粒度分布的端元建模分析及检验:以“吉兰泰—河套”盆地西部DK-12钻孔晚第四纪沉积物为例*

端元建模分析能够从复杂的多峰分布特征的沉积物中提取出具有不同沉积动力过程的端元,但是,由于沉积物的粒度分布还受到沉积环境等多种因素的影响,该方法的有效性及获得的端元组分的地质意义有待其他环境代用指标的进一步检验。以位于“吉兰泰—河套”盆地西部磴口次级隆起区的DK-12钻孔晚第四纪沉积物为例,采用BEMMA算法对该钻孔沉积物的粒度资料进行了端元建模分析,并以黏土矿物组合和前人的孢粉组合数据作为检验指标,结合该地区的区域地质背景,对获得的4个端元进行了综合检验分析,认为获得的沉积物粒度端元具有明确的地质意义,其中EM 1为远源粉尘、EM 2为近源的风成沙、EM 3和EM 4为河流冲积沙。     

Optically stimulated luminescence dating as a tool for calculating sedimentation rates in Chinese loess: comparisons with grain-size records

Understanding loess sedimentation rates is crucial for constraining past atmospheric dust dynamics, regional climatic change and local depositional environments. However, the derivation of loess sedimentation rates is complicated by the lack of available methods for independent calculation; this limits interpretation of the environmental changes revealed by the loess record. In particular, while the Quaternary/Neogene Chinese loess and Red Clay sequences have the potential to provide detailed records of past sedimentation and climate change, there is great uncertainty concerning: (i) the influences on sediment grain‐size and accumulation; and (ii) their relationship through time and across the depositional region. This uncertainty has led to the widespread use of assumptions concerning the relationship between sedimentation rate and grain‐size in order to derive age models and climate reconstructions. To address this uncertainty, detailed independent age models, based on optically stimulated luminescence dating, undertaken at 10 to 40 cm intervals at five sections across the Loess Plateau in China, have been used to calculate sedimentation rates and make comparisons with grain‐size changes over the late Pleistocene and Holocene. The results demonstrate that sedimentation rates are site specific, extremely variable over millennial timescales and that this variation is often not reflected in grain‐size changes. In the central part of the Loess Plateau, the relationship between grain‐size and sedimentation rate appears most complex, suggesting an interplay between local conditions at source and sink and a changing emplacement mechanism. This observation further undermines the common use of loess sedimentation age models that rely on a derived relationship between grain‐size and sedimentation rate from a type section. The results also highlight the difficulty in assigning specific environmental causes to sedimentation rate changes and, to a lesser extent, grain‐size shifts.     

Terrigenous sedimentation processes along the continental margin off NW Africa: implications from grain-size analysis of seabed sediments

The terrigenous fraction of seabed sediments recovered along the north‐west African continental margin illustrates spatial variability in grain size attributed to different transport mechanisms. Three subpopulations are determined from the grain‐size analyses (n = 78) of the carbonate‐free silt fraction applying an end‐member modelling algorithm (G. J. Weltje, 1997). The two coarsest end‐members are interpreted as representing aeolian dust, and the fine‐grained end‐member is related to fluvial supply. The end‐member model thus allows aeolian fallout to be distinguished from fluvial‐sourced mud in this area. The relative contributions of the end‐members show distinct regional variations that can be related to different transport processes and pathways. Understanding present‐day sediment dispersal and mixing is important for a better understanding of older sedimentary records and palaeoclimate reconstructions in the region.     

Some methods for statistical analysis of multimodal distributions and their application to grain-size data

Some of the methods used in the resolution of mixed normal distributions are discussed under three headings: analytical, graphical, and numerical methods. Attention is given to their applicability in the analysis of grain-size data as derived from sieving. Comparisons are made by applying several methods to published data. It is concluded that the numerical methods offer most scope, especially the method of nonlinear least squares. Some analyses of beach sediments, using this method, are presented. The adoption of a convention for the number of individuals in the sample increases ease of interpretation.     

