Infrared measurements of the chemical composition of C/2006 P1 McNaught

C/2006 P1 McNaught is a dynamically new comet from the Oort cloud that passed very close to the Sun, driving overall volatile production rates up to about 10³¹ molecules s⁻¹. Post-perihelion observations were obtained in a target-of-opportunity campaign using the CSHELL instrument at the NASA Infrared Telescope Facility atop Mauna Kea, Hawaii, on UT 2007 January 27 and 28. Eight parent volatiles (H₂O, CH₄, C₂H₂, C₂H₆, HCN, CO, NH₃, H₂CO) and two daughter fragments (OH and NH₂) were detected, enabling the determination of a rotational temperature and production rate for H₂O on UT January 27 and absolute and relative production rates for all the detected parent species on UT January 28. The chemical composition measured in the coma suggests that this close perihelion passage stripped off processed outer surface layers, likely exposing relatively fresh primordial material during these observations. The post-perihelion abundances we measure for CO and CH₄ (relative to H₂O) are slightly depleted while C₂H₂, NH₂ and possibly NH₃ are enhanced when compared to the overall comet population. Measured abundances for other detected molecular species were within the range typically observed in comets.     

SWAN observations of 9P/Tempel 1 around the Deep Impact event

The SWAN instrument observed the coma of Comet 9P/Tempel 1 at Lyman alpha around the Deep Impact event. From these observations, a water production rate profile for 3 weeks after the impact was derived. The comet could not be identified in images taken before the impact because of the relatively low production rates. The most important feature of the profile is that the production rate increases by about a factor of two more than a week after the impact. This is too late to be directly caused by the impact plume itself. Although it is not impossible that the impact triggered a resurfacing event, the comet is known to show sudden outburts, and the elevated production rate is similar to what has been reported on previous apparitions.     

A multi-wavelength study of parent volatile abundances in Comet C/2006 M4 (SWAN)

Volatile organic emissions were detected post-perihelion in the long-period Comet C/2006 M4 (SWAN) in October and November 2006. Our study combines target-of-opportunity infrared observations using the Cryogenic Echelle Spectrometer (CSHELL) at the NASA-IRTF 3-m telescope, and millimeter wavelength observations using the Arizona Radio Observatory (ARO) 12-m telescope. Five parent volatiles were measured with CSHELL (H₂O, CO, CH₃OH, CH₄, and C₂H₆), and two additional species (HCN and CS) were measured with the ARO 12-m. These revealed highly depleted CO and somewhat enriched CH₃OH compared with abundances observed in the dominant group of long-period (Oort cloud) comets in our sample and similar to those observed recently in Comet 8P/Tuttle. This may indicate highly efficient H-atom addition to CO at very low temperature (∼10-20 K) on the surfaces of interstellar (pre-cometary) grains. Comet C/2006 M4 had nearly “normal” C₂H₆ and CH₄, suggesting a processing history similar to that experienced by the dominant group. When compared with estimated water production at the time of the millimeter observations, HCN was slightly depleted compared with the normal abundance in comets based on IR observations but was consistent with the majority of values from the millimeter. The ratio CS/HCN in C/2006 M4 was within the range measured in ten comets at millimeter wavelengths. The higher apparent H-atom conversion efficiency compared with most comets may indicate that the icy grains incorporated into C/2006 M4 were exposed to higher H-atom densities, or alternatively to similar densities but for a longer period of time.     

Radar observations of Comet P/2005 JQ5 (Catalina)

Arecibo radar observations of Comet P/2005 JQ5 (Catalina) have produced the first delay-Doppler images of a comet nucleus and the first radar detection of large-grain ejection from a Jupiter-family comet. The nucleus is small (1.4 km diameter), rough, and rapidly rotating. The large (>cm) grains have low velocities (∼1 m/s) and a low production rate.     

