Development of P-T prograde and P-retrograde, T-prograde isogradic surfaces during blueschist to eclogite regional deformation/metamorphism in New Caledonia, as indicated by progressively developed porphyroblast microstructures

Abstract The mid-Tertiary blueschists, eclogites and eclogitic gneisses of northern New Caledonia are the products of four phases of regional metamorphism and deformation (D₁–D₄). Omphacite, lawsonite and Mn-rich garnet isogradic surfaces were developed during the second deformation (D₂) under prograde pressure and temperature conditions. Subsequent deformations (D₃–D₄) folded these D₂ isogradic surfaces. However, within the P-retrograde, T-prograde metamorphic environment of the D₄ phase, omphacite altered to albite and chlorite; as a result, a late-stage sub-horizontal isogradic surface developed for omphacite-out where this mineral preserved as relics within syn-D₄ albite porphyroblasts. Other minerals that crystallized for the first time (epidote) or had rim additions (almandine phengite) during D₄, also form nearly horizontal isogradic surfaces. Porphyroblastic garnet and albite contain inclusion trails, which allow their microstructural development and crystallization of the matrix to be traced from D₂ to D₄. Late syn-D₄ the temperature increased markedly in association with an extensive exothermic decarbonation, even though the rocks were in a state of pressure retrogression. This caused considerable neocrystallization, recrystallization and growth of mattix and porphyroblasts such that, although S₂ foliation crenulated by D₃ and D₄ is readily observable, almost all signs of stored strain due to D₃ and D₄ have been removed, and the deeper schists and eclogitic gneisses superficially appear to have undergone a drastic annealing recrystallization, post-dating deformation.     

Tectonic Imprints of the Hazara Kashmir Syntaxis on the Mesozoic Rocks Exposed in Munda,Mohmand Agency,Northwest Pakistan

Two well-developed mesoscopic folds, D_2 and D_3, which postdate the middle amphibolite metamorphism, were recognized in the western hinterland zone of Pakistan. NW–SE trending D_2 folds developed during NE–SW horizontal bulk shortening followed by NE–SW trending D_3 folds, which developed during SE–NW shortening. Micro- to mesoscopically the NW–SE trending S2 crenulation cleavage, boudins and mineral stretching lineations are overprinted by D_3. The newly established NW–SE trending micro- to mesoscopic structures in Munda termed D_2, which postdated F_1/F_2, is synchronously developed with F3 structures in the western hinterland zone of Pakistan. We interpret that D_2 and D_3 folds are counterclockwise rotated in the tectonic event that has evolved the Hazara Kashmir Syntaxis after the main phase Indian plate and Kohistan Island Arc collision. Chlorite replacement by biotite in the main matrix crenulation cleavages indicates prograde metamorphism related with D_2. The inclusion of muscovite and biotite in garnet porphyroblasts and the presence of staurolite in these rocks indicate that the Barrovian metamorphic conditions predate D_2 and D_3. We interpret that garnet, staurolite and calcite porphyroblasts grew before D_2 because the well developed S2 crenulation cleavage wraps around these porphyroblasts.     

Prograde evolution of Sulu UHP metamorphic rock in Yangzhuang,Junan region,deduced by combined Raman and petrological studies

The prograde metamorphic history of the Sulu ultrahigh‐pressure metamorphic terrane has been revealed using Raman‐based barometry of the SiO₂ phases and other mineral inclusions in garnet porphyroblasts of a coesite eclogite from Yangzhuang, Junan region, eastern China. Garnet porphyroblasts have inner and outer segments with the boundary being marked by discontinuous changes in the grossular content. In the inner segment, the SiO₂ phase inclusions are α‐quartz with no coesite or relict features such as radial cracks. The residual pressures retained by the quartz inclusions systematically increase from the crystal centre to the margin of the inner segment. The metamorphic conditions estimated by calculation from the residual pressure and conventional thermodynamic calculation range from 500 to 630 °C and 1.3 to 2.3 GPa for the stage of the inner segment. Coesite and its pseudomorph occur as inclusions in the outer segment of the garnet and matrix omphacite. This occurrence of coesite is consistent with the pressure and temperature conditions of 660–725 °C and 3.1 GPa estimated by conventional geothermobarometry. Our results suggest that the quartz inclusions in the inner segment were trapped by garnet under α‐quartz‐stable conditions and survived phase transition to coesite at the peak metamorphic stage. The SiO₂ phases and other inclusions in the garnet have retained evidence of the pre‐eclogite prograde stage even during exhumation stage. The combined Raman spectroscopic and petrological approaches used here offers a powerful means for obtaining more robust constraints prograde stages involving garnet growth where different SiO₂ phases are present as inclusions.     

