Geophysical Study of Annular Well Seals

Geophysical logging was conducted in 35 in-service water and monitoring wells installed in unconsolidated sediments using a downhole ultrasonic probe to assess how sealant type, construction method, and site geology affect annular seals. Collapsed sand and gravel was frequently detected in the annulus of wells constructed with mud-rotary methods, precluding the placement of sealant and, in some wells, potentially providing a preferential pathway for contamination. High-solids bentonite grout appeared to create high-quality seals when formation materials did not collapse into the annulus. Seals composed of bentonite chips and pellets remained intact when hydrated upon placement; those not hydrated during placement remained dry and porous, posing a risk of surface water infiltration. Seals made with cement-bentonite grout were generally unsaturated and possibly cracked. Analysis of the data suggests that well designers should specify a construction method that minimizes collapse of the formation to ensure that the sealant is placed where intended. When collapse is avoided, high-solids bentonite grout and hydrated bentonite chips and pellets appear to yield intact seals. However, bentonite chips and pellets may not hydrate adequately in the annulus unless hydration water is added during installation. When cement-bentonite grouts are used, the well designer should ensure that the grout will remain intact and plastic after installation.     

A Dry Injection System for the Emplacement of Filter Packs and Annular Seals in Ground Water Monitoring Wells

The reliability of filter pack and annular seal emplacements, and the degree of integrity of installed seals, are two of the most important factors to be considered when both installing and later utilizing ground water monitoring wells.
Numerous, and often costly, problems of using existing methods of installing filter packs and annular seals during the construction of ground water monitoring wells have led to the development of a technique of installing these monitoring well components using a dry injection system.
The dry injection system has been used to construct monitoring wells in extremely complex overburden/bedrock environments with a variety of drilling techniques. The system has shown that a high degree of reliability in the, construction of monitoring wells and greater confidence in obtaining representative ground water samples can be achieved over existing methods of filter pack and annular seal emplacement. The system has also been more cost effective than existing methods, especially for deep boreholes and multilevel monitoring system installations.     

New Method for Continuous Transmissivity Profiling in Fractured Rock

A new method is presented to search for hydraulically transmissive features in open boreholes in bedrock. A flexible borehole liner made of a watertight, nylon fabric is filled with water to create a constant driving head to evert (reverse of invert) the liner down the hole so that the liner pushes the borehole water out into transmissive fractures or other permeable features. The descent rate is governed by the bulk transmissivity of the remaining permeable features below the liner. Initially, the liner descent rate or velocity is a measure of transmissivity (T) of the entire hole. As the everting liner passes and seals each permeable feature, changes in the liner velocity indicate the position of each feature and an estimate of T using the Thiem equation for steady radial flow. This method has been performed in boreholes with diameters ranging from 96 to 330 mm. Profiling commonly takes a few hours in holes 200‐ to 300‐m long. After arrival of the liner at the bottom of the hole, the liner acts as a seal preventing borehole cross connection between transmissive features at different depths. Liner removal allows the hole to be used for other purposes. The T values determined using this method in a dolostone aquifer were found to be similar to the values from injection tests using conventional straddle packers. This method is not a replacement for straddle‐packer hydraulic testing of specific zones where greater accuracy is desired; however, it is effective and efficient for scanning entire holes for transmissive features.     