Light curves and photometric parameters of the comets C/1999 S4 (LINEAR), C/2001 Q4 (NEAT), C/2002 T7 (LINEAR), C/2002 V1 (NEAT), C2004 Q2 (Machholz), and 153P/2002 C1 (Ikeya-Zhang)

Light curves of six comets, C/1999 S4 (LINEAR), C/2001 Q4 (NEAT), C/2002 T7 (LINEAR), C/2002 V1 (NEAT), C/2004 Q2 (Machholz), and 153P/2002 C1 (Ikeya-Zhang), were built and investigated. The photometric parameters H ₀, H ₁₀, and n were calculated for these comets, and they were found to change both before and after perihelion. The shift of light curve peak with respect to perihelion passage moment was determined for each comet. Our white-light curves are compared to the results of polarimetric and electrophotometric observations of the comets C/2002 T7 (LINEAR) and C/2004 Q2 (Machholz).     

C/2002 VQ94 (LINEAR) and 29P/Schwassmann-Wachmann 1 — CO and N2 rich comets

We investigated comets active at large heliocentric distances using observations obtained at the 6-m BTA telescope (SAO RAS, Russia). Long-slit and photometric modes of the focal reducer SCORPIO were used. Two of the comets, 29P/Schwassmann-Wachmann 1 (SW1) and C/2002 VQ94 (LINEAR) were observed to be emission rich. Detection of CO⁺ and N⁺₂ emissions in the comae of these comets is evidence that they were formed in the outer regions of the Solar System or in a pre-solar interstellar cloud in a low temperature environment with T?25 K. The ratio of N⁺₂/CO⁺ is equal to 0.011 and 0.027 for SW1 and LINEAR, respectively. Comet LINEAR is the most distant object in the Solar System (7.332 AU) for which CO⁺ and N⁺₂ are measured. The photometric maximum of the isolated CO⁺ coma in Comet LINEAR is shifted by 1.4 arcsec (7.44×¹⁰³ km) relative to the photometric maximum of the dust coma. This shift deviates from the sunward direction by 63 degrees.     

Thermal model of water and CO activity of Comet C/1995 O1 (Hale-Bopp)

An investigation of the activity of Comet C/1995 O1 (Hale-Bopp) with a thermophysical nucleus model that does not rely on the existence of amorphous ice is presented. Our approach incorporates recent observations allowing to constrain important parameters that control cometary activity. The model accounts for heat conduction, heat advection, gas diffusion, sublimation, and condensation in a porous ice-dust matrix with moving boundaries. Erosion due to surface sublimation of water ice leads to a moving boundary. The movement of the boundary is modeled by applying a temperature remapping technique which allows us to account for the loss in the internal energy of the eroded surface material. These kind of problems are commonly referred to as Stefan problems. The model takes into account the diurnal rotation of the nucleus and seasonal effects due to the strong obliquity of Hale-Bopp as reported by Jorda et al. (Jorda, L., Rembor, K., Lecacheux, J., Colom, P., Colas, F., Frappa, E., Lara, L.M. [1997]. Earth Moon Planets 77, 167-180). Only bulk sublimation of water and CO ice are considered without further assumptions such as amorphous ices with certain amount of occluded CO gas. Confined and localized activity patterns are investigated following the reports of Lederer and Campins (Lederer, S.M., Campins, H. [2002]. Earth Moon Planets 90, 381-389) about the chemical heterogeneity of Hale-Bopp and of Bockelée-Morvan et al. (Bockelée-Morvan, D., Henry, F., Biver, N., Boissier, J., Colom, P., Crovisier, J., Despois, D., Moreno, R., Wink, J. [2009]. Astron. Astrophys. 505, 825-843) about a strong CO source at a latitude of 20°. The best fit to the observations of Biver et al. (Biver, N. et al. [2002]. Earth Moon Planets 90, 5-14) is obtained with a low thermal conductivity of 0.01 W m⁻¹ K⁻¹. This is in agreement with recent results of the Deep Impact mission to 9P/Tempel 1 (Groussin, O., A’Hearn, M.F., Li, J.-Y., Thomas, P.C., Sunshine, J.M., Lisse, C.M., Meech, K.J., Farnham, T.L., Feaga, L.M., Delamere, W.A. [2007]. Icarus 187, 16-25) and with previous thermal simulations (Kührt, E. [1999]. Space Sci. Rev. 90, 75-82). The water production curve matches the production rates well from −4 AU pre-perihelion to the outgoing leg while the model does not reproduce so well the water production beyond 4 AU pre-perihelion. The CO production curve is a good fit to the measurements of Biver et al. (2002) over the whole measured heliocentric range from −7 AU pre- to 15 AU post-perihelion.     