Pressure-temperature Evolution of the Metapelites in the Motuo Area,the Eastern Himalayan Syntaxis

The Motuo area is located in the east of the Eastern Himalayan Syntaxis. There outcrops a sequence of high-grade metamorphic rocks, such as metapelites. Petrology and mineralogy data suggest that these rocks have experienced three stages of metamorphism. The prograde metamorphic mineral assemblages(M1) are mineral inclusions(biotite + plagioclase + quartz ± sillimanite ± Fe-Ti oxides) preserved in garnet porphyroblasts, and the peak metamorphic assemblages(M2) are represented by garnet with the lowest XSps values and the lowest XFe# ratios and the matrix minerals(plagioclase + quartz ± Kfeldspar + biotite + muscovite + kyanite ± sillimanite), whereas the retrograde assemblages(M3) are composed of biotite + plagioclase + quartz symplectites rimming the garnet porphyroblasts. Thermobarometric computation shows that the metamorphic conditions are 562–714°C at 7.3–7.4 kbar for the M1 stage, 661–800°C at 9.4–11.6 kbar for the M2 stage, and 579–713°C at 5.5–6.6 kbar for the M3 stage. These rocks are deciphered to have undergone metamorphism characterized by clockwise P-T paths involving nearly isothermal decompression(ITD) segments, which is inferred to be related to the collision of the India and Eurasia plates.     

Metamorphic and structural evolution of the Early Proterozoic Puolankajärvi Formation, Finland – I. Structural and textural relations

The amphibolite facies Puolankajärvi Formation (PjF) occupies the western margin of the Early Proterozoic Kainuu Schist Belt (KSB) of northern Finland. The lower and middle parts of the PjF consist of turbiditic psammites and pelites and tempestitic semipelites. This report concentrates on the pelitic lithologies which include quartz–two-mica–plagioclase schists with variable amounts of garnet, staurolite, andalusite and biotite porphyroblasts as well as sillimanite and cordierite segregations. The KSB forms a major north–south-trending synclinorium between two Archaean blocks. It contains both autochthonous and allochthonous units and is cut by faults and shear zones. The PjF lies on the western side of the KSB and is probably allochthonous. The formation has undergone six major deformation phases (D₁, D₂, D_3a, D_3b, D₄ and D₅). During D_3a-D₅ the maximum principal stress (σ₁) changed in a clockwise direction from south-west to north-east. Between D₂ and D₃ the intermediate principal stress (σ₂) changed from horizontal to vertical and the interval between D₂ and D₃ marks a transition from thrust to strike-slip tectonics. Relict structures in the porphyroblasts indicate the following mineral growth–deformation evolution in the PjF. (1) Throughout the PjF there was a successive crystallization of garnet (syn-D₁), poryphyroblastic biotite (inter-D_3/4) and staurolite (inter-D_3/4) during the pre-D₄ stage. (2) A syn-D₄-inter-D_4/5 crystallization of kyanite, sillimanite (fibrolite), porphyroblastic tourmaline, magnetite, rutile, cordierite and muscovite–biotite–plagioclase pseudomorphs after staurolite was most localized at and near D₄ shear zones. (3) A syn- to post-D₅ generation of andalusite, ilmenohematite and sheet silicates after staurolite and after cordierite occurred near D₅ faults. The evolution outlined here permits the relative dating of the PjF parageneses, which is used in the second part of the study (Tuisku & Laajoki, 1990), and, together with the knowledge of the pressure–temperature conditions during various growth events, makes it possible to compile pressure–temperature–deformation paths for the PjF.     

