalous concentrations of Cr(VI) occur in groundwaters of the Adamantina Aquifer, in a large region in the western state of São Paulo, sometimes exceeding the potability limit (0.05 mg L⁻¹). To identify the possible geochemical reactions responsible for the occurrence of Cr in groundwater in Urânia, borehole rock samples were collected in order to carry out mineralogical and chemical analyses. In addition, multilevel monitoring wells were installed and groundwater samples were analyzed. Analyses of the borehole rock samples show the occurrence of a geochemical anomaly of Cr in the quartzose sandstones (average concentrations of 221 ppm). Chrome-diopside is one of the main minerals contributing to this anomaly, having an average Cr content of 1505 ppm. Sequential extraction experiments indicated weakly adsorbed Cr in the order of 0.54 ppm, and this quantity is enough to provide the Cr concentrations observed in groundwater. Groundwaters from the monitoring wells proved to be stratified, with the highest concentrations of Cr(VI) (0.13 mg L⁻¹) being associated with high redox and pH values (over 10) and high concentrations of Na. Geochemical reactions that may explain the release of Cr from the solid phase to groundwater involve the release of Cr(III) from minerals (like chrome-diopside and Cr-Fe hydroxide), followed by oxidation of Cr(III) to Cr(VI), probably related to the reduction of Mn oxides present in the aquifer. Then cation exchange occurs and dissolution of carbonates which increases the pH of groundwater, resulting in the desorption and mobilization of Cr(VI) into groundwater.     

Hydrochemical relationships in groundwater from central São Paulo State, Brazil

Groundwater samples from different aquifers occurring at center/northeast portion of São Paulo State, Brazil, were collected and chemically analyzed. The waters leaching Mesozoic sediments are generally more acid (pH_average=5.9) and have lower values for total dissolved solids (TDS_average=105 mg/L) than those obtained for waters leaching Paleozoic sediments of Tubarão Group. First-degree trend surfaces revealed that the deeper tubular wells occur towards east/southeast and exploit Paleozoic sediments as well fractured/fissured diabases/basalts, whereas the tubular wells in the west/northwest region are shallower. Piper diagrams indicated that the majority of the waters are a blend of waters from different lithologies. Significant correlations were found among nitrate, chloride and bicarbonate, suggesting the occurrence of some anthropogenic inputs, whereas elevated alpha activity of geogenic ²²⁶Ra indicated the need of a broad radiometric survey in the area.     

Stable isotopic constraints on Kuroko-type paleohydrothermal systems in the Mesoproterozoic Serra do Itaberaba group,São Paulo State,Brazil

Mesoproterozoic oceanic paleohydrothermal systems developed in the volcanosedimentary Serra do Itaberaba Group, which comprises part of the Ribeira fold belt. Hydrothermal alteration associated with these systems was responsible for large premetamorphic chloritic alteration halos (CZ1 rocks), overprinted by restricted premetamorphic chloritic (CZ2 rocks), argillic, and advanced argillic alterations that correspond to intensely leached rocks within feeder zones. Well-defined trends of increasing δ¹⁸O values with the progressive intensity of the alteration process are observed for igneous metabasites, metabasic hydroclastic rocks, and intermediate metamorphosed igneous and volcaniclastic rocks from CZ1. Systematic stable isotope variations evince that, in the Serra do Itaberaba metamorphosed hydrothermalized rocks, the preexisting isotope signatures of the hydrothermal systems were at least partially preserved. Highly evolved hot seawater is suggested for the genesis of the CZ1 rocks, whereas for the CZ2 rocks and marundites, the ¹⁸O fluid enrichments are interpreted as due to the major contribution of evolved seawater-derived fluids with a subordinate magmatic water component. An early near-seafloor, low-temperature alteration in a mid-ocean ridge environment was responsible for heterogeneous ¹⁸O whole-rock enrichments and followed by steady hydrothermal circulation with discharge of hot fluids, which previously underwent isotopic exchange with the ¹⁸O enriched volcanic rocks in the deeper part of the system with high temperatures and low water: rock ratios in a backarc environment. The subordinate magmatic water component derived from andesitic and rhyodacitic intrusions. The extremely high δ¹⁸O anomalies from the CZ1 rocks suggest an associated base metal massive sulfide ore body. The lower δ¹⁸O values related to the CZ2 rocks represent alteration by a higher temperature fluid, which might indicate the proximity of possible ore zones. The identification of several premetamorphic hydrothermally altered zones, similar to those of Kuroko-type base metal mineralizations, expands the mineral potential of base metal deposits in the Serra do Itaberaba Group and the volcanosedimentary sequences from the Ribeira fold belt.     

