The effect of metasomatism on the Cr-PGE mineralization in the Finero Complex, Ivrea Zone, Southern Alps

The magmatic metasomatism that was responsible for producing chromitite–dunite bodies in the unusual phlogopite peridotite of the Finero Complex in Permian to Triassic times also influenced the Cr-platinum group elements (PGE) mineralization. At least the end stages of this metasomatism are recorded in compositional zoning of chromite grains in the podiform chromitite. Metasomatic melt, with or without vapor, reacted with chromite to produce core-to-rim Cr enrichment of extant chromite grains and was concurrent with pyroxene crystallization. Under conditions of lower melt/rock ratio, metasomatism resulted in core-to-rim Al enrichment in chromite and crystallization of amphibole between chromite and clinopyroxene. This early, high-temperature metasomatism is unrelated to the later and pervasive K-metasomatism that crystallized phlogopite and was associated with the intrusion of clinopyroxenite dikes that cut the peridotite. Much later, serpentinization of olivine locally depleted chromite in Al and enriched it in Fe and formed minor amounts of magnetite.The PGE, which are present mainly as laurite inclusions in chromite, were remobilized by the early metasomatism. This resulted in substantial variation in the PGE contents of chromitites and imposed a characteristic PGE pattern in which chondrite-normalized Os, Ir, Ru and Rh contents are high but Pt and Pd contents are low. The slopes of PGE chondrite-normalized concentration patterns are systematically related to absolute PGE abundance and to rock mode. Chromitites with low modal orthopyroxene, clinopyroxene, and amphibole exhibit negative PGE slopes and contain relatively high PGE concentrations, whereas chromitites rich in these silicate minerals have positive slopes and low PGE contents.     

Anatexis and fluid regime of the deep continental crust: New clues from melt and fluid inclusions in metapelitic migmatites from Ivrea Zone (NW Italy)

We investigate the inclusions hosted in peritectic garnet from metapelitic migmatites of the Kinzigite Formation (Ivrea Zone, NW Italy) to evaluate the starting composition of the anatectic melt and fluid regime during anatexis throughout the upper amphibolite facies, transition, and granulite facies zones. Inclusions have negative crystal shapes, sizes from 2 to 10 μm and are regularly distributed in the core of the garnet. Microstructural and micro‐Raman investigations indicate the presence of two types of inclusions: crystallized silicate melt inclusions (i.e., nanogranitoids, NI), and fluid inclusions (FI). Microstructural evidence suggests that FI and NI coexist in the same cluster and are primary (i.e., were trapped simultaneously during garnet growth). FI have similar compositions in the three zones and comprise variable proportions of CO₂, CH₄, and N₂, commonly with siderite, pyrophyllite, and kaolinite, suggesting a COHN composition of the trapped fluid. The mineral assemblage in the NI contains K‐feldspar, plagioclase, quartz, biotite, muscovite, chlorite, graphite and, rarely, calcite. Polymorphs such as kumdykolite, cristobalite, tridymite, and less commonly kokchetavite, were also found. Rehomogenized NI from the different zones show that all the melts are leucogranitic but have slightly different compositions. In samples from the upper amphibolite facies, melts are less mafic (FeO + MgO = 2.0–3.4 wt%), contain 860–1700 ppm CO₂ and reach the highest H₂O contents (6.5–10 wt%). In the transition zone melts have intermediate H₂O (4.8–8.5 wt%), CO₂ (457–1534 ppm) and maficity (FeO + MgO = 2.3–3.9 wt%). In contrast, melts at granulite facies reach highest CaO, FeO + MgO (3.2–4.7 wt%), and CO₂ (up to 2,400 ppm), with H₂O contents comparable (5.4–8.3 wt%) to the other two zones. Our results represent the first clear evidence for carbonic fluid‐present melting in the Ivrea Zone. Anatexis of metapelites occurred through muscovite and biotite breakdown melting in the presence of a COH fluid, in a situation of fluid–melt immiscibility. The fluid is assumed to have been internally derived, produced initially by devolatilization of hydrous silicates in the graphitic protolith, then as a result of oxidation of carbon by consumption of Fe³⁺‐bearing biotite during melting. Variations in the compositions of the melts are interpreted to result from higher T of melting. The H₂O contents of the melts throughout the three zones are higher than usually assumed for initial H₂O contents of anatectic melts. The CO₂ contents are highest at granulite facies, and show that carbon‐contents of crustal magmas are not negligible at high T. The activity of H₂O of the fluid dissolved in granitic melts decreases with increasing metamorphic grade. Carbonic fluid‐present melting of the deep continental crust represents, together with hydrate‐breakdown melting reactions, an important process in the origin of crustal anatectic granitoids.     

