Neoarchean and Paleoproterozoic granitoids marginal to the Jeceaba-Bom Sucesso lineament (SE border of the southern São Francisco craton): Genesis and tectonic evolution

The sialic crust of the southern São Francisco craton along the Jeceaba-Bom Sucesso lineament, central-southern part of Minas Gerais (Brazil), encompasses, among other rock types, Neoarchean and Paleoproterozoic granitoids. These granitoids, according to their petrographic, lithogeochemical and geochronologic characteristics, were grouped into two Neoarchean suites (Samambaia-Bom Sucesso and Salto Paraopeba-Babilônia) and three Paleoproterozoic suites (Cassiterita-Tabuões, Ritápolis and São Tiago). Varied processes and tectonic environments were involved in the genesis of these suites. In particular, the lithogeochemistry of the (Archean and Paleoproterozoic) TTG-type granitoids indicates an origin by partial melting of hydrated basaltic crust in a subduction environment. In the Neoarchean, between 2780 and 2703 Ma, a dominant TTG granitoid genesis related to an active continental margin was followed by another granite genesis related to crustal anatexis processes at 2612–2550 Ma. In the Paleoproterozoic, the generation of TTG and granites s.s. occurred at three distinct times: 2162, 2127 and 1887 Ma. This fact, plus the rock-type diversity produced by this granite genesis, indicates that the continental margin of the southern portion of the São Francisco craton was affected by more than one consumption episode of oceanic crust, involving different island arc segments, and the late Neoarchean consolidate continent. A Paleoproterozoic tectonic evolution in three stages is proposed in this work.     

Pb / Pb-ages of zircons from syn-collisional I-type porphyritic granites of the central Ribeira belt, SE Brazil

In the central segment of the Ribeira belt, southeast Brazil, several foliated porphyritic granitic bodies intrude high-grade migmatitic gneisses of the Andrelândia and Juiz de Fora domains and Embú Complex. Results of geological, geochemical and geochronological investigations of the Maromba, Pedra Selada, Serra do Lagarto and Funil porphyritic I-type granites provide profound similarities, except for the distinct geochemical behavior of the Funil Granite, perhaps related to a different crustal source. These granitoids show similar structural, textural and mineralogical features. Pb-evaporation of single zircons provided ages of 586 ± 6, 579.6 ± 6.3, 586.3 ± 4.8 and 584 ± 5 Ma for the granites, respectively, coincident with the syn-collision I episode of the central Ribeira belt. The intrusion of I-type porphyritic granitoids coeval with the main collisional event has not often been reported in the geological literature. The most common syn-collisional granitic magmatism has normally an S-type signature or even a slightly peraluminous I-type character. However, the occurrence of coeval I- and S-type syn-tectonic granites along the central Ribeira belt, as observed in the investigated area and discussed in this paper is noteworthy.     

Magnetic fabrics, rock magnetism, cathodoluminescence and petrography of apparently undeformed Bambui carbonates from São Francisco Basin (Minas Gerais State, SE Brazil): An integrated study