Structural history of high-pressure metamorphic rocks in the southern vanoise massif,french alps,and their relation to alpine tectonic events

A nappe of amphibolite-facies metamorphic rocks of pre-Permian age in the southern Vanoise massif (the Arpont schist) has been affected by an Alpine HP/LT metamorphism. The first mesoscopically recognizable deformation (D₁) post-dated the high-pressure peak (jadeitic pyroxene + quartz, glaucophane + ?lawsonite), and was associated with glaucophane + epidote. D₁ produced a flat-lying schistosity and a NW-trending glaucophane lineation, and was probably associated with nappe displacement involving NW-directed subhorizontal shear. D₂ formed small-scale folds and a foliation associated with chlorite + albite. The changing parageneses during the period pre-D₁ to D₁ to D₂ suggest decreasing pressure, so that the deformation appears to have been related to the uplift history, rather than to the process of tectonic burial. D₂ was followed by a static metamorphism (green biotite + chlorite + albite), possibly of Lepontine age. SE-directed backthrusting and folding (D₃), and later differential uplift along steep faults, took place under low-grade conditions.     

Pseudomorphs and associated microstructures of western Maine,USA

In metapelitic rocks of western Maine, a pluton-related M3 metamorphic gradient ranging in grade from garnet to upper sillimanite zone was superposed on a fairly uniform M2 regional metamorphic terrain characterized by the assemblage andalusite+staurolite+biotite+/−garnet. As a result, M2 assemblages re-equilibrated to the P, T, and aH₂O conditions of M3, and both prograde and retrograde pseudomorphism of M2 porphyroblasts occurred. The type of pseudomorph and degree of development is directly related to the rock's position within the M3 metamorphic gradient, a function of its proximity to the Mooselookmeguntic pluton. Several ‘hinge’ zones occur in which the M3 minerals that pseudomorphed a particular M2 phase change. For example, M2 garnet was replaced by M3 chlorite or biotite, depending on its position within the M3 gradient. Similarly, in a transition zone between M3 upper staurolite and lower sillimanite zones, M2 staurolite was stable and shows M3 growth rims. Downgrade from this transition zone, staurolite was pseudomorphed by chlorite and muscovite, whereas upgrade, the pseudomorphs contain muscovite and some biotite. M3 pseudomorphs commonly retain crystal shapes of the original M2 porphyroblasts, reflecting relatively low regional deviatoric stress during and after M3. Although evidence for textural disequilibrium is common, chemical equilibrium was closely approached during M3. This study demonstrates for M3 that: (1) the pseudomorphic replacement was a constant volume process, and (2) fabrics produced by tectonic events can be erased by subsequent deformation and/or sufficiently intense subsequent recrystallization.     

Intergranular diffusion rates from the analysis of garnet surfaces: Implications for metamorphic equilibration

Novel approaches to garnet analysis have been used to assess rates of intergranular diffusion between different matrix phases and garnet porphyroblasts in a regionally metamorphosed staurolite‐mica‐schist from the Barrovian‐type area in Scotland. X‐ray maps and chemical traverses of planar porphyroblast surfaces reveal chemical heterogeneity of the garnet grain boundary linked to the nature of the adjacent matrix phase. The garnet preserves evidence of low temperature retrograde exchange with matrix minerals and diffusion profiles documenting cation movement along the garnet boundaries. Garnet–quartz and garnet–plagioclase boundaries preserve evidence of sluggish Mg, Mn and Fe diffusion at comparable rates to volume diffusion in garnet, whereas diffusion along garnet–biotite interfaces is much more effective. Evidence of particularly slow Al transport, probably coupled to Fe³⁺ exchange, is locally preserved on garnet surfaces adjacent to Fe‐oxide phases. The Ca distribution on the garnet surface shows the most complex behaviour, with long‐wavelength heterogeneities apparently unrelated to the matrix grain boundaries. This implies that the Ca content of garnet is controlled by local availability and is thought likely to reflect disequilibrium established during garnet growth. Geochemical anomalies on the garnet surfaces are also linked to the location of triple junctions between the porphyroblasts and the matrix phases, and imply enhanced transport along these channels. The slow rates of intergranular diffusion and the characteristics of different boundary types may explain many features associated with the prograde growth of garnet porphyroblasts. Thus, minerals such as quartz, Fe‐oxides and plagioclase whose boundaries with garnet are characterized by slow intergranular diffusion rates appear to be preferentially trapped as inclusions within porphyroblasts. As such grain boundary diffusion rates may be a significant kinetic impediment to metamorphic equilibrium and garnet may struggle to maintain chemical and textural equilibrium during growth in pelites.     