藏南罗布莎蛇绿岩辉绿岩中锆石SHRIMP测年

罗布莎蛇绿岩是雅鲁藏布江蛇绿岩带东段出露较好,也是研究程度较高的蛇绿岩片之一。对该蛇绿岩的形成时代至今存在分歧。本文获得该蛇绿岩辉绿岩中的锆石SHRIMPU-Pb定年的结果为162.9±2.8Ma,表明该蛇绿岩的形成时代为中侏罗世,同时发现,在罗布莎地区新特提斯洋形成时,可能存在地幔熔融的岩浆在扩张脊上涌过程中俘获老洋壳或者深海沉积物中锆石的情况;并且在侵位过程中,在该蛇绿岩的局部由于蚀变而产生了变质锆石。     

Tephrostratigraphy of the late glacial and Holocene sediments of Puyehue Lake (Southern Volcanic Zone, Chile, 40°S)

We document the mineralogical and geochemical composition of tephra layers identified in the late Quaternary sediments of Puyehue Lake (Southern Volcanic Zone of the Andes, Chile, 40°S) to identify the source volcanoes and to present the first tephrostratigraphic model for the region. For the last millennium, we propose a multi-criteria correlation model based on five tephra layers identified at seven coring sites. The two upper tephras are thin fine-grained green layers composed of more than 80% rhyodacitic glass shards, and associated to the AD 1960 and AD 1921-22 eruptions of the Puyehue-Cordon de Caulle volcanic complex. The third tephra is a sandy layer dominated by orthopyroxene, and related to the AD 1907 eruption of Rininahue maar. An olivine-rich tephra was deposited at the end of the 16th century, and a tephra characterized by a two-pyroxene association marks the second half of the first millennium AD. In addition, we detail the tephra succession of an 11.22-m-long sediment core covering the last 18,000 yr. The results demonstrate that the central province of the Southern Volcanic Zone has been active throughout the last deglaciation and the Holocene, with no increase in volcanic activity during glacial unloading.     

The timing of sub-solidus hydrothermal alteration in the Central Zone, Limpopo Belt (South Africa): Constraints from titanite U–Pb geochronology and REE partitioning

In the Central Zone of the Limpopo Belt (South Africa), Palaeoproterozoic granulite-facies metamorphism was superimposed on an earlier Archaean orogenic history. Previously determined ages of  2030–2020 Ma obtained from high-temperature chronometers (zircon, garnet, monazite) are generally thought to provide the best estimate of the peak of Palaeoproterozoic granulite-facies metamorphism in the Central Zone, whereas ages as young as  2006 Ma from late melt patches suggest that temperatures remained above the wet solidus for an extended period. We present a new MC-ICP-MS ²⁰⁷Pb–²⁰⁶Pb age of 2030.9 ± 1.5 Ma for titanite found in amphibolite- to greenschist-facies alteration zones developed adjacent to quartz vein systems and related pegmatites that cut a strongly deformed Central Zone metabasite. This age could potentially date cooling of rocks at this locality to temperatures below the wet solidus. Alternatively, the titanite could be inherited from the metabasite host, and the age determined from it date the peak of metamorphism. Integration of the geochronology with LA-ICP-MS trace element data for minerals from the metabasite, the hydrothermal vein systems and comparable rocks elsewhere shows that the titanite formed during the amphibolite-facies hydrothermal alteration, not at the metamorphic peak or during the greenschist-facies phase of veining. This suggests that high-grade rocks in the Central Zone have cooled differentially through the wet solidus, and provides timing constraints on when Palaeoproterozoic reworking in the Central Zone began. This study illustrates the potential of combined geochronological and high-resolution geochemical studies to accurately match mineral ages to distinct crustal processes.     

