A Multiscale Assessment of Shallow Groundwater Salinization in Michigan

Managing nonpoint-source (NPS) pollution of groundwater systems is a significant challenge because of the heterogeneous nature of the subsurface, high costs of data collection, and the multitude of scales involved. In this study, we assessed a particularly complex NPS groundwater pollution problem in Michigan, namely, the salinization of shallow aquifer systems due to natural upwelling of deep brines. We applied a system-based approach to characterize, across multiple scales, the integrated groundwater quantity–quality dynamics associated with the brine upwelling process, assimilating a variety of modeling tools and data—including statewide water well datasets scarcely used for larger scientific analysis. Specifically, we combined (1) data-driven modeling of massive amounts of groundwater/geologic information across multiple spatial scales with (2) detailed analysis of groundwater salinity dynamics and process-based flow modeling at local scales. Statewide “hotspots” were delineated and county-level severity rankings were developed based on dissolved chloride (Cl⁻) concentration percentiles. Within local hotspots, the relative impact of upwelling was determined to be controlled by: (1) streams—which act as “natural pumps” that bring deeper (more mineralized) groundwater to the surface; (2) the occurrence of nearly impervious geologic material at the surface—which restricts fresh water dilution of deeper, saline groundwater; and (3) the space–time evolution of water well withdrawals—which induces slow migration of saline groundwater from its natural course. This multiscale, data-intensive approach significantly improved our understanding of the brine upwelling processes in Michigan, and has applicability elsewhere given the growing availability of statewide water well databases.     

Pollution of Sources of Drinking Water Supply of Large Cities with Pharmaceuticals (the Example of Moscow,Russia)

Identification of contaminants, determination of their biological hazard and content in water are important practical tasks while assessing water quality in sources of drinking water supply of large cities. Presented herein is a review regarding pharmaceutical pollution of waters in various countries. Given are original data concerning contamination of water objects—sources of water supply of Moscow with components of pharmaceuticals and metabolites of therapeutic agents. Worked out is a retrieval and calculation technology of assessing hazards of substances. Proposed is the use of “structure-activity” calculation technologies for prediction of side effects of pharmaceuticals and pharmacological activity of other organic xenobiotics not used in medicine. Certain ways of decreasing pharmaceutical pollution are recommended.     

Bioassessment of water quality and defining of critical levels of multicontamination for aquatic life

The existing approaches to and methods for bioassessment of water quality are critically analyzed. The significance of the methodological approach under the concept of ecosystem “health” as the most integral numerical method for assessing pollution effects. Comparative analysis is given to the significance of criteria based on the state of individuals, populations, and communities. The results of practical testing of the methods developed for biological assessment of water quality for some water bodies are presented. Critical levels are established based on the construction of dose-effect dependences. The basic principles for limiting surface water pollution are formulated.     

Storm surge computations for the west coast of Britain using a finite element model (TELEMAC)

An unstructured mesh finite element model of the sea region off the west coast of Britain is used to examine the storm surge event of November 1977. This period is chosen because accurate meteorological data to drive the model and coastal observations for validation purposes are available. In addition, previous published results from a coarse-grid (resolution 7 km) finite difference model of the region and high-resolution (1 km) limited area (namely eastern Irish Sea) model are available for comparison purposes. To enable a “like with like” comparison to be made, the finite element model covers the same domain and has the same meteorological forcing as these earlier finite difference models. In addition, the mesh is based on an identical set of water depths. Calculations show that the finite element model can reproduce both the “external” and “internal” components of the surge in the region. This shows that the “far field” (external) component of the surge can accurately propagate through the irregular mesh, and the model responds accurately, without over- or under-damping, to local wind forcing. Calculations show significant temporal and spatial variability in the surge in close agreement with that found in earlier finite difference calculations. In addition, root mean square errors between computed and observed surge are comparable to those found in previous finite different calculations. The ability to vary the mesh in nearshore regions reveals appreciable small-scale variability that was not found in the previous finite difference solutions. However, the requirement to perform a “like with like” comparison using the same water depths means that the full potential of the unstructured grid model to improve resolution in the nearshore region is inhibited. This is clearly evident in the Mersey estuary region where a higher resolution unstructured mesh model, forced with uniform winds, had shown high topographic variability due to small-scale variations in topography that are not resolved here. Despite the lack of high resolution in the nearshore region, the model showed results that were consistent with the previous storm surge models of the region. Calculations suggest that to improve on these earlier results, a finer nearshore mesh is required based upon accurate nearshore topography.     

