Integrated approach for delineating potential zones to explore for groundwater in the Pageru River basin, Cuddapah District, Andhra Pradesh, India

Hydrogeomorphological, hydrogeological and geophysical investigations were carried out in the Pageru River basin of Cuddapah district, Andhra Pradesh, to delineate potential zones for future groundwater exploration. The study area is underlain by Proterozoic formations of the Indian Peninsula comprising limestones and shales as the sedimentary cover. Limestone and shale formations of the Cuddapah Super group that are later overlain by the Kurnool group (shale, limestone and quartzite) are exposed extensively. The high drainage density (2.61 km/km²) in the western region also suggests that the area is characterized by low permeable zones compared with low drainage density (1.04 km/km²) of the flood plains, which form the potential aquifers in the east. The hydro-geomorphological data are further supported from evidence of the water-table fluctuation in wells and resistivity of the saturated formations. The results indicate that the favourable, moderately favourable and poor zones characterized geomorphologically, have water-level fluctuations in the range of 0–2, 2–6 and above 6 m, respectively. The resistivities of these zones are also in the range of 1–26, 40–466, and >1,900 ohm-m. A few pumping tests have also been conducted to assess the broad range in the values of aquifer parameters. Based on these data, good to poor potential zones for obtaining groundwater have been delineated in the study area.

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Resumen Se llevaron a cabo investigaciones hidrogeomorfológicas, hidrogeológicas y geofísicas en la cuenca del Río Pageru del distrito Cuddapah, Andhra Pradesh, con objeto de delimitar zonas potenciales para exploración futura de aguas subterráneas. El área de estudio consiste de formaciones Proterozoicas de la Península India con calizas y lutitas como cubierta sedimentaria. Las formaciones de caliza y lutita del Grupo Cuddapah Superior afloran extensamente y están cubiertas por el Grupo Kurnool (lutita, caliza, y cuarcita). La alta densidad de drenaje (2.61 km/km²) en la región occidental también indica que el área se caracteriza por zonas de baja permeabilidad en comparación con las planicies de inundación de baja densidad (1.04 km/km²) que forman los acuíferos potenciales del oriente. Los datos hidrogeomorfológicos tienen apoyo adicional a partir de evidencia proveniente de la fluctuación del nivel freático en pozos y resistividad de las formaciones saturadas. Los resultados indican que las zonas caracterizadas geomorfológicamente como zonas favorables, moderadamente favorables, y pobres tienen fluctuaciones de niveles de agua en el rango de 0–2, 2–6, y mayor de 6 m, respectivamente. Las resistividades de estas zonas también se encuentran en el rango de 1–26, 40–466, y mayores de 1,900 ohm-m. Se realizaron algunas pruebas de bombeo para evaluar los amplios rangos que tienen los valores de los parámetros de los acuíferos. Basado en esta información se delimitaron zonas con potencial bueno a pobre para obtener agua subterránea en la zona de estudio.

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Résumé Des investigations hydrogéomorphologiques, hydrogéologiques et géophysiques ont été menées sur le bassin de la rivière Pageru du district de Cuddapah, Andhra Pradesh, pour délimiter les zones potentielles dans la future recherche deaux souterraines. La zone étudiée est, à la base, constituée par les formations protérozoïques de la péninsule indienne comprenant les calcaires et les shales de la couverture sédimentaire. Les calcaires et les shales du Super Groupe Cuddapah qui sont recouverts par le Groupe Kurnool (shale, calcire, quartzite) sont exposés de manière extensive. La densité importante de drainage (2.61 km/km²) dans la région ouest montre également que la zone est caractérisée par des perméabilités faibles par comparaison avec les plaines dinondation (densité de drainage: 1.04 km/km²), formant les aquifères potentiels de lEst. Les données hydrogéomorphologiques vont également dans le sens des données de fluctuation de la nappe et de résistivité des formations saturées. Les résultats indiquent que les zones caractérisées géomorphologiquement comme favorables, moyennement favorables et pauvres, possèdent des fluctuations respectives de lordre de 0 à 2, 2 à 6 et de plus de 6 m. La résistivité de ces zones est également de lordre de 1 à 26, 40 à 466 et de plus de 1900 ohm-m. Quelques pompages dessais ont également été conduits pour déterminer les valeurs moyennes des paramètres de laquifère. En se basant sur ces données, des zones potentielles bonnes à pauvres pour lexploitation des eaux souterraines ont été délimitées.

