江苏省灌河流域污染特征及污染控制对策

基于2008年江苏省沿海地区灌河流域各城市污染源统计及调查数据,分析灌河流域主要污染物来源构成和污染特征,对污染物入河量进行计算及修正.结果表明:灌河的CODMn入河总量为36944.2 t/a,氨氮入河总量为4366.5 t/a,总氮和总磷入河总量分别为6507.4 t/a、444.6 t/a,各污染源均主要来源于农业污染.同时,针对灌河流域的污染特征,明确各类污染源的治理重点,提出了污染控制对策,为有效保护灌河水环境质量,支撑灌河口和灌河沿线的开发提供依据.     

浙江省出入太湖河道水量水质及污染物通量变化(2007-2019年)

自2007年太湖无锡水危机事件后,太湖流域内各项水污染防治工作进入快车道,近年来浙江省持续开展水环境治理,针对不同污染源进行分类施策、精准治理,整体水环境质量得到了显著改善.本文根据2007-2019年浙江省环太湖水文巡测资料及主要出入太湖河道水质监测成果,全面分析了出入湖河道的水量、水质及污染物通量的时空变化趋势.结...     

Experimental transplanting of Posidonia australis seagrass in Port Hacking, Australia, to assess the feasibility of restoration

Over the last 50 years, about one-third of the original area of the seagrass Posidonia australis has been lost from Port Hacking (Australia) due to anthropogenic impacts. To assess the feasibility of restoring these seagrass meadows, healthy Posidonia rhizomes were transplanted to four impact sites and one control site. Survival rates of transplanted shoots were monitored in situ bi-monthly for 16 months and, at the end of the experiment, rhizome growth, shoot growth, shoot production and growth architecture were assessed by harvesting tagged rhizomes. A total of 575 shoots were transplanted and after 16 months 650 shoots were present. Four of the five sites exhibited high survival rates in the short term (less than six months) but only two impact sites, Burraneer Bay (BB) and Red Jacks Point (RJP), and the control site (CS) survived to the end of the experiment. Total number of shoots increased by 61% at CS, tripled at BB, but decreased by 22% at RJP. Rhizome growth varied significantly between site, from 22.3 +/- 1.4 cm yr(-1) at BB to 9.1 +/- 1.0 cm yr(-1) at RJP. Shoot growth did not vary significantly between sites and was approximately 2-3 cm yr(-1). At BB and CS there was substantial colonisation of the surrounding substrate, with new rhizomes, orthotropic shoots and transitional shoots produced. Survival of transplants appeared to depend on whether the factors that had caused the original loss of Posidonia were still operating in the study area.     

2010-2011水文年浙江省环太湖河道水质水量及污染物通量

根据2010-2011水文年浙江省环太湖河道水质水量同步监测资料,分析了进出太湖的水量、水质及污染物通量的时空变化.监测期内,浙江省入湖水量为22.890×108m3,出湖水量为31.576×108m3,环湖河道水质总体上保持稳定,主要污染物指标基本处于Ⅱ～Ⅲ类标准.污染物通量的估算结果表明,环湖河道的高锰酸盐指数、氨氮、总磷和总氮通量均以出湖为主,入湖污染物通量的减少主要源于入太湖河流倒流流量的增加.     

The source and distribution of polychlorinated dibenzo-p-dioxin and polychlorinated dibenzofurans in sediments of Port Jackson, Australia

Concentrations of polychlorinated dibenzo-p-dioxins (dioxins)(PCDDs) and polychlorinated dibenzofurans (PCDFs)(furans) in sediments from Port Jackson ranged from 32 to 4352 pg WHO-TEQ DF g(-1)dw with a mean of 712 pg g(-1)dw. Maximum total dioxins plus furans concentrations in this sediment was 6,290,000 pg g(-1)dw, which is the highest recorded in Australia and among the highest reported for sediment globally. Permanent bans were placed on fin fishing and prawn trawling in February, 2006 for the whole estuary, based on dioxin tissue burdens. A distinct congener profile corresponded to chemicals known to have been produced by industry on the shores of Homebush Bay in the upper estuary. These chemicals are being dispersed extensively and exceed pre-anthropogenic concentrations in even distant, less developed parts of the harbour. Remediation of sediments is currently being undertaken, with the intention of containing dispersion of dioxins and reducing body burdens in fin fish and prawn populations.     

