The Geochemistry of Lake Joyce, McMurdo Dry Valleys, Antarctica

Lake Joyce is one of the least studied lakes of the McMurdo Dry Valleys. Similar to other lakes in this region, Lake Joyce is a closed-basin, permanently ice-covered, meromictic lake. We present here a detailed investigation of major ions, nutrients, and dissolved trace elements for Lake Joyce. Specifically, we investigate the role of iron and manganese oxides and hydrous oxides in trace metal cycling.Lake Joyce is characterized by fresh, oxic waters overlying an anoxic brine, primarily Na–Cl. Surface waters have a maximum nitrate concentration of 26M with a molar dissolved inorganic nitrogen to phosphorus ratio of 477. The supply of nitrogen is attributed to atmospheric deposition, possibly from polar stratospheric clouds. Dissolved phosphorus is scavenged by hydrous iron oxides. The pH is highest (10.15) just beneath the 7-m thick ice cover and decreases to a minimum of 7.29 in the redox transition zone. Dissolved Al exceeds 8M in surface waters, and appears to be controlled by equilibrium with gibbsite. In contrast, concentrations of other trace elements in surface waters are quite low (e.g., 5.4nM Cu, 0.19nM Co, <20pM La). Dissolved Fe, Mn, Ni and Cd were below our detection limits of 13 nM, 1. 8 nM, 4.7 nM and 15pM (respectively) in surface waters. There was a 6-m vertical separation in the onset of Mn and Fe reduction, with dissolved Mn appearing higher in the water column than Fe. Based on thermodynamic calculations, dissolved Mn appears to be controlled by equilibrium with hausmannite (Mn3O4). Co tracks the Mn profile closely, suggesting Co(III) is bound in the lattice of Mn oxides, whereas the Ce profile is similar, yet the Ce anomaly suggests oxidative scavenging of Ce. Release of Cu, Ni, Cd and trivalent REE appears to be controlled by pH-induced desorption from Fe and Mn oxides, although Cu (and perhaps Ni) may be scavenged by organic matter in surface waters.     

Crystallization and Degassing in the Basement Sill, McMurdo Dry Valleys, Antarctica

The Basement Sill is part of the Ferrar Large Igneous Provinceexposed in the McMurdo Dry Valleys, Antarctica. The sill is330 m thick in the Bull Pass area and 450 + m thick in the Daisarea, 12 km to the west, and is characterized by phenocryst-freelower and upper margins and an orthopyroxene-rich central ‘tongue’(opx 1–5 mm in size). Halogen variations in apatite froma suite of samples collected along vertical transects throughthe sill were examined to evaluate the process of crystallization-induceddegassing (i.e. second boiling) and its effects on magma chemistry.Apatite grains from any given sample are generally unzoned withrespect to Cl and F concentrations, but may vary by 20–30mol% in the halogen site between grains. Overall average Cl/Fmass ratios increase with height from the lower margin to thecenter of the sill, and then decrease to near zero towards thetop margin where the rocks are relatively oxide-rich. The Cl/Ftrend parallels those of bulk MgO and grain size. The uppermargin contains abundant mafic pegmatoids and the apatite inthese segregations has lower Cl/F ratios compared with thatin the host-rocks, although REE show no measurable difference.Numerical modeling illustrates that a cooling and crystallizingsill initially develops two separate vapor-saturated zones atthe lower and upper margins owing to the irreversible heat lossto the cooler country rock. Vapor separating from the lowerzone migrates upward into hotter silicate liquid, where it isresorbed, thus increasing the Cl/F mass ratio of the liquid.This process leads to saturation and precipitation of apatitefrom the liquid with a higher Cl/F ratio than would otherwiseoccur. Volatile enrichment can also aid compaction and graingrowth in the central part of the sill. In contrast, the relativelyFe-rich, Cl-poor nature of the upper zone rocks suggests thatthese rocks may have crystallized from more evolved, degassedsilicate liquid, possibly compacted out of the underlying crystalmush. In addition, as vapor sourced from the lower and centralparts of the sill ascends into the cooler upper zone of thesill, the vapor may be localized (along with late interstitialsilicate liquid) to form pegmatoids at temperatures at whichCl is less favored in apatite and can be leached from existingapatite by the ascending vapor, the latter causing the observeddecrease in the Cl/F mass ratio of apatite in the (evolved)pegmatoids. KEY WORDS: Ferrar Igneous Province; halogens; fluid; apatite     