Magnetic measurements were performed on apparently undeformed limestones and carbonate shales from 44 sites in nearly horizontal stratigraphic layers mainly from the basal units of the Neoproterozoic Bambui Group in the southern part of the São Francisco Basin. Rock magnetism, cathodoluminescence, transmitted and reflected light microscopy analyses reveal that there is a mix of ferromagnetic minerals, mainly magnetite and pyrrhotite, in most sites. In some sites, however, the ferromagnetic minerals are magnetite and hematite. Fine-grained pyrrhotite and pyrite accompany rare fine-grained graphite and probably amorphous carbon in some of stylolites, while pyrrhotite is also present as larger interstitial masses in coarse-grained domains outside, but close to the stylolites. Magnetic fabrics were determined applying both anisotropy of low-field magnetic susceptibility (AMS) and anisotropy of anhysteretic remanence magnetization (AAR). The AAR tensor was less well defined than the AMS fabric due to the low ferromagnetic mineral content. The analysis at the individual-site scale defines three AMS fabric types. The first type (two sites) shows K_min perpendicular to the bedding plane, while K_max and K_int are scattered within bedding plane itself. This fabric is usually interpreted as primary (sedimentary-compactional), typical of totally undeformed sediments. The second type shows the three well-clustered AMS axes with K_min still perpendicular to the bedding plane. This fabric is the most important since it was found in the majority of the sites. The third type (two sites) is characterized by well-clustered K_max in the bedding plane, while K_min and K_int are distributed along a girdle. The second and third fabric types are interpreted as combinations of sedimentary-compactional and tectonic contributions at the earliest, and at a slightly later stage of deformation, respectively. AMS represents the contribution of all the rock-forming minerals, while AAR isolates the contribution of remanence-bearing minerals from the matrix minerals. However, rock magnetism shown that anhysteretic remanence only reaches grains with coercivity < 100 mT because the maximum AF in the majority of the available instruments is 100 mT. Therefore, hematite and pyrrhotite probably do not contribute to AAR, which is due to the shape-preferred orientation of magnetite grains. For some sites, the AMS and AAR fabric orientations are different, mainly with respect to the lineation orientations (K_max and A_max, respectively). In general, K_max is well developed and follows the trend of the main regional thrusts, fold axes and faults generated in the first deformational phase, while A_max follows both this trend and that of structural lineaments formed during the second deformational phase. These deformation phases arose from the compression, which occurred during the evolution of the Brasília fold belt during the last stages of the Brasiliano event. The magnetic fabrics of the apparently undeformed Bambui limestones are typical of very weakly deformed sediments, in which the depositional-compaction fabric has been partly overprinted by a tectonic one, with minimum susceptibility direction remaining perpendicular to bedding. This result is in agreement with the textures given by the petrographic observations.     

Magnetic fabrics and rock magnetism of Archaean and Proterozoic dike swarms in the southern São Francisco Craton, Brazil

Magnetic fabric and rock magnetism studies were performed on three mafic dike swarms (total of 38 dikes) from the southernmost part of the São Francisco Craton (SFC) (Minas Gerais State, SE Brazil). They cut Archaean granite–gneiss–migmatite and paleoprototerozoic terranes. These swarms are classified as basic–noritic (Sm–Nd age  2.65 Ga), basic (Rb–Sr age  1.87 Ga) and metamorphic (Rb–Sr age  1.87 Ga) suites, in which the second is the most important. Magnetic fabrics were determined by applying both anisotropy of low-field magnetic susceptibility (AMS) and anisotropy of anhysteretic remanent magnetization (AARM). In most sites magnetic susceptibility is dominantly carried by ferromagnetic minerals, however, in some sites the paramagnetic contribution exceeds 70% of bulk susceptibility. Mainly coarse to fine-grained Ti-poor titanomagnetite up to pure magnetite carry the magnetic fabrics.Three primary AMS fabrics are recognized which are all coaxial with the AARM fabric. Normal AMS fabric is dominant in the basic suite (16 of 20 analyzed dikes) and occurs in 4 and 3 dikes from the basic–noritic and metamorphic suites, respectively. This fabric is interpreted as a result of magma flow in which the analysis of K_max inclination permitted to infer that the majority of dikes were fed by inclined flows (30° < K_max < 60°), although 44% of dikes from the basic suite were fed by horizontal or sub-horizontal flows (K_max < 30°). Intermediate AMS fabric was found in 50% of dikes from the basic–noritic and metamorphic suites, but in only 2 dikes from the basic suite. It is interpreted as due to vertical compaction of a static magma column with the minimum stress along the dike strike. Inverse AMS fabric is a minority (2 dikes from each suite). The parallelism between AMS and AARM tensors for dikes with abnormal fabrics suggests a primary origin for them. Gyroremanent magnetization (GRM) effect was negligible for the majority of dikes, but it was found in two dikes from the basic suite with normal AMS fabric.Magnetic fabrics recognized for the three studied swarms do not depend on magnetic mineralogy, geochemical composition, dike strikes, nor the age of the swarms since the same magnetic minerals and magnetic fabric types are found in dikes from all suites. Inclined and horizontal flows allow us to infer the relative position of at least three magma sources (or magma chambers) from which the dikes were fed.     