Timing of porphyroblast growth in the Fleur de Lys Supergroup, Newfoundland

Abstract In the Fleur de Lys Supergroup, western Newfoundland, inclusion trails in garnet and albite porphyroblasts indicate that porphyroblasts overgrew a crenulation foliation, without rotation, probably during the deformation event that produced the crenulations. Further deformation of the matrix resulted in strong re-orientation and retrograde metamorphism of the matrix foliation, which is consequently highly oblique to the crenulation foliation preserved in the porphyroblasts. The resulting matrix foliation locally preserves relics of the early crenulations, and also has itself been crenulated later in places. Thus the porphyroblasts grew before the later stages of deformation, rather than during the final stage, as had been suggested previously. The new interpretation is consistent with available ⁴⁰Ar/³⁹Ar cooling ages which indicate a late Ordovician-early Silurian metamorphic peak, rather than the Devonian peak suggested by previous workers. The inclusion patterns and microprobe data indicate normal outward growth of garnet porphyroblasts from a central nucleus, rather than as a series of veins as proposed by de Wit (1976a, b). However, the observations presented here support growth of porphyroblasts without rotation, which is implied by the de Wit model.     

A comparison of microstructural and chemical patterns in garnet from the Fleur de Lys Supergroup,Newfoundland

This study uses compositional analyses of garnet porphyroblasts to test a previously published microstructure-based model of garnet growth in the Fleur de Lys Supergroup. X-ray maps reveal significant compositional anomalies within garnet, including zoning reversals and steepened compositional gradients. These anomalies occur at the margin of the proposed first stage of garnet growth (G₁), and coincide with truncations of inclusion trails and changes in the inclusion assemblage. Intervals of reversed composition zoning and steepened compositional gradients across this boundary are interpreted to represent a hiatus in garnet growth, possibly accompanied by garnet consumption, during which changes in the garnet-forming reaction, P–T conditions and deformation kinematics occurred. The junction of the proposed second and third stages of garnet growth (G₂ and G₃) coincides with the transition between successive crenulation cleavages, without substantial microstructural truncations or changes in the inclusion assemblage. The G₂–G₃ boundary is generally marked by uninterrupted normal zoning, with subtle compositional anomalies in some samples. This boundary may in fact record continuous garnet growth, or alternatively mark a relatively short intra-orogenic pause in garnet growth with minimal affect on zoning patterns. Individual porphyroblasts with contrasting inclusion trail microstructures also have different zoning patterns, and this supports the previous recognition of contrasting growth histories between individual porphyroblasts. A combined structural–metamorphic model is presented that integrates the timing of garnet growth and foliation development, reaction history and the P–T–t path in the Fleur de Lys Supergroup.     