     

Evaluation of morphometric parameters of drainage networks derived from topographic maps and DEM in point of floods

An evaluation of morphometric parameters of two drainage networks derived from different sources was done to determine the influence of sub-basins to flooding on the main channel in the Havran River basin (Balıkesir-Turkey). Drainage networks for the sub-basins were derived from both topographic maps scaled 1:25.000 and a 10-m resolution digital elevation model (DEM) using geographic information systems (GIS). Blue lines, representing fluvial channels on the topographic maps were accepted as a drainage network, which does not depict all exterior links in the basin. The second drainage network was extracted from the DEM using minimum accumulation area threshold to include all exterior links. Morphometric parameters were applied to the two types of drainage networks at sub-basin levels. These parameters were used to assess the influence of the sub-basins on the main channel with respect to flooding. The results show that the drainage network of sub-basin 4—where a dam was constructed on its outlet to mitigate potential floods—has a lower influence morphometrically to produce probable floods on the main channel than that of sub-basins 1, 3, and 5. The construction of the dam will help reduce flooding on the main channel from sub-basin 4 but it will not prevent potential flooding from sub-basin 1, 3 and 5, which join the main channel downstream of sub-basin 4. Therefore, flood mitigation efforts should be considered in order to protect the settlement and agricultural lands on the floodplain downstream of the dam. In order to increase our understanding of flood hazards, and to determine appropriate mitigation solutions, drainage morphometry research should be included as an essential component to hydrologic studies.     

A GIS and remote sensing based evaluation of groundwater potential zones in a hard rock terrain of Vaigai sub-basin, India

In this paper, remote sensing, geographic information systems (GIS) and fieldwork techniques were combined to study the groundwater conditions in Vaigai basin, Tamilnadu. Several digital image processing techniques, including standard color composites, intensity–hue–saturation transformation and decorrelation stretch were applied to map rock types. Remote sensing data were interpreted to produce lithological and lineament maps such as geology, geomorphology, soil hydrological group, land use/land cover and drainage map were prepared and analyzed using GIS Arc Map GIS Raster Calculator module as geomorphology?×?12?+?drainage?×?9?+?lineament?×?5?+?geology?×?8?+?land use?×?2?+?relief?×?4. The final cumulative map generated by applying the above equation had weight values ranging from 0.315 to 4.515. The overall results demonstrate that the use of remote sensing and GIS provide potentially powerful tools to study groundwater resources and design a suitable exploration plan, the thematic maps for the study area.     

Integrated multi-parameter approach for delineating groundwater potential zones in a crystalline aquifer of southern India

Groundwater resources in the semi-arid regions of southern India are under immense pressure due to large-scale groundwater abstraction vis-à-vis meager rainfall recharge. Therefore, understanding and evaluating the spatial distribution of groundwater is essential for viable utilization of the resource. Here, we assess groundwater potential at the watershed scale, in a semi-arid environment with crystalline aquifer system without a perennial surface water source using remote sensing, geophysical, and GIS-based integrated multi-parameter approach. GIS-based weighed overlay analysis is performed with input parameters, viz., geology, geomorphology, lineament density, land use, soil, drainage density, slope, and aquifer thickness. The watershed is categorized into four zones, namely, “very good” (GWP4), “good” (GWP3), “moderate” (GWP2), and “low” (GWP1) in terms of groundwater potential. Overall, ~?70% of the study area falls under moderate to low groundwater potential, indicating a serious threat to the future availability of the resource. Therefore, serious measures are required for maintaining aquifer resilience in this over-exploited aquifer (e.g., restricting groundwater withdrawal from GWP1 and GWP2 zones). Further, as the aquifer is under tremendous anthropogenic pressure, rainwater harvesting and artificial recharge during monsoon are advocated for sustainable aquifer management. Due to the direct dependence of crop production vis-à-vis farmer economy on groundwater, this study is an important step towards sustainable groundwater management and can be applied in diverse hydrological terrains.     