Ages of Detrital Zircon from Siliciclastic Successions South of the São Francisco Craton, Brazil: Implications for the Evolution of Proterozoic Basins

In this work we report ²⁰⁷Pb/²⁰⁶Pb LA-ICPMS ages of 152 detrital zircons from lower greenschist facies quartzites from Proterozoic basin successions of the southern border of the São Francisco Craton, southern Minas Gerais State, Brazil. These are the intracratonic São João del Rei basin, the intraplate continental margin Andrelândia basin, and the Serra do Ouro Grosso sequence, developed on a crystalline basement older than 1.8 Ga, and deformed and metamorphosed during the Brasiliano Orogeny, ca. 0.59–0.50 Ga. The data constrain both the ages of the sources and the interval of sedimentation. The detrital zircons of the Serra do Ouro Grosso sequence were derived predominantly from the erosion of a Neoarchean crust, 2.5–2.8 Ga old, with only one grain showing a Paleoproterozoic age (2, 245±83 Ma) older than the Transamazonian event. Zircons extracted from a shelf quartzite of the lowermost sequence of the São João del Rei basin indicate derivation from the 1.8–2.2 Ga Transamazonian crust, with subordinate contribution from the 2.5–2.9 Ga Archean crust. The 1, 809±41 Ma age is interpreted as the maximum limit for sedimentation in this basin. The results confirm the regional correlation with the Espinhaço Rift successions. The zircons extracted from an autochthonous quartzite of the Andrelândia sequence yielded ages in the 1.0–2.2 Ga range, with a modal class at 1.2–1.3 Ga. Only two of the forty analyzed zircons yield Archean ages. The youngest zircon yields 1, 086±85 Ma. The zircons from the allochthonous quartzite yield ages between 1.0–2.7 Ga, with a modal class at 2.1–2.2 Ga. Only five of 45 analyzed grains yield Archean ages. The youngest zircon has an age of 1, 047±77 Ma. The results indicate that the detrital sediments deposited during the second marine flooding event of the Andrelândia sedimentation were mainly derived from the erosion of Mesoproterozoic and Paleoproterozic rocks. The 1, 047±77 Ma age is interpreted as the maximum depositional age for the described association.     

Geochemistry and Crustal Evolution of Volcano-sedimentary Successions and Orthogneisses in the São Gabriel Block, Southernmost Brazil — Relics of Neoproterozoic Magmatic Arcs

