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1.
The present paper deals with the determination of LTm values of zolone, rogor, sumithion and abate for Channa gachua by conducting static bioassay experiments. The TLm values for zolone came out to be 0.08275 mg/l, 0.08225 mg/l, 0.0815 mg/l and 0.0810 mg/l; for rogor 5.155 mg/l; 4.955 mg/l, 4.65 mg/l and 4.475 mg/l; for sumithion 12.60 mg/l, 12.50 mg/l, 12.30 mg/l and 12.20 mg/l and for abate 217.25 mg/l, 225.575 mg/l, 221.575 mg/l and 217.25 mg/l for 24, 48, 72 and 96 hours, respectively. Relative susceptibility indicates that this fish is not susceptible to zolone and less to rogor, sumithion and abate, respectively. Present studies also show that increased temperature and pH increase the toxicity of all the biocides, but increased hardness of water decreases the toxicity of biocide solutions. The safe concentrations for zolone, rogor, sumithion and abate came out to be 0.02437 mg/l, 1.3733 mg/l, 3.6907 mg/l and 66.678 mg/l, respectively. 相似文献
2.
An attempt has been made to study the toxicity of two commonly used pesticides aldrin (organochlorine) and ethyl-parathion (organophosphorus) to the fish Colisa fasciatus (Anabantidae) and Notopterus notopterus (Notopteridae). During bioassay studies, the behaviour of the fishes was recorded. The aldrin concentration used lies between 0.021 mg/1 and 0.042 mg/1 for C. fasciatus and 0.00056 mg/1 and 0.00135 mg/1 for N. notopterus. The ethyl-parathion concentration used lies between 1.8 mg/1 and 3.7 mg/1 for C. fasciatus and 0.49 mg/1 and 1.00 mg/1 for N. notopterus.
- – The effect of lethal aqueous concentrations of pesticides on the Fishes prior to death are usually manifested by excitation, erratic swimming ability, difficulty in respiration, increasing in ventilation rate, jerky movements of body and fin fast, up- and downward movements, convulsions, loss of equilibrium, loss of the original colour of the body skin and the excess secretion of mucus by the gills and the body wall.
- – the TLm values for 24, 48 and 96 hours of exposition are determined for both species of fish and both pesticides at the following variables:
- ? three levels of temperature,
- ? three levels of dissolved oxygen,
- ? three levels of pH,
- ? three fish sizes.
- – statistical analysis of variance shows, that all variables have a significant effect on the TLm values of both pesticides for both fish species;
- – Aldrin (chlorinated hydrocarbon) is more toxic than ethylparathion (organophosphate) at all variables;
- – Colisa fasciatus is the more resistant species than Notopterus notopterus.
- – the relationship between the total number of the fishes N0, survival numbers N and time t can be expressed by a mathematical formula as:
- – the harmless concentration to C. fasciatus ranged from 0.0049 mg/1 to 0.0161 for aldrin, 0.54 mg/1 to 0.99 mg/1 for ethyl-parathion and to N. notopterus from 0.00012 mg/1 to 0.00045 mg/1 for aldrin, 0.10 mg/1 to 0.21 mg/1 for ethyl-parathion;
- – the aldrin should be diluted at least 4000 times and ethyl-parathion 320 times of its actual concentration.
3.
The present paper deals with the evaluation of the relative resistance of 12 species of fish in static toxicity bioassay tests of electroplating waste. The electroplating waste is highly toxic as it contains several toxic metals like copper, nickel, cadmium, zinc, lead and chromium alongwith cyanides, acids and alkalies. On the basis of TL50, the fish Clarias batrachus ist the most resistant fish and Labeo rohita the most sensitive. The relative resistance of the fish is in the decreasing order: Clarias batrachus, Saccobranchus fossilis, Ophiocephalus gachua, Ophiocephalus punctatus, Puntius stigma, Puntius sophore, Mystus vittatus, Cyprinus carpio, Colisa fasciatus, Notopterus notopterus, Cirrhina mrigala and Labeo rohita. 相似文献
4.
Fingerlings of Channa punctatus are exposed to 12 mg/l zinc sulphate for 31 d at daily feeding. From the 19th day a significant decrease of growth (increase of weight) by 7 … 8 % as compared with the untreated control fishes was found. After exposure for 30 d the RNA- and protein-contents of the muscles are lower by 10 and 13 %, respectively. 相似文献
5.