Shallow groundwater systems in a polar desert, McMurdo Dry Valleys, Antarctica

The McMurdo Dry Valleys (MDVs), Antarctica, exist in a hyperarid polar desert, underlain by deep permafrost. With an annual mean air temperature of ?18 °C, the MDVs receive <10 cm snow-water equivalent each year, collecting in leeward patches across the landscape. The landscape is dominated by expansive ice-free areas of exposed soils, mountain glaciers, permanently ice-covered lakes, and stream channels. An active layer of seasonally thawed soil and sediment extends to less than 1 m from the surface. Despite the cold and low precipitation, liquid water is generated on glaciers and in snow patches during the austral summer, infiltrating the active layer. Across the MDVs, groundwater is generally confined to shallow depths and often in unsaturated conditions. The current understanding and the biogeochemical/ecological significance of four types of shallow groundwater features in the MDVs are reviewed: local soil-moisture patches that result from snow-patch melt, water tracks, wetted margins of streams and lakes, and hyporheic zones of streams. In general, each of these features enhances the movement of solutes across the landscape and generates soil conditions suitable for microbial and invertebrate communities.     

Rare earth elements in the water column of Lake Vanda, McMurdo Dry Valleys, Antarctica

We present data on the composition of water from Lake Vanda, Antarctica. Vanda and other lakes in the McMurdo Dry Valleys of Antarctica are characterized by closed basins, permanent ice covers, and deep saline waters. The meromictic lakes provide model systems for the study of trace metal cycling owing to their pristine nature and the relative simplicity of their biogeochemical systems. Lake Vanda, in the Wright Valley, is supplied by a single input, the Onyx River, and has no output. Water input to the lake is balanced by sublimation of the nearly permanent ice cap that is broken only near the shoreline during the austral summer. The water column is characterized by an inverse thermal stratification of anoxic warm hypersaline water underlying cold oxic freshwater.Water collected under trace-element clean conditions was analyzed for its dissolved and total rare earth element (REE) concentrations by inductively coupled plasma mass spectrometry. Depth profiles are characterized by low dissolved REE concentrations (La, Ce, <15 pM) in surface waters that increase slightly (La, 70 pM; Ce, 20 pM) with increasing depth to ∼55 m, the limit of the fresh oxic waters. Below this depth, a sharp increase in the concentrations of strictly trivalent REE (e.g., La, 5 nM) is observed, and a submaximum in redox sensitive Ce (2.6 nM) is found at 60- to 62-m depth. At a slightly deeper depth, a sharper Ce maximum is observed with concentrations exceeding 11 nM at a 67-m depth, immediately above the anoxic zone. The aquatic concentrations of REE reported here are ∼50-fold higher than previously reported for marine oxic/anoxic boundaries and are, to our knowledge, the highest ever observed at natural oxic/anoxic interfaces. REE maxima occur within stable and warm saline waters. All REE concentrations decrease sharply in the sulfidic bottom waters. The redox-cline in Lake Vanda is dominated by diffusional processes and vertical transport of dissolved species driven by concentration gradients. Furthermore, because the ultraoligotrophic nature of the lake limits the potential for organic phases to act as metal carriers, metal oxide coatings and sulfide phases appear to largely govern the distribution of trace elements. We discuss REE cycling in relation to the roles of redox reactions and competitive scavenging onto Mn- and Fe-oxides coatings on clay sized particles in the upper oxic water column and their release by reductive dissolution near the anoxic/oxic interface.     

Carbon Sequestration and Release from Antarctic Lakes: Lake Vida and West Lake Bonney (McMurdo Dry Valleys)