The organic composition of Comet C/2000 WM1 (LINEAR) revealed through infrared spectroscopy

We investigated the parent volatile composition of the Oort cloud Comet C/2000 WM₁ (LINEAR) on 23-25 November 2001, using the Near Infrared Echelle Spectrograph on the Keck II telescope. Flux-calibrated spectra, absolute production rates, and mixing ratios are presented for H₂O, HCN, CH₄, C₂H₂, C₂H₆, H₂CO, CH₃OH and CO. Compared with “organics-normal” comets, WM₁ is moderately depleted in HCN, CH₄ and CH₃OH, and is even more depleted in C₂H₂ and CO. Its composition is thus intermediate to comets that are severely depleted in their organic volatile composition and those that exhibit “normal” organic volatile abundances. We argue that WM₁ may have formed closer to the young Sun than “organics-normal” comets, but at greater distance than the severely depleted comets, before its ejection to the Oort cloud. The mixing ratios of the above-listed organic volatiles agree day-by-day for 23-25 November 2001. Thus, there is no evidence of macroscopic heterogeneity in chemistry of this comet’s nucleus at the achieved measurement accuracy. As the first comet to show moderate organic depletion in parent volatiles, WM₁ represents an important addition to the emerging taxonomic classification based on chemical composition.     

A tale of two very different comets: ISO and MSX measurements of dust emission from 126P/IRAS (1996) and 2P/Encke (1997)

We present the characteristics of the dust comae of two comets, 126P/IRAS, a member of the Halley family (a near-isotropic comet), and 2P/Encke, an ecliptic comet. We have primarily used mid- and far-infrared data obtained by the ISOPHOT instrument aboard the Infrared Space Observatory (ISO) in 1996 and 1997, and mid-infrared data obtained by the SPIRIT III instrument aboard the Midcourse Space Experiment (MSX) in 1996. We find that the dust grains emitted by the two comets have markedly different thermal and physical properties. P/IRAS's dust grain size distribution appears to be similar to that of fellow family member 1P/Halley, with grains smaller than 5 microns dominating by surface area, whereas P/Encke emits a much higher fraction of big (20 μm and higher) grains, with the grain mass distribution being similar to that which is inferred for the interplanetary dust population. P/Encke's dearth of micron-scale grains accounts for its visible-wavelength classification as a “gassy” comet. These conclusions are based on analyses of both imaging and spectrophotometry of the two comets; this combination provides a powerful way to constrain cometary dust properties. Specifically, P/IRAS was observed preperihelion while 1.71 AU from the Sun, and seen to have a 15-arcmin long mid-infrared dust tail pointing in the antisolar direction. No sunward spike was seen despite the vantage point being nearly in the comet's orbital plane. The tail's total mass at the time was about 8×10⁹ kg. The spectral energy distribution (SED) is best fit by a modified greybody with temperature T=265±15 K and emissivity ε proportional to a steep power law in wavelength λ: ε∝λ^−α, where α=0.50±0.20(2σ). This temperature is elevated with respect to the expected equilibrium temperature for this heliocentric distance. The dust mass loss rate was between 150-600 kg/s (95% confidence), the dust-to-gas mass loss ratio was about 3.3, and the albedo of the dust was 0.15±0.03. Carbonaceous material is depleted in the comet's dust by a factor of 2-3, paralleling the C₂ depletion in P/IRAS's gas coma. P/Encke, on the other hand, observed while 1.17 AU from the Sun, had an SED that is best fit by a Planck function with T=270±15 K and no emissivity falloff. The dust mass loss rate was 70-280 kg/s (95% confidence), the dust-to-gas mass loss ratio was about 2.3, and the albedo of the dust was about 0.06±0.02. These conclusions are consistent with the strongly curved dust tail and bright dust trail seen by Reach et al. (2000; Icarus 148, 80) in their ISO 12-μm imaging of P/Encke. The observed differences in the P/IRAS and P/Encke dust are most likely due to the less evolved and insolated state of the P/IRAS nuclear surface. If the dust emission behavior of P/Encke is typical of other ecliptic comets, then comets are the major supplier of the interplanetary dust cloud.     