A comparison of grain‐size analysis methods for sand‐dominated fluvial sediments

Grain‐size distribution is a fundamental tool for interpreting sedimentary units within depositional systems. The techniques assessed in this study are commonly used to determine grain‐size distributions for sand‐dominated sediments. However, the degree of consistency and differences in interpretation when using a combination of grain‐size methods have not yet been assessed systematically for sand‐dominated fluvial sediments. Results obtained from laser diffraction, X‐ray attenuation and scanning electron microscopy grain‐size analysis techniques were compared with those obtained from the traditional sieve/hydrometer method. Scanning electron microscopy was shown to provide an inaccurate quantitative analysis of grain‐size distributions because of difficulties in obtaining representative samples for examination. The X‐ray attenuation method is unsuitable for sand‐dominated sediments because of its upper size range of only 300 μm. The consistently strong correlation between the laser diffraction results and the sieve/hydrometer results shows that these methods are comparable for sand‐dominated fluvial sediments. Provided that sample preparation is consistent, the latter two methods can be used together within a study of such sediments while maintaining a high degree of accuracy. These results indicate that data for sand‐dominated fluvial sediments gained from the long‐established sieve/hydrometer method can be compared with confidence to those obtained by modern studies using laser diffraction techniques.     

Sedimentation and time‐of‐transition techniques for measuring grain‐size distributions in lagoonal flats: comparability of results

A comparative study was performed of three instruments used to measure the grain‐size distribution of thirty sediment samples from shallow lagoonal flats: the hydrometer, the Sedigraph 5100 and the CIS‐1. The hydrometer and Sedigraph are based on sedimentation whereas the CIS‐1 uses the time of transition. The percentage of the samples accounted for by the <8 μm fraction was not affected by the technique used, but this was not the case with the clay fraction (<2 μm). Due to its relative independence from the analytical method applied, the <8 μm fraction can be used in ternary diagram classifications. This fraction also has an environmental significance in coastal lagoons in terms of hydrodynamics, organic enrichment and macrozoobenthos assemblages. The linear relationships obtained in this study may provide useful operational indications for similar studies.     

Compositional data analysis of Holocene sediments from the West Bengal Sundarbans,India: Geochemical proxies for grain-size variability in a delta environment

This paper is part of a special issue of Applied Geochemistry focusing on reliable applications of compositional multivariate statistical methods. This study outlines the application of compositional data analysis (CoDa) to calibration of geochemical data and multivariate statistical modelling of geochemistry and grain-size data from a set of Holocene sedimentary cores from the Ganges-Brahmaputra (G-B) delta. Over the last two decades, understanding near-continuous records of sedimentary sequences has required the use of core-scanning X-ray fluorescence (XRF) spectrometry, for both terrestrial and marine sedimentary sequences. Initial XRF data are generally unusable in ‘raw-format’, requiring data processing in order to remove instrument bias, as well as informed sequence interpretation. The applicability of these conventional calibration equations to core-scanning XRF data are further limited by the constraints posed by unknown measurement geometry and specimen homogeneity, as well as matrix effects. Log-ratio based calibration schemes have been developed and applied to clastic sedimentary sequences focusing mainly on energy dispersive-XRF (ED-XRF) core-scanning. This study has applied high resolution core-scanning XRF to Holocene sedimentary sequences from the tidal-dominated Indian Sundarbans, (Ganges-Brahmaputra delta plain). The Log-Ratio Calibration Equation (LRCE) was applied to a sub-set of core-scan and conventional ED-XRF data to quantify elemental composition. This provides a robust calibration scheme using reduced major axis regression of log-ratio transformed geochemical data. Through partial least squares (PLS) modelling of geochemical and grain-size data, it is possible to derive robust proxy information for the Sundarbans depositional environment. The application of these techniques to Holocene sedimentary data offers an improved methodological framework for unravelling Holocene sedimentation patterns.     