Perennial ice covers on many Antarctic lakes have resulted in high lake inorganic carbon contents. The objective of this paper was to evaluate and compare the brine and CO₂ chemistries of Lake Vida (Victoria Valley) and West Lake Bonney (Taylor Valley), two lakes of the McMurdo Dry Valleys (East Antarctica), and their potential consequences during global warming. An existing geochemical model (FREZCHEM-15) was used to convert measured molarity into molality needed for the FREZCHEM model, and this model added a new algorithm that converts measured DIC into carbonate alkalinity needed for the FREZCHEM model. While quite extensive geochemical information exists for ice-covered Taylor Valley lakes, such as West Lake Bonney, only limited information exists for the recently sampled brine of >25 m ice-thick Lake Vida. Lake Vida brine had a model-calculated pCO₂ = 0.60 bars at the field pH (6.20); West Lake Bonney had a model-calculated pCO₂ = 5.23 bars at the field pH (5.46). Despite the high degree of atmospheric CO₂ supersaturation in West Lake Bonney, it remains significantly undersaturated with the gas hydrate, CO₂·6H₂O, unless these gas hydrates are deep in the sediment layer or are metastable having formed under colder temperatures or greater pressures. Because of lower temperatures, Lake Vida could start forming CO₂·6H₂O at lower pCO₂ values than West Lake Bonney; but both lakes are significantly undersaturated with the gas hydrate, CO₂·6H₂O. For both lakes, simulation of global warming from current subzero temperatures (?13.4 °C in Lake Vida and ?4.7 °C in West Lake Bonney) to 10 °C has shown that a major loss of solution-phase carbon as CO₂ gases and carbonate minerals occurred when the temperatures rose above 0 °C and perennial ice covers would disappear. How important these Antarctic CO₂ sources will be for future global warming remains to be seen. But a recent paper has shown that methane increased in atmospheric concentration due to deglaciation about 10,000 years ago. So, CO₂ release from ice lakes might contribute to atmospheric gases in the future.     

Contact Partial Melting of Granitic Country Rock, Melt Segregation, and Re-injection as Dikes into Ferrar Dolerite Sills, McMurdo Dry Valleys, Antarctica

Numerous, interconnected, granitic dikes (<30 cm in widthand hundeds of meters in length) cut Ferrar dolerite sills ofthe McMurdo Dry Valleys, Antarctica. The source of the graniticdikes is partial melting of granitic country rock, which tookplace in the crust at a depth of about 2–3 km adjacentto contacts with dolerite sills. Sustained flow of doleriticmagma through the sill generated a partial melting front thatpropagated into the granitic country rock. Granitic partialmelts segregated and collected at the contact in a melt-rich,nearly crystal-free reservoir adjacent to the initial doleritechilled margin. This dolerite chilled margin was subsequentlyfractured open in the fashion of a trapdoor by the graniticmelt, evacuating the reservoir to form an extensive complexof granitic dikes within the dolerite sills. At the time ofdike injection the dolerite was nearly solidified. Unusuallycomplete exposures allow the full physical and chemical processesof partial melting, segregation, and dike formation to be examinedin great detail. The compositions of the granitic dikes andthe textures of partially melted granitic wall rock suggestthat partial melting was characterized by disequilibrium mineraldissolution of dominantly quartz and alkali feldspar ratherthan by equilibrium melting. It is also unlikely that meltingoccurred under water-saturated conditions. The protolith granitecontains only 7 vol.% biotite and estimated contact temperaturesof 900–950°C suggest that melting was possible ina dry system. Granite partial melting, under closed conditions,extended tens of meters away from the dolerite sill, yet meltsegregation occurred only over less than one-half a meter fromthe dolerite chilled margin where the degree of partial meltingwas of the order of 50 vol.%. This segregation distance is consistentwith calculated length scales expected in a compaction-drivenprocess. We suggest that the driving force for compaction wasdifferential stress generated by a combination of volume expansionas a result of granite partial melting, contraction during doleritesolidification, and relaxation of the overpressure driving doleriteemplacement. On a purely chemical basis, the extent of meltsegregation necessary under fractional and batch melting tomatch the Rb concentrations between melt and parent rock isa maximum of 48 and 83 vol.% melt, respectively. KEY WORDS: Antarctica; dike injection; disequilibrium; granite partial melting; silicic melt segregation     

Micro-relief development in polygonal patterned ground in the Dry Valleys of Antarctica

Polygonal patterned ground in polar regions of both Earth and Mars has received considerable attention. In comparison with the size, shape, and arrangement of the polygons, the diverse micro-relief and topography (termed here simply “relief”) of polygonal patterned ground have been understudied. And yet, the relief reflects important conditions and processes occurring directly below the ground surface, and it can be observed readily in the field and through remote sensing. Herein, we describe the relief characteristic of the simplest and relatively young form of patterned ground in the Dry Valleys of Antarctic. We also develop a numerical model to examine the generation of relief due to subsurface material being shouldered aside contraction cracks by incremental sand wedges growth, and to down-slope creep of loose granular material on the surface. We model the longterm subsurface deformation of ice-cemented permafrost as a non-linear viscous material. Our modeling is guided and validated using decades of field measurements of surface displacements of the permafrost and relief. This work has implications for assessing the activity of surfaces on Earth and Mars, and much larger scale potential manifestations of incremental wedging in icy material, namely the distinct paired ridges on Europa.     