B. S. Khangarot 《洁净——土壤、空气、水》1981,9(6):639-649
Static bioassay acute toxicity tests of Zinc, Copper and Mercury were conducted to determine the median lethal concentrations (LC50s) of a freshwater teleost Channa marulius (HAM .) The 96 h LC50 and 95% confidence limits for Zn2+ were 25.61 (24.13 … 27.12) mg/l; 0.90 (0.80 … 1.038) mg/l; for Cu2+ and 0.314 (0.257 … 0.371) mg/l for Hg2+. However, these values decreased at 240 h of exposure and were: 21.09 (18.29 … 24.60) mg Zn2+/l; 0.66 (0.568 … 0.841) mg Cu2+/l; and 0.131 (0.103 … 0.158) mg Hg2+/l. The relative potency ratio of Zn/Hg, Zn/Cu and Cu/Hg suggests that fish were most sensitive to Hg, followed by Cu and Zn ions. The acute toxicities of mixtures of Zn2+?Cu2+; Zn2+?Hg2+, Cu2+?Hg2+ and Zn2+?Cu2+?Hg2+ up to 48 h of exposure were also investigated. The additive index and ranges for Zn2+?Cu2+ were ?0.241 (-0.577 … 0.054); 0.056 (-0.269 … 0.475) for Zn-Hg; 0.285 (-0.043 … 0.718) for Cu-Hg; and -0.542 (-1.215 … 0.005) for Zn-Cu-Hg. All the mixtures tested showed a greater than additive toxicity because index ranges overlapped zero. 相似文献
6.
Effects of acute cadmium poisoning on survival, its residual values and histopathology in certain organs of a freshwater airbreathing fish, Channa punctatus (BLOCH ) were investigated. The threshold concentration, MATC and LC50 values obtained from 96 h static bioassay, revealed that Channa is more susceptible to cadmium ions at higher temperature. The atomic absorption spectrophotometric determination of cadmium residues differed significantly in organs of specimens having survived and died after 96 h of exposure. The gill accumulate the highest amount of cadmium, the liver accumulated a slightly smaller amount than the gill, while the kidney accumulated the least. The histopathological lesions subjected to sublethal (5.2 mg/l Cd) and lethal (8.4 mg/l Cd) concentrations of cadmium were: detachment and rupture of lamellar epithelium, collapse of pillar cells and hypertrophy in mucus producing gland cells in the gill; vacuolization and coagulative necrosis in hepatic cells of the liver; and expansion, necrosis and accumulation of cellular debris in renal tubules of the kidney. The probable causes for death of fish due to cadmium ions have been discussed. 相似文献
7.
I. A. Ansari 《洁净——土壤、空气、水》1987,15(2):175-178
This paper deals with the toxicity of sodium nitrite to freshwater fishes, Channa punctatus (BL.) and Mystus (M). vittatus (Bl.) as to determine the acute toxicity. The LC 50 values were obtained by using a static bioassay method for a period of 24, 48, 72 and 96 hour intervals. The LC 50 values of sodium nitrite for C. punctatus were 375, 325, 250 and 200 ppm and for M. (M). vittatus 164, 140, 90 and 64 ppm, respectively. A profuse mucus secretion was evident at higher concentrations as compared to lower ones. The probable causes of mortality of the fishes are also discussed. 相似文献
8.
The toxicity of ten polynuclear aromatic hydrocarbons (PNAs) to Neanthes arenaceodentata was studied in replicate 96 h bioassays with specific hydrocarbons in solution. Relative solubilities for each PNA were derived in short-term equilibration experiments. Disappearance of representative di-, tri, tetra- and pentacyclic-aromatic hydrocarbons from test solutions was also characterized by ultraviolet spectrophotometry. PNA toxicity and residence time in test solutions were directly related to molecular weight (MW), while relative solubility is inversely related to MW. 96 h TLm values for the diaromatic PNAs naphthalene, 2,6-dimethylnaphthalene, and 2,3,6-trimethylnaphthalene were 3.8, 2.6 and 2.0 ppm, respectively. Phenanthrene, fluorene and 1-methylphenanthrene (triaromatics) exhibited 96 h TLm values of 0.6, 1.0 and 0.3 ppm, respectively. None of the tetra- and pentacyclic-aromatics (chrysene, 3,4-benzo(a)pyrene, 1,2,5,6-dibenzanthracene) were toxic up to the highest concentration tested (1 ppm), excepting fluoranthene, with a 96 h TLm of 0.5 ppm. PNA toxicity appears to be related to both solubility and residence time in test solutions. 相似文献
9.