Bioaccumulation of radiocaesium in Arctic seals

Seals are high trophic level feeders that bioaccumulate many contaminants to a greater degree than most lower trophic level organisms. Their trophic status in the marine food web and wide-spread distribution make seals useful sentinels of arctic environmental change. The purpose of this investigation is to document the levels and bioaccumulation potential of radiocaesium in high latitude seal species for which data have not previously been available. The study was carried out on harp, ringed, and bearded seals caught north of the island archipelago of Svalbard (82°N) in 1999. The results are then compared with previous studies in order to elucidate factors responsible for bioaccumulation in Arctic seals. Concentrations of ¹³⁷Cs were determined in muscle, liver and kidney samples from a total of 10 juvenile and one adult seal. The mean concentration in muscle samples for all animals was 0.23±0.045 Bq/kg f.w. ¹³⁷Cs concentrations in both liver and kidney samples were near detection limits (≈0.2 Bq/kg f.w.). The results are consistent with previous studies indicating low levels of radiocaesium in Arctic seals in response to a long term trend of decreasing levels of ¹³⁷Cs in the Barents Sea region. Bioconcentration factors (BCFs) estimated for seals from NE Svalbard are low, ranging from 34 to 130. Comparing these values with reported BCFs for Greenland seals from other sectors of the European Arctic, we suggest that the combination of physiological and ecological factors on radiocaesium bioaccumulation is comparable among different Arctic seal populations. The application of this work to Arctic monitoring and assessment programs is discussed.     

Contamination from Sand-Bentonite Seal in Monitoring Wells Installed in Aquitards

A six year field experiment has shown that a sand-bentonite mixture used to seal monitoring wells in aquitards contributes solutes to the ground water sampled from these wells. Monitoring wells were installed at field sites with hydraulic conductivity (K) ranging from 5 × 10 ^-9 m/s to 3 × 10¹¹ m/s. In most cases the boreholes remained dry during installation which allowed the placement of a dry powdered bentonite/sand mixture tagged with potassium bromide (KBr) to seal and separate sampling points. Over six years, wells were sampled periodically and ground-water samples were analyzed for Br and Cl and other major ions. Typical Br results ranged from 10 mg/1 to 35 mg/1 in the first 700 days, as compared to an estimated initial concentration in the seal material of about 75 mg/1. After six years the bromide concentrations had decreased to between 3 mg/1 and 5 mg/1. The total mass of Br removed in six years is less than 50% of that placed; therefore the contamination effects, although considerably diminished, persist. The trends of Br, Cl, Na, and SO₄ indicate that varying degrees of contamination occur. These data show that the materials used to seal monitoring wells in aquitards can have a significant and long-lasting impact on the chemistry of the water in the wells.     

Long-Term Confidence in Ground Water Monitoring Systems

State-of-the-art analytical techniques are capable of detecting contamination In the part per billion (ppb) range or lower. At these levels, a truly representative ground water sample Is essential to precisely evaluate ground water quality. The design specifications of a ground water monitoring system are critical in ensuring the collection of representative samples, particularly throughout the long-term monitoring period.
The potential interfaces from commonly used synthetic well casings require a thorough assessment of site, hydrogeology and the geochemical properties of ground water. Once designed, the monitoring system must be installed following guidelines that ensure adequate seals to prevent contaminant migration during the installation process or at some time in the future. Additionally, maintaining the system so the wells are in hydraulic connection with the monitored zone as well as periodically Inspecting the physical integrity of the system can prolong the usefulness of the wells for ground water quality. When ground water quality data become suspect due to potential interferences from existing monitoring wells, an appropriate abandonment technique must be employed to adequately remove or destroy the well while completely sealing the borehole.
The results of an inspection of a monitoring system comprised of six 4-inch diameter PVC monitoring wells at a hazardous well facility Indicated that the wells were improperly installed and in some cases provided a pathway for contamination. Subsequent down hole television inspections confirmed inaccuracies between construction logs and the existing system as well as identified defects in casing materials. An abandonment program was designed which destroyed the well casings in place while simultaneously providing a competent seal of the re-drilled borehole.     

Recent contamination by persistent organochlorines in Baikal seal (Phoca sibirica) from Lake Baikal, Russia