Bacterial contribution to sedimentary organic matter; a comparative study of lipid moieties in bacteria and Recent sediments

A systematic study of the lipid composition of thirteen bacterial species and three Recent sediments (methanogenic sediment, cyanobacterial mat and evaporative gypsum crust) was undertaken in an attempt to recognize bacterial organic matter in sediments. A sequential method, which distinguishes between three different modes of occurrence of lipid moieties (free, OH⁻- and H⁺-labile), was applied. The acid-labile fractions are discussed.The three main groups of bacteria, archaebacteria, gram-positive eubacteria and gram-negative eubacteria, are easily distinguished. Methanogenic and extremely halophilic archaebacteria are characterized by the presence of diphytanyl glyceryl ether and the absence of fatty acids. The gram-positive eubacteria contain primarily iso- and anteiso-branched fatty acids whereas the gram-negative bacteria and sediments are dominated by β- and α-hydroxy fatty acids. A wide variety of H⁺-labile hydroxy fatty acids was observed which included several, as yet unknown, structures.β-Hydroxy fatty acids in this H⁺-labile mode of occurrence are exclusively present in bacteria. Their distribution patterns in sediments are considered “fingerprints” of past and present bacterial populations. The specific differences in β -hydroxy fatty acid compositions observed in the different bacteria and the three sediments investigated, suggest that amide-linked β-hydroxy fatty acid patterns are useful as markers of bacterial populations and therefore of environmental conditions.     

Estimating the settling velocity of bioclastic sediment using common grain‐size analysis techniques

Most techniques for estimating settling velocities of natural particles have been developed for siliciclastic sediments. Therefore, to understand how these techniques apply to bioclastic environments, measured settling velocities of bioclastic sedimentary deposits sampled from a nearshore fringing reef in Western Australia were compared with settling velocities calculated using results from several common grain‐size analysis techniques (sieve, laser diffraction and image analysis) and established models. The effects of sediment density and shape were also examined using a range of density values and three different models of settling velocity. Sediment density was found to have a significant effect on calculated settling velocity, causing a range in normalized root‐mean‐square error of up to 28%, depending upon settling velocity model and grain‐size method. Accounting for particle shape reduced errors in predicted settling velocity by 3% to 6% and removed any velocity‐dependent bias, which is particularly important for the fastest settling fractions. When shape was accounted for and measured density was used, normalized root‐mean‐square errors were 4%, 10% and 18% for laser diffraction, sieve and image analysis, respectively. The results of this study show that established models of settling velocity that account for particle shape can be used to estimate settling velocity of irregularly shaped, sand‐sized bioclastic sediments from sieve, laser diffraction, or image analysis‐derived measures of grain size with a limited amount of error. Collectively, these findings will allow for grain‐size data measured with different methods to be accurately converted to settling velocity for comparison. This will facilitate greater understanding of the hydraulic properties of bioclastic sediment which can help to increase our general knowledge of sediment dynamics in these environments.     

Multi-scale study of permeability evolution of a bentonite clay owing to pollutant transport: Part II. Application to an MG-bentonite

This paper is concerned with the application of a multi-scale model of permeability evolution to the simulation of permeation tests of lead nitrate solutions in a compacted natural bentonite. In a previous work, the weathered hydraulic conductivity has been measured for different pollutant concentrations. Textural and structural evolutions induced by heavy metal sorption have also been investigated, therefore giving us information about the various pore spaces that may be encountered during the process of pollutant leaching. Such knowledge has been exploited during the construction of the numerical microstructures. First of all, pure water permeability tests have been simulated, this has allowed us to ascertain the representation of compacted clay before pollutant permeation. For both Prrenjas and Wyoming clays, permeation tests after pollutant permeation have then been simulated, using connected and non-connected macro-voids configurations. Different conclusions have been drawn based on simulation results for the two different clays investigated, which are supported by experimental evidence.     

The influence of grain-size analysis methods and sediment mixing on curve shapes and textural parameters: Implications for sediment trend analysis