环太湖江苏段入湖河道污染物通量与湖区水质的响应关系

基于2008-2018年环太湖江苏段入湖河道污染物通量及湖区水质数据,从时空变化及相关关系两个方面探讨了入湖污染物通量与湖区水质的响应关系,并分析了污染物进入湖体影响水质的主要因子.结果表明:太湖污染减排已见成效,氨氮、总氮、高锰酸盐指数和化学需氧量入湖污染物通量整体呈下降趋势,年均下降率分别为8.0%、2.0%、1.6%和2.2%,湖体氨氮和总氮时间格局响应较好,年均下降率分别为2.1%和2.3%.湖体氨氮、总氮、总磷、高锰酸盐指数和化学需氧量与入湖污染物通量整体由西北部、西部湖区向东南部、东部湖区递减,空间格局上响应基本一致.全湖区年尺度总氮、氨氮浓度与入湖河道污染物通量分别呈显著正相关、极显著正相关关系;影响湖区总氮、氨氮的主要因子为入湖河道的总氮、氨氮浓度,其次为入湖河道浓度与原湖区水质差值,因此亟需加强入湖河道水质浓度的控制.     

Groundwater monitoring at the watershed scale: An evaluation of recharge and nonpoint source pollutant loading in the Clear Creek Watershed,Iowa

Determining the groundwater contribution of nonpoint source pollution at a watershed scale is a challenging issue. In this study, we utilized a top‐down approach to characterize representative groundwater response units (GRUs) based on land use and landscape position (e.g., upland, sideslope, or floodplain) in the 275‐km² Clear Creek Watershed, Iowa. Groundwater monitoring wells were then established along downslope transects in representative GRUs. This unique combination of top‐down/bottom‐up approaches allowed us to estimate groundwater pollutant loads at the watershed scale with minimal monitoring. For the 2015 study period, results indicated that more groundwater recharge occurred in the floodplain (404 mm) compared to the uplands or sideslopes (281 and 165 mm, respectively), irrespective of land use. Recharge in the floodplains consisted of 37% of the annual precipitation, whereas upland wells averaged 26% and sideslopes averaged 15% of the annual precipitation. Less recharge was found to occur beneath perennial grass compared to row crop and urbanized areas. Baseflow discharge accounted for 69% of the total NO₃‐N exported from the Clear Creek Watershed, with row crop areas contributing approximately 95% of the annual load. Orthophosphorus (OP) yields were approximately 0.72 kg/ha beneath urban and suburban areas, three times higher than those in row crop or perennial areas. Urban and suburban areas accounted for 21.4% of groundwater orthophosphorus and chloride loads in the watershed compared to only 8.5% of the land area. Overall, the groundwater load allocation model for baseflow nutrient discharge to Clear Creek can be used to target future nonpoint source load reduction strategies at the watershed scale. The use of GRUs can pinpoint better areas of concern for controlling nutrient loads.     

Long-term investigation of benthic fauna and the influence of treated ballast water disposal in Port Valdez,Alaska

Benthic faunal structure and hydrocarbon concentrations in sediments were examined annually for 10 years (1989-1998) in Port Valdez, Alaska, where a near-bottom permitted discharge of treated tanker ballast waters containing residual petroleum has occurred since 1977. Measured concentrations of hydrocarbons in sediments near the discharge showed detectable increases in concentration, but on only one occasion were these increases either to levels exceeding ecotoxicological thresholds (Effects-Range Low, ER-L) or associated with alterations in the benthic community. Changes in faunal structure indicating disturbance were observed at one station near the discharge from 1995 to 1997 and were apparent as increased numbers of opportunistic taxa and anomalous trends in abundance and diversity. Minimum-effect (ME) hypotheses provided evidence of negligible to small effects on benthic infauna from disposal of treated ballast water. ME hypotheses have the potential to assist both researchers and managers by providing a tool to relate scientific results to ecological importance and decision criteria.     