Precambrian metaplutonic rocks of the São Gabriel block in southernmost Brazil comprise juvenile Neoproterozoic calc-alkaline gneisses (Cambaí Complex). The connection with associated (ultra-)mafic metavolcanic and metasedimentary rocks (Palma Group) is not well established. The whole complex was deformed during the Brasiliano orogenic cycle. Both metasedimentary and metavolcanic rocks as well as metaplutonic rocks of the Cambaí Complex have been sampled for geochemical analyses in order to get constraints on the tectonic setting of these rocks and to establish a tectonic model for the São Gabriel block and its role during the assembly of West-Gondwana. The major element compositions of the igneous rocks (Palma Group and Cambaí Complex) indicate a subalkaline character; most orthogneisses have a calc-alkaline chemistry; many metavolcanic rocks of the Palma Group show signatures of low-K tholeiitic volcanic arc basalts. Trace element data, especially Ti, Zr, Y, Nb, of most igneous samples from both the lower Palma Group and the Cambaí Complex indicate origin at plate margins, i.e., in a subduction zone environment. This is corroborated by relative enrichment in LREE, low contents of Nb and other high field strength elements and enrichment in LILE like Rb, Ba, and Th. The data indicate the possible existence of two suites, an oceanic island arc and a continental arc or active continental margin. However, some ultramafic samples of the lower Palma Group in the western São Gabriel block indicate the existence of another volcanic suite with intra-plate character which possibly represents relics of oceanic island basalts (OIB). Trace element data indicate contributions from andesitic to mixed felsic and basic arc sources for the metasedimentary rocks. The patterns of chondrite- and N-MORB-normalized spider diagrams resemble the patterns of the igneous rocks, i.e., LILE and LREE enrichment and HFS depletion. The geochemical signatures of most igneous and metasedimentary samples and their low (⁸⁷Sr/⁸⁶Sr)_t ratios suggest only minor contribution of old continental crust.A geotectonic model for the São Gabriel block comprises east-ward subduction and following accretion of an intra-oceanic island arc to the eastern border of the Rio de la Plata Craton at ca. 880 Ma, and westward subduction beneath the newly formed active continental margin between ca. 750 and 700 Ma. The São Gabriel block represents relics of an early Brasiliano oceanic basin between the Rio de la Plata and Kalahari Cratons. This ocean to the east of the Rio de la Plata Craton might be traced to the north and could possibly be linked with Neoproterozoic juvenile oceanic crust in the western Brasília belt (Goiás magmatic arc).     

Global correlation of the Vazante Group, São Francisco Basin, Brazil: Re–Os and U–Pb radiometric age constraints

The Vazante Group consists of Precambrian carbonate-dominated platform deposits that extend along more than 300 km in the external zone of the Brasilia Fold Belt of the São Francisco Basin in east central Brazil. The sequence is about 4.8 km thick and contains a preserved glaciomarine diamictite unit (containing dropstone) at the top and a lower diamictite unit at the bottom. Previous C- and Sr-isotope profiles suggested the correlation of the upper diamictite unit with the “Sturtian” glacial event (ca. 750–643 Ma). However, new Re–Os isotope data from the shales associated with the upper diamictites yield radiometric age estimates between 993 ± 46 and 1100 ± 77 Ma. U–Pb measurements on a suite of clear euhedral zircon crystals that were separated from the same shales associated with the upper diamictite and from the arkosic sandstone above the lower diamictite yield ages as young as 988 ± 15 and 1000 ± 25 Ma, respectively. Based on the Re–Os and U–Pb ages, the best age estimate of the Vazante Group is constrained to be 1000–1100 Ma and thus the two diamictite units are not correlative with the Sturtian glaciation(s) but most likely are records of glacial events that occurred during the late Mesoproterozoic.     

U–Pb and Sm–Nd geochronology of amphibolites from the Curaçá Belt, São Francisco Craton, Brazil: Tectonic implications

The Curaçá terrane is part of the Itabuna–Salvador–Curaçá (I–S–C) Paleoproterozoic orogen in the São Francisco craton, northeastern Brazil, and comprises supracrustal rocks, gneisses of their probable basement, amphibolites, and mafic-ultramafic Cu-bearing bodies (including the Caraíba Cu-Mine), all affected by D₁-D₃ deformation events associated to M₁-M₃ metamorphism under high-T granulite and amphibolite facies, and assisted by G₁-G₃ tonalitic-granodioritic-granitic intrusions. U–Pb and Sm–Nd Thermal Ionization Mass Spectrometry (TIMS) isotopic data from amphibolite, tonalite, and granite, sampled in a well-known outcrop, indicate partial reset and heterogeneous modification of the original isotopic systems, attributable to deformation and metamorphism. The ages obtained from these systems agree with each other, and also with other previously published U–Pb data, and imply that 2.6 Ga is the crystallization age of the protolith of the amphibolite. Together with key structural relationships, they also indicate a 2.08–2.05 Ga interval for M₃ metamorphism, and make even a less precise age (2.2–2.3 Ga) acceptable, as it suggests contamination in the amphibolite with material in a syn-D₂ tonalite crystallized 2248 ± 36 Ma ago. The new data demonstrate the existence of Neoarchean fragments of both oceanic and continental crusts and constrain the Archean-Paleoproterozoic development of the Curaçá belt, the I–S–C orogen, and the São Francisco craton.     