Dating synmagmatic folds: a case study of Schlingen structures in the Strona-Ceneri Zone (Southern Alps, northern Italy)

The Strona-Ceneri Zone (Southern Alps) contains folds with moderately to steeply inclined axial planes and fold axes, and amplitudes of up to several kilometres (so-called 'Schlingen'). These amphibolite facies folds deform the main schistosity of Late Ordovician metagranitoids and are discordantly overlain by unmetamorphic Permian sedimentary rocks. Mutually cross-cutting relationships between these folds and garnet-bearing leucotonalitic dykes indicate that these dykes were emplaced during folding. Sm–Nd systematics and the strongly peraluminous composition of these dykes point to an anatectic origin. Pb step leaching of magmatic garnet from a leucotonalitic dyke yielded a 321.3±2.3  Ma intrusive age. Rb–Sr ages on muscovites from leucotonalitic dykes range from 307 to 298  Ma, interpreted as cooling ages during retrograde amphibolite facies metamorphism. Conventional U–Pb data of zircons from an older granodioritic dyke that pre-dates the Schlingen folds yielded discordant U–Pb ages ranging from 371 to 294  Ma. These ages reflect a more complicated multi-episodic growth history which is consistent with the observed polyphase structural overprint of this dyke. Schlingen folding was accompanied by prograde amphibolite facies metamorphism, during the thermal peak of which the leucotonalitic dyke material was generated by partial melting in a deeper source region from where these S-type magmas intruded the presently exposed level. Because partial melting may occur in a relatively late stage of a clockwise P–T–t path, or even during decompression on the retrograde path, we do not exclude the possibility that Schlingen folding had already started in Early Carboniferous time. Schlingen folds also occur in Penninic and Austroalpine basement units with a very similar pre-Alpine history, indicating that Variscan folding affected large segments of the future Alpine realm.     

The denudation history of the Argentera Alpine External Crystalline Massif (Western Alps,France-Italy): an overview from the analysis of fission tracks in apatites and zircons

Apatite/zircon fission track (FT) records of the Argentera external crystalline massif (Western Alps) show three tectonic pulses, respectively at 22 Ma (zircons), 6 and 3.5 Ma (apatites). The first pulse is consistent with the basement exhumation and initiation of the major deformation recorded in the foreland of the belt from Middle to early Upper Miocene. The two others might be respectively local expressions of the syncollisional extension mainly controlled by a westward sedimentary cover detachment and a Plio-Quaternary uplift acceleration. Zircon ages of 50-80 Ma in a limited NW area and evidence of an uplift elsewhere show that in a large fraction of the massif, temperatures in post-Variscan times never reached 320°C. Finally, FT data show that the Argentera massif did not behave as a single block during its denudation. First, in the NW of the massif, a small fault-limited block was already separated since the Cretaceous and later on recorded the 6 Ma denudation event, the 22 Ma pulse being recorded only in the remaining part of the massif. Second, less than 3.5 Ma ago, the northeastern part of the massif overthrust the southwestern block along the Bersézio-Veillos fault zone.     

太白岩体南缘铜(钼)矿化地质特征及找矿标志

在太白岩体南缘发现了铜(钼)矿,圈出铜矿体2个,铜矿化体1个,钼矿化体5个。铜矿体长度245~445 m,平均厚度2.03~2.81 m,平均Cu品位1.57%~1.67%;钼矿化体长度50 m,厚度2.03~2.81 m,Mo品位0.01%~0.54%。铜钼矿化受岩体岩石、构造及蚀变带的三重控制。总结出了岩体、构造、围岩蚀变、氧化物及硫化物露头是寻找铜钼矿的重要标志。对矿区矿石中辉钼矿采用Re-Os法同位素年龄测试,获得模式年龄119.3~123.7 Ma数据,说明本区铜钼矿化形成于燕山晚期。依据矿体与含矿岩体的关系、赋存状态、矿物组分及矿石的结构构造等因素,结合区域上铜钼矿化形成规律,初步认为该矿成因类型可能为与区域性花岗斑岩活动有关的热液型。这一结论对在本区寻找与花岗斑岩活动有关的热液型铜钼矿有着重要的现实意义。     