A continuous multi-millennial record of surficial bivalve mollusk shells from the São Paulo Bight,Brazilian shelf

To evaluate the potential of using surficial shell accumulations for paleoenvironmental studies, an extensive time series of individually dated specimens of the marine infaunal bivalve mollusk Semele casali was assembled using amino acid racemization (AAR) ratios (n = 270) calibrated against radiocarbon ages (n = 32). The shells were collected from surface sediments at multiple sites across a sediment-starved shelf in the shallow sub-tropical São Paulo Bight (São Paulo State, Brazil). The resulting ¹⁴C-calibrated AAR time series, one of the largest AAR datasets compiled to date, ranges from modern to 10,307 cal yr BP, is right skewed, and represents a remarkably complete time series: the completeness of the Holocene record is 66% at 250-yr binning resolution and 81% at 500-yr binning resolution. Extensive time-averaging is observed for all sites across the sampled bathymetric range indicating long water depth-invariant survival of carbonate shells at the sediment surface with low net sedimentation rates. Benthic organisms collected from active depositional surfaces can provide multi-millennial time series of biomineral records and serve as a source of geochemical proxy data for reconstructing environmental and climatic trends throughout the Holocene at centennial resolution. Surface sediments can contain time-rich shell accumulations that record the entire Holocene, not just the present.     

Geochronological constraints on the evolution of the Embu Complex, São Paulo, Brazil

Petrologic and geochronological work was carried out on a roadside outcrop of amphibolite facies orthogneisses near São Lourenço da Serra, about 50 km southwest of São Paulo City. These orthogneisses belong to the Embu Complex, within the Neoproterozoic Brasiliano Orogenic Cycle mobile belts of SE Brazil. The outcrop consists of predominantly foliated biotite tonalites and granodiorites, which were cut by granitic veins and pegmatites prior to final deformation. SHRIMP U/Pb measurements on zircons from one granodioritic–tonalitic gneiss indicate magmatic crystallization of the protolith at 811±13 Ma (MSWD=1.0). Zircons with dates of ca. 2000 and ca. 1000 Ma in this rock are interpreted as inherited from older crust. One zircon analyzed from the gneiss and three zircons from a discordant pegmatitic vein indicate an event at 650–700 Ma, perhaps related to the intrusion of the pegmatites. A regression of Rb–Sr whole rock data for four biotite gneisses yielded an imperfect isochron, giving an apparent age of 821±68 Ma and an elevated initial ⁸⁷Sr/⁸⁶Sr ratio of 0.719±0.005. The elevated initial ⁸⁷Sr/⁸⁶Sr ratio and the inherited zircons indicate involvement of older crust in the genesis of the gneisses. Rb–Sr feldspar and whole rock pairs yield ca. 560 Ma tielines, giving the time of final cooling below 300–350 °C, and the cessation of medium-grade metamorphism and ductile deformation. These results document a series of tectono-thermal events spanning 250 million years during the Brasiliano Orogenic Cycle. They relate to ca. 800 Ma magmatic arc activity and later allochthonous terrane assembly during closure of the Adamastor Ocean, resulting in the accretion of Western Gondwana.     

Facies analysis of tertiary alluvial fan deposits in the Jundiaí region, São Paulo, southeastern Brazil

This article presents an analysis of facies of sedimentary sequences that occur as discontinuous bodies in the Jundiaí region, west of the main Tertiary continental basins of the southeastern Brazil continental rift. Nine identified sedimentary facies, grouped into four associations, suggest the existence of an ancient alluvial fan system whose source area was the Japi mountain range (Serra do Japi). The deposits are considered Tertiary in age and chronocorrelated with those identified in the Atibaia region and at other sites up to 100 km east and northeast of Jundiaí. The depositional model adopted to explain the filling of the basin proposes that the alluvial fans, which directly derive from the source area, terminated in a braided channel longitudinal to the basin axis that flowed to northwest, in a similar configuration to that of the present day. This basin may have extended to the Atibaia region or formed a set of small basins laterally contiguous to the faults associated with the rift. Such occurrences show that the formation of rift basins was broader than the area presently occupied by the main deposits.     