Landscape modification by meltwater channels at margins of cold-based glaciers, Dry Valleys, Antarctica

This article describes distinctive lateral meltwater channels at the margins of low-elevation cold-based glaciers in the Dry Valleys. The channels significantly modify the ground surface and indicate that cold-based glaciers can be active geomorphic agents. Summer meltwater from the glacier surface flows over ice-aprons and erodes into the frozen ground creating channels up to 3 m deep and 10 m wide adjacent to unmodified ground that is protected beneath the glacier itself. Rapid fluvial excavation in the channels leads to undercutting and collapse of channel walls, which is capable of overturning large boulders. During glacial retreat, a succession of channels is incised into newly exposed ground creating a distinctive series of nested lateral channels and ridges. These represent the most obvious and persistent geomorphological signature of cold-based glacier activity in the region. Cold-based glaciers may advance and retreat over the same area many times without necessarily destroying older features, thereby creating a complex series of channels, deposits and remnant surfaces with a disordered chronology. Recognizing the role of cold-based glaciers and their meltwater channels on landscape evolution is critical for interpreting the timing and style of glacial events in the Antarctic.     

Development of sediment–landform associations at cold glacier margins,Dry Valleys,Antarctica

The impact of modern cold glaciers on arid periglacial landscapes has received little attention compared with other glacial regimes, and there is a widely held assumption that cold glaciers are not effective geomorphological agents, despite recent studies to the contrary. This paper focuses on the processes operating at the margins of a number of glaciers in the Dry Valleys of Victoria Land, notably the Wright Lower Glacier. The glaciers are entraining primarily older drift deposits and highly weathered regolith which texturally are sandy gravels, as well as well‐sorted sands of fluvial origin. Despite basal temperatures of the order of ?16°C, frozen layers and blocks of sand and gravel are being incorporated into the base of the glaciers by folding and thrusting. The sedimentary products are ridges and aprons several metres high within which the principal lithofacies are sand, gravel, foliated glacier ice, lake ice and snow. These facies are glaciotectonized strongly. Draped over these landforms is a veneer of well‐sorted aeolian sand up to half a metre thick. Supraglacial streams flowing off the glaciers incise these landforms and the sediment is redeposited as alluvial fans, lake deltas and lake‐bottomset deposits. Overall the sediment/landform association differs markedly from those of other glacial regimes, with sand and gravel being the dominant facies, while the usual indicators of glacier working (such as facets and striations on clasts) are lacking. The preservation potential for these landforms on a thousand‐year time scale is high, as modification in this arid regime by slope processes and running water is limited. Sublimation of buried ice is so slow that ridge features are likely to remain ice‐cored almost indefinitely, modified only by wind transport and weathering.     

Large-scale Mechanical Redistribution of Orthopyroxene and Plagioclase in the Basement Sill, Ferrar Dolerites, McMurdo Dry Valleys, Antarctica: Petrological, Mineral-chemical and Field Evidence for Channelized Movement of Crystals and Melt