Territorial exclusion and violence: the case of the state of São Paulo, Brazil

If we had to point out one single feature to define Brazilian cities today, it would be the existence of a dual built environment: a landscape produced by private entrepreneurs and contained within the framework of detailed urban legislation, and another one, three times greater, self-produced by the poor and eternally situated in an intermediate zone between the legal and the illegal. In addition to being an expression of economic and social disparities, this contrast has profound implications on the form and functioning of the cities. The sprawl of the precarious peripheries has lead to an absurd disconnection of poorly urbanized spaces and the city center where jobs, cultural and economic opportunities are concentrated. The effects of this persistent territorial exclusion are devastating and occur in both the peripheries and the city center. The purpose of this paper is to explore the nexus between the precarious and risky urbanization which took place in Brazilian cities and the urban violence that seems to be the most recent and visible face of this model, using the concrete example of different cities in the state of São Paulo. In order to construct the links it is first important to understand how patterns of economic development and population trends have contributed to the generation of risk urbanization and how planning and urban management policies interact with it.     

Chemostratigraphy of the Tamengo Formation (Corumbá Group,Brazil): A contribution to the calibration of the Ediacaran carbon-isotope curve

The Corumbá Group, cropping out in the southern Paraguay Belt in Brazil, is one of the most complete Ediacaran sedimentary archives of palaeogeographic, climatic, biogeochemical and biotic evolution in southwestern Gondwana. The unit hosts a rich fossil record, including acritarchs, vendotaenids (Vendotaenia, Eoholynia), soft-bodied metazoans (Corumbella) and skeletal fossils (Cloudina, Titanotheca). The Tamengo Formation, made up mainly of limestones and marls, provides a rich bio- and chemostratigraphic record. Several outcrops, formerly assigned to the Cuiabá Group, are here included in the Tamengo Formation on the basis of lithological and chemostratigraphical criteria. High-resolution carbon isotopic analyses are reported for the Tamengo Formation, showing (from base to top): (1) a positive δ¹³C excursion to +4‰ PDB above post-glacial negative values, (2) a negative excursion to −3.5‰ associated with a marked regression and subsequent transgression, (3) a positive excursion to +5.5‰, and (4) a plateau characterized by δ¹³C around +3‰. A U-Pb SHRIMP zircon age of an ash bed interbedded in the upper part of the δ¹³C positive plateau yielded 543 ± 3 Ma, which is considered as the depositional age ( Babinski et al., 2008a). The positive plateau in the upper Tamengo Formation and the preceding positive excursion are ubiquitous features in several successions worldwide, including the Nama Group (Namibia), the Dengying Formation (South China) and the Nafun and Ara groups (Oman). This plateau is constrained between 542 and 551 Ma, thus consistent with the age of the upper Tamengo Formation. The negative excursion of the lower Tamengo Formation may be correlated to the Shuram–Wonoka negative anomaly, although δ¹³C values do not fall beyond −3.5‰ in the Brazilian sections. Sedimentary breccias occur just beneath this negative excursion in the lower Tamengo Formation. One possible interpretation of the origin of these breccias is a glacioeustatic sea-level fall, but a tectonic interpretation cannot be completely ruled out.     