Late Neogene–Quaternary evolution of the intermontane Clusone Basin (Southern Alps,Italy): integration of seismic and geological data

In the Clusone Basin (a large intermontane basin filled by thick late Neogene–Quaternary sediments in the Middle Val Seriana, Southern Alps), two high‐resolution seismic profiles have been acquired in order to reconstruct the geometries of the sediments that fill the depression, with a maximum thickness of more than 200 m as documented by available well data, and to define their relationships with the bedrock, consisting of Late Triassic carbonates. In addition to standard seismic reflection processing, a seismic refraction inversion technique has been applied. The integration of geological (both surface and well data) and seismic data indicates a complex history of the drainage patterns of the Clusone Basin, documenting a shift of the Serio River from a palaeodrainage toward the southeast (Val Borlezza) to the present situation, toward the south (Val Seriana): between the older and the present‐day drainages an important depositional stage occurred, as documented by the thick sediments that fill the Clusone Basin, controlling the capture of the Serio River along the Val Seriana. Copyright © 2004 John Wiley & Sons, Ltd.     

Early cretaceous ophiolites of the Yarlung Zangbo Suture Zone: insights from dolerites and peridotites from the Baer upper mantle suite,SW Tibet (China)

The Baer ophiolitic massif is located in the northern sub-belt of the western segment of the Yarlung Zangbo Suture Zone (YZSZ) and mainly consists of a lherzolite-dominant mantle suite, dolerite intrusions and limited crustal outcrops. The dolerites show sub-ophitic texture and light rare earth element-depleted chondrite-normalized rare earth element patterns similar to normal-mid-ocean ridge basalts (N-MORB); though, they display enrichments in fluid-mobile elements (Rb, Ba, and Sr) and marked depletions in Th and Nb. The U–Pb ages of several magmatic zircon grains recovered from two dolerite samples indicate that the intrusion of the dikes into the Baer lherzolitic mantle occurred at 125.6–126.3 Ma, consistent with the widespread mafic magmatism between 120 and 130 Ma in the Yarlung Zangbo ophiolites. The dolerites have slightly more radiogenic ⁸⁷Sr/⁸⁶Sr ratios (0.7043–0.7054) in comparison to N-MORB, whereas they show ¹⁴³Nd/¹⁴⁴Nd values (0.513067–0.513114) similar to N-MORB and high zircon Hf-isotope compositions. They have a limited range of Nd-isotope (ε_Nd(t) values: +8.2 to +9.1) and juvenile Hf-isotope compositions (ε_Hf(t) values: +8.4 to +14.2 and +10.0 to +15.1) indicating derivation from mantle melts. The moderate spread in the ε_Hf (t) values of zircons indicates derivation of the dolerites parental magma from a weakly contaminated spinel-bearing mantle source. This is also corroborated by the geochemical signatures of the Baer dolerites (enrichment in LILE and depletion in HFSE) suggesting minor slab input to the mantle source of the dike-filling melt. We suggest that the genesis of the dolerite dike-forming melt happened at a stage of subduction initiation in a sub-oceanic mantle domain mildly affected by fluids emanating from the downgoing slab. Our data combined with literature data allow us to presume that the intrusion of the dolerites into the Baer mantle corresponds to an early phase of subduction initiation beneath a developing forearc basin.     