A dynamical model with a new inversion technique applied to observations of Comet C/2000 WM1 (LINEAR)

Three continuum images of Comet C/2000 WM₁ (LINEAR) obtained on Nov 10, Nov 19, and Dec 03, 2001, are analyzed with the aid of a dynamical model, i.e. with a model that uses the size-dependent motion of dust grains under solar radiation pressure to determine the dust size distribution and its temporal change. The frames are photometrically calibrated in terms of the albedo filling factor product. On Nov 20.2 the Earth transited the orbital plane of the comet and an anti-tail was recognized in the image of Nov 19. For the determination of the particle fluxes describing the contribution of monodisperse particle shells to the cometary brightness the model uses a new regularization method employing Chebyshev polynomials of selected orders in emission time and particle size. It guarantees positiveness of the particle fluxes and imposes a varying degree of smoothness on their dependence on particle size and emission time. The particle emission velocities are still derived by trial and error. The dynamical model is described in detail. Results are presented for several low orders of the Chebyshev polynomials and are compared in order to understand the limitations imposed by the regularization process. The size distributions derived from the different observations do not always agree. This is particularly true for the earliest and most recent synchrones contributing to an image. In the observations of Nov 10 and Dec 03, i.e. excluding the anti-tail image, the integrated mass loss strongly decreases in the most recent time steps of the model although the comet is still approaching the Sun. This is interpreted as an artifact introduced by the overlap of the shells of large particle size emitted shortly before the observation. The model derives an increasing number of small particles released by the comet in the second half of November. This is at least in part considered as real and attributed to particle fragmentation occurring when the comet was at a heliocentric distance of about 1.4 AU.     

Circular polarization in comets: Observations of Comet C/1999 S4 (LINEAR) and tentative interpretation

Comet C/1999 S4 (LINEAR) was exceptional in many respects. Its nucleus underwent multiple fragmentations culminating in the complete disruption around July 20, 2000. We present circular polarization measurements along the cuts through the coma and nucleus of the comet during three separate observing runs, in June 28-July 2, July 8-9, and July 21-22, 2000. The circular polarization was detected at a rather high level, up to 0.8%. The left-handed as well as right-handed polarization was observed over the coma with the left circularly polarized light systematically observed in the sunward part of the coma. During our observations the phase angle of the comet varied from 61 up to 122°, which allowed us to reveal variations of circular polarization with the phase angle. Correlation between the degree of circular polarization, visual magnitude, water production rate, and linear polarization of Comet C/1999 S4 (LINEAR) during its final fragmentation in July 2000 was found. The mechanisms that may produce circular polarization in comets and specifically in Comet C/1999 S4 (LINEAR) are discussed and some tentative interpretation is presented.     

The molecular composition of Comet C/2007 W1 (Boattini): Evidence of a peculiar outgassing and a rich chemistry

We measured the chemical composition of Comet C/2007 W1 (Boattini) using the long-slit echelle grating spectrograph at Keck-2 (NIRSPEC) on 2008 July 9 and 10. We sampled 11 volatile species (H₂O, OH^∗, C₂H₆, CH₃OH, H₂CO, CH₄, HCN, C₂H₂, NH₃, NH₂, and CO), and retrieved three important cosmogonic indicators: the ortho-para ratios of H₂O and CH₄, and an upper-limit for the D/H ratio in water. The abundance ratios of almost all trace volatiles (relative to water) are among the highest ever observed in a comet. The comet also revealed a complex outgassing pattern, with some volatiles (the polar species H₂O and CH₃OH) presenting very asymmetric spatial profiles (extended in the anti-sunward hemisphere), while others (e.g., C₂H₆ and HCN) showed particularly symmetric profiles. We present emission profiles measured along the Sun-comet line for all observed volatiles, and discuss different production scenarios needed to explain them. We interpret the emission profiles in terms of release from two distinct moieties of ice, the first being clumps of mixed ice and dust released from the nucleus into the sunward hemisphere. The second moiety considered is very small grains of nearly pure polar ice (water and methanol, without dark material or apolar volatiles). Such grains would sublimate only very slowly, and could be swept into the anti-sunward hemisphere by radiation pressure and solar-actuated non-gravitational jet forces, thus providing an extended source in the anti-sunward hemisphere.     