Paleoproterozoic Crustal Evolution of the São Luís Craton, Brazil: Evidence from Zircon Geochronology and Sm-Nd Isotopes

The São Luís Craton, northern Brazil, is composed of a few granitoid suites and a metavolcano-sedimentary succession. New single zircon Pb evaporation ages and Nd isotope data, combined with other available information, show that the metavolcano-sedimentary succession developed from 2240 Ma to approximately 2200-2180 Ma from juvenile protoliths. The subduction-related calc-alkaline suites of granitoids, spatially associated with the metavolcano-sedimentary sequence, formed in an oceanic island arc setting between 2168-2147 Ma. Most of these granitoids are tonalitic and formed from juvenile, mantle- or oceanic plate-derived protoliths, whereas minor true granites are the product of the reworking of the juvenile island arc material. These arc-related successions represent an accretionary event around 2.20±0.05 Ga, which is coincident with one of the main periods of crustal growth in the South American Platform. This accretionary orogen has subsequently been involved in a collision episode, at ca. 2100-2080 Ma, which is mainly recorded in the nearby Gurupi Belt. The rock associations, inferred geological settings, and the crustal evolution detected in the São Luís Craton are similar to what is described in Paleoproterozoic domains of major geotectonic units of the South American Platform, such as part of the São Francisco Craton, southeastern Guyana Shield, and of the West African Craton.     

Petrology of ultramafic nodules from São Tomé Island, Cameroon Volcanic Line (oceanic sector)

Ultramafic xenoliths were found in recent alkali basalts from São Tomé Island. These include spinel peridotites (lherzolites, harzburgites and dunites) and pyroxenites (orthopyroxenites and clinopyroxenites). Textures and mineral compositions indicate that pyroxenites originated from crystal/liquid separation processes operating on magmas similar to those giving rise to their present host rocks whereas spinel peridotite xenoliths had an accidental origin; Fo (>89) and Ni (>0.36 wt.%) contents in olivines, Mg# (91–95) of orthopyroxenes and low Ti in clinopyroxene (primary crystals: TiO₂<0.06 wt.%) and in spinel (TiO₂<0.1 wt.%) are within the range reported for abyssal peridotites, indicating São Tomé spinel peridotites represent refractory residues of melting. Nevertheless, the lack of correlation between mineral chemistry and modal composition suggests that spinel peridotite xenoliths are not simple residues and were affected by infiltration of fluid/melts within the mantle. The wide temperature range obtained for spinel peridotites (700 to >1150 °C) is compatible with a long period of pre-entrainment cooling supporting Fitton's [Tectonophysics 94 (1983) 473] hypothesis that proposes oceanic lithosphere uprising in the Cameroon Volcanic Line prior to the initiation of the current thermal regime, related to São Tomé magmatism. The association of upper mantle (peridotite) xenoliths with igneous cumulates (pyroxenites) suggests that the spinel peridotite suite originated in the uppermost mantle above the São Tomé magma storage zone(s), probably in a region of high strain rate, near the boundary between the mantle and the overlying oceanic crust.     

Sediment hosted lead–zinc deposits of the Neoproterozoic Bambuí Group and correlative sequences, São Francisco Craton, Brazil: A review and a possible metallogenic evolution model

The Proterozoic sediment-hosted Zn–(Pb) sulfide and non-sulfide deposits of the São Francisco Craton, Brazil, are partially syn-diagenetic and epigenetic and were probably formed during extensional events. The majority of the deposits occur within shallow water dolomites. The Pb isotopic data of sulfides are relatively homogeneous for individual deposits and plot above the upper crust evolution curve of the Plumbotectonic model. Some of the deposits are characterized by highly radiogenic lead (²⁰⁶Pb/²⁰⁴Pb ≥ 21) originating from the highly radioactive crust of the São Francisco Craton. Pb and S isotopic data suggest the sources of metal and sulfur for the deposits to be the basement rocks and seawater sulfates in the sediments, respectively. The relatively high temperatures of formation (100 to 250 °C) and moderate salinity (3% to 20% NaCl equiv.) of the primary fluid inclusions in the sphalerite crystals suggest the participation of basinal mineralizing fluids in ore formation. The steep paleo-geothermal gradient generated by the radioactively enriched basement rocks probably assisted in heating up the circulating mineralizing fluids.     