苏北东海青龙山变斑状榴辉岩的变质演化

青龙山部分榴辉岩以含绿帘石、蓝晶石和滑石变斑晶为特征,但是其峰变质矿物组合由基质中细粒的石榴石+绿辉石+多硅白云母+柯石英+金红石+绿帘石构成,它们定向分布形成片理构造。相图中石榴石组成等值线温压计确定的峰变质组合为:石榴石+绿辉石+多硅白云母+蓝晶石+金红石+柯石英+硬柱石+滑石,与岩相学观察结果不符。这可能是超高压变质流体显著偏离计算相图假设的流体相为纯水所致。无定向的变斑晶切割片理,晚于峰变质组合结晶于弱剪切应力的环境。岩相学观察和相图模拟结果显示,变斑晶的形成顺序为蓝晶石-绿帘石-滑石。绿帘石在<2GPa大量生长形成变斑晶,它包含柯石英并不一定说明二者平衡共生,更可能是温压快速下降后峰变质组合被绿帘石变斑晶包含。由矿物组合限定的青龙山变斑状榴辉岩P-T路径为典型的"发卡式"。含水矿物出现于岩石的各个变质组合,并且沿退变质P-T路径陆续结晶数量增多,表明在退变质过程中不断有流体渗入岩石。     

Fractionation of bulk rock composition due to porphyroblast growth: effects on eclogite facies mineral equilibria, Pam Peninsula, New Caledonia

Chemically zoned porphyroblasts in metamorphic rocks indicate that diffusional processes could not maintain equilibrium conditions on a grain scale during porphyroblast growth or establish it afterwards. An effect of this inability to maintain equilibrium is the progressive removal of elements forming garnet cores from any metamorphic reaction that occurs at the porphyroblast boundaries or in the matrix of the rock. To examine this effect on mineral assemblages, the Bence–Albee matrix correction was applied to X‐ray intensity maps collected using eclogite samples from northern New Caledonia in order to determine the chemical composition of all parts of the sample. The manipulation of these element maps allows a quantitative analysis of the fractionation of the bulk rock composition between garnet cores and the matrix. A series of calculated equilibrium‐volume compositions represents the change in matrix chemistry with progressive elemental fractionation as a consequence of prograde garnet growth under high‐P conditions. Pressure–temperature pseudosections are calculated for these compositions, in the CaO–Na₂O–FeO–MgO–Al₂O₃–SiO₂–H₂O system. Assemblages, modal proportions and mineral textures observed in the New Caledonian eclogites can be closely modelled by progressively ‘removing’ elements forming garnet cores from the bulk rock composition. The pseudosections demonstrate how chemical fractionation effects the peak metamorphic assemblage, prograde textures and the development of retrograde assemblages.     

Microstructural features of albite porphyroblasts as indicators of sequential Barrovian metamorphic mineral growth in the Caledonides of the SW Scottish Highlands

Inclusion – porphyroblast and porphyroblast – porphyroblast relationships show that abundant albite in mica schists in the Caledonides of the SW Scottish Highlands are part of the Barrovian metamorphic assemblage. Growth early in the D2 deformational phase of porphyroblast cores followed the growth of Mn‐rich garnet but preceded the growth of porphyroblasts of the index mineral almandine. Two sets of inclusion trails in the albite correspond to the regionally expressed S1 and S2. Straight trails of muscovite, chlorite, quartz, epidote and the earliest growth of biotite make up S1. Crenulated trails express deformation of S1 early in D2 with muscovite, chlorite, biotite, quartz, epidote and the Mn‐rich garnet associated with the development of S2 crenulation cleavage. The geometries of these trails uniquely record early stages of D2 deformational history. An _0?3 growth is related to the temporal coincidence of the formation of S1–S2 crenulation cleavage hinges as favourable sites for nucleation and the release of large amounts of water from prograde reactions during tectonothermal reconstitution of first cycle immature sediments with a volcanic component. The main characteristics of the regionally expressed D2 schistosity were developed during the major grain coarsening that followed both albite and almandine porphyroblast growth. Essentially inclusion‐free An _4?19 rims grew on the inclusion‐containing cores in the almandine zone in the later stages of schistosity growth and unoriented porphyroblasts of muscovite, biotite and chlorite indicate that mineral growth extended from the later stages of D2 to post‐D2. Previous interpretations of the albite porphyroblast growth having been during D4 to post‐D4 contemporaneous with retrogression are inconsistent with the microstructural evidence.     