Zircon megacrysts from basalts of the Venetian Volcanic Province (NE Italy): U–Pb ages, oxygen isotopes and REE data

Mafic alkaline lavas from the Venetian Volcanic Province (NE Italy) contain orange–brown zircon megacrysts up to 15 mm long, subhedral to subrounded and showing equant morphology, with width-to-length ratios of 1:2–1:2.5. U–Pb ages of zircon (51.1 ± 1.5 to 30.5 ± 0.51 Ma) fit the stratigraphic age of the host lava (Middle Eocene and Oligocene) and their oxygen isotope composition (δ¹⁸O = 5.31–5.51‰) is similar to that of zircon formed in the upper mantle. Cathodoluminescence images and crystal chemical features, e.g. depletion of incompatible elements such as REE, Y, U and Th at constant Hf content, indicate that centre-to-edge zircon zoning is not consistent with evolution of the melt by fractional crystallization. All the above features, together with the fact that zircon and host basalts are coeval, indicate that the studied Zr megacrysts crystallised from a primitive alkaline mafic magma, which later evolved to the less alkaline host magma.     

Magnetic and ground probing radar measurements for soil pollution mapping in the industrial area of Val Basento (Basilicata Region, Southern Italy): a case study

The joint application of electromagnetic techniques for near-surface exploration is a useful tool for soil pollution monitoring and can also contribute towards describing the spatial distribution of pollutants. The results of a geophysical field survey that was carried out for characterizing the heavy metal and waste disposal soil pollution phenomena in the industrial area of Val Basento (Basilicata region, Southern Italy) are presented here. First, topsoil magnetic susceptibility measurements have been carried out for defining the spatial distribution of superficial pollution phenomena in the investigated area. Second, detailed and integrated measurements based on a high-resolution magnetic mapping and ground probing radar (GPR) profiling have been applied to investigate the subsurface in two industrial areas located in more polluted sites that were identified during the first phase. Our monitoring strategy discloses the way to rapidly define the zone characterized by high pollution levels deriving from chemical industries and traffic emissions and to obtain the way information about the presence of local buried sources of contamination.     

Dolomite characteristics and diagenetic model of the Calcari Grigi Group (Asiago Plateau,Southern Alps – Italy): an example of multiphase dolomitization

A multidisciplinary study, conducted over the carbonate platform deposits of the Liassic Calcari Grigi Group (Southern Alps), highlighted how the use of outcrop analogues can contribute to better define the distribution of dolomitic bodies related to fault networks, to characterize the petrophysical properties of the dolomitic sequence and unravel a complex diagenetic history. This study was carried out in the Asiago Plateau (southernmost part of the eastern Southern Alps, northern Italy) which provides excellent outcrops of the Jurassic Calcari Grigi Group. The dolomitization of the Jurassic sequence is variable in terms of stratigraphic extension and geographic distribution. In the studied localities the dolomitization is generally limited to the Mount Zugna Formation and is characterized by an undulatory front, with ‘sub‐vertical dolomitic chimneys’ along the major faults. Within this unit, and often associated with faults, stacked high‐porosity and permeability bed‐parallel dolomitic bodies are developed that show excellent petrophysical properties. The dolomitic intervals are characterized by pervasive unimodal and patchy polymodal dolomite crystals. Thin section, cathodoluminescence, isotopic and fluid inclusion analyses were used to constrain the paragenetic evolution of the sequence which is similar in all the studied localities. The first dolomitization stage is marked by zoned dolomite crystals with a dull luminescent core. The porosity is thought to have increased after this stage, with dark blue luminescent dolomite accompanied by the corrosion of older crystals. The appearance of saddle dolomite marks the onset of the porosity reduction stage, ending with the infilling of vugs and the remaining open pores with calcite cement. The diagenetic evolution locally stopped at the saddle dolomite stage with the complete occlusion of the remaining pores. Paragenetic and fluid‐inclusion data suggest an evolutionary trend of increasing temperatures and decreasing salinity toward brackish fluids responsible for dolomite and calcite precipitation. The integration of the available data seem to indicate that the diagenetic evolution of the study area is related to: (i) the interplay between evolving fluids (from marine to brackish); (ii) the burial of the sequence (increasing temperature); and (iii) the evolution of the hydrogeological system (fault and fracture network, fluid mixing). This complex paragenetic evolution is strongly linked to the evolution of the porosity framework that evolved from a good, widespread network in the early stages of the burial history to a confined system in the later stages due to reduction of porosity by the deposition of late calcite and dolomite cements.     