Integration of geoelectric and hydrochemical approaches for delineation of groundwater potential zones in alluvial aquifer

Geoelectric and hydrochemical approaches are employed to delineate the ground-water potential zones in District Okara, a part of Bari Doab, Punjab, Pakistan. Sixty-seven VES surveys are conducted with the Electrical Resistivity Meter. The resultant resistivity verses depth model for each site is estimated using computer-based software IX1D. Aquifer thickness maps and interpreted resistivity maps were generated from interpreted VES results. Dar-Zarrouk parameters, transverse resistance (TR), longitudinal conductance (SL) and anisotropy (λ) were also calculated from resistivity data to delineate the potential zones of aquifer. 70% of SL value is ≤3S, 30% of SL value is > 3S. According to SL and TR values, the whole area is divided into three potential zones, high, medium and low potential zones. The spatial distribution maps show that north, south and central parts of study area are marked as good potential aquifer zones. Longitudinal conductance values are further utilized to determine aquifer protective capacity of area. The whole area is characterized by moderate to good and up to some extent very good aquifer protective area on the basis of SL values. The groundwater samples from sixty-seven installed tube wells are collected for hydro-chemical analysis. The electrical conductivity values are determined. Correlation is then developed between the EC (μS/cm) of groundwater samples vs. interpreted aquifer resistivity showing R2 value 0.90.     

Numerical analysis and evaluation of groundwater recession in a flood detention basin

This study analyzes the groundwater environment in the Yangzhuang flood detention basin in Henan Province, China. A numerical model of groundwater flow is established based on the hydrogeological conditions in the basin and changes of groundwater level in the flood detention basin under flood detention and recession conditions. The results show that during flood diversion and storage, the groundwater level in the basin rises, mainly in four flood detention zones, with a maximum rise of 1.0 m. After the floodwater recedes, the groundwater level slowly drops in the detention basin along with flood discharge, finally returning to its original level fifty days later. This study indicates that groundwater recession in the flood detention basin is a slow process, where the rise of groundwater level may cause environmental problems such as soil swamping.     

Integrated studies for characterization of lineaments used to locate groundwater potential zones in a hard rock region of Karnataka, India

An integrated study was carried out to investigate the subsurface geological conditions in a hard rock environment, with the aim of identifying zones with groundwater resource potential. The study, in Bairasagara watershed, Karnataka, India, considered geomorphology, water level, resistivity imaging, self potential, total magnetic field and susceptibility. The signatures due to lineaments have been clearly identified and their role in groundwater movement has been documented. Synthetic simulation methods were used to model the electrical response of the lineament using finite differential modeling scheme. The inverted image of the field data is compared with the synthetic image and iteration were performed on the initial model until a best match was obtained resulting on the generation of the calibrated resistivity image of the subsurface. Resistivity imaging revealed that the dykes are weathered/fractured to a depth of 6–8 m and are compact at deeper levels, and that they behave as barriers to groundwater movement, yet facilitate a good groundwater potential zone on the upgradient side. The results of magnetic surveys were utilized in differentiating granites and dolerite dykes with an insignificant resistivity contrast. Geomorphological expression alone cannot reveal the groundwater potential associated with a lineament. However, characterizing the nature of the feature at depth with integrated geophysical methods provides essential information for assessing that potential.An erratum to this article can be found at     

Integrated studies for characterization of lineaments used to locate groundwater potential zones in a hard rock region of Karnataka, India

An integrated study was carried out to investigate the subsurface geological conditions in a hard rock environment, with the aim of identifying zones with groundwater resource potential. The study, in Bairasagara watershed, Karnataka, India, considered geomorphology, water level, resistivity imaging, self potential, total magnetic field and susceptibility. The signatures due to lineaments have been clearly identified and their role in groundwater movement has been documented. Synthetic simulation methods were used to model the electrical response of the lineament using finite differential modeling scheme. The inverted image of the field data is compared with the synthetic image and iteration were performed on the initial model until a best match was obtained resulting on the generation of the calibrated resistivity image of the subsurface. Resistivity imaging revealed that the dykes are weathered/fractured to a depth of 6–8 m and are compact at deeper levels, and that they behave as barriers to groundwater movement, yet facilitate a good groundwater potential zone on the upgradient side. The results of magnetic surveys were utilized in differentiating granites and dolerite dykes with an insignificant resistivity contrast. Geomorphological expression alone cannot reveal the groundwater potential associated with a lineament. However, characterizing the nature of the feature at depth with integrated geophysical methods provides essential information for assessing that potential.The online version of the original article can be found at     