Sigmoidal inclusion trails, punctuated fabric development, and interactions between metamorphism and deformation

Porphyroblast inclusion fabrics are consistent in style and geometry across three Proterozoic metamorphic field gradients, comprising two pluton-related gradients in central Arizona and one regional gradient in northern New Mexico. Garnet crystals contain curved ‘sigmoidal’ inclusion trails. In low-grade chlorite schists, these trails can be correlated directly with matrix crenulations of an older schistosity (S1). The garnet crystals preferentially grew in crenulation hinges, but some late crenulations nucleated on existing garnet porphyroblasts. At higher grade, biotite, staurolite and andalusite porphyroblasts occur in a homogeneous S2 foliation primarily defined by matrix biotite and ilmenite. Biotite porphyroblasts have straight to sigmoidal inclusion trails that also represent the weakly folded S1 schistosity. Staurolite and andalusite contain distinctive inclusion-rich and inclusion-poor domains that represent a relict S2 differentiated crenulation cleavage. Together, the inclusion relationships document the progressive development of the S2 fabric through six stages. Garnet and biotite porphyroblasts contain stage 2 or 3 crenulations; staurolite and andalusite generally contain stage 4 crenulations, and the matrix typically contains a homogeneous stage 6 cleavage. The similarity of inclusion relationships across spatially and temporally distinct metamorphic field gradients of widely differing scales suggests a fundamental link between metamorphism and deformation. Three end-member relationships may be involved: (1) tectonic linkages, where similar P-T-time histories and similar bulk compositions combine to produce similar metamorphic and structural signatures; (2) deformation-controlled linkages, where certain microstructures, particularly crenulation hinges, are favourable environments for the nucleation and/or growth of porphyroblasts; and (3) reaction-controlled linkages, where metamorphic reactions, particularly dehydration reactions, are associated with an increase in the rate of fabric development. A general model is proposed in which (1) garnet and biotite porphyroblasts preferentially grow in stage 2 or 3 crenulation hinges, and (2) chlorite-consuming metamorphic reactions lead to pulses in the rate of fabric evolution. The data suggest that fabric development and porphyroblast growth may have been quite rapid, of the order of several hundreds of thousands of years, in these rocks. These microstructures and processes may be characteristic of low-pressure, first-cycle metamorphic belts.     

Field and textural relationship in pelitic schists and gneisses from the area around Mangpu, Darjeeling district, West Bengal

The metasedimentary rocks of the area around Mangpu constitute a portion of the hinge zone of the northern limb of the major synform of Lower Darjeeling Himalaya. The rocks display evidences of multiple deformation and at least three major phases of deformation have been recognized. The time relations between the phases of deformation (D₁, D₂, D₃) and metamorphic crystallization reveal a single major prograde metamorphic event that initiated with the D₁ deformation and finally outlasted it. The earlier phase of this metamorphism is essentially regional syn-tectonic lowgrade (greenschist facies) which may be designated (M₁, early). This was followed by regional static metamorphism (M₁, late) in the post-tectonic phase between D₁ and D₂ deformations (upper green schist and amphibolite facies). This M1 metamorphism is superposed by later retrogressive metamorphism (M₂) during the D₂ and D₃ deformations (lower greenschist facies). Within the study area four isograds have been delineated by the first appearance of index minerals in the pelitic schists and gneiss which display Barrovian type of metamorphism.     