Aquatic Ecological and Human Health Risk Assessment of Chemicals in Wet Weather Discharges in the Sydney Region, New South Wales, Australia

Sydney Water has completed a risk assessment to assess the risks to human health and aquatic organisms in creeks, rivers, estuaries and ocean waters affected by wet weather sewage overflows, stormwater and sewage treatment plant discharges. The risk assessment methodology consists of a comparison of measured and predicted concentrations of chemicals with toxicity reference values. Estimates of receiving water chemical concentrations were derived using data from a 10-year period so that the variable rainfall pattern was represented. Computer models were used to simulate and predict wet weather discharges during this ten year period. Risks were validated by bioassays and bioassessments. Risks to aquatic life from wet weather discharges were attributed to 14 chemicals at one or more of the sites and stormwater was the predominate source of the chemicals. There were no risks to people engaged in water based activities. Noncarcinogenic risks from fish ingestion are predicted at three sites. Predicted cancer risks for most individual chemicals were relatively small. Carcinogenic risks were typically associated with organochlorine compounds, polycyclic aromatic hydrocarbons, dichlorobenzene, and arsenic. The predicted cancer risks also appear to be largely the result of stormwater rather than sewage overflow inputs and largely due to historical contamination by organochlorine pesticides. It is expected the concentrations of these chemicals will decrease over time.     

Influences of climate,terrain and land cover on stream salinity in southeastern Australia,and implications for management through reforestation

Reforestation of cleared land has the potential to reduce groundwater recharge, salt mobilization and streamflow. Stream salinity change is the net result of changes in stream salt load and streamflow. The net effect of these changes varies spatially as a function of climate, terrain and land cover. Successful natural resource management requires methods to map the spatial variability of reforestation impacts. We investigated salinity data from 2000 bores and streamflow and salinity measurements from 27 catchments in the Goulburn–Broken region in southeast Australia to assess the main factors determining stream salinity and opportunities for management through reforestation. For groundwater systems of similar geology, relationships were found between average annual rainfall and groundwater salinity and between groundwater salinity and low‐flow salinity. Despite its simplicity, we found that the steady‐state component of a simple conceptual coupled water–salt mass balance model (BC2C) adequately explained the spatial variation in streamflow and salinity. The model results suggest the efficiency of afforestation to reduce stream salinity could be increased by more than an order of magnitude through spatial planning. However, appreciable reductions in stream salinity in large rivers through land cover change alone would still require reforestation on an unprecedented scale. Copyright © 2008 John Wiley & Sons, Ltd.     

Groundwater system response at sites with different agricultural land uses: case of the Guarani Aquifer outcrop area,Brotas/SP-Brazil

A system identification approach can be incorporated in groundwater time series analysis, revealing information concerning the local hydrogeological situation. The aim of this work was to analyse water table fluctuations in an outcrop area of the Guarani Aquifer System (GAS) in Brotas/SP, Brazil, using data from a groundwater monitoring network. The water table dynamic was modelled using continuous time series models that reference the hydrogeological system upon which they operate. The model’s climatological inputs of precipitation and evapotranspiration generate impulse response (IR) functions with parameters that can be related to the physical conditions concerning the hydrological processes involved. The interpretation of the model parameters from two sets of monitoring wells selected at different land-use sites is presented, exemplifying the effect of different water table depths and the distance to the nearest drainage location. Systematic trends of water table depths were also identified from model parameters at specific periods and related to plant development, crop harvest and land-use changes.