Blubber samples of Baikal seals pups (Phoca sibirica) collected in 2001 and 2002 were analyzed for persistent organochlorines (OCs) such as PCBs (polychlorinated biphenyls), DDTs (dichlorodiphenyltrichloroethane and its metabolites), HCHs (hexachlorocyclohexane isomers), CHLs (chlordane related compounds), TCPMe [tris(4-chlorophenyl)methane] and TCPMOH [tris(4-chlorophenyl)methanol]. The distribution pattern of OCs was in the following order: DDTs>PCBs>CHLs>HCHs>TCPMOH>TCPMe. Organochlorine concentrations and composition patterns in eight pup blubber samples (2002) analyzed in the present study were compared with the corresponding levels in juvenile Baikal seals from 1992 survey, and it was found that residue levels of OC compounds have declined during the 10 year period. In particular, concentrations of PCBs, HCHs and CHLs in seals collected in 2002 were approximately two times lower, while DDTs levels were three times lower than the corresponding levels in 1992. Furthermore, higher ratios of beta-HCH/HCHs and p,p(')-DDE/DDTs were found in 2002 samples. While comparing the OC levels with those in other seal pups it appeared that all the OC concentrations were lower than the levels in seals from coastal California known as one of the most polluted areas. PCB and DDT concentrations in the present specimens were higher than that in Arctic seal pups. The proportions of tri-, tetra-, penta- and hexachlorobiphenyls in pups captured in 2002 were higher than those in 1992. TEQ concentrations of non- and mono-ortho coplanar PCBs in Baikal seals collected in 2002 were higher than those in seals collected from some locations in the world, where human and industrial activities are extensive, suggesting potential for toxic implications of coplanar PCBs in Baikal seals.     

Temporal trends of mercury in marine biota of west and northwest Greenland

Temporal trends in mercury concentrations ([Hg]) during the last two to three decades were determined in liver of shorthorn sculpin, ringed seal and Atlantic walrus from northwest Greenland (NWG, 77 degrees N) and in liver of shorthorn sculpin and ringed seal from central west Greenland (CWG, 69 degrees N) during the last decade. Stable-nitrogen (delta(15)N) and carbon (delta(13)C) isotope values were determined in muscle of ringed seals to provide insight into potential trophic level changes through time. Log-linear regressions on annual median [Hg] did not reveal any temporal trend in shorthorn sculpin from CWG and NWG and walrus from NWG. In ringed seals from NWG, an increase in [Hg] of 7.8% per year was observed. When based on delta(15)N-adjusted [Hg] this rate increased to 8.5% but was still non-significant. In ringed seal from CWG no trend was found in [Hg] during the period 1994-2004. However, during the last part of the period (1999-2004) the [Hg] increased significantly. Including tissue delta(15)N values as a covariate had a marked effect on these results. The annual changes in delta(15)N-adjusted [Hg] was estimated to -5.0% for the whole period and 2.2% during the last 5 years compared to -1.3% and 12.4%, respectively, for the non-adjusted [Hg].     

A new method to characterize hydraulic short-circuits in defective borehole seals

A new approach has been developed to detect, characterize, and quantify hydraulic short-circuits in boreholes with faulty seals. The methodology, applicable to an aquifer-aquitard-aquifer system, involves a series of successive, constant-rate pumping tests in the lower aquifer while determining the leakage rate with a simultaneous nonreactive tracer test. During each pumping step, the tracer is injected under constant concentration and constant hydraulic head from a piezometer in the upper aquifer. If a seal defect exists, the tracer will follow the leak and will be recovered from the pumped water. The theoretical equations relate the leakage rate, the pumping rate, the concentration of the injected tracer, and the recovered concentration. Leakage rates can be determined for any pumping rate. The theory is tested using numerical analysis and a full-scale field test.     

Entanglement of Australian sea lions and New Zealand fur seals in lost fishing gear and other marine debris before and after Government and industry attempts to reduce the problem

In recent years, Australian governments and fishing industry associations have developed guiding principles aimed at reducing the impact of fishing on non-target species and the benthos and increasing community awareness of their efforts. To determine whether they reduced seal entanglement in lost fishing gear and other marine debris, we analysed Australian sea lion and New Zealand fur seal entanglement data collected from Kangaroo Island, South Australia. Contrary to our expectations, we found that entanglement rates did not decrease in recent years. The Australian sea lion entanglement rate (1.3% in 2002) and the New Zealand fur seal entanglement rate (0.9% in 2002) are the third and fourth highest reported for any seal species. Australian sea lions were most frequently entangled in monofilament gillnet that most likely originated from the shark fishery, which operates in the region where sea lions forage--south and east of Kangaroo Island. In contrast, New Zealand fur seals were most commonly entangled in loops of packing tape and trawl net fragments suspected to be from regional rock lobster and trawl fisheries. Based on recent entanglement studies, we estimate that 1478 seals die from entanglement each year in Australia. We discuss remedies such as education programs and government incentives that may reduce entanglements.     