Reconstructing the migration patterns of late Pleistocene mammals from northern Florida, USA

We used analyses of the strontium isotope (⁸⁷Sr/⁸⁶Sr) ratios of tooth enamel to reconstruct the migration patterns of fossil mammals collected along the Aucilla River in northern Florida. Specimens date to the late-glacial period and before the last glacial maximum (pre-LGM). Deer and tapir displayed low ⁸⁷Sr/⁸⁶Sr ratios that were similar to the ratios of Florida environments, which suggest that these taxa did not migrate long distance outside of the Florida region. Mastodons, mammoths, and equids all displayed a wide range of ⁸⁷Sr/⁸⁶Sr ratios. Some individuals in each taxon displayed low ⁸⁷Sr/⁸⁶Sr ratios that suggest they ranged locally, while other animals had high ⁸⁷Sr/⁸⁶Sr ratios that suggest they migrated long distances (> 150 km) outside of the Florida region. Mastodons were the only taxa from this region that provided enough well-dated specimens to compare changes in migration patterns over time. Pre-LGM mastodons displayed significantly lower ⁸⁷Sr/⁸⁶Sr ratios than late-glacial mastodons, which suggests that late-glacial mastodons from Florida migrated longer distances than their earlier counterparts. This change in movement patterns reflects temporal changes in regional vegetation patterns.     

Petrology and thermobarometry of mafic granulites and migmatites from the Chafalote Metamorphic Suite: New insights into the Neoproterozoic P–T evolution of the Uruguayan—Sul-Rio-Grandense shield

This paper reports a study of the metamorphic evolution of pelitic, semi-pelitic migmatites and mafic granulites of the Chafalote Metamorphic Suite (CMS), Uruguay, which represents the southernmost exposures of high-grade metamorphic rocks in the Dom Feliciano Belt, Uruguain—Sul-Rio-Grandense shield, South America. This belt is one of the Brasiliano orogens that crop out along the Brazilian and Uruguayan Atlantic margin, and the CMS is one of several disconnected segments of supracrustal rock in a dominantly granitic terrain. Petrological evidence from CMS mafic granulites and semi-pelitic migmatites indicates four distinct metamorphic assemblages. The early prograde assemblage (M₁) is preserved only as inclusions in porphyroblasts of the peak-metamorphic (M₂) assemblage. Peak-metamorphism was followed by near-isothermal decompression (M₃), which resulted in symplectites and coronitic textures in the mafic granulites and compositional zoning of Ca in garnet (decreasing rimwards) and plagioclase (increasing rimwards) in the semi-pelitic migmatites. The retrograde metamorphic assemblage (M₄) is represented by hydration reaction textures replacing minerals of the M₂ and M₃ assemblages. Average P–T calculations using the program THERMOCALC and conventional thermobarometric methods yield peak-metamorphic (M₂) P–T conditions of 7–10 kbar and 830–950 °C, near-decompressional (M₃) P–T conditions of 4.8–5.5 kbar and 788–830 °C and M₄ retrograde P–T conditions of 3–6 kbar and 600–750 °C. The calculated P–T path for the CMS rocks is ‘clockwise’ and incorporates a near-isothermal decompression segment followed by minor cooling, consistent with a history of crustal thickening followed by extensional collapse at ca. 650–600 Ma. The metamorphism recorded by rocks of this crustal segment may be correlated with 650 Ma metamorphism in the Coastal Terrane of the Kaoko Belt in Namibia, being the first unequivocal match between South America and Africa provided by crystalline rocks south of the Congo Craton.     

Dolomitic marbles and associated calc-silicates, Tandilia belt, Argentina: Geothermobarometry, metamorphic evolution, and P–T path