EDITOR D. Koutsoyiannis

ASSOCIATE EDITOR L. Ruiz     

Dynamic Changes of Sediment Discharge and the Influencing Factors in the Yellow River,China, for the Recent 90 Years

The dynamic changes in the sediment discharge over 90 years from 1919 to 2008 in the Yellow River in China were assessed on the basis of annual rainfall series and annual sediment series in Shan County hydrological station. The key factors affecting sediment discharge, such as rainfall, and human activities were studied. Anomaly accumulation method and double mass curve were employed to test the stage changes of sediment discharge, and to determine the main factors of sediment decline. Results showed that the annual average sediment discharge under natural conditions was about 16 × 10⁸ t, but the measured annual average sediment during 1919–2008 was 12.71 × 10⁸ t. The highest annual average during the study period was 39.10 × 10⁸ t in 1933 while the lowest was 1.77 × 10⁸ t in 2008. Sediment discharge in the Yellow River experienced two low sediment stages (1924–1931 and 1979–2008) and a high sediment stage (1932–1971), respectively. Since 1979, there was a significant decreasing trend in the sediment discharge, and the main influencing factor was fierce human activities. Annual average sediment discharge in the post‐development period (1979–2008) was 69.7% lower than that in the pre‐development period (1919–1978), with average reduction of 81 and 19% caused by human activities and rainfall, respectively. These results provide important evidence for making protecting policy for water resources quality and environmental safety of the Yellow River.     

Seasonal and spatial variability of water quality parameters in the Port of Genoa, Italy, from 2000 to 2007

This paper presents the results of the statistical analysis of a set of physico-chemical and biological water quality parameters, monthly collected from 2000 to 2007 in the Genoa Harbour area (Ligurian Sea). We applied multivariate methods, such as principal component analysis (PCA) and dynamic factor analysis (DFA) for investigating the spatial and temporal variability and for providing important background information on pollution problems in the region. PCA evidenced the role of the sewage and river discharges and of the exchanges with the open sea in determining the harbour water quality. DFA was used to estimate underlying common trends in the time series. The DFA results partly show a general improvement of water quality over the 8-years period. However, in other areas, we found inter-annual variations but no significant multi-annual trend. Furthermore, we included meteorological variables in our statistical analyses because of their potential influence on the water quality parameters. These natural forcings explain part of the variability in water quality parameters that are superimposed on the dominating anthropogenic pollution factors.     

Nutrient,heavy metal and organic pollutant composition of suspended and bed sediments in the Rhone River

The environmental quality of the Rhone River (Switzerland-France) has been assessed with a geochemical survey of the pollutants bound to suspended sediments. Ten samples were collected between Lake Geneva and the Mediterranean Sea in Nobember 1989 by continuous flow centrifugation and analysed for grain size distribution, carbonate, organic C, N, forms of particulate P, trace metals, and organic compounds (chlorobenzenes, organochlorine pesticides, PCBs, and PAHs). Four bed sediment samples were also studied for comparative purposes. The suspended solids provide lower variance by parameter than the bed sediments and are clearly most suitable for synoptic monitoring.The Upper Rhone River carries a glacial derived sediment with a low nutrient content, the stretch from Geneva to Lyon provides a sediment dominated by carbonate, and in the Lower Rhone the organic matter and phosphorus are relatively increased, mainly due to wastewater effluents and to an industrial P source. High concentrations of metals and organic micropollutants downstream of Lyon indicate a multiple contamination in the Lower Rhone, whereas more specific inputs are located downstream of Geneva and Arles.The comparison with data from other polluted major systems, the Rhine, the Niagara and the Detroit rivers, shows on overall similarity confirming that the Rhone quality is degraded downstream of Lyon. The levels of particular concern are for Hg, DDT metabolites which reveal a recent release in the basin, PCBs with a likely high chlorine content, and PAHs.The statistical evaluation of the compositional variables indicates a limited number of well defined associations, suggesting that the contamination of the suspended sediments results from the combination of numerous and intermittent point and diffuse sources in the Rhone River basin.     