Territorial exclusion and violence: the case of the state of São Paulo, Brazil

If we had to point out one single feature to define Brazilian cities today, it would be the existence of a dual built environment: a landscape produced by private entrepreneurs and contained within the framework of detailed urban legislation, and another one, three times greater, self-produced by the poor and eternally situated in an intermediate zone between the legal and the illegal. In addition to being an expression of economic and social disparities, this contrast has profound implications on the form and functioning of the cities. The sprawl of the precarious peripheries has lead to an absurd disconnection of poorly urbanized spaces and the city center where jobs, cultural and economic opportunities are concentrated. The effects of this persistent territorial exclusion are devastating and occur in both the peripheries and the city center. The purpose of this paper is to explore the nexus between the precarious and risky urbanization which took place in Brazilian cities and the urban violence that seems to be the most recent and visible face of this model, using the concrete example of different cities in the state of São Paulo. In order to construct the links it is first important to understand how patterns of economic development and population trends have contributed to the generation of risk urbanization and how planning and urban management policies interact with it.     

Arsenic in groundwater affected by phosphate fertilizers at São Paulo, Brazil

. This paper studies metalloid mobility in soils produced by conventional farming methods. The mobility of arsenic in soils depends on several factors including redox potential, soil mineralogy, pH, and the presence of other anions that compete with As for soil retention sites, for example, phosphate. Phosphate enhances the mobility of As in soils by competing for adsorption sites. Arsenic may accumulate in soil through the application of fertilizers. Ingestion of inorganic arsenic contained in drinking water is known to cause cancer. Studies were carried out in an area of Jundiaí, São Paulo in Brazil with high arsenic levels in natural water from domestic wells. The mobility of arsenic in the soil of Jundiaí was studied in the period 1998–2001. The application of phosphate fertilizers on a wide scale is a common agricultural practice. Based on data from the field and laboratory experiments, the deterioration of soil and groundwater quality is a result mainly of fertilizer use due to excessive P application, overdosing of soil with phosphate, and undesirable additions of arsenic in P fertilizers.     

Cenozoic tectonic events at the border of the Paraná Basin, São Paulo, Brazil

In the last decade, even in areas that had been considered tectonically stable, a great amount of Cenozoic, including the Quaternary period, structural data have been collected throughout Brazil. The main goal of this study is to describe the Cenozoic structures and tectonic evolution of an area that is located at the border of the Paraná Basin in the state of São Paulo.The research methods consisted of the analysis of: (1) brittle structure data, mainly conjugate fractures and fault slip data; (2) lineaments traced on air photos and TM Landsat and radar images; and (3) a second-order base surface map.The study area, during the Cenozoic, has been affected by five strike–slip tectonic events, which generated mainly strike–slip faults, and secondarily normal and reverse ones. The events were named, from the oldest to the youngest, E1-NE, E2-EW, E3-NW, E4-NS, and E5-NNE; and the maximum principal stresses σ1 strike approximately NE–SW, E–W, NW–SE, N–S, and NNE–SSW, respectively. Event E2-EW seems to have been contemporaneous with the deposition of the Rio Claro Formation, the most important Cenozoic deposit of probable Neogenic age, and also to have controlled the distribution of its deposits. Event E3-NW was the strongest one in the area, as is pointed out by structural data, and the maximum principal stress σ1 of event E5-NNE is partially concordant with the orientation of σH-max of well break-out data in the Paraná Basin, suggesting a Neotectonic activity for this event. Finally, discontinuities parallel and correlated to the directions of strike–slip faults of the Cenozoic events seem to have actively controlled the sculpturing of the relief in the study area.     