Observations of the long-lasting activity of the distant Comets 29P Schwassmann-Wachmann 1, C/2003 WT42 (LINEAR) and C/2002 VQ94 (LINEAR)

We investigated three comets, which are active at large heliocentric distances, using observations obtained at the 6-m BTA telescope (SAO RAS, Russia) in the photometric mode of the focal reducer SCORPIO. The three comets, 29P/Schwassmann-Wachmann 1, C/2003 WT42 (LINEAR), and C/2002 VQ94 (LINEAR), were observed after their perihelion passages at heliocentric distances between 5.5 and 7.08 AU. The dust production rates in terms of Afρ was measured for these comets. Using the retrieved values, an average dust production rate was derived under different model assumptions. A tentative calculation of the total mass loss of the comet nucleus within a certain observation period was executed. We calculated the corresponding thickness of the depleted uppermost layer where high-volatile ices completely sublimated. The results obtained in our study strongly support the idea that the observed activity of Comet SW1 requires a permanent demolition of the upper surface layers.     

New Molecular Species in Comet C/1995 O1 (Hale-Bopp) Observed with the Caltech Ssubmillimeter Observatory

We present millimeter-wave observations of HNCO, HC₃N, SO, NH₂CHO, H¹³CN, and H₃O⁺ in comet C/1995 O1 (Hale-Bopp)obtained in February–April, 1997 with the Caltech Submillimeter Observatory (CSO). HNCO, first detected at the CSO in comet C/1996B2 (Hyakutake), is securely confirmed in comet Hale-Bopp via observations of three rotational transitions. The derived abundance with respect to H₂O is (4-13) × 10^-4. HC₃N, SO, and NH₂CHO are detected for the first time in a comet. The fractional abundance of HC₃N based on observations of three rotational lines is (1.9 ± 0.2) × 10^-4. Four transitions of SO are detected and the derived fractional abundance, (2-8) ×10^-3, is higher than the upper limits derived from UV observations of previous comets. Observations of NH₂CHO imply a fractional abundance of (1-8) × 10^-4. H₃O is detected for the first time from the ground. The H¹³CN (3-2)transition is also detected and the derived HCN/H¹³CN abundance ratio is 90 ± 15, consistent with the terrestrial¹²C/¹³C ratio. In addition, a number of other molecular species are detected, including HNC, OCS, HCO⁺, CO⁺, and CN(the last two are first detections in a comet at radio wavelengths). This revised version was published online in July 2006 with corrections to the Cover Date.     

Cometary dust properties retrieved from polarization observations: Application to C/1995 O1 Hale-Bopp and 1P/Halley

The analysis of the polarized light scattered by cometary dust particles provides information on the physical properties of the solid component of cometary comae for C/1995 O1 Hale-Bopp and 1P/Halley. A model of light scattering by a size distribution of aggregates of up to 256 submicron-sized grains (spherical or spheroidal) mixed with single spheroidal particles has been developed, with its parameters adjusted to fit the phase angle and wavelength dependence of the polarization observations. The particles are built of two materials: a non-absorbing silicates-type material and a more absorbing organic-type material. The model reproduces accurately the inversion angle and the positive branch of the polarization phase curves from the visible to the near-infrared spectral domains. A negative branch of the polarization phase curves appears in our model, although the negative branch is not deep enough to reproduce accurately the observations. Significant differences are shown between the two comets, with dominance of small grains in the coma of Comet C/1995 O1 Hale-Bopp, well fitted by a distribution of the volume-equivalent diameter, a, following a^−3.0 with a lower cutoff around 0.20 μm and an upper cutoff of at least 40 μm. For 1P/Halley, the size distribution follows a^−2.8 with a lower cutoff around 0.26 μm and an upper cutoff of about 38 μm. The relative amount of organic-type particles is larger for 1P/Halley while the amount of aggregates, significant for both comets, is larger for C/1995 O1 Hale-Bopp.     