Dehydration-related deformation during regional metamorphism, NW Sardinia, Italy

The relationship between deformation and dehydration has been investigated in Hercynian regionally metamorphosed rocks exposed on NW Sardinia. Two episodes of prograde mineral growth (M₁ & M₂) involving dehydration are recognized: growth of chlorite/phengite porphyroblasts at anchizone metamorphic conditions, contemporaneous with the first phase of deformation, D₁, and growth of biotite from chlorite and phengite coincident with the second phase of deformation, D₂. Deformation during both episodes of dehydration is characterized by penetrative axial planar foliations defined by well-developed phyllosilicate preferred orientations quantified by XRD textural goniometry, tight to isoclinal similar folds (interlimb angles <40°), and mineral-filled veins (hydrofractures) orientated parallel to axial planar foliations, that formed contemporaneously with the development of the penetrative foliations. No prograde mineral growth occurred during D₂ at chlorite-zone conditions. D₂ deformation in the absence of dehydration is characterized by non-penetrative crenulation cleavages, poorly developed phyllosilicate preferred orientations, relatively open (interlimb angles >40°), low-strain similar folds and minor brittle deformation. Systematic variations in macrofold interlimb angles, with respect to the timing of mineral growth, indicate that enhanced shortening (c. 80%) occurred during dehydration. Microfabrics show that the onset of dehydration is associated with the transition from a crenulation cleavage to a penetrative foliation. The presence of axial planar hydrofractures that formed coevally with dehydration and fabric development requires that supralithostatic fluid pressures and low differential stresses (<c. 20 MPa) accompanied dehydration. These features demonstrate a connection between the timing of dehydration and the style of deformation.     

Metamorphic <Emphasis Type="Italic">P</Emphasis>–<Emphasis Type="Italic">T</Emphasis> paths of the Zanhuang amphibolites and metapelites: constraints on the tectonic evolution of the Paleoproterozoic Trans-North China Orogen

Garnet-bearing metapelites and amphibolites are exposed in the south and middle parts of the Zanhuang complex, which is located in the central segment of the nearly NS-striking Trans-North China Orogen. These rocks preserve three metamorphic mineral assemblages forming at the prograde, peak and post-peak decompression stages. The prograde metamorphic stage (M₁) is represented by mineral inclusions within garnet porphyroblasts, the peak metamorphic stage (M₂) is represented by garnet rims and matrix minerals, whereas the retrograde stage (M₃) is represented by amphibole + plagioclase symplectite rimming garnet porphyroblasts in the amphibolites and biotite + plagioclase symplectite rimming garnet porphyroblasts in the metapelites. All garnet porphyroblasts in the metapelites preserve prograde chemical zoning except for the ubiquitous, quite narrow zones from the underwent post-peak decompression. It has been determined through thermobarometric computation that the metamorphic conditions are 650–710°C at 8.2−9.2 kbar for the M₁ (inclusion) assemblages, >810°C at >12.5 kbar for the metamorphic peak M₂ (matrix) assemblages, and 660–680°C at 4.4–4.5 kbar for the retrograde M₃ (symplectite) assemblages. These rocks are thus determined to have undergone metamorphism with clockwise P–T paths involving nearly isothermal decompression (ITD) segments, which is inferred to be related to the amalgamation of the Eastern and Western Blocks to form the coherent basement of the North China Craton along the Trans-North China Orogen in the late Paleoproterozoic (1.88–1.85 Ga).     

有效全岩成分的计算方法及其在变质相平衡模拟中的应用

变质相平衡模拟是变质岩领域近几十年最重要的进展之一，它已经成为确定变质作用P-T-t轨迹和探索变质演化过程的有力工具。变质岩的矿物组合不但与其形成的温度（T）和压力（P）条件有关，而且受控于岩石的全岩成分（X）。但是变质岩通常是不均匀的并且往往保留两期以上的矿物组合，因此计算不同成分域或不同变质演化期次的有效全岩成分是模拟P-T视剖面图的核心问题之一。在中-低温变质岩中，石榴石变斑晶的生长会不断地将其核部成分"冻结"而不参与后续变质反应，这导致根据实测全岩成分计算的P-T视剖面图无法有效地模拟石榴石幔部或边部生长阶段的变质演化过程。"瑞利分馏法"和"球体积法"利用电子探针实测的石榴石成分环带可以模拟计算石榴石各个生长阶段所对应的有效全岩成分，本文推荐使用这两个方法来处理石榴石变斑晶的分馏效应问题。相比较而言，石榴石在高温变质岩中通常无法保留生长阶段的成分环带特征，这是因为石榴石成分在高温条件下会发生扩散再平衡，并同时与多数基质矿物达到热力学平衡，这时一般不需要考虑石榴石的分馏效应。但是高温变质岩通常会发生部分熔融并伴随熔体的迁移，进而改变岩石的有效全岩成分。因此，通过P-T视剖面图模拟熔体迁移前后的变质演化过程需要使用"相平衡法"计算迁移的熔体成分以及熔体迁移前后岩石的有效全岩成分。此外，后成合晶与反应边是变质岩中最常见的退变质反应结构，但是后成合晶或反应边中的矿物之间并未达到热力学平衡。这种情况需要结合岩相学观察和矿物成分，利用最小二乘法确定后成合晶或反应边中发生的平衡反应方程式，进而获取变质反应发生时的有效全岩成分并通过计算P-T视剖面图来估算退变质的温压条件。除此之外，岩石体系中三价铁（Fe₂O₃）和H₂O含量的估算一直以来都是相平衡模拟研究中的难点，本文推荐使用P/T-X（Fe³⁺/Fe^tot，MH₂O）视剖面图来确定这两个组分的含量，这是因为P/T-X图可以估算各个变质演化阶段或特定矿物组合的Fe₂O₃或H₂O含量。     