Distribution of heavy metals in tissues of the common seal

The lead, cadmium and mercury content of soft tissues and bone were determined for the common seal (Phoca vitulina) collected from off the coast of East Anglia and the West of Scotland. Lead levels were low in all tissues, cadmium accumulated with age in the kidney of West Scotland seals and mercury accumulated to high levels in the liver of seals from both areas. Comparison of our results with those of other workers, suggests that the rate of mercury accumulation in the liver of seals increases in the order: Canadian Arctic and Atlantic coast < West Scotland < East Anglia < Netherlands coast. Accumulation of mercury in the kidney and spleen of older seals, lends tentative support to the hypothesis that a protective demethylation and retention process in the liver may begin to leak mercury to other tissues at the high concentrations which have been recorded in the liver of older seals, and at the high dose rates which have been used in toxicological experiments.     

Blood metal levels and metal-influenced immune functions of harbour seals in captivity

Immunological blood parameters and the effects of environmental pollutants on the immune system are important to assess the health status of seals. Animals living permanently in seal centres are useful for development and validation of diagnostic tools for free-ranging animals. In this study, parameters of cellular immunity as well as metal concentrations in blood and metal influence on cell proliferation of seven seals from a seal centre were investigated repeatedly using multi-element analysis and a lymphocyte proliferation assay. The metal concentrations, except for tin and chromium, were in general comparable to those of free-ranging animals of the North Sea. The unstimulated and mitogen-stimulated lymphocyte proliferation showed strong intra- and inter-individual variability, which reflected variability in activation of the immune status. Furthermore, both immunosuppressive and stimulative influences of metals on lymphocytes were found. Summarising, the methods used in this investigation provided useful information on these animals, and their application to free-ranging animals can be recommended.     

Detecting a Defective Casing Seal at the Top of a Bedrock Aquifer

An improperly sealed casing can produce a direct hydraulic connection between two or more originally isolated aquifers with important consequences regarding groundwater quantity and quality. A recent study by Richard et al. (2014) investigated a monitoring well installed in a fractured rock aquifer with a defective casing seal at the soil–bedrock interface. A hydraulic short circuit was detected that produced some leakage between the rock and the overlying deposits. A falling‐head permeability test performed in this well showed that the usual method of data interpretation is not valid in this particular case due to the presence of a piezometric error. This error is the direct result of the preferential flow originating from the hydraulic short circuit and the subsequent re‐equilibration of the piezometric levels of both aquifers in the vicinity of the inlet and the outlet of the defective seal. Numerical simulations of groundwater circulation around the well support the observed impact of the hydraulic short circuit on the results of the falling‐head permeability test. These observations demonstrate that a properly designed falling‐head permeability test may be useful in the detection of defective casing seals.     

A pre- and post-MARPOL Annex V summary of Hawaiian monk seal entanglements and marine debris accumulation in the northwestern Hawaiian Islands, 1982-1998

Entanglements of Hawaiian monk seals, Monachus schauinslandi, were documented in the northwestern Hawaiian Islands (NWHI) from 1982 to 1998, and debris which presented a threat of entanglement was inventoried and removed from 1987 to 1996. A total of 173 entanglements was documented. The number of entanglements did not change after implementation of MARPOL Annex V in 1989. Pups and juvenile seals were more likely to become entangled than older seals, and became entangled primarily in nets, whereas entanglement of subadults and adults was more likely to involve line. The subpopulation of seals at Lisianski Island experienced the most entanglements, although Lisianski did not accumulate the most debris. Localized high entanglement rates may gravely affect individual monk seal subpopulations. Accumulation of debris has not diminished since implementation of Annex V, nor has occurrence of derelict drift nets abated since a 1989 moratorium. Debris washing ashore has likely been circulating in the North Pacific Ocean for some time.     