To this day, deterministic physical models capable of explaining the evolution of grain-size distributions in the course of transport are still lacking. For this reason, various attributes of particle frequency distributions, in particular curve shapes and textural parameters, have for many decades been investigated for potential information about transport behaviour and size-sorting processes of sediments in numerous environments. Such approaches are essentially conceptual and hence rely heavily on the validity of the assumptions on which they are based. A factor which has to date been largely ignored in this context, is the fact that different methods of grain-size analysis (e. g. sieving, laser absorption and diffraction, settling velocity measurements), when applied to the same sample material, produce variable curve shapes, and hence incongruous textural data. This is illustrated by selected examples showing the differences between sieving and settling results, conversion of settling velocities into equivalent settling diameters (psi-phi-transformations), and the influences of particle shape, particle density, and water temperature. It is demonstrated that particle-size distributions are not only method-dependent but also dependent on the adopted post-processing procedure. As a result, only frequency curves generated by the same method and subsequently processed by identical computational procedures can be meaningfully compared. Furthermore, the computation of textural parameters from bi- or multimodal size distributions produces spurious results which are unrelated to the processes leading to the mixing of different size populations frequently observed in nature. In such cases, only the decomposition of such distributions into individual populations and the spatial comparison of such populations makes any sense. Because a physical explanation for the generation of size distributions is lacking, a particular curve shape of a grain-size population has no meaning on its own. Only a systematic comparison of progressively changing curve shapes (and associated textural parameters) of sediments collected on a closely spaced grid can yield data suitable for sediment trend analysis.     

Particle size distribution analysis of sand-sized particles by laser diffraction: an experimental investigation of instrument sensitivity and the effects of particle shape

Laser diffraction is now widely used for particle size distribution analysis of sediments and soils. The technique can be very precise, and offers advantages of speed and cost over many other methods when used to analyse mixtures of sand, silt and clay. This study presents the results of an experimental investigation that examined the sensitivity of the Beckman-Coulter LS230 instrument to mixtures of different grain populations and differences in particle shape. The instrument was found to have high sensitivity to coarse particles in a finer matrix (detection threshold 1–2%), but much lower sensitivity to finer particles in a coarser mixture (detection threshold 12–17%). Experiments using near-spherical ballotini showed that laser analysis provides very similar values to dry sieving for the mean, median and mode, but for a range of natural sand samples values for the mean, median and mode were offset by 8–21%, with an average of ca 15%, compared with sieving. Analysis using a Beckman-Coulter RapidVUE instrument, which provides both size and shape information, provided support for the hypothesis that the differences between laser analysis and sieving are partly attributable to the effects of particle shape. However, an additional factor is the way in which the laser software interprets the optical diffraction data. The software predicts a high degree of log-normality in the size distribution, such that highly skewed, truncated or bimodal samples are poorly represented. Experiments using sieved fractions of ballotini indicated that, even with near-perfectly spherical particles, the particle size distribution predicted by the laser software includes a relatively large percentage of particles outside the sieve class limits.     

相混合计算法确定蒙脱石含量的对比研究

基于X射线粉晶衍射分析、化学成分分析数据,依据物质平衡原理,应用相混合计算法对陕西洋县、河南确山、内蒙古赤峰三地的膨润土进行了定量物相分析。根据电子探针微区分析所得蒙脱石晶粒化学成分数据,采用以阴离子为基准的氢当量法,计算了膨润土中蒙脱石的晶体化学式。应用CELLSR软件,计算得到膨润土中各主要矿物的晶胞参数。通过与传统的确定膨润土中蒙脱石含量的吸蓝量法和X射线衍射多相Rietveld分析法进行定量对比,结果表明,相混合计算法是确定多种矿物共生的膨润土中蒙脱石含量最有效的物相分析方法。尽管受不同分析方法的误差积累影响,但是由该法确定蒙脱石的含量仍能保证±20％的计算精度。     

Variability in terrigenous sedimentation processes off northwest Africa and its relation to climate changes: Inferences from grain-size distributions of a Holocene marine sediment record

Variations in deposition of terrigenous fine sediments and their grain-size distributions from a high-resolution marine sediment record offshore northwest Africa (30°51.0′N; 10°16.1′W) document climate changes on the African continent during the Holocene. End-member grain-size distributions of the terrigenous silt fraction, which are related to fluvial and aeolian dust transport, indicate millennial-scale variability in the dominant transport processes at the investigation site off northwest Africa as well as recurring periods of dry conditions in northwest Africa during the Holocene. The terrigenous record from the subtropical North Atlantic reflects generally humid conditions before the Younger Dryas, during the early to mid-Holocene, as well as after 1.3 kyr BP. By contrast, continental runoff was reduced and arid conditions were prevalent at the beginning of the Younger Dryas and during the mid- and late Holocene. A comparison with high- and low-latitude Holocene climate records reveals a strong link between northwest African climate and Northern Hemisphere atmospheric circulation throughout the Holocene. Due to its proximal position, close to an ephemeral river system draining the Atlas Mountains as well as the adjacent Saharan desert, this detailed marine sediment record, which has a temporal resolution between 15 and 120 years, is ideally suited to enhance our understanding of ocean-continent-atmosphere interactions in African climates and the hydrological cycle of northern Africa after the last deglaciation.     