Impure marbles from the UHP Brossasco-Isasca Unit (Dora-Maira Massif, western Alps): evidence for Alpine equilibration in the diamond stability field and evaluation of the X(CO2) fluid evolution

Two impure ultrahigh-pressure (UHP) marbles, a calcite marble with the peak assemblage Grt + Phe + Cpx + Rt + (Arg) and a dolomite marble with the peak assemblage Crn + Chl + Rt + Dol (±Arg), from the same lens from the polymetamorphic complex of the Brossasco-Isasca Unit (BIU) (southern Dora-Maira Massif) have been petrologically investigated and modelled by calculating P – T phase-diagram projections for H₂O–CO₂ mixed-volatile systems. Thermobarometric data obtained from the calcite marble suggest Alpine peak conditions in the diamond stability field (4.0 GPa at 730 °C), and allow reconstruction of the earlier portion of the Alpine retrograde P – T path, which is characterized by a significant decompression coupled with a moderate and continuous cooling to 650 °C at 2.50 GPa. The modelled fluid compositions at peak conditions point to 0.025 ≤  X (CO₂) ≤ 0.10 and X (CO₂) ≤ 0.0012 in the calcite marble and dolomite marble, respectively, suggesting fluid heterogeneity at the local scale and an internally buffered fluid evolution of the studied impure marbles. The lack of micro-diamond in the BIU marbles is explained by the very-low X (CO₂) values, which favoured relatively high f O₂-conditions, preventing the formation of diamond at the UHP peak metamorphic conditions.     

High‐pressure metamorphic evolution of eclogite and associated metapelite from the Chuacús complex (Guatemala Suture Zone): Constraints from phase equilibria modelling coupled with Lu‐Hf and U‐Pb geochronology

As is common in suture zones, widespread high‐pressure rocks in the Caribbean region reached eclogite facies conditions close to ultrahigh‐pressure metamorphism. Besides eclogite lenses, abundant metapelitic rocks in the Chuacús complex (Guatemala Suture Zone) also preserve evidence for high‐pressure metamorphism. A comprehensive petrological and geochronological study was undertaken to constrain the tectonometamorphic evolution of eclogite and associated metapelite from this area in central Guatemala. The integration of field and petrological data allows the reconstruction of a previously unknown segment of the prograde P–T path and shows that these contrasting rock types share a common high‐pressure evolution. An early stage of high‐pressure/low‐temperature metamorphism at 18–20 kbar and 530–580°C is indicated by garnet core compositions as well as the nature and composition of mineral inclusions in garnet, including kyanite–jadeite–paragonite in an eclogite, and chloritoid–paragonite–rutile in a pelitic schist. Peak high‐pressure conditions are constrained at 23–25 kbar and 620–690°C by combining mineral assemblages, isopleth thermobarometry and Zr‐in‐rutile thermometry. A garnet/whole‐rock Lu‐Hf date of 101.8 ± 3.1 Ma in the kyanite‐bearing eclogite indicates the timing of final garnet growth at eclogite facies conditions, while a Lu‐Hf date of 95.5 ± 2.1 Ma in the pelitic schist reflects the average age of garnet growth spanning from an early eclogite facies evolution to a final amphibolite facies stage. Concordant U‐Pb LA‐ICP‐MS zircon data from the pelitic schist, in contrast, yield a mean age of 74.0 ± 0.5 Ma, which is equivalent to a U‐Pb monazite lower‐intercept age of 73.6 ± 2.0 Ma in the same sample, and comparable within errors with a less precise U‐Pb lower‐intercept age of 80 ± 13 Ma obtained in post‐eclogitic titanite from the kyanite‐bearing eclogite. These U‐Pb metamorphic ages are interpreted as dating an amphibolite facies overprint. Protolith U‐Pb zircon ages of 167.1 ± 4.2 Ma and 424.6 ± 5.0 Ma from two eclogite samples reveal that mafic precursors in the Chuacús complex originated in multiple tectonotemporal settings from the Silurian to Jurassic. The integration of petrological and geochronological data suggests that subduction of the continental margin of the North American plate (Chuacús complex) beneath the Greater Antilles arc occurred during an Albian‐Cenomanian pre‐collisional stage, and that a subsequent Campanian collisional stage is probably responsible of the amphibolite facies overprint and late syncollisional exhumation.     