Use of geospatial technology for delineating groundwater potential zones with an emphasis on water-table analysis in Dwarka River basin,Birbhum, India

Dwarka River basin in Birbhum, West Bengal (India), is an agriculture-dominated area where groundwater plays a crucial role. The basin experiences seasonal water stress conditions with a scarcity of surface water. In the presented study, delineation of groundwater potential zones (GWPZs) is carried out using a geospatial multi-influencing factor technique. Geology, geomorphology, soil type, land use/land cover, rainfall, lineament and fault density, drainage density, slope, and elevation of the study area were considered for the delineation of GWPZs in the study area. About 9.3, 71.9 and 18.8% of the study area falls within good, moderate and poor groundwater potential zones, respectively. The potential groundwater yield data corroborate the outcome of the model, with maximum yield in the older floodplain and minimum yield in the hard-rock terrains in the western and south-western regions. Validation of the GWPZs using the yield of 148 wells shows very high accuracy of the model prediction, i.e., 89.1% on superimposition and 85.1 and 81.3% on success and prediction rates, respectively. Measurement of the seasonal water-table fluctuation with a multiplicative model of time series for predicting the short-term trend of the water table, followed by chi-square analysis between the predicted and observed water-table depth, indicates a trend of falling groundwater levels, with a 5% level of significance and a p-value of 0.233. The rainfall pattern for the last 3 years of the study shows a moderately positive correlation (R ² = 0.308) with the average water-table depth in the study area.     

太行山前平原浅层地下水污染的分子生物学响应特征——以滹沱河流域为例

分子生物学技术是地下水污染研究的前沿技术,常用于场地尺度,区域尺度罕见。以太行山前平原滹沱河流域的典型浅层地下水为研究对象,沿河布点采样67组,采用高通量测序技术,测定样品16S rDNA基因序列,以化学需氧量、硝酸盐、溶解性总固体为环境因子,分析与污染相关的微生物种群结构响应及功能性指示菌属。结果显示:采用累积概率分布法将样品分为背景(B)、硝酸盐污染(N)、有机污染(Y)3组,该分类阈值与地下水质量标准的Ⅲ类水阈值可较好对应;微生物群落丰富度为B组N组Y组,有机污染使微生物种群趋于单一,且与背景差异更大。有机污染功能性指示菌属为Acinetobacter,硝酸盐污染为Nitrospira。以上形成的分子生物学响应特征研究方法可为区域调查及修复提供技术方法理论依据。     

中国西北内陆干旱盆地地下水形成演化模式及其意义

随着系统理论分析方法的引入和同位素、遥感、计算机技术和先进物探手段等的应用,内陆干旱区的地下水勘查与研究得到迅速发展。本文以作者在中国西北地区近十几年的地下水勘查与研究成果为主要基础,将内陆干旱盆地平原区地下水划分为四级地下水流系统,即山前局部地下水流系统（Ｉ）、区域地下水流系统（Ⅱ）、滞流地下水流系统（Ⅲ）和细土平原区易变的局部地下水流系统（Ⅳ）。盆地地下水的形成演化和盐分迁移主要发生在Ｉ、Ⅱ和     

Integrated approach for identification of potential groundwater zones in Seethanagaram Mandal of Vizianagaram District,Andhra Pradesh,India

Identifying a good site for groundwater exploration in hard rock terrain is a challenging task. In hard rocks, groundwater occurs in secondary porosity developed due to weathering, fracturing, faulting, etc., which is highly variable within short distance and contributing to near-surface inhomogeneity. In such situations topographic, hydrogeological and geomorphological features provide useful clues for the selection of suitable sites. Initially, based on satellite imagery, topographical, geomorphological and hydrogeological features, an area of about 149 km² was demarcated as a promising zone for groundwater exploration in the hard rock tract of Seethanagaram Mandal, Vizianagaram District, Andhra Pradesh, India. A total of 50 Vertical Electrical Soundings (VES) were carried out using Wenner electrode configuration. An interactive interpretation of the VES data sharpened the information inferred from geomorphological and hydrogeological reconnaissance. Ten sites were recommended for drilling. Drilling with Down-The-Hole Hammer (DTH) was carried out at the recommended sites down to 50 to 70 m depths. The interpreted VES results matched well with the drilled bore well lithologs. The yields of bore wells vary from 900 to 9000 liters per hour (lph).     