小型水坝拆除后河貌演变模拟分析——以西河水坝为例

小型水坝随着服役时间的增长,其面临的安全、经济和生态方面问题日益突出,针对一些修复价值较低的病险水坝,实施降等或报废拆除已成为一种综合最佳的管理措施。拆坝后,原库区大量淤沙无控释放将改变原有河道形态,对水生生物栖息地造成影响。为预测拆坝后河道在不同时间尺度上的变化特征,以长江流域乌江水系内的西河水坝为研究对象,建立二维水沙数学模型,分别研究了拆坝后水沙输运造成的短期和长期河床形态变化。结果表明:拆坝后短期内,坝址上游主河道发生了强烈的冲刷下切,且水库淤沙前缘部分出现了显著的淤积抬高,相比而言,坝址下游河床变化并不明显,只有坝下河段及河口附近出现较显著的泥沙淤积;在拆坝后长期的河床演变过程中,坝址上下游河道均发生了不同程度的冲刷下切,拆坝2年后下游河床逐渐趋于稳定,而上游主河道由冲刷下切转化为冲淤交替的演变趋势,河床形态不断调整变化。本研究可为病险坝和小水电报废拆坝后的河道治理、水生生物栖息地修复提供参考依据。     

Environmental pollution impact on water and sediments of Kumaun lakes, Lesser Himalaya, India: a comparative study

A study of the water and sediment chemistry of the Nainital, Bhimtal, Naukuchiyatal and Sattal Lakes of Kumaun, has shown that the water of these lakes are alkaline and that electrical conductivity, total dissolved solid and bicarbonate HCO ₃ ⁻ are much higher in Nainital than in the other three lakes. The weathering of limestone lithology and anthropogenic pollution, the latter due to the very high density of population in the Nainital valley, are the primary sources of enhanced parameters. The low pH of Nainital Lake water is due to low photosynthesis and enhanced respiration, increasing CO₂ in the water and the consequent enhancement of Ca²⁺ and HCO ₃ ⁻ . The dissolved oxygen in Nainital Lake is less compared to other lakes, indicating anoxic conditions developing at the mud–water interface at depth. The PO ₄ ³⁻ content in Nainital is higher (124 μg/l), showing an increasing trend over time leading to eutrophic conditions. The trace metals (Cu, Co, Zn, Ni, Mn, and Sr) are present in greater amounts in the water of Nainital Lake than in the other three lakes, though Fe and Cr are high in Bhimtal and Fe in Naukuchiyatal. The higher abundance is derived from the leaching of Fe–Mg from metavolcanic and metabasic rocks. Most of the heavy metals (Cr, Ni, Cu, Mn, Fe, Sr, and Zn) significantly enrich the suspended sediments of the lakes compared to the bed sediments which due to their adsorption on finer particles and owing to multiple hydroxide coating and organic content, except for Fe, which is enriched in the bed sediments. The high rate of sedimentation, 11.5 mm/year in Nainital, compared to Bhimtal with 4.70 mm/year, Naukuchiyatal with 3.72 mm/year, and Sattal with 2.99 mm/year, has resulted in shorter residence time, poor sorting of grains, and lesser adsorption of heavy metals, leading consequently, their depletion in the bed sediments of Nainital Lake.     