Soft-sediment deformation structures in late Albian to Cenomanian deposits, São Luís Basin, northern Brazil: evidence for palaeoseismicity

Soft-sediment deformation structures from the Alcântara Formation (late Albian to Cenomanian), São Luís Basin, northern Brazil, consist of (1) contorted structures, which include convolute folds, ball-and-pillow structures, concave-up paths with consolidation lamination, recumbently folded cross-stratification and irregular convolute stratification that grades into massive beds; (2) intruded structures, which include pillars, dykes, cusps and subsidence lobes; and (3) brittle structures, represented by fractures and faults displaying planes with a delicate, ragged morphology and sharp peaks. These structures result from a complex combination of processes, mostly including reverse density gradients, fluidization and liquefaction. Reverse density gradients, promoted by differential liquefaction associated with different degrees of sediment compaction, led to the genesis of convolute folds. More intense deformation promoted the development of ball-and-pillow structures, subsidence lobes and sand rolls, which are attributed to denser, and thus more compacted (less liquefied), portions that sank down into less dense, more liquefied sediments. Irregular convolute stratification that grades into massive beds would have formed at periods of maximum deformation. The subsidence of beds was accompanied by lateral current drag and fluid escape from water-saturated sands. In addition, the fractures and faults record brittle deformation penecontemporaneous with sediment deposition. All these mechanisms were triggered by a seismic agent, as suggested by a combination of criteria, including (1) the position of the study area at the edge of a major strike-slip fault zone that was reactivated several times from the Albian to the Holocene; (2) a relative increase in the degree of deformation in sites located closer to the fault zone; (3) continuity of the deformed beds over large distances (several kilometres); (4) restriction of soft-sediment deformation structures to single stratigraphic intervals bounded by entirely undeformed strata; (5) recurrence through time; and (6) similarities to many other earthquake-induced deformational structures.     

Neoproterozoic glacial dynamics revealed by provenance of diamictites of the Bebedouro Formation, São Francisco Craton, Central Eastern Brazil

One of the main questions on Neoproterozoic geology regards the extent and dynamics of the glacial systems that are recorded in all continents. We present evidence for short transport distances and localized sediment sources for the Bebedouro Formation, which records Neoproterozoic glaciomarine sedimentation in the central-eastern São Francisco Craton (SFC), Brazil. New data are presented on clast composition, based on point counting in thin section and SHRIMP dating of pebbles and detrital zircon. Cluster analysis of clast compositional data revealed a pronounced spatial variability of clast composition on diamictite indicating the presence of individual glaciers or ice streams feeding the basin. Detrital zircon ages reveal distinct populations of Archean and Palaeoproterozoic age. The youngest detrital zircon dated at 874 ± 9 Ma constrains the maximum depositional age of these diamictites. We interpret the provenance of the glacial diamictites to be restricted to sources inside the SFC, suggesting deposition in an environment similar to ice streams from modern, high latitude glaciers.     

The origin of enriched mantle beneath São Miguel, Azores

Lavas from the island of São Miguel, Azores Archipelago have long been known to display large radiogenic isotopic variability, that ranges from “depleted” isotopic signatures (e.g. high ε_Nd ∼ +5) in the west, typical of many ocean island basalts, to more “enriched” compositions (e.g. low ε_Nd ∼ +1) in the east. Here, we further characterise the geochemistry of lavas from this remarkable locality, focussing on the nature and origin of the enriched source. Our new isotope data define a striking, linear array in Nd and Hf isotope space that points towards an unusual, enriched composition below the mantle array. This distinctive Hf-Nd isotope signature is associated with elevated values of all three radiogenic Pb isotope ratios. Although the enriched component has certain geochemical similarities to both terrigenous sediments and some samples of the continental mantle lithosphere, such comparisons do not stand closer examination. In the absence of a clear, modern analogue we explore the isotope evolution of some simple, model melt compositions to investigate plausible means of producing an appropriate enriched component. Nd-Hf isotope characteristics provide the tightest constraints and can be reproduced by an ancient (∼3 Ga), modest-degree melt (∼2%) from a garnet peridotite source. Currently, modest-degree melts from garnet-bearing sources are found forming some major oceanic islands. Subduction, isolation and later mixing of small amounts (<5%) of such basaltic material with more ubiquitous ambient mantle can account for the isotopic characteristics of the enriched São Miguel source. Yet the incompatible element ratios of the enriched São Miguel lavas do not show “recycled” signatures of near-surface alteration nor subduction zone dehydration. Thus, we infer that the enriched component was originally under-plated basalt, intruded into oceanic mantle lithosphere rather than forming the island edifice itself. Since the extreme isotope compositions of São Miguel reflect unextraordinary, albeit ancient, magmatic fractionation, the general rarity of such signatures indicates the efficiency of mantle processes in homogenising or hiding similar sources.     