A spatially distributed model for assessment of the effects of changing land use and climate on urban stream quality

While the effects of land use change in urban areas have been widely examined, the combined effects of climate and land use change on the quality of urban and urbanizing streams have received much less attention. We describe a modelling framework that is applicable to the evaluation of potential changes in urban water quality and associated hydrologic changes in response to ongoing climate and landscape alteration. The grid‐based spatially distributed model, Distributed Hydrology Soil Vegetation Model‐Water Quality (DHSVM‐WQ), is an outgrowth of DHSVM that incorporates modules for assessing hydrology and water quality in urbanized watersheds at a high‐spatial and high‐temporal resolution. DHSVM‐WQ simulates surface run‐off quality and in‐stream processes that control the transport of non‐point source pollutants into urban streams. We configure DHSVM‐WQ for three partially urbanized catchments in the Puget Sound region to evaluate the water quality responses to current conditions and projected changes in climate and/or land use over the next century. Here, we focus on total suspended solids (TSS) and total phosphorus (TP) from non‐point sources (run‐off), as well as stream temperature. The projection of future land use is characterized by a combination of densification in existing urban or partially urban areas and expansion of the urban footprint. The climate change scenarios consist of individual and concurrent changes in temperature and precipitation. Future precipitation is projected to increase in winter and decrease in summer, while future temperature is projected to increase throughout the year. Our results show that urbanization has a much greater effect than climate change on both the magnitude and seasonal variability of streamflow, TSS and TP loads largely because of substantially increased streamflow and particularly winter flow peaks. Water temperature is more sensitive to climate warming scenarios than to urbanization and precipitation changes. Future urbanization and climate change together are predicted to significantly increase annual mean streamflow (up to 55%), water temperature (up to 1.9 °C), TSS load (up to 182%) and TP load (up to 74%). Copyright © 2016 John Wiley & Sons, Ltd.     

Continental drift,plateau uplift,and the evolutions of monsoon and arid regions in Asia,Africa, and Australia during the Cenozoic

Monsoon and arid regions in the Asia-Africa-Australia(A-A-A) realm occupy more than 60% of the total area of these continents. Geological evidence showed that significant changes occurred to the A-A-A environments of the monsoon and arid regions, the land-ocean configuration in the Eastern Hemisphere, and the topography of the Tibetan Plateau(TP) in the Cenozoic. Motivated by this background, numerical experiments for 5 typical geological periods during the Cenozoic were conducted using a coupled ocean-atmosphere general circulation model to systemically explore the formations and evolutionary histories of the Cenozoic A-A-A monsoon and arid regions under the influences of continental drift and plateau uplift. Results of the numerical experiments indicate that the timings and causes of the formations of monsoon and arid regions in the A-A-A realm were very different. The northern and southern African monsoons existed during the mid-Paleocene, while the South Asian monsoon appeared in the Eocene after the Indian Subcontinent moved into the tropical Northern Hemisphere. In contrast, the East Asian monsoon and northern Australian monsoon were established much later in the Miocene. The establishment of the tropical monsoons in northern and southern Africa, South Asia, and Australia were determined by both the continental drift and seasonal migration of the Inter-Tropical Convergence Zone(ITCZ), while the position and height of the TP were the key factor for the establishment of the East Asian monsoon. The presence of the subtropical arid regions in northern and southern Africa,Asia, and Australia depended on the positions of the continents and the control of the planetary scale subtropical high pressure zones, while the arid regions in the Arabian Peninsula and West Asia were closely related to the retreat of the Paratethys Sea. The formation of the mid-latitude arid region in the Asian interior, on the other hand, was the consequence of the uplift of the TP.These results from this study provide insight to the important roles played by the earth's tectonic boundary conditions in the formations and evolutions of regional climates during geological times.     