藏南白朗地区宗卓组混杂岩的物质来源和形成时代——来自岩石学和碎屑锆石U-Pb定年的证据

本文通过对藏南白朗地区宗卓组混杂岩"基质"进行岩石学、碎屑锆石形态学和U-Pb同位素测年等研究,结果表明:"基质"中碎屑岩岩屑成分以中酸性熔岩为主,石英颗粒在阴极发光下主要呈不发光或弱发光,为低温变质成因的自生石英再沉积;碎屑锆石以岩浆成因锆石为主,少量变质成因锆石,多因经历了一定距离的搬运磨蚀作用而呈浑圆状、椭圆状;碎屑锆石年龄绝大多数分布于422~2867 Ma(43.5%)和71~205 Ma(52.2%),在中元古代(1032~1569 Ma)和早白垩世(102~142 Ma)形成两个年龄主峰。综合研究将研究区宗卓组混杂岩中"基质"的形成时代限定为晚白垩统马斯特里赫特期,雅鲁藏布江缝合带北侧冈底斯弧与南侧印度大陆北缘均对其物源具有一定的贡献。     

云南二叠纪白马寨铜镍硫化物矿床的成因:地壳混染与矿化的关系

云南金平白马寨-营盘街-带的奥陶纪变砂岩和板岩中出露大量小型约260Ma的镁铁-超镁铁质岩体,其中白马寨地区三个岩体具明显铜-镍硫化物矿化：三号岩体有一个中型铜镍硫化物矿床,一号和二号岩体可见微弱矿化。一号岩体的Ni／Cu值为0．7～2．2,二号岩体的Ni／Cu值为1．4～4．0,与三号岩体的比值（Ni／Cu=-0．5～6．7）相近,说明他们的母岩浆成分接近,为富Mg的镁铁质或苦橄质岩浆。三个岩体遭受不同程度的地壳混染,表现为强烈的Nb（Ta）异常,很低的Nb／La值（O．5～O．7）和很负的￡。。（f）值（一5．1～一9．O）。根据全岩的Th／Yb和Nb／Th值估算,一号岩体的地壳混染程度为5％～20％,二号岩体的地壳混染程度为5％～10％,而三号岩体的地壳混染程度高达35％。三个岩体的地壳混染程度与岩体中硫化物的含量呈正相关关系,表明地壳混染是导致白马寨岩体硫化物饱和的主要因素。     

Magmatic-hydrothermal Evolution and Mineralization Mechanisms of the Wangjiazhuang Cu (-Mo) Deposit in the Zouping Volcanic Basin, Shandong Province, China: Constraints from Fluid Inclusions