潜水地下水动态成因类型的综合判别方法——以三江平原松花江流域为例

传统地下水动态类型的判别方法存在受人为主观因素影响大、易产生多解性等问题。为提高地下水动态成因类型判断的可靠性,本文提出了基于水文地质条件定性分析与实测数据定量分析相结合的综合判别方法。根据研究区的气象、水文及水文地质条件等,将地下水各补给项及排泄项对地下水动态的影响进行定量化,对动态数据进行相关分析及逻辑判断,辨识出对地下水位动态贡献最大的补给项和排泄项,并依此确定地下水动态的成因类型。基于该方法,以三江平原松花江流域2011年及2015年相同的57个地下水观测点为例,结合地下水位埋深、地下水位、河水位、降水量、观测井距河流的距离、包气带岩性等资料,将研究区地下水动态成因类型共划分为水文型、降水入渗型、降水入渗-蒸发型、降水入渗-径流型、降水入渗-开采型和人工开采型6种类型;对比2011年及2015年研究区地下水动态类型的变化,降水入渗型、降水入渗-径流型等天然地下水动态成因类型占比减少,而受人类活动影响的地下水动态成因类型占比增加,表明人工开采活动对地下水动态的影响日益增强。相比根据地下水动态曲线特征确定动态成因类型的传统定性分析方法,本研究提出的综合判别方法能够在充分考虑水文地质...     

主砂体及其构造改造样式的盆地产铀远景评价判据

本文在介绍并分析美国和前苏联总结的砂岩型铀矿区域评价判据的基础上, 引入当今碎屑岩沉积学和盆地地球动力学方面的若干新进展, 提出以主砂体及其随后经历的构造改造样式相结合的盆地产铀远景评价判据和以分析区域构造活动史和原型盆地演化相结合的盆地产铀远景评价模式。最后以潮水盆地为例, 具体分析了盆地各个时代盖层容存后生铀矿化的可能性, 指出盆地中的主要找矿目标层位和远景成矿地段。     

Prediction criteria for groundwater potential zones in Kemuning District,Indonesia using the integration of geoelectrical and physical parameters

The presence of groundwater is strongly related to its geological and geohydrological conditions.It is,however,important to study the groundwater potential in an area before it is utilized to provide clean water.Werner-Schlumberger’s method was used to analyze the groundwater potential while hydraulic properties such as soil porosity and hydraulic conductivity were used to determine the quality and ability of the soil to allow water’s movement in the aquifer.The results show that the aquifer in the Sekara and Kemuning Muda is at a depth of more than 6 meters below the ground level with moderate groundwater potential.It is also found that the aquifer at depths of over 60 m have high groundwater potential.Moreover,soil porosity in Kemuning is found to be average while the ability to conduct water was moderate.This makes it possible for some surface water to seep into the soil while the remaining flows to the rivers and ditches.     

Delineation of groundwater potential zones in Wadi Saida Watershed of NW-Algeria using remote sensing,geographic information system-based AHP techniques and geostatistical analysis

Sustainable management of groundwater resources has now become an obligation,especially in arid and semi-arid regions given the socio-economic importance of this resource.The optimization in zoning for groundwater exploitation helps in planning and managing groundwater supply works such as boreholes and wells in the catchment.The objective of this study is to use remote sensing and GIS-based Analytical Hierarchy Process(AHP)techniques to evaluate the groundwater potential of Wadi Saida Watershed.Spatial analysis such as geostatistics was also used to validate results and ensure more accuracy.Through the GIS tools and remote sensing technique,earth observation data were converted into thematic layers such as lineament density,geology,drainage density,slope,land use and rainfall,which were combined to delineate groundwater potential zones.Based on their respective impact on groundwater potential,the AHP approach was adopted to assign weights on multi-influencing factors.These results will enable decision-makers to optimize hydrogeological exploration in large-scale catchment areas and map areas.According to the results,the southern part of the Wadi Saida Watershed is characterized as a higher groundwater potential area,where 32%of the total surface area falls in the excellent and good class of groundwater potential.The validation process revealed a 71%agreement between the estimated and actual yield of the existing boreholes in the study area.     