The Jurassic Ferrar dolerite sills of the McMurdo Dry Valleys,Antarctica represent the plumbing system for flood basalt eruptionsassociated with the breakup of Gondwana. Among the Ferrar sills,the 350–450 m thick cumulate-textured Basement Sill isdifferentiated into a Lower Marginal Zone (LMZ) gabbronorite,a thick Lower Zone (LZ) orthopyroxene–plagioclase orthocumulatepyroxenite, a strongly layered mela- to leuco-gabbronorite MiddleZone (MZ), a thick Upper Zone (UZ) gabbronorite with ferrogabbroicpods, and an Upper Marginal Zone (UMZ) gabbronorite. Texturesand mineral compositions in the LZ pyroxenite and MZ–UZgabbronorites are nearly identical, the main distinction beingthe greater relative proportion of plagioclase in the MZ–UZgabbronorites, and of pigeonite in the UZ. Most orthopyroxenein the LZ, MZ and UZ occurs as sub-euhedral, normally zonedprimocrysts, commonly with rounded plagioclase inclusions. Plagioclaseis usually sub-euhedral and normally zoned, but can containsodic cores interpreted to be xenocrystic. Orthopyroxene andfeldspar compositions thoughout the sill are generally fairlyuniform, and resemble the compositions of micro-phenocrystsin the chilled margins. We infer that the sill was filled bya c. 1250°C slurry of orthopyroxene + plagioclase phenocrystsor primocrysts that subsequently unmixed in response to buoyancyforces. The LZ websterite contains numerous anorthosite to gabbronoriteschlieren, veins and pipes (< 2 m diameter), which we interpretas fossil segregation channels. Textures and mineral compositionsin these felsic channels are very similar both to UZ and MZgabbronorites, and to the groundmass separating accumulatedorthopyroxene primocrysts in the LZ and MZ. We infer that plagioclase-charged,hydrous pore melt from the pyroxenite may have segregated, pooledand ascended through these conduits to feed growth of the UZgabbronorite. Detailed mapping shows that the pipes are separatedby about 15 m on average. Calculations suggest that this numberdensity of conduits could have drained the LZ cumulates of theirinterstitial melt + plagioclase in about 8 days. Sequences (eachc. 5–10 m thick) of layered leuco-gabbronorite in theMZ could represent intra-cumulate sills that formed from plagioclase-richslurries ascending in segregation channels. Fe–Ti-richpyroxenitic veins and pods (some pegmatitic) and an unusualcoarse-grained plagioclase facies occur at the contacts betweenmassive leuco-gabbronorite layers in the MZ. Discordant ferro-pegmatitepods and dykes occur throughout the UZ. We interpret these Fe-richpegmatoidal rocks as evolved residual melts expelled from thecompacting gabbronoritic cumulates of the MZ and UZ. KEY WORDS: Ferrar; cumulates; differentiation; Antarctica; layering     

Origin of crystalline,cold desert salts in the McMurdo region,Antarctica

The distribution of crystalline salt minerals in deposits in the McMurdo region of Antarctica has been examined to study the origin of these salts. Sulphate, chloride, sodium and calcium salts are most frequently encountered. Salts containing chloride and sodium ions become less common away from the coast. Sulphate salts are more regularly distributed but tend to be related isotopically to sea water sulphate. Salts containing magnesium ion tend to exist mainly on substrates composed of basic igneous rocks, whereas calcium and carbonate salts are present on all rock types in the region.These distributions show that salts of marine origin are regionally and quantitatively most important but that chemical weathering of mafic materials in rocks and soils is also significant. However, biological, volcanic and hydrothermal processes are or have been active contributing to salts in local areas, that include penguin rookeries and eastern Taylor Valley, the summit area of Erebus Volcano, and subsurface rocks, respectively.     

论中国盐湖

中国是一个多盐湖的国家，并有悠久的盐湖开发历史。第四纪盐湖主要分布于我国西部和东北部。笔者将中国盐湖划分为4个盐湖区和13个盐湖亚区。已知的4种盐湖水化学类型在中国均已找到。这些盐湖水化学类型以柴达木－塔里木东部干旱（极干旱）地区为中心，向外围发生有规律的变化。自第四纪以来，中国盐湖带反映出有6次以上干旱扩张期，该发现对于阐明中国乃于东亚第四纪古气候环境演变有着重要意义。     

Origin of blocky aragonite cement in Cenozoic glaciomarine sediments,McMurdo Sound,Antarctica