Tectonometamorphic evolution of the Permo-Triassic Songrim (Indosinian) orogeny: evidence from the late Paleozoic Pyeongan Supergroup in the northeastern Taebaeksan Basin,South Korea

The deformed and metamorphosed middle Pennsylvanian to Early Triassic (?) rocks of the Pyeongan Supergroup, occurring in northeastern flank of the Paleozoic Taebaeksan Basin, east central South Korea, record the impact of the Late Permian–Triassic Songrim (Indosinian) collisional orogeny in the eastern Eurasia margin. Analysis of meso- and microstructures and their relationship with porphyroblast growth has revealed that these metasedimentary rocks were affected by four deformation events (D₁–D₄). During the polyphase deformations, successive foliations with alternately steep (S₁ and S₃) and flat-lying (S₂ and S₄) orientations were produced with growth of chloritoid, andalusite and kyanite porphyroblasts during D₁ and D₂, and growth of garnet, staurolite and andalusite porphyroblasts during D₃ and D₄. SHRIMP U–Pb detrital zircon ages (330–310 Ma) from metapelites in the oldest unit of the Pyeongan Supergroup in the study area, combined with the previous data on sandstone compositions, indicate magmatic activity that was contemporaneous with the initial deposition of the Pyeongan Supergroup. This also suggests that the Pyeongan Supergroup was deposited in an arc-related foreland basin at an active continental margin during the Late Carboniferous and Permian time. Two contractional deformation events (D₁ and D₃) and two events related to gravitational flattening (D₂ and D₄), along with Barrovian-type medium-pressure regional metamorphism, may have resulted from the Late Permian–Triassic Songrim orogeny, related to collision between the North and South China blocks and/or collision between the Eastern Eurasia margin and the proto-Japan terrane.     

Metastable staurolite–cordierite assemblage of the Bossòst dome: Late Variscan decompression and polyphase metamorphism in the Axial Zone of the central Pyrenees

A kilometre-scale shear zone is recognized in the Cambro–Ordovician schist of the Bossòst dome, a Variscan metamorphic and structural dome in the Axial Zone of the central Pyrenees. Non-coaxial deformation is recorded by rotated garnet and staurolite porphyroblasts following regional metamorphism M₁, while coaxial conditions prevailed during later contact metamorphic M₂ growth of andalusite and cordierite. Mineral compositions and bulk rock analyses show that garnet–staurolite–andalusite–cordierite assemblages are significantly enriched in Mg and Mn over the garnet–staurolite assemblage, which lacks sufficient Mg for cordierite to form. The garnet–staurolite assemblage preserves conditions during M₁, estimated by AFM diagrams and P–T pseudosections to be 5.5 kbar and 580 °C, respectively. Pseudosections also indicate that staurolite is not a stable phase in cordierite–andalusite assemblages of M₂, suggesting polyphase metamorphism and decompression along a clockwise P–T path for the staurolite–cordierite–andalusite assemblages. This concurs with proposed extensional tectonics along the regional shear zone. To cite this article: J.E. Mezger et al., C. R. Geoscience 336 (2004).