No compelling evidence of distributed production of CO in Comet C/1995 O1 (Hale-Bopp) from millimeter interferometric data and a re-analysis of near-IR lines

Based on long-slit infrared spectroscopic observations, it has been suggested that half of the carbon monoxide present in the atmosphere of Comet C/1995 O1 (Hale-Bopp) close to perihelion was released by a distributed source in the coma, whose nature (dust or gas) remains unidentified. We re-assess the origin of CO in Hale-Bopp’s coma from millimeter interferometric data and a re-analysis of the IR lines.Simultaneous observations of the CO J(1–0) (115 GHz) and J(2–1) (230 GHz) lines were undertaken with the IRAM Plateau de Bure interferometer in single-dish and interferometric modes. The diversity of angular resolutions (from 1700 to 42,000 km diameter at the comet) is suitable to study the radial distribution of CO and detect the extended source observed in the infrared. We used excitation and radiative transfer models to simulate the single-dish and interferometric data. Various CO density distributions were considered, including 3D time-dependent hydrodynamical simulations which reproduce temporal variations caused by the presence of a CO rotating jet. The CO J(1–0) and J(2–1) observations can be consistently explained by a nuclear production of CO. Composite 50:50 nuclear/extended productions with characteristic scale lengths of CO parent L_p > 1500 km are rejected.Based on similar radiation transfer calculations, we show that the CO v = 1–0 ro-vibrational lines observed in Comet Hale-Bopp at heliocentric distances less than 1.5 AU are severely optically thick. The broad extent of the CO brightness distribution in the infrared is mainly due to optical depth effects entering in the emitted radiation. Additional factors can be found in the complex structure of the CO coma, and non-ideal slit positioning caused by the anisotropy of dust IR emission.We conclude that both CO millimeter and infrared lines do not provide compelling evidence for a distributed source of CO in Hale-Bopp’s atmosphere.     

Water production and release in Comet 153P/Ikeya-Zhang (C/2002 C1): accurate rotational temperature retrievals from hot-band lines near 2.9-μm

Multiple non-resonance fluorescence lines of water (H₂O) were detected in Comet 153/P Ikeya-Zhang (2002 C1) between UT 2002 March 21.9 (R_h=0.51 AU) and April 13.9 (R_h=0.78 AU), using the Cryogenic Echelle Spectrometer (CSHELL) at the NASA Infrared Telescope Facility. Analysis of 2.9-μm water lines enabled accurate determination of rotational temperatures on three dates. The derived H₂O rotational temperatures were 138⁺⁶₋₅, 141⁺¹⁰₋₉, and 94±3 K on UT 2002 March 22.0, March 23.0, and April 13.8, respectively. Water production rates were retrieved from spectral lines measured in nineteen separate grating settings over seven observing periods. The derived heliocentric dependence of the water production rate was Q=(9.2±1.1)×10²⁸[R_h^{(−3.21±0.26)}] molecules s⁻¹. The spatial distribution of H₂O in the coma was consistent with its release directly from the nucleus (as a native source) on all dates.     

Chemical and physical properties of gas jets in comets: II. Modeling OH, CN and C2 jets in Comet C/1995 O1 (Hale-Bopp) one month after perihelion

We present an analysis of OH, CN, and C₂ jets observed in Comet Hale-Bopp during April 22-26, 1997. We conclude that an extended source, which peaks in productivity after a certain amount of time has passed after being released from the nucleus (8.5, 2.5, and 42.6×¹⁰⁴ s, respectively) is responsible for the observed coma jet morphology in all three species. Sub-micron organic grains are the favored explanation for the extended source. Our models indicate that this extended source produces approximately 40% of the OH, 50% of the C₂, and 75% of the CN. The balance for each species is created by a diffuse nuclear gas source. Compared with the nuclear gas source and normalized to the CN abundance, the composition of the extended source is depleted in OH by a factor of ∼6, and depleted in C₂ by a factor of ∼2. The existence of anti-sunward jets do not require production of radicals throughout the cometary night. Instead, our model demonstrates that active areas exposed to near-twilight conditions throughout the comet's rotational period can produce the observed anti-sunward morphology.     