Tracing water resources flows by complementary use of hydrological and water accounting models

Historically, there has been a dispute over water allocation between users and policymakers in Iran's Zayandeh-Roud Basin (ZRB). In this study, we used the “System of Environmental-Economic Accounting for Water” (SEEAW) framework in combination with the hydrologic model “Soil and Water Assessment Tool” (SWAT) to achieve the water balance in ZRB. We used SEEAW to combine a wide range of water-related statistics across stakeholders and SWAT to evaluate the unknown agricultural water use. The SWAT model is calibrated based on the stream flows and crop yields in the basin. The model assess the renewable water of the basin into two components, about 363 and 70 mm as green and blue water, respectively. Also results from the physical water supply and water use tables demonstrates that the agricultural sector uses 78% of the total renewable freshwater, followed by the residential, 16%, and the industrial sector, 6%. The flows of water from source to services in ZRB are traced based on the water supply and water use tables. The flow diagram shows that 8 MCM of industrial reused water was transferred to the agricultural sector, and 137 MCM and 18 MCM of water from the wastewater treatment plants to the agricultural and industrial sectors, respectively. Furthermore, the results show that the index of the basin dependence on groundwater resources is high (61%), the value of water stress is high (0.88) and the dependence of the basin on transboundary water resources is 30%. Therefore, this method is highly beneficial for achieving a conceptual water balance in disputed basins without enough agricultural water uses data.     

Contribution of baseflow nitrate export to non-point source pollution

As a common pollutant of nitrogen in groundwater, nitrate contamination has become a major concern worldwide. Baseflow, one of the dominant hydrological pathways for nitrate migration to streamflow, has been confirmed as a leading nitrate source for stream water where groundwater or subsurface flow contaminated heavily by nitrate. That is, sufficient improvements of water quality may not be attained without proper management for baseflow, even if non-point sources (NPS) pollutants discharged through surface runoff are being well managed. This article reviews the primary nitrate sources, the main factors affecting its transport, and the methodologies for baseflow nitrate estimation, to give some recommendations for future works, including: (1) giving sufficient consideration for the effects of climatological, morphological, and geological factors on baseflow recessions to obtain more reliable and accurate baseflow separation; (2) trying to solve calibration and validation problems for baseflow loads determining in storm flow period; (3) developing a simple and convenient algorithm with certain physics that can be used to separate baseflow NPS pollution from the total directly in different regions, for a reliable estimation of baseflow NPS pollution at larger scale (e.g., national scale); (4) improving groundwater quality simulation module of existing NPS pollution models to have a better simulation for biogeochemical processes in shallow aquifers; (5) taking integrated measures of “source control”, “process interception” and “end remediation” to prevent and control NPS nitrate pollution effectively, not just only the strict control of nutrients loss from surface runoff.     

Ecohydrological modelling with EcH2O‐iso to quantify forest and grassland effects on water partitioning and flux ages

We used the new process‐based, tracer‐aided ecohydrological model EcH₂O‐iso to assess the effects of vegetation cover on water balance partitioning and associated flux ages under temperate deciduous beech forest (F) and grassland (G) at an intensively monitored site in Northern Germany. Unique, multicriteria calibration, based on measured components of energy balance, hydrological function and biomass accumulation, resulted in good simulations reproducing measured soil surface temperatures, soil water content, transpiration, and biomass production. Model results showed the forest “used” more water than the grassland; of 620 mm average annual precipitation, losses were higher through interception (29% under F, 16% for G) and combined soil evaporation and transpiration (59% F, 47% G). Consequently, groundwater (GW) recharge was enhanced under grassland at 37% (~225 mm) of precipitation compared with 12% (~73 mm) for forest. The model tracked the ages of water in different storage compartments and associated fluxes. In shallow soil horizons, the average ages of soil water fluxes and evaporation were similar in both plots (~1.5 months), though transpiration and GW recharge were older under forest (~6 months compared with ~3 months for transpiration, and ~12 months compared with ~10 months for GW). Flux tracking using measured chloride data as a conservative tracer provided independent support for the modelling results, though highlighted effects of uncertainties in forest partitioning of evaporation and transpiration. By tracking storage—flux—age interactions under different land covers, EcH₂O‐iso could quantify the effects of vegetation on water partitioning and age distributions. Given the likelihood of drier, warmer summers, such models can help assess the implications of land use for water resource availability to inform debates over building landscape resilience to climate change. Better conceptualization of soil water mixing processes and improved calibration data on leaf area index and root distribution appear obvious respective modelling and data needs for improved simulations.     