2012-2018年巢湖水质变化趋势分析和蓝藻防控建议

巢湖自1990s中期至2012年间水质明显改善,但是近年来水质改善效果变缓,2018年蓝藻水华面积显著增加,为有效评估巢湖水体环境的变化,通过对2012-2018年巢湖17个点位的逐月调查数据分析阐述了近年来巢湖水质和藻情的变化特征,并在流域空间尺度上分析了巢湖流域水污染治理的进展和不足,为后续治理方向的调整和确定提供支撑.2012-2018年湖区调查数据显示:巢湖湖体总磷和总氮浓度显著升高,铵态氮浓度显著下降,水华蓝藻总量显著升高.在空间上,各污染指标水平呈现由西向东呈逐渐降低的趋势,但是各指标在不同湖区随时间的变化趋势差异明显,西部湖区的总磷、总氮和水华蓝藻指标近年来略有下降或持平,中部和东部湖区则显著升高,所以巢湖湖体总氮和总磷浓度的升高主要源于中、东部湖区的升高,这也是这两个湖区水华蓝藻变动的主要驱动因素.主要入湖河口数据显示:西部4条主要入湖污染河流(南淝河、十五里河、塘西河和派河)水质明显改善,但仍处于较高污染水平,中东部入湖河流(兆河、双桥河和柘皋河)总磷浓度明显升高,是中东部湖区水体营养盐升高的主要原因.中东部河流入湖污染的增加加剧了该区域湖体的富营养化水平,尤其是总磷...     

Preliminary evaluation of the occurrence of herbicides and PAHs in the Wet Tropics region of the Great Barrier Reef, Australia, using passive samplers

The proximity of the Great Barrier Reef (GBR) Marine Park to areas of intensive agriculture and increasing urbanisation places the park under potential threat of contamination by land-based pollutants. Passive samplers were deployed at inshore reef and river mouth sites in the Wet Tropics region of the GBR during a dry and a wet season to measure levels of land-based organic pollutants in this environment. Two types of passive sampling devices were deployed: (i) a polar sampler, which can be used to monitor polar herbicides and (ii) semipermeable membrane devices (SPMDs) which sequester more hydrophobic compounds (e.g. PAHs, chlorpyrifos). Herbicides (diuron, simazine, atrazine, hexazinone and/or flumeturon) were detected at low concentrations (ng L⁻¹) at all sites sampled and in both seasons. Chlorpyrifos was not detected while PAHs were present in SPMDs at levels below limits of detection. The results show that the GBR environment does contain low levels of organic pollutants and that passive sampling provides a sensitive monitoring tool for measuring waterborne organic pollutants.     

Water quality management in Singapore: the role of institutions,laws and regulations

Abstract

The paper analyses the legal and regulatory instruments for water quality management that have been set in place in Singapore for control of water pollution, and their evolution since the time of independence in 1965. The role of institutions in the strict implementation of the laws and regulations is also discussed, with special emphasis on the efficient inter-institutional coordination machinery that has made it possible. The analyses show that overall long-term planning and policy-making and a strong political will have been instrumental to give all aspects of water management high priority in the national agenda, thus directly supporting urban, industrial and commercial growth.

Editor Z.W. Kundzewicz     

Application of 1D paleo‐fluvial process modelling at a basin scale to augment sparse borehole data: example of a Permian formation in the Galilee Basin,Australia

The heterogeneous hydraulic conductivity (K) in water‐bearing formations controls subsurface flow and solute transport processes. Geostatistical techniques are often employed to characterize the K distribution in space based on the correlation between K measurements. However, at the basin scale, there are often insufficient measurements for inferring the spatial correlation. This is a widespread problem that we address in this study using the example of the Betts Creek Beds (BCB) in the Galilee Basin, Australia. To address the lack of data, we use a 1D stochastic fluvial process‐based model (SFPM) to quantify the total sediment thickness, Z( x ), and the sandstone proportion over the total thickness, P_s( x ), in the BCB. The semivariograms of Z( x ) and P_s( x ) are then extracted and used in sequential Gaussian simulation to construct the 2D spatial distribution of Z( x ) and P_s( x ). P_s( x ) can be converted to a K distribution based on classical averaging methods. The results demonstrate that the combination of SFPM and geostatistical simulation allows for the evaluation of upscaled K distribution with a limited number of K measurements. Copyright © 2015 John Wiley & Sons, Ltd.