Use of geoprocessing in the study of land degradation in urban environments: the case of the city of São Carlos,state of São Paulo,Brazil

This paper presents a methodology for the geological engineering survey of land degradation in urban environments using both remote sensing and geoprocessing tools. The area under study was the city of São Carlos, state of São Paulo, Brazil (urban and expansion area). The data presented here were obtained from earlier studies, photointerpretation and geological engineering mapping. The Envi 4.1 software package was used to prepare the digital orthophotos that served as a reference base for the information. Orthorectification of the Ikonos image (PSM, 1 m) was done and compared with other orthophotos from studies of environmental degradation in urban areas. The evolution of land degradation processes was analyzed based on the photointerpretation of aerial photographs taken on different dates and using Ikonos image. This study allowed to conclude that most of the degradation occurring in the city has been caused by unplanned land occupation, in disregard of environmental conditions, resulting in environmental degradation and thus impacting the quality of life of the urban population.     

Geochemical and stable isotopic evolution of the Guarani Aquifer System in the state of São Paulo, Brazil

The purpose of this report is to explain geochemical and stable isotopes trends in the Brazilian unit of the Guarani Aquifer System (Botucatu and Piramboia aquifers) in S?o Paulo State, Brazil. Trends of dissolved species concentrations and geochemical modeling indicated a significant role of cation exchange and dissolution of carbonates in downgradient evolution of groundwater chemistry. Loss of calcium by the exchange for sodium drives dissolution of carbonates and results in Na–HCO₃ type of groundwater. The cation-exchange front moves downgradient at probably much slower rate compared to the velocity of groundwater flow and at present is located near to the cities of Sert?ozinho and águas de Santa Barbara (wells PZ-34 and PZ-148, respectively) in a shallow confined area, 50–70 km from the recharge zone. Part of the sodium probably enters the Guarani Aquifer System. together with chloride and sulfate from the underlying Piramboia Formation by diffusion related to the dissolution of evaporates like halite and gypsum. High concentrations of fluorine (up to 13.3 mg/L) can be explained by dissolution of mineral fluoride also driven by cation exchange. However, it is unclear if the dissolution takes place directly in the Guarani Aquifer System or in the overlying basaltic Serra Geral Formation. There is depletion in δ ²H and δ ¹⁸O values in groundwater downgradient. Values of δ ¹³C(DIC) are enriched downgradient, indicating dissolution of calcite under closed system conditions. Values of δ ¹³C(DIC) in deep geothermal wells are very high (>–6.0‰) and probably indicate isotopic exchange with carbonates with δ ¹³C about –3.0‰. Future work should be based on evaluation of vertical fluxes and potential for penetration of contamination to the Guarani Aquifer System. Electronic Publication     

Initial assessment of the infiltration and overland flow for different rainfall events in land constituted of sandstones of the Botucatu Formation (Guarani Aquifer), State of São Paulo, Brazil

This study was carried out in the Córrego do Vaçununga basin constituted of eolic sandstones of Botucatu Formation and residual unconsolidated materials (>90%), considered the most important unconfined aquifer in Brazil, in the city of Luiz Antonio, State of São Paulo, Brazil. Laboratory and in situ tests were performed to characterize the unconsolidated materials in terms of basic physical properties, potential infiltration rate, suction and hydraulic conductivity. The results for infiltration and overland flow depths were obtained according to Morel-Seytoux and Khanji (Water Resour Res 10(4):795–800, 1976) and Chu (Water Resour Res 14(3):461–466, 1978) adaptation of the Green and Ampt [J Agr Sci 4(Part 1):1–24, 1911] model for steady and transient rainfalls, respectively. Rainfall data were collected from January of 2000 to December of 2002, and 12 scenarios were defined considering the intensity and durations. Rather than high homogeneity in terms of the texture of unconsolidated materials, the infiltration and overland flow ratio depends on the type of land use and associated management practices. The results showed that rainfall with high intensity and short duration do not produce high overland flow ratio as we have observed for transient scenarios with long duration and low intensities.     