Contaminants still high in top-level carnivores in the Southern California Bight: levels of DDT and PCBs in resident and transient pinnipeds

Highly industrialized areas, such as the Southern California Bight, often have high levels of contaminants in marine sediments, which can cause chronic exposure to organisms long after their use has ceased. tDDT and tPCB were analyzed in the blubber of 145 stranded pinnipeds that died at local marine mammal centers between 1994 and 2006. Resident species (California sea lion and Pacific harbor seal) had significantly higher concentrations of tDDT and tPCB than the transient species (northern elephant seal). Adult female California sea lions had significantly lower concentrations of tDDT and tPCB than pups, yearlings, and adult males. Concentrations of both tDDT and tPCB in California sea lions significantly declined over time, but did not change in northern elephant seals. Current concentrations of tDDT and tPCB in California sea lions and harbor seals are among the highest values reported worldwide for marine mammals and exceed those reported to cause adverse health effects.     

Modeling of terracette‐hillslope soil moisture as a function of aspect,slope and vegetation in a semi‐arid environment

In the semi‐arid western United States, water availability plays a defining role in land use. Soil moisture, vegetation, and microtopography are key variables in the hydrologic function of these ecosystems. Previous research has not addressed the influence of site‐specific aspect, vegetation, or slope gradient on terracette soil moisture patterns in semi‐arid rangelands. Therefore, the objectives of this study were to: (1) assess the influence of terracette site aspect, vegetation cover, and slope on soil moisture; (2) conceptualize conditions at the hillslope scale given terracette morphology; and (3) estimate the extent of terracettes at a regional scale. The Simultaneous Heat and Water (SHAW) model was used to simulate soil water dynamics of terracettes given variations in site conditions. These results were coupled with time‐of‐flight laser scans to quantify terracette bench and riser percent‐area, and statewide assessments of terracette extent using digital orthoimagery and a geographical information system (GIS). Modeling results indicated site aspect had minimal influence (±0.005 m³ m^?3) on terracette soil moisture. Vegetation, represented as leaf area index (LAI), had the single‐most influential effect on terracette volumetric water content (θ _v) demonstrated by an inverse relationship of LAI to mean terracette hillslope θ _v; and slope increases of ≥15% on northern azimuths increased mean θ _v which contrasted with southern azimuths for similar slope increases. Laser scanning results indicated bench width and riser length could be estimated from mean site slope (R ² = 0.82 risers and R ² = 0.93 benches). Aerial orthoimagery/GIS assessments estimated >159 000 ha of terracettes throughout the State of Idaho, with >41 000 ha (~26%) occurring on lands managed as grazing allotments. These findings provide an increased understanding of rangeland hydrologic processes as influenced by cattle density, vegetation, and terracettes which can aide land managers in their selection and application of best management practices on these lands. Copyright © 2017 John Wiley & Sons, Ltd.     

Heavy metals and high pup mortality in the Saimaa ringed seal population in eastern Finland

Hair nickel, mercury, cadmium, lead and chromium concentrations were measured from still-born ringed seal pups and from other ringed seal groups from Lake Saimaa in Finland. Nickel concentration was significantly higher in the hair samples of still-born pups as compared to live-born pups and to adult seals. There was assumed to be some connection between the stillbirth of the pups and nickel concentration of the hair. Mercury concentration of the natal hair of pups was significantly higher than the mercury concentration of the first adult hair but no clear connection between stillbirth and mercury pollution was observed. No differences were observed in cadmium, lead and chromium concentrations of the hair of still-born and other ringed seal groups.     