REPRODUCTION OF THE RUNOFF-RECORD OF THE RIO MOTATAN BY RAIN DATA,ESTABLISHING THE TRUE MONTHLY RUNOFF-FACTOR

Abstract

In 1950 only 10 years of streamflow observations and runoff data existed on the Rio Motatan in Western Venezuela (4,200 km² of watershed, Anden territory) with 24 raingauge stations in or near the watershed having a simultaneous record but only 3 recording stations with 30 years of observation. The “curve of dry spell”—January to April—was first determined on semilog hydrographs (logs of daily discharge vs. time) and by splitting the total flow into surface and groundwater components an abacus was established, relating the average monthly rain with the “true runoff”. (True runoff) = (observed runoff)—(part due to former month of rain) + (share in following months). For checking purposes the observed runoff record was reproduced, using data based on rain, reaching a high degree of accuracy. Then the same abacus was applied to the 20 years of isolated rain data and the corresponding runoff values were obtained. Recently seven more years of runoff data were successfully checked against the graphs.     

Management of the Wellfield Contaminated by Dense Chlorinated Hydrocarbons in Vilnius,Lithuania

Drinking water supply in Lithuania is entirely based on groundwater. Wellfields of Vilnius develop intermorainic ca. 50 m deep (in average) aquifer which is locally contaminated by chlorinated hydrocarbons— volatile organic compounds (VOCs). Groundwater abstraction activates VOCs migration from an abandoned factory into the pumping wells of one wellfield named “Vingis.” However monitoring data testify that only traces of VOCs were detected on the territory of this factory. Subsequent studies revealed the “secret”: dense VOCs have migrated from the territory of the polluter and have accumulated in lowermost places of pumped aquifer inside the wellfield. An attempt to ensure low concentration of VOCs in pumped water manipulating by pumping rates of more or less contaminated abstraction wells was not effective. Finally, an acceptable concentration of VOCs in supplied drinking water was ensured by permanent pumping out of the most polluted groundwater from some abstraction wells of the wellfield and diverting this water to the Neris River.     

UV-Derivativ-Spektren zur Vorabschätzung des Gehaltes von polycyclischen aromatischen Kohlenwasserstoffen in Schwebstoffen und Sedimenten der Gewässer Derivative UV Spectra for Estimating the Contents of Polycyclic Aromatic Hydrocarbons in Suspended Solids and Sediments of Waters

By means of UV spectra of cyclohexane extracts from aquatic sediments it is possible to distinguish: “normal” mineral oil aromatics (e. g. of the middle distillation fraction), used oils, and highboiling raffinates, tar oils, and — as representative of aromatics listed in the German drinking water ordinance — fluoranthene. Starting with less selective extractants and the basic UV spectra, it is shown that spectra of higher orders frequently allow a quantitative determination of fluoranthene. If it is justified to assume a constant conversion factor, the result of the measurement can be used to calculate the contents of the whole group of aromatics listed in the German drinking water ordinance. A comparison with other methods (HPLC etc.) and with results from other laboratories showed good agreement. Finally, the diagnostic capacity (fingerprint) of derived spectra is pointed out.     

A framework for sourcing of evaporation between saturated and unsaturated zone in bare soil condition

ABSTRACT

Sourcing subsurface evaporation (E_ss) into groundwater (E_g) and unsaturated zone (E_u) components has received little scientific attention so far, despite its importance in water management and agriculture. We propose a novel sourcing framework, with its implementation in dedicated post-processing software called SOURCE (used along with the HYDRUS1D model), to study evaporation sourcing dynamics, define quantitatively “shallow” and “deep” water table conditions and test the applicability of water table fluctuation (WTF) and “bucket” methods for estimation of E_g and E_u separately.