Mapping favorable groundwater potential recharge zones using a GIS-based analytical hierarchical process and probability frequency ratio model:A case study from an agro-urban region of Pakistan

In Punjab(Pakistan),the increasing population and expansion of land use for agriculture have severely exploited the regional groundwater resources.Intensive pumping has resulted in a rapid decline in the level of the water table as well as its quality.Better management practices and artificial recharge are needed for the development of sustainable groundwater resources.This study proposes a methodology to delineate favorable groundwater potential recharge zones(FPRI) by integrating maps of groundwater potential recharge index(PRI) with the DRASTIC-based groundwater vulnerability index(VI).In order to evaluate both indexes,different thematic layers corresponding to each index were overlaid in ArcGIS.In the overlay analysis,the weights(for various thematic layers) and rating values(for sub-classes) were allocated based on a review of published literature.Both were then normalized and modified using the analytical hierarchical process(AHP) and a frequency ratio model respectively.After evaluating PRI and FPRI,these maps were validated using the area under the curve(AUC) method.The PRI map indicates that 53% of the area assessed exists in very low to low recharge zones,22% in moderate,and 25% in high to excellent potential recharge zones.The VI map indicates that 38% of the area assessed exists in very low to low vulnerability,33% in moderate,and 29% in high to very high vulnerability zones.The FPRI map shows that the central region of Punjab is moderately-to-highly favorable for recharge due to its low vulnerability and high recharge potential.During the validation process,it was found that the AUC estimated with modified weights and rating values was 79% and 67%,for PRI and VI indexes,respectively.The AUC was less when evaluated using original weights and rating values taken from published literature.Maps of favorable groundwater potential recharge zones are helpful for planning and implementation of wells and hydraulic structures in this region.     

Hydrogeochemical parameters for assessment of groundwater quality in the upper Gunjanaeru River basin,Cuddapah District,Andhra Pradesh,South India

In the management of water resources, quality of water is just as important as its quantity. In order to know the quality and/or suitability of groundwater for domestic and irrigation in upper Gunjanaeru River basin, 51 water samples in post-monsoon and 46 in pre-monsoon seasons were collected and analyzed for various parameters. Geological units are alluvium, shale and quartzite. Based on the analytical results, chemical indices like percent sodium, sodium adsorption ratio, residual sodium carbonate, permeability index (PI) and chloroalkaline indices were calculated. The pre-monsoon waters have low sodium hazard as compared to post-monsoon season. Residual sodium carbonate values revealed that one sample is not suitable in both the seasons for irrigation purposes due the occurrence of alkaline white patches and low permeability of the soil. PI values of both seasons revealed that the ground waters are generally suitable for irrigation. The positive values of Chloroalkaline indices in post-monsoon (80%) and in pre-monsoon (59%) water samples indicate absence of base-exchange reaction (chloroalkaline disequilibrium), and remaining samples of negative values of the ratios indicate base-exchange reaction (chloroalkaline equilibrium). Chadha rectangular diagram for geochemical classification and hydrochemical processes of groundwater for both seasons indicates that most of waters are Ca–Mg–HCO₃ type. Assessment of water samples from various methods indicated that majority of the water samples in both seasons are suitable for different purposes except at Yanadipalle (sample no. 8) that requires precautionary measures. The overall quality of groundwater in post-monsoon season in all chemical constituents is on the higher side due to dissolution of surface pollutants during the infiltration and percolation of rainwater and at few places due to agricultural and domestic activities.     

The Sis palaeovalley: a record of proximal fluvial sedimentation and drainage basin development in response to Pyrenean mountain building

