The topographic imprint of a transient climate episode: the western Andean flank between 15·5° and 41·5°S

Mountain‐range topography is determined by the complex interplay between tectonics and climate. However, often it is not clear to what extent climate forces topographic evolution and how past climatic episodes are reflected in present‐day relief. The Andes are a tectonically active mountain belt encompassing various climatic zones with pronounced differences in rainfall, erosion, and glacier extent under similar plate‐boundary conditions. In the central to south‐western Andes, climatic zones range from hyperarid desert with mean annual rainfall of 5 mm/a (22·5°S) to year‐round humidity with 2500 mm/a (40°S). The Andes thus provide a unique setting for investigating the relationship between tectonics, climate, and topography. We present an analysis of 120 catchments along the western Andean watersheds between 15·5° and 41·5°S, which is based on SRTMV3‐90m data and new medium‐resolution rainfall, tropical rainfall measurement mission (TRMM) dataset. For each basin, we extracted geometry, relief, and climate parameters to test whether Andean topography shows a climatic imprint and to analyze how climate influences relief. Our data document that elevation and relief decrease with increasing rainfall and descending snowline elevation. Furthermore, we show that local relief reaches high values of 750 m in a zone between 28°S to 35°S. During Pleistocene glacial stages this region was affected by the northward shifting southern hemisphere Westerlies, which provided moisture for valley‐glacier formation and extended glacial coverage as well as glacial erosion. In contrast, the southern regions between 35°S to 40°S receive higher rainfall and have a lower local relief of 200 m, probably related to an increased drainage density. We distinguish two different, climatically‐controlled mechanisms shaping topography: (1) fluvial erosion by prolonged channel‐hillslope coupling, which smoothes relief, and (2) erosion by valley glaciers that generates relief. Finally, Our results suggests that the catchment‐scale relief of the Andes between 28°S to 35°S is characterized by a pronounced transient component reflecting past climatic conditions. Copyright © 2010 John Wiley & Sons, Ltd.     

The Carbonate Radical (HCO3·/CO3–·) as a Reactive Intermediate in Water Chemistry: Kinetics and Modelling

Results from kinetic laboratory studies of reactions of the carbonate radical anion (CO₃^–·) with aromatic compounds in aqueous solution at T = 298 K are presented. Data were obtained in using a laser photolysis laser long-path absorption (LP-LPLA) apparatus which was designed for direct time-resolved studies of radical reactions. For the reactions of CO₃^–· with hydroquinone dimethyl ether (2), methyl anisole (3), benzene (4), p-xylene (5), toluene (6), chlorobenzene (7), nitrobenzene (8), and benzonitrile (9), rate coefficients of k₂ = (3.0 ± 0.6)·10⁷ M^–1 s^–1, k₃ = (9.7 ± 1.7)·10⁵ M^–1 s^–1, k₄ = (3.2 ± 0.7)·10⁵ M^–1 s^–1, k₅ = (3.8 ± 0.9)·10⁴ M^–1 s^–1, k₆ = (6.8 ± 2.3)·10⁴ M^–1 s^–1, k₇ = (2.7 ± 0.6)·10⁵ M^–1 s^–1, k₈ = (1.4 ± 0.5)·10⁴ M^–1 s^–1, and k₉ < 1.3·10² M^–1 s^–1 were obtained. In further studies the effect of temperature on the reactions (2), (4), and (5) has been studied. The kinetic data obtained for the reaction of the carbonate radical anion with aromatic compounds were compared to the corresponding reactions of the hydroxyl radical. Finally, these kinetic data were used within a simple model system to investigate the implications of carbonate radical anion kinetics within water treatment processes. It is shown that the degradation of organic pollutants in ^·OH-radical based water treatment may proceed via the CO₃^–·/HCO_3· radical under certain conditions.