In the batch experiment with daily exchange of medium the acute toxicity of Ag from AgNO3 to Channa punctatus, Lebistes reticulatus and Puntius sophore is determined over 12 to 96 h exposure. In general, the sensitivity of species increases in the order mentioned. The LC50, 96h are 18.89 μg/l Ag for Channa punctatus, 7.55 μg/l Ag for Puntius sophore and 6.44 μg/l for Lebistes reticulatus. For 12 and 48 h exposure the values in the same order of species are: 62 and 30, 44 and 14 as well as 57 and 16 μg/l Ag. 相似文献
10.
Hydrobiological Investigations of the Water Quality of the Water Supply Reservoirs Husinec and Římov
P. Porcalov 《洁净——土壤、空气、水》1985,13(2):149-153
The two eutrophicated reservoirs Husinec (2.6 km3, 35 ha, zmax 18 m, MQ 1.87 m3/s) and ?ímov (34.5 hm3, 216 ha, zmax 44 m, MQ 4.14 m3/s) show concentrations of total phosphorus of 10… 50 mg/m3 and chlorophyll contents of 7… 36 mg/m3 in the summer season. For both reservoirs a good correlation exists between the chlorophyll concentration and the density of the phytoplankton (20 · 103… 13 · 106 ind./l). With average concentrations of 10… 20 mg/m3 chlorophyll a in summer, the water can be treated for producing drinking water only at a higher expenditure. The water quality will be improved by a reduction of the phosphorus load. 相似文献
11.
The effects of exposure to LC50 (10.5 mg/l) for 96 h and to a sublethal concentration (1.05 mg/l) of Sevin for 120 days have been observed on some haematological, biochemical and enzymatic parameters of Channa punctatus. The fish were hyperglycemic and hyperlactemic and the glycogen content of the liver and muscles decreased, but the lactic acid content of two tissues increased. The activity of hexokinase increased in the kidney, intestine, liver and muscles but decreased in the gills and brain. The activity of lactate dehydrogenase decreased in the kidney and intestine, and increased in the liver, muscles, brain and gills. The pyruvate dehydrogenase activity decreased in all the six tissues. Both the exposures produced a decrease in the succinate dehydrogenase activity of the liver. The enzyme activity decreased in the brain, gills and muscles after chronic exposure, whereas the kidney and intestine showed an elevation in enzyme activity. 相似文献
12.
Prolonged exposure to two pesticides Sevin and Thiodan for 30 days produced impairments in the brain of Channa striatus on the following ways:
- – Separation and damage to meninges of cerebral hemispheres
- – severe damage to all the five layers of the optic textum
- – severe damage to torus longitudinalis
- – partial damage to the molecular and grannular layers of the corpus cerebelli.
- – no effect on diencephalon and myelencephalon.
13.
Lebistes reticulatus (Peters) was exposed to various concentrations of phenol, pentachlorophenol and sodium pentachlorophenolate to determine their toxicity, lethal concentrations and slope functions by a static bioassay procedure. Simultaneous controls were also run. The 94h LC50 values were 47.5mg/l (42.04 … 53.68) for phenol, 0.77 mg/l (0.616 … 0.963) for sodium pentachlorophenate and 0.97 mg/l (0.866 … 1.086) for pentachlorophenol. On this basis, the rank order is sodium pentachlorophenolate-pentachlorophenol-phenol. During the treatment, fish showed an abnormal swimming reflex, excessive mucus secretion, haemorrhage near lips, abdomen and basis of fins and loss of equilibrium followed by death. 相似文献
14.
The LC50-values of As3+-compounds for Channa punctatus are determined for a 48-h exposure to 19.4 (18.02… 21.3) mg/1 and for a 96-h exposure to 14.3 (13.06… 16.80) mg/1. At a long-time exposure to 7.0 mg/1 As3+, during the first seven days there does not occur any change of growth, then the growth in length and the increase in weight decreased by 6.6 and 11.7%, respectively, till the 31st day. At the same time, the RNA content of the muscle decreased by 11.5% to 966.7 μg/g fresh weight and the protein content decreased by 12.5 % to 95.39 mg/g fresh weight. 相似文献
15.