The Sis conglomerate body represents the Middle Eocene to Oligocene transfer‐zone trunk palaeovalley fill of the Sis fluvial system, a drainage system established within the Pyrenees during Late Palaeocene times. The spatial stability of the fluvial transfer zone (active for at least 38 My), and hence the longevity of its aggradational palaeovalley component (>19·5 My), was controlled by its location between long‐lived pre‐existing structures. Coarse‐grained fluvial facies dominate the palaeovalley fill, with alluvial fan facies shed from its defining marginal structures. The detailed sedimentology of very proximal fluvial facies deposited within the dominantly erosional realm of an active mountain belt has rarely been documented before because of their poor preservation potential. The Sis conglomerate body contains a robust internal stratigraphy with stratigraphic units defined by distinct bounding surfaces, across which there are pronounced changes in facies and provenance. These mark the reorganization of the headward portions of the Sis fluvial system during the evolution of the Pyrenean Axial Zone antiformal stack. Major changes in discharge resulted, demonstrating the highly variable nature of even mountain belt‐scale fluvial systems when viewed on timescales of several to tens of millions of years. Provenance details indicate that initial unroofing of Hercynian granitoids, situated within the Pyrenean Axial Zone, occurred around 54·5 Ma (early Ypresian) immediately before the first significant exhumation event within the drainage basin of the Sis fluvial system. This is earlier than previously constrained by apatite fission track studies. Rock uplift accelerated in the Lutetian and Bartonian with the initial aggradation of the palaeovalley fill (the Cajigar and Cornudella Formations and Sis One and Two Members). This became marked in the Priabonian (Sis Three and Four Members), with significant activity on local structures including the Morreres backthrust. An increase in basement‐derived clasts and a headwater decapitation event also indicate pronounced Axial Zone antiformal stack development at this time. Axial Zone development intensified further in the Oligocene with the deposition of the Collegats Formation and the switch in the main depositional loci of the system from the Tremp‐Graus thrust‐sheet‐top basin to the Ebro Basin to the south.     

典型黄土塬区地下水水化学成因机制及碳循环意义

水岩相互作用包括了溶解、沉淀和离子交换等作用, 其参与了各种地质作用和生态-环境过程; 而目前对离子交换作用在水中离子来源解析和同位素示踪等方面考虑不足, 这限制了对水化学演化规律和碳循环刻画等方面的认识。本研究选择水文地质条件较为简单的甘肃陇东地区董志塬, 在对降水入渗补给评估、地下水定年(³H和¹⁴C)等水循环规律刻画的基础上, 通过对降水元素输入和阳离子交换容量分析, 以及应用硝酸盐同位素(δ¹⁵N-NO₃和δ¹⁸O-NO₃)、硫酸盐同位素(δ³⁴S-SO₄和δ¹⁸O-SO₄)、⁸⁷Sr/⁸⁶Sr (包括地下水及黄土各分量)、阳离子关系等手段, 解析了董志塬地下水中主要离子来源。研究结果显示, 降水入渗补给量为39±8mm/a, 土壤水运移速度为0.13±0.03m/a; 研究区包气带较厚(主要在40~75m), 这说明年降水需要250~750年才能补给到地下水, 但持续的补给使得自然条件下每年约有(3167±650)×10⁴m³地下水通过泉水补给两侧河流。地下水年龄较老, 不含³H, ¹⁴C校正年龄在417年至19420年之间, 因此水化学组成受现代人类活动影响可忽略; 地下水中Cl^-和SO₄^2-主要来自于古降水, 并反演出古降水SO₄^2-平均含量为1.2mg/L, 显著低于受化石燃料等影响的现代含量(平均为6.6mg/L); 而地下水NO₃^-则主要来自于土壤氮的硝化。地下水⁸⁷Sr/⁸⁶Sr比值(0.7107至0.7114)与黄土中碳酸盐的比值(0.7103至0.7111)基本一致, 表明Ca²⁺和Mg²⁺主要来自于碳酸盐矿物的溶解, 部分被吸附至粘土矿物。研究区黄土具有较高的阳离子交换容量(149±33meq/kg), 地下水总Na⁺中, 降水贡献平均占29%, 其余Na⁺主要来源于水中Ca²⁺和Mg²⁺和粘土矿物中Na的交换(平均为71%), 硅酸盐溶解对水中Na⁺贡献可忽略(硅酸盐溶解会导致⁸⁷Sr/⁸⁶Sr增加), 而以往研究大多认为除了降水输入、蒸发岩溶解外, 水中Na⁺主要来自于硅酸盐矿物的溶解, 并贡献了碳汇。本研究认为在研究区地下水中, 硅酸盐风化的碳汇效应可忽略; 同时强调了在含有粘土矿物的流域或水岩体系, 阳离子交换作用在示踪水中离子来源及碳循环中的重要性。