Elemental abundance analyses with DAO spectrograms: XXXII. HR 6455 (A3 III), δ Aqr (A3 V), η Lep (F2 V), and 1 Boo (A1 V)

We examine the sharp‐lined stars HR 6455 (A3 III, v sin i = 8.7 km s^–1) and η Lep (F2 V, v sin i = 13.5 km s^–1) as well as δ Aqr (A3 V, v sin i = 81 km s^–1) and 1 Boo (A1 V, v sin i = 59 km s^–1) to increase the number consistently analyzed A and F stars using high dispersion and high S/N (≥200) spectrograms obtained with CCD detectors at the long Coudé camera of the 1.22‐m telescope of the Dominion Astrophysical Observatory. Such studies contribute to understanding systematic abundance differences between normal and non‐magnetic main‐sequence band chemically peculiar A and early F stars. LTE fine analyses of HR 6455, δ Aqr, and 1 Boo using Kurucz's ATLAS suite programs show the same general elemental abundance trends with differences in the metal richness. Light and iron‐peak element abundances are generally solar or overabundant while heavy element and rare earth element abundances are overabundant. HR 6455 is an evolved Am star while δ Aqr and 1 Boo show the phenomenon to different extents. Most derived abundances of η Lep are solar (© 2011 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)     

Revised vertical cloud structure of Uranus from UKIRT/UIST observations and changes seen during Uranus’ Northern Spring Equinox from 2006 to 2008: Application of new methane absorption data and comparison with Neptune

Long-slit spectroscopy observations of Uranus by the United Kingdom InfraRed Telescope UIST instrument in 2006, 2007 and 2008 have been used to monitor the change in Uranus’ vertical and latitudinal cloud structure through the planet’s Northern Spring Equinox in December 2007.These spectra were analysed and presented by Irwin et al. (Irwin, P.G.J., Teanby, N.A., Davis, G.R. [2009]. Icarus 203, 287-302), but since publication, a new set of methane absorption data has become available (Karkoschka, E., Tomasko, M. [2010]. Methane absorption coefficients for the jovian planets from laboratory, Huygens, and HST data. Icarus 205, 674-694.), which appears to be more reliable at the cold temperatures and high pressures of Uranus’ deep atmosphere. We have fitted k-coefficients to these new methane absorption data and we find that although the latitudinal variation and inter-annual changes reported by Irwin et al. (2009) stand, the new k-data place the main cloud deck at lower pressures (2-3 bars) than derived previously in the H-band of ∼3-4 bars and ∼3 bars compared with ∼6 bars in the J-band. Indeed, we find that using the new k-data it is possible to reproduce satisfactorily the entire observed centre-of-disc Uranus spectrum from 1 to 1.75 μm with a single cloud at 2-3 bars provided that we make the particles more back-scattering at wavelengths less than 1.2 μm by, for example, increasing the assumed single-scattering albedo from 0.75 (assumed in the J and H-bands) to near 1.0. In addition, we find that using a deep methane mole fraction of 4% in combination with the associated warm ‘F’ temperature profile of Lindal et al. (Lindal, G.F., Lyons, J.R., Sweetnam, D.N., Eshleman, V.R., Hinson, D.P. [1987]. J. Geophys. Res. 92, 14987-15001), the retrieved cloud deck using the new (Karkoschka and Tomasko, 2010) methane absorption data moves to between 1 and 2 bars.The same methane absorption data and retrieval algorithm were applied to observations of Neptune made during the same programme and we find that we can again fit the entire 1-1.75 μm centre-of-disc spectrum with a single cloud model, providing that we make the stratospheric haze particles (of much greater opacity than for Uranus) conservatively scattering (i.e. ω = 1) and we also make the deeper cloud particles, again at around the 2 bar level more reflective for wavelengths less than 1.2 μm. Hence, apart from the increased opacity of stratospheric hazes in Neptune’s atmosphere, the deeper cloud structure and cloud composition of Uranus and Neptune would appear to be very similar.