The metamorphic evolution of dolomitic marbles and associated calc-silicate rocks from Punta Tota (NE Tandilia belt, Buenos Aires province, Argentina) has been evaluated through petrographic, geothermobarometric, and fluid inclusion studies. Thin beds of dolomitic marble are intercalated in amphibolites and constitute the upper part of a stratified basement sequence, which starts at the base with garnet migmatites showing a great abundance of pegmatitic segregates, overlain by biotite–garnet gneisses. Peak metamorphic conditions are estimated at 750–800 °C and 5–6 kb, followed by near isobaric cooling to about 500–450 °C and 5.5–6.5 kb. Anhydrous progressive metamorphic assemblages in both marbles (Fo + Cal + Dol + Cpx + Spl) and adjacent calc-silicate rocks (Cpx + An + Cal + Qtz) strongly retrogressed to hydrous minerals (Tr, Tlc, Grs, Czo, Srp) with decreasing temperatures and increasing water activities. The intense rehydration of the rocks relates to the emplacement of volatile-rich pegmatitic bodies (Qtz + Pl + Kfs + Bt + Grt), which also resulted in the crystallization of clinochlore + phlogopite in the marble and biotite + muscovite in the adjacent calc-silicate rocks. Metamorphic reactions based on textural relations and evaluated on a suitable petrogenetic grid, combined with geothermobarometric results and fluid inclusion isochores, indicate a metamorphic evolution along a counterclockwise P–T path. Two probable geotectonic settings for the determined P–T trajectory are proposed: (1) thinning of the crust and overlying supracrustal basin in an ensialic intraplate tectonic setting and (2) development of a marginal back-arc basin, associated with an oceanic–continental convergent plate margin. In both models, the initial extensional regime is followed by a compressional stage, with overthickening of the basement and supracrustal rocks, during the climax of the Transamazonian cycle at approximately 1800 Ma ago. Continuous convergence and blockage of structures produce transition to transcurrent tectonics (transpression) with a consequent moderate uplift.     

Botryococcus—A planktonic green alga, the source of petroleum through the ages: Transmission electron microscopical studies of oil shales and petroleum source rocks

The hydrocarbon secreting alga Botryococcus has been identified in organic remains of sediments ranging from Precambrian to Recent, and is believed to have been a major source material for petroleum generation throughout the geological time. In some petroleum source rocks of Lower Palaeozoic and Precambrian age, identification of the alga is only possible by electron microscopy. Transmission electron microscopy (TEM) has been used in the present study to identify microstructures of the algal remains in a range of oil shales and petroleum source rocks. It has been established that Botryococcus is the predominant alga in the Kukersite oil shale of Estonia. Similarly, the alga has been shown to be a major contributor to petroleum source rocks in Cambrian and Precambrian sedimentary basins in Australia. TEM has been applied to observations of Botryococcus in torbanites and to products from simulated maturation experiments on torbanite. A comparison with algal remains from Cambrian and Precambrian sediments ranging from undermature to overmature, enabled the distinction of organic matter in various stages of oil generation. Maturation/thermal effects on alginite have been established by reflectance and fluorescence, and compared with experimental results.     

Taxonomy and affinity of Early Mesoproterozoic megascopic helically coiled and related fossils from the Rohtas Formation, the Vindhyan Supergroup, India

A well preserved assemblage of compressed, straight, circular to sinuously coiled megascopic and helical carbonaceous fossils and other varied megascopic morphoforms are known from the Early Mesoproterozoic Rohtas Formation, Semri Group within Vindhyan Supergroup exposed in Katni district of central India. These megascopic remains are preserved as impressions, compressions, partially mineralized remains, and/or epi-relief. Some of the forms are typical filamentous empty sheaths and others are trichomes, with cell like entities under various stages of degradation. This study, based on fresh collections and also of the topotype material of the helically coiled megascopic fossils, straight forms and related fossilized remains occurring as epi-relief from Katni indicate that the two morphotaxa are distinct entities and possibly appear to be prokaryotes. Grypania spiralis and Katnia singhii are most likely of cyanobacterial origin. Spirally coiled and circular fossils, with epi-relief, and which probably represents a tissue grade organism, are considered as Spiroichnus beerii Mathur, 1983. Linear sheet-like carbonaceous solitary form has been placed in the morphotaxon Proterotainia and described as P. katniensis n. sp. Certain rare circular, carbonaceous forms are considered as Chuaria sp. A few circular disc-like forms found in the assemblage are treated as dubiofossils.