Modeling the thermal evolution of an active geothermal system

Temperature inversions at shallow to moderate depths have been observed commonly in boreholes drilled in geothermal areas. The inversions result from thermal disequilibria generated by steam and/or hydrothermal fluids invading shallow horizontal, or sub-horizontal fractures, or permeable horizons, from a deep vertical, or sub-vertical feeder-fracture.Subsurface distribution of temperatures in Momotombo geothermal area of Nicaragua, Central America, indicates that the anomaly is generated by steam and water, convecting in a narrow feeder-fracture-zone located at the western edge of the field. The north-trending zone of the feeder-fracture is bound on the west by the area of massive, impermeable andesitic rocks, and is capped by an impermeable, approximately 300 m. thick silica-cap, which seals if from the ground surface. The thermal fluids penetrate a system of horizontal, or sub-horizontal fractures, extending east of the feeder-fracture beneath the silica cap. The flow of thermal fluids eastward through the system of the horizontal, or sub-horizontal fractures is generating a plume-like geothermal anomaly, which is expressed by the temperature inversion zone pervasive in the boreholes to the east of the feeder-fracture.A time-dependant model for a semi-infinite half-space (z > 0) in contact with a hot, well stirred, isotropic fluid flowing through an aquifer overlain by a finite space of constant thickness is solved for the data collected from the Momotombo geothermal boreholes. Curve fitting between the simulated and observed temperature/depth profiles suggests that the thermo-tectonic events which caused the present-day Momotombo hydrothermal system occurred approximately 5,500 years ago, following development of vertical, or subvertical fractures along a N5°E trending faultline. Hot fluids emerging from these fractures move eastward through a system of horizontal, or sub-horizontal fractures, with a velocity of 11 to 20 m/yr.     

Spatial aspects of organochlorine contamination in northern fur seal tissues

Northern fur seals from the Pribilof Islands, Alaska (St. George Is. and St. Paul Is.) were examined for organochlorine contamination (OC) and whether the organochlorine levels differed between the populations and were at levels that may adversely affect their health. Fur seal blubber and milk samples were obtained from pups, sub-adult males, and adult females on both Pribilof Islands. These samples were analyzed for organochlorine contaminants including dioxin-like PCBs and other selected PCBs and pesticides by high performance liquid chromatography/photodiode array. Results showed that there are clear differences between the two islands in the patterns of fur seal OC distribution. Generally, these differences are confined to the PCBs with only minimal differences in the DDTs. There are also clear biological differences in the levels shown between milk, pup blubber, and sub-adult male blubber. When considering blubber, St. George Is. fur seals show higher OC levels than St. Paul Is., for both pups and sub-adults. On the other hand, milk samples from St. Paul Is. showed higher PCB levels than St. George Is. For the milk, the overall OC levels may impact the immune function of the pups, but are probably of only minimal impact to humans. However, for blubber, the overall toxic equivalency shows levels exceeding those levels recommended for human consumption at St. George Is. and approaching those levels at St. Paul Is. The concentration curves suggest that the movement of OC in and out of milk follows a complex set of reactions dependent on how the OC compounds on a congener level are associated with lipid. In fact, there is some evidence that they may not follow the lipid as closely as we had thought and that lipid levels can vary without impacting the total OC level in the milk.     

制样方法对非饱和压实黄土强度变化影响的试验研究

为研究不同制样方法对非饱和压实黄土抗剪强度指标的影响规律,进行不同干密度压实土在预湿及加湿两种制样方法下的剪切试验研究。结果表明:预湿制样试验中,存在一个临界含水率影响着试验黄土的黏聚力、摩擦角,当试样的含水率低于临界含水率时,抗剪强度随含水率增加而提高,而当含水率高于临界含水率时,抗剪强度随含水率的增加而降低;抗剪强度指标总体随试样干密度的增大而增大。加湿制样试验中,随着试样含水率的增加,黏聚力连续降低,摩擦角随含水率的增加先提高后降低,对比预湿试样而言,含水率对摩擦角的折减程度降低。可以看出制样方法对非饱和压实黄土黏聚力的影响特征比较突出,当含水率低于临界含水率时加湿试样的黏聚力比预湿试样大,而当含水率高于临界含水率时预湿试样的黏聚力较高,认为加湿试样存在类似"木桶效应",而预湿试样则与试样整体水平有关。研究结果对于进一步加深非饱和黄土抗剪强度指标的适用性研究具有一定参考价值。