Fractional Crystallization and Liquid Immiscibility Processes in the Alkaline-Carbonatite Complex of Juqui (So Paulo, Brazil)

The Juqui circular intrusion, which is Cretaceous in age (130–135Ma), crops out in the Precambrian gneissic basement in Brazilover an area of 14 km2. It consists of olivine clinopyroxen-itecumulates (with minor olivine gabbros) in the northeastern sector(74 vol.%), whereas ijolites-melteigites-urtites (4%) and nephelinesyenites with minor essexites and syenodiorites (21%) outlinesubannular concentric patterns with an Mg-carbonatite core (1%), in the southwestern part of the complex. Petrographical, bulk rock, and mineral compositional trendsindicate that the origin of the complex can be largely accountedfor by shallow-level fractional crystallization of a carbonatedbasanitic parental magma. Such a magma was generated deep inthe subcontinental lithosphere by low-degree partial meltingof a garnet-phlogopite peridotite source. Mass-balance calculations in agreement with field volume estimatespermit definition of several fractionation stages of the magmaticevolution under nearly closed-system conditions, with inwarddevelopment of zonally arranged side-wall cumulates. These stagesinvolved: (1) fractionation from basanite to essexite magma(liquid fraction F = 33–5%) by crystallization of olivineclinopyroxenite plus minor olivine alkali gabbro cumulates;(2) derivation of the least differentiated mafic nepheline syenite(F = 5–5 %) from essexitic magma by subtraction of a syenodioriteassemblage; (3) exsolution of a carbonatite liquid (5%) froma CO₂-enriched mafic nepheline syenite magma, which also underwentcontinuous fractionation giving rise to ijolite-melteigite-urtitecumulates. The proportion of cumulus clinopyroxene and biotiteand intercumulus nepheline and alkali feldspar in these lastrocks, as well as the absence of alkalis in carbonatite, maybe attributed, at least in part, to loss of alkali-rich hydrousfluids released during and after the unmixing formation of thetwo conjugate liquids. The KD values determined for Mg-carbonatite/nepheline syeniteare lower (1–4–2–9) for light rare earth elements(LREE) than for REE from Eu to Yb (4–6–7–8),in contrast to recent experimental results (Hamilton et al.,1989). A possible explanation is that Juquia Mg-carbonatiterepresents an alreadydifferentiated magma, which underwent extensivefractionation of LREE-enriched calcite. In this way, the highvariability of K₀ REE patterns observed in several alkaline-carbonatitecomplexes can also be accounted for. The remarkably constant initial ⁸⁷Sr/⁸⁶Sr ratios (mostly between0–7052 and 0–7057) support the interpretation ofthe intrusion as having been generated by fractrional crystallizationand liquid immiscibility from a common parental magma. Iligherisotopic ratios (0–7060–0–7078), found mainlyin dykes and in the border facies of the intrusion, may be dueto contamination by the gecissic basement.     

Spatial policy and metropolitan economic growth in Sao Paulo,Brazil

The Sao Paulo Metropolitan Area is the second largest urban centre in terms of population among the developing countries of the world. The federal and state government authorities responsible for planning urban development in the State of Sao Paulo in Brazil have been actively considering whether to advocate a new policy initiative to decentralise manufacturing industry from the metropolitan area as a further strategy to restrain future growth. This paper discusses the particular situation facing policy-makers in Sao Paulo in the mid-eighties, as well as using the Sao Paulo policy problem to illustrate a number of themes of relevance to all would-be large city restraint strategies in developing nations. The paper draws upon a programme of research undertaken in the World Bank between 1980 and 1982; in particular, on a large industrial survey of companies establishing in new locations during 1977–1979 in the State. The policy recommendations are cautious, given continuing levels of ambiguity in policy objectives and of uncertainty in the pattern of underlying market forces.     