For the “shallow” and “deep” water table we propose E_g?>?0.95E_ss and E_g = 0 criteria, respectively. Assessment of the WTF method allowed sourcing of very small fluxes otherwise neglected by standard hydrological methods. Sourcing with SOURCE software was more accurate than the standard “bucket” method mainly because of greater flexibility in spatio-temporal discretization. This study emphasized the dry condition relevance of groundwater evaporation which should be analysed by applying coupled flow of heat, vapour and liquid water.

Editor D. Koutsoyiannis; Associate editor S. Kanae     

流域综合管理方法与技术

流域作为一个具有明确边界的地理单元,流域以水为纽带,将上、中、下游组成一个普遍具有因果联系的复合生态系统,是实现资源和环境管理的最佳单元.流域综合管理已经被认为是实现资源利用和环境保护相协调的最佳途径.然而,由于流域综合管理涉及多学科,多部门,内容非常广泛.近年的流域管理还主要停留在一个目标.本文在流域模拟管理研究及实践的相关经验基础上,系统地讨论了流域综合管理实施方法、关键技术以及主要技术问题.     

Challenges Facing Environmentally Sustainable Ground Water Use in South Africa

In 1998, South Africa promulgated a Water Act that is widely regarded as one of the most progressive and enabling pieces of environmental legislation in the world. The environmental aspects of the Water Act are commonly referred to as “resource-directed measures.” These measures attempt to find the right balance between (1) leaving water in the resource (“nonconsumptive use”) to provide ecological goods and services for society and (2) taking the water out of the system for “consumptive” human use. These measures also attempt to ensure that both nonconsumptive and consumptive use is sustainable. This article discusses some of the challenges faced in using the measures to achieve environmentally sustainable ground water use. A major challenge is that misunderstanding still abounds regarding the environmental aims of this legislation. Other major challenges identified included a severe shortage of technical capacity, an inordinately long water use license application process, incorporating adaptive management to deal with uncertainty, incorporating the public participation process, and revising policy implementation processes to accommodate highly localized aquifers. Selecting appropriate scientific methodology—neither too simplistic nor too involved—is a recurring challenge. It is suggested that an important part of addressing these and the other challenges identified is a period of reflection and dialogue between the various sectors involved.     

Sediment balance at river mouths and the formation of deltas at rising or falling sea level

Sediment balance at river mouths—a physical basis of delta dynamics—is considered. The specific features of relationships between sediment balance components at a mouth of a river are established for a stable, rising, or dropping sea level. The development of the delta of the Chilia branch at the Danube mouth is considered as an example of delta dynamics under the conditions of a relatively stable sea level. The evolution of the Sulak delta in the Caspian Sea with a highly variable level is considered as an example of delta dynamics in the case of a considerable rise and drop of water level in the water body. The anthropogenic reduction of sediment runoff of the rivers (by a factor of two in the Danube, and by a factor of nine in the Sulak) is taken into account. The relationship between the sediment runoff of a river and the volume of the “backwater prism” that formed due to sea level rise is shown to be the key factor in the development of delta in the case of sea level rise. In the case of a drop in the sea level, the relationship between the “active” and “passive” progradation of the delta into the sea is determined by the sediment runoff of the river, the rate of sea level drop, and the bed slope in the coastal area of the nearshore zone.     

Simulatoren meteorologischer Eingangsgrößen für mathematische Modelle der Wassergütewirtschaft

Operational stochastic models with different time discretisation levels have been developed for generation of meteorological input processes for hydrologic models. These stochastic models can also supply the input simulation for water quality management models. In this paper they are outlined with special regard to the threshold model for intermittend processes of short time intervals (less than about ten days) with is based on a “pressed” power transformation to normality and a method of quantiles or alternatively a modified method of moments for estimating the correlation coefficients.     