Inorganic aragonite occurs in a wide spectrum of depositional environments and its precipitation is controlled by complex physio-chemical factors. This study investigates diagenetic conditions that led to aragonite cement precipitation in Cenozoic glaciomarine deposits of McMurdo Sound, Antarctica. A total of 42 sandstones that host intergranular cement were collected from the CIROS-1 core, located proximal to the terminus of Ferrar Glacier. Standard petrography, Raman spectroscopy and electron microprobe analysis reveal a prominent aragonite cement phase that occurs as a pore-filling blocky fabric throughout the core. Oxygen isotope compositions (δ¹⁸O = −30·0 to −8·6‰ Vienna Pee-Dee Belemnite) and clumped isotope temperatures (TΔ₄₇ = 13·1 to 31·5°C) determined from the aragonite cements provide precise constraints on isotopic compositions (δ¹⁸O_w) of the parent fluid, which mostly range from −10·8 to −7·2‰ Vienna Standard Mean Ocean Water. The fluid δ¹⁸O_w values are consistent with those of pore water, previously identified as cryogenic brine in the nearby AND-2A core. Petrographic and geochemical data suggest that aragonite cement in the CIROS-1 core precipitated from a similar brine. The brine likely formed and infiltrated sediments in flooded glacial valleys along the western margin of McMurdo Sound during the middle Miocene Climatic Transition, and subsequently flowed basinward in the subsurface. Consequently, the brine forms as a longstanding subsurface fluid that has saturated Cenozoic sediments below southern McMurdo Sound since at least the middle Miocene. Aragonite cementation in the CIROS-1 core is interpreted to reflect its proximal position to sites of brine formation and greater likelihood of experiencing brines with sustained high carbonate saturation states and Mg/Ca ratios. This unusual occurrence expands the range of known natural occurrences of aragonite cement. Given the potential for cryogenic brine formation in glaciomarine settings, blocky aragonite, as the end member of the spectrum of aragonite cement morphology, may be more widespread in glaciomarine sediments than currently thought.     

Rare earth element evidence for differentiation of McMurdo volcanics,Ross Island,Antarctica

Eighteen samples of the McMurdo volcanics on Ross Island, Antarctica consisting of basanitoid, trachybasalt and phonolite have been analyzed for rare earth elements (REE) in order to determine the details of differentiation using quantitative trace element modeling. The basanitoids have REE patterns similar to those for alkali basalts or nephelinites from ocean islands. Since there is no correlation between REE and silica contents among five basanitoids, some of the variability in the REE contents must be related to the extent of partial melting, variation in the residual mineralogies of the mantle during melting, or to inhomogeneities in the REE composition of the mantle.In order to explain the data, more than one differentiation sequence is necessary. In each case a basanitoid melt is the parent which differentiates to trachybasalt upon separation of olivine, clinopyroxene, spinel, ±kaersutite±plagioclase±apatite. If clinopyroxene, kaersutite, anorthoclase, plagioclase and apatite separate from a trachybasalt melt, a mafic phonolite results.If, however, no kaersutite is involved, an anorthoclase phonolite results. A distinct type of mafic phonolite results if kaersutite is one of the minerals that separates from the anorthoclase phonolite. If the anorthoclase phonolite precipitates plagioclase and anorthoclase and if the melt reacts with plagioclase-rich continental rocks, a trachyte results.Formerly spelled: Shine Soon Sun     

The Origins of Glass and Amphibole in Spined--Wehrlite Xenoliths from Foster Crater, McMurdo Volcanic Group, Antarctica

Vesicular interstitial glass in four kaersutite-bearing spinel–wehrlitexenoliths from Foster Crater, Antarctica has reacted with hostolivine (Fo_75–79) and clinopyroxene (Ca₄₇ Mg₄₅ Fe₈) andcontains a microphenocryst assemblage of spinel, olivine, andclinopyroxene together with later rhonite and plagioclase. Electronmicroprobe analyses of the glasses have low SiO₂ (46–49wt. per cent) and MgO (2.2–3.7) contents and high contentsof alkalis, TiO₂ (3.4–4.8), Al₂O₃ (18.1–20.6) andP₂O₅ (1.1–1.3). Olivine microphenocryst cores in glassare magnesian (up to Fo₈₈) and must have precipitated from moreprimitive liquids; rim compositions are Fe-rich (Fo₇₅) and inequilibrium with glass. Continuous core to rim zonation in theolivine microphenocrysts indicate that glass compositions havefractionated due to crystallization of the enclosed mineralassemblage. Mass balance addition calculations, using the compositionsand proportions of the crystals in glass, produce melt compositionsappropriate to primary alkali basaltic magmas. Glasses showlight rare earth element (REE) enrichment relative to chondrites(Ce/YbN = 10.5) and, together with Ba, Rb, Cr, Hf, Ta, and Thare similar to many of the basanites from the Erebus VolcanicProvince. Textural relationships of the kaersutite are complex owing tothe instability of kaersutite in the presence of melt. However,in the association with glass we observe textural evidence suchas olivine and clinopyroxene microphenocrysts, identical tothe liquidus phases of the glasses, enclosed by kaersutite crystals.We believe that relationships such as this link the crystallizationof kaersutite to mafic melt which infiltrated and reacted withthe host wehrlite. Thus, the melt did not form in situ withinthe xenolith but originated elsewhere in the upper mantle.     