Linking invertebrate burrow distributions (neoichnology) to physicochemical stresses on a sandy tidal flat: implications for the rock record

Invertebrate burrow distributions (neoichnology) across a modern tidal flat are presented as an analogue for interpreting the ichnology of palaeo‐tidal‐flat successions. Burrow distributions are linked to physical and chemical (physicochemical) stresses to establish the main controls on the distribution of biosedimentary structures. Across the tidal flat, there is clear heterogeneity in both the diversity of traces and the intensity of burrowing. This heterogeneity reflects a myriad of physicochemical stresses, with the sedimentation rate dominating burrow distributions. Across all substrates, the total area occupied by organisms rarely exceeds 3% of the tidal‐flat surface, and is commonly <1%; this equates to a bioturbation index value of one. To reach bioturbation index values of two to six, sediments must be available to biogenic reworking and/or recolonization. With an increasing sedimentation rate, substrates are rapidly buried and re‐exposed, which limits the time when a substrate is available to colonization. For palaeo‐ichnological studies, this research presents several key results. (i) Burrow cross‐cutting relationships in tidal‐flat successions commonly reflect natural heterogeneities in the areal distribution of infaunal communities, rather than infaunal tiering. (ii) Ichnofabric analysis of palaeo‐tidal flats with a high sedimentation rate would yield fabrics that reflect heterogeneities in the areal distribution of infaunal communities rather than variability in the physicochemical stresses of the environment. (iii) The composite trace‐fossil assemblage of tidal flats cannot be attributed to a single ichnofacies, but instead comprises elements typical of multiple ichnofacies. (iv) The main controls on trace assemblages across tidal flats in fully marine settings are sedimentological and include the sedimentation rate and, to a lesser extent, grain size.     

Numerical analysis of an embankment built on soft soil reinforced with deep mixing columns: Parametric study

The behaviour of an embankment built on normally consolidated soft soil reinforced with deep mixing columns is studied using a coupled soil–water formulation. The numerical predictions are analysed in terms of settlements, increments in vertical effective stresses and excess pore pressures. Firstly, the effectiveness of the use of deep mixing columns is studied. Afterwards, a parametric analysis is performed to study the influence on the soil-columns system of the replacement ratio (columns’ spacing), the deformability of the embankment and columns, and the coefficient of vertical permeability of the columns.     

Subaerial terminoglacial fans II: a semi-quantitative sedimentological analysis of the middle and distal environments

Twenty-five fans in NE Poland, formed under subaerial terminoglacial (previously called ice-contact) conditions, were investigated to model the dominant genetic processes involved. These fans show, as do other types, a proximal, a middle and a distal subenvironment. It is found, however, that the characteristics of these subenvironments as present in subaerial terminoglacial fans differ in several respects from those in fans formed under other climatic conditions. The present study deals with the middle and distal subenvironments. These appear to be much less complex than the proximal subenvironment in this type of fan. The middle terminoglacial fan comprises two sandy facies, characterized by unchannelized transport (mainly sheet floods) and stream flows. The distal terminoglacial fan is characterized by one (sandy/silty) facies, resulting from unchannelized currents and from settling in ephemeral ponds; braided streams play a secondary part in this fan subenvironment. The characteristics of the middle and distal fan subenvironments are described and illustrated, as is the facies from the distal subenvironment. Their vertical and lateral relationships are presented in a facies model.     

A computer-assisted thin-section study of Lake Baikal sediments: a tool for understanding sedimentary processes and deciphering their climatic signal

A freeze-drying technique for cutting thin-sections of soft sediments without disturbance is used to study several Lake Baikal sedimentary microstructures. Image analysis methodology is applied to selected thin-sections. This new technique provides quantification of the size, shape, orientation and packing of the objects forming the sedimentary structures. Sedimentary processes, which were previously poorly documented, have been identified, and others are better understood. Spheroidal lens-like pure aggregates of the diatom genus Synedra are found in hemipelagic sediments, providing a new insight into their traditional paleoecological interpretation. They are possibly related to a transportation mechanism from the littoral zone or to lacustrine snow. Laminae of Aulacoseira have also been recorded. Evidence of rapid sedimentation suggests they are due to massive algal blooms. The depositional mechanism that was suggested by other studies for explaining the laminations at the Buguldeika uplift is confirmed: the hemipelagic sedimentation is interrupted by terrigenous pulses due to discharge events. The sedimentation rate appears to be increasing during these pulses. Preliminary results from the Academician Ridge show stronger microbioturbation during cold periods. This observation strengthens the hypothesis of intense water circulation during colder times. Thin-section image analysis provides crucial information for deciphering lacustrine records and their regional and palaeoclimatic significance. Received: 27 November 1998 / Accepted: 13 September 1999