Continuous Bayesian networks for probabilistic environmental risk mapping

Bayesian networks (BNs) are being increasingly applied to environmental research. Nonetheless, most of the literature related to environmental sciences use discrete or discretized data, which entails a loss of information. We propose a novel methodology based on continuous BNs to predict the probability that surface waters do not meet the standards, in relation to nitrate concentration, established by the European Water Framework Directive. In order to achieve our purpose, a Tree Augmented Naive Bayes (TAN), was developed and applied to estimate and map the risk of failing to meet the European standards established. The TAN models were tested by means of the k-fold cross validation method. The results revealed that the TAN model performed proper risk maps and suggested that poor water quality is highly probable in watersheds dominated by irrigated herbaceous crops. On the contrary, “good surface water status” is more likely to occur in areas where forest is notably present.     

Biological activity and physicochemical properties of thermally activated water types: Mollusk-based bioassay

Physicochemical and bioassay methods are used to carry out a comprehensive study of the properties of two types of activated waters: “thermally activated,” i.e., thermal water, referred to as “white spring” or “cold boiling water” in folk medicine, and “melt” water after quick freeze. The test object for bioassay were apple shell mollusks Pomacea canaliculata from a laboratory culture used to carry out patented and widely tested methods of freshwater quality bioassay. Oxygen and hydrogen peroxide concentrations and pH were determined in water. The integral biological activity of water was evaluated by a method based on the use of absorption spectra to evaluate the rate of redox transformation in the quinone-hydroquinol system. Similar studies were carried out with three types of reference samples: settled original tap water, the same water cooled to the freezing point, and water artificially enriched with hydrogen peroxide. The water activated by thermal impact has been found to have higher biological activity than the original tap water.     

Characterization of regional variability of seasonal water balance within Omo-Ghibe River Basin,Ethiopia

In this study we quantify the spatial variability of seasonal water balances within the Omo-Ghibe River Basin in Ethiopia using methods proposed within the Prediction in Ungauged Basins initiative. Our analysis consists of: (1) application of the rainfall–runoff model HBV-Light to several sub-catchments for which runoff data are available, and (2) estimation of water balances in the remaining ungauged catchments through application of the model with regionalized parameters. The analyses of the resulting water balance outcomes reveal that the seasonal water balance across the Omo-Ghibe Basin is driven by precipitation regimes that change with latitude, from being strongly “seasonal” in the north to “precipitation spread throughout the year, but with a definite wetter season” in the south. The basin is divided into two distinct regions based on patterns of seasonal water balance and, in particular, seasonal patterns of soil moisture storage.

EDITOR D. Koutsoyiannis

ASSOCIATE EDITOR A. Efstratiadis     

Data‐Driven Approach for Analyzing Hydrogeology and Groundwater Quality Across Multiple Scales

Recent trends of assimilating water well records into statewide databases provide a new opportunity for evaluating spatial dynamics of groundwater quality and quantity. However, these datasets are scarcely rigorously analyzed to address larger scientific problems because they are of lower quality and massive. We develop an approach for utilizing well databases to analyze physical and geochemical aspects of groundwater systems, and apply it to a multiscale investigation of the sources and dynamics of chloride (Cl^?) in the near‐surface groundwater of the Lower Peninsula of Michigan. Nearly 500,000 static water levels (SWLs) were critically evaluated, extracted, and analyzed to delineate long‐term, average groundwater flow patterns using a nonstationary kriging technique at the basin‐scale (i.e., across the entire peninsula). Two regions identified as major basin‐scale discharge zones—the Michigan and Saginaw Lowlands—were further analyzed with regional‐ and local‐scale SWL models. Groundwater valleys (“discharge” zones) and mounds (“recharge” zones) were identified for all models, and the proportions of wells with elevated Cl^? concentrations in each zone were calculated, visualized, and compared. Concentrations in discharge zones, where groundwater is expected to flow primarily upwards, are consistently and significantly higher than those in recharge zones. A synoptic sampling campaign in the Michigan Lowlands revealed concentrations generally increase with depth, a trend noted in previous studies of the Saginaw Lowlands. These strong, consistent SWL and Cl^? distribution patterns across multiple scales suggest that a deep source (i.e., Michigan brines) is the primary cause for the elevated chloride concentrations observed in discharge areas across the peninsula.