The Wangjiazhuang Cu (-Mo) deposit, located within the Zouping volcanic basin in western Shandong Province, China, is unique in this area for having an economic value. In order to expound the metallogenetic characteristics of this porphyry-like hydrothermal deposit, a detailed fluid inclusion study has been conducted, employing the techniques of representative sampling, fluid inclusion petrography, microthermometry, Raman spectroscopy, LA-ICP-MS analysis of single fluid inclusions, as well as cathode fluorescence spectrometer analysis of host mineral quartz. The deposit contains mainly two types of orebodies, i.e. veinlet-dissemination-stockwork orebodies in the K-Si alteration zone and pegmatitic-quartz sulfide veins above them. In addition, minor breccia ore occurs locally. Four types of fluid inclusions in the deposit and altered quartz monzonite are identified: L-type one- or two-phase aqueous inclusions, V-type vapor-rich inclusions with V/L ratios greater than 50%–90%, D-type multiphase fluid inclusions containing daughter minerals or solids and S-type silicate-bearing fluid inclusions containing mainly muscovite and biotite. Ore petrography and fluid inclusion study has revealed a three-stage mineralization process, driven by magmatic-hydrothermal fluid activity, as follows. Initially, a hydrothermal fluid, separated from the parent magma, infiltrated into the quartz monzonite, resulting in its extensive K-Si alteration, as indicated by silicate-bearing fluid inclusions trapped in altered quartz monzonite. This is followed by the early mineralization, the formation of quartz veinlets and dissemination-stockwork ores. During the main mineralization stage, due to the participation and mixing of meteoric groundwater with magmatic-sourced hydrothermal fluid, the cooling and phase separation caused deposition of metals from the hydrothermal fluids. As a result, the pegmatitic-quartz sulfide-vein ores formed. In the late mineralization stage, decreasing fluid salinity led to the formation of L-type aqueous inclusions and chalcopyrite-sulfosalt ore. Coexistence of V-type and D-type inclusions and their similar homogenization temperatures with different homogenization modes suggest that phase separation or boiling of the ore-forming fluids took place during the early and the main mineralization stages. The formation P-T conditions of S-type inclusions and the early and the main mineralization stages were estimated as ca. 156–182 MPa and 450–650°C, 350–450°C, 18–35 MPa and 280–380°C, 8–15 MPa, respectively, based on the microthermometric data of the fluid inclusions formed at the individual stages.     

Mineralization events in the Xiaokele porphyry Cu (–Mo) deposit,NE China: Evidence from zircon U–Pb and K‐feldspar Ar–Ar geochronology and petrochemistry

The Great Xing'an Range (GXR), Northeast (NE) China, is a major polymetallic metallogenic belt in the eastern segment of the Central Asian Orogenic Belt. The newly discovered Xiaokele porphyry Cu (–Mo) deposit lies in the northern GXR. Field geological and geochronological studies have revealed two mineralization events in this deposit: early porphyry‐type Cu (–Mo) mineralization, and later vein‐type Cu mineralization. Previous geochronological studies yielded an age of ca. 147 Ma for the early Cu (–Mo) mineralization. Our ⁴⁰Ar/³⁹Ar dating yielded ⁴⁰Ar/³⁹Ar plateau ages of 124.8 ± 0.4 to 124.3 ± 0.4 Ma on K‐feldspar in altered Cu‐mineralized diorite porphyrite dikes that represent the overprinting vein‐type Cu mineralization, consistent with zircon U–Pb ages of the diorite porphyrite (126.4 ± 0.5 to 125.0 ± 0.5 Ma). The Cr and Ni contents and Mg^# of the Xiaokele diorite porphyrites are high. The diorite porphyrites at Xiaokele are enriched in light rare‐earth elements (REEs), and large‐ion lithophile elements (e.g., Rb, Ba, and K), are depleted in heavy REEs and high‐field‐strength elements (e.g., Nb, Ta, and Ti), and have weak negative ε_Hf(t) values (+0.29 to +5.27) with two‐stage model ages (T_DM2) of 1,164–845 Ma. Given the regional tectonic setting in Early Cretaceous, the ore‐bearing diorite porphyrites were likely formed in an extensional environment related to lithospheric delamination and asthenospheric upwelling induced by subduction of the Paleo‐Pacific Plate. These tectonic events caused large‐scale magmatic activity, ore mineralization, and lithospheric thinning in NE China.     

岩浆熔融体性质及演化在成矿过程中的作用——以西藏玉龙斑岩铜(钼)矿床为例

玉龙斑岩铜(钼)矿床是亚洲最大的斑岩型铜矿床,包含多种矿化类型,成矿作用复杂。作为典型的斑岩型矿床,岩浆熔融体的性质在玉龙铜矿床的形成过程中起到了至关重要的作用。本文将分别从岩浆熔融体的物理和化学性质出发,解释玉龙矿床为何能成为玉龙成矿带中唯一一个超大型矿床的原因。在熔体演化方面,笔者主要通过对熔体密度、粘度的计算获得有关数据,以了解熔体运移、含矿流体分离的过程,以解释玉龙铜矿床为何能形成如此规模的矿床。