Global correlation of the Vazante Group, São Francisco Basin, Brazil: Re–Os and U–Pb radiometric age constraints

The Vazante Group consists of Precambrian carbonate-dominated platform deposits that extend along more than 300 km in the external zone of the Brasilia Fold Belt of the São Francisco Basin in east central Brazil. The sequence is about 4.8 km thick and contains a preserved glaciomarine diamictite unit (containing dropstone) at the top and a lower diamictite unit at the bottom. Previous C- and Sr-isotope profiles suggested the correlation of the upper diamictite unit with the “Sturtian” glacial event (ca. 750–643 Ma). However, new Re–Os isotope data from the shales associated with the upper diamictites yield radiometric age estimates between 993 ± 46 and 1100 ± 77 Ma. U–Pb measurements on a suite of clear euhedral zircon crystals that were separated from the same shales associated with the upper diamictite and from the arkosic sandstone above the lower diamictite yield ages as young as 988 ± 15 and 1000 ± 25 Ma, respectively. Based on the Re–Os and U–Pb ages, the best age estimate of the Vazante Group is constrained to be 1000–1100 Ma and thus the two diamictite units are not correlative with the Sturtian glaciation(s) but most likely are records of glacial events that occurred during the late Mesoproterozoic.     

华北和圣弗朗西斯科克拉通前寒武纪地质对比

一些学者提出华北克拉通在新元古代早期之前与圣弗朗西斯科克拉通（圣弗朗西斯科-刚果克拉通）相邻,但缺少证据;本文总结两个古陆地质记录,为评价这一古构造格局模型提供线索。两个古陆陆壳生长的峰期均为～2.7 Ga前;不同之处是,华北古陆经历了显著的～2.5 Ga前的陆壳生长和改造,而圣弗朗西斯科克拉通则似乎没有。华北古陆2.4～2.2 Ga期间发育少量变质火山-沉积岩系和花岗岩,～2.1 Ga前后广泛发育裂谷火山-沉积建造及侵入岩,2.0～1.9 Ga发育超高温变质作用和类似弧岩浆活动,导致两个克拉通（东、西华北克拉通）拼合形成统一的华北古陆;同一时期,圣弗朗西斯科克拉通南、北缘发育2.4～2.0 Ga岩浆作用,指示长期处于大陆边缘弧或者岛弧背景,～2.0 Ga还发育超高温变质作用。两个古陆都发育～2.0 Ga前类似大陆边缘弧特点的岩浆活动,只是圣弗朗西斯科克拉通时代稍早。1.8 Ga以来,两个古陆均发育多期岩墙群,部分基本同期,如～1.78 Ga岩墙群、～1.7 Ga岩墙群和～0.92 Ga岩墙群等;不同的是,华北古陆发育约1.3～1.2 Ga岩床/墙群,而圣弗朗西斯克拉通发育～1.5 Ga岩墙群。1.8～0.8 Ga,两个古陆上都断续发育（火山）-沉积建造：1.8～1.6 Ga以及1.4～1.2 Ga,两者的沉积建造同样以石英砂岩等碎屑岩为主,碳酸盐岩较少;1.2～1.0 Ga前,两者的记录均较少,或暂不能确定;1.0～0.8 Ga,两者均发育碎屑岩和碳酸盐岩;1.6～1.4 Ga,华北古陆发育碳酸盐岩建造,而圣弗朗西斯科克拉通则发育碎屑岩建造。华北古陆新元古界地层中碎屑锆石常显示～1.5 Ga的峰值,该期岩浆岩鲜少报道于华北古陆,但却见于圣弗朗西斯科克拉通。两个陆块都发育太古宙-古元古代条带状铁建造铁矿、古元古代石墨矿、中新元古代沉积-喷流型铅锌矿等。不过,华北古陆发育的古元古代硼矿、菱镁矿,中元古代碳酸岩型稀土矿等在圣弗朗西斯科不发育;而后者发育的绿岩带型相关金矿、镍矿、祖母绿宝石矿等,华北似乎不发育。另外,0.7～0.5 Ga,圣弗朗西斯科克拉通周边广泛发育泛非期造山带,而华北古陆并没有这一事件的明确记录;显生宙,圣弗朗西斯科克拉通相对稳定,中生代与刚果克拉通分离;但华北古陆内部经历强烈的构造-岩浆活动（峰期在中生代）。华北与圣弗朗西斯科克拉通前寒武纪是否相邻还需进一步地质对比和古地磁工作,尤其应关注约2.0～1.9 Ga岩浆-变质（造山）事件、约1.8～1.7 Ga岩浆-沉积（裂谷）事件以及约0.9 Ga岩浆-沉积（裂谷）事件。从地质记录的相似性角度来看,华北东南缘与圣弗朗西斯科南缘的地质记录相似性最大,可延续性最强,最可能相邻。