Rare earth element geochemistry of Late Cenozoic alkaline lavas of the McMurdo Volcanic Group, Antarctica

Rare earth element (REE) concentrations were determined in 16 Ross Island and northern Victoria Land alkaline lava samples which were representative of four lava lineages of the McMurdo Volcanic Group, Antarctica. A kaersutite and two feldspar mineral separates were also analysed.

Two of the lava lineages, a basanite to nepheline benmoreite and a basanite to phonolite, have similar chondrite-normalized REE fractionation patterns, with a continuous enrichment of light and heavy REE and depletion of middle REE. The patterns result from the fractionation of olivine, clinopyroxene, spinels, feldspar, kaersutite and apatite. Kaersutite is an important fractionated phase responsible for the middle REE depletion.

Another of the lava lineages is mildly potassic with trachyandesite to peralkaline K-trachyte lavas which have partly overlapping REE fractionation patterns. There is a depletion in REE from tristanite to K-trachyte. Fractionation of olivine, clinopyroxene, feldspar and apatite probably control the REE chemistry of the lineage, greater degrees of apatite fractionation deplete the K-trachyte in REE relative to the tristanite. Feldspar fractionation in the genesis of the peralkaline K-trachyte is shown by a large negative Eu anomaly (Eu/Eu* = 0.10).

A nepheline hawaiite to anorthoclase phonolite lava lineage from the Erebus Centre shows enrichment of REE, although minor overlapping in the middle REE does occur. Anorthoclase phonolite has a positive Eu anomaly (Eu/Eu* = 1.31), indicating possible accumulation of anorthoclase. The lineage resulted from fractionation of olivine, clinopyroxene, magnetite and apatite.     

Lipid biomarker analysis of cyanobacteria-dominated microbial mats in meltwater ponds on the McMurdo Ice Shelf,Antarctica

The lipid biomarker composition of microbial mat communities from three meltwater ponds from the McMurdo Ice Shelf, Antarctica, was investigated for the first time. Hydrocarbons, ether-linked components, fatty acids (FAs), wax esters, hopanols and sterols from Fresh, Orange and Salt Ponds were analysed. The dominance of cyanobacteria and the presence of bacterial sulfate reducers were confirmed using signature FAs in all three mats. Wax ester analysis suggested the presence of Chloroflexus spp. The dominance of short chain hydrocarbons, wax esters and FAs indicated that microorganisms are the major source of organic matter in these meltwater ponds. A variety of sterols were present in different relative abundances. The greatest diversity of sterols was in Salt Pond, followed by Fresh Pond, which was attributed to differences in the present eukaryotic diversity. Lipid profiles of the three communities were similar despite the presence of a salinity gradient. Analysis of lipid biomarkers allowed the creation of profiles for these unique Antarctic cryo-ecosystems. This will assist in the comparison of present and past microbial communities and in the monitoring of Antarctic biodiversity in response to global climate change and other environmental perturbations.     

Cenozoic noncoaxial transtension along the western shoulder of the Ross Sea, Antarctica, and the emplacement of McMurdo dyke arrays

Field data on Cenozoic faults and the McMurdo dyke arrays in the Reeves Glacier–Mawson Glacier area, Victoria Land, Antarctica, allow us to support noncoaxial transtensional tectonics along the N–S-trending western shoulder of the Ross Sea. Dyke injection within a crustal-scale right-lateral strike-slip shear zone is testified by magma filled, tension gash-like arrangements within some master fault zones, and by the left-stepping arrangements of dykes in the intrafault zones. The noncoaxiality of deformation is shown by the re-activation of many dyke walls as right-lateral strike-slip faults. This suggests an increase in the strike-slip component over time along the western shoulder of the Ross Sea. Our data support the relevance of transtensional to strike-slip tectonics for triggering melting and controlling the geometry and modes of magma emplacement.