In the dimict lake Arend (5.1 km2, 146 hm3, 49.5 m zmax), nitrogen is production-limiting with concentrations below the detection limit during the production period. Phytoplankton achieves biomasses of up to 18 mg/l fresh matter, essential contributions being made by Aphanizomenon with 2 mg/l and Anabaena with up to 10 mg/l. Nitrogen fixation was measured by the ethine reduction technique (acetylene reduction) during periods of the occurrence of heterocystforming Cyanophyceae and achieved peak values up to 6.59 μg N2 · h?1 · l?1 or 14.87 m?2 · h?1 g N2 · m?2 · h?1. The rates of fixation show a safe correlation with the biomass of heterocyst-containing Cyanophyceae (r = 0.88), their development beginning at values below the N : P-ratio of 2.66. 相似文献
16.
Chris Marone 《Pure and Applied Geophysics》1991,137(4):409-419
Theoretical constraints on the stress-dilation relation for a deforming Coulomb material requirev ifC=0 andv sin-1(
m
/
m
) always, wherev is the dilation angle, is the friction angle,C is cohesion,
m
is the maximum shear stress, and
m
is the mean effective stress. Recent laboratory measurements of friction and dilatancy of simulated fault gouge show that small amplitude shear-load cycling causes compaction and consolidation. Comparison of the data with theory indicates that such load cycling produces: (1) increased coefficient of friction (or friction angle), (2) increased cohesion, and (3) increased dilatancy rate (or dilation angle). Under certain conditions of load cycling without significant plastic shear strain accumulation (
p
<0.005) we find thatv exceeds both and, in contrast to theory, sin-1(
m
/
m
). This result is interpreted in terms of enhanced cohesion and overconsolidation, which lead to residual stresses within the gouge. An analogy is drawn between these special loading conditions and those extant on natural faults. In particular, our results imply that jostling and minor stress variations associated with microearthquakes may produce strengthening of fault gouge and changes in the fault zone's stress-dilatancy relation. Hence, compaction associated with microseismicity may lead to subsequent dilation of fault gouge, even for faults with large displacement rates and large net offsets (e.g., San Andreas). In regions where such dilation persists over sufficient displacements (on the order of the critical slip distance for seismic faulting) it may tend to inhibit unstable slip. 相似文献
17.
B. S. Khangarot 《洁净——土壤、空气、水》1982,10(3):285-292
Static bioassay tests were carried out on Channa punctatus Bloch in the laboratory after renewal of concentrations every 24 h. The LC50 values and 95 per cent confidence limits were 45.21 (39.62 … 51.11) ppm at 12 h and 29.8 (27.49 … 31.95) ppm of Zn at 96 h of exposure. The actual dissolution values of zinc were also determined in test solutions using an atomic absorption spectrophotometer. Behavioural changes were the higher rate of opercular movements, surfacing, loss of equilibrium and haemorrhage near mouth and caudal fin. The LT50 values indicate that survival was increased with decreasing Zn concentration. The histopathological changes observed due to Zn toxicity in the gills have been discussed in relation to fish mortality. 相似文献
18.
Stream pollution by industrial wastes is posing a problem in Uttar Pradesh. In the present investigations an attempt has been made to study the ecological features of a section of the Kalinadi so as to find out the cumulative or detrimental effect of pollution on fish and fisheries by the effluent discharge of sugar factory and distillery wastes near Mansurpur (District Muzaffarnagar), U. P. This paper is part I of the project. The liquid wastes produced by the sugar factory vary from 66 × 106 to 88 × 106 litres/day excluding condenser water and contain variable quantities of cane fibres, cellulose, lime, waxes, fermented sugar juice, mollasses, and some quantities of sulphate, phosphate, and nitrogen, the oxygen being nil with high values of B. O. D. and C. O. D. The liquid waste from the distillery is called spent wash. The spent wash (62 × 104 litres/day) is highly coloured and acidic (pH 4.3 … 2.9). The B. O. D. and C. O. D. values were very high in the order of 28,526 mg/1 … 45,146 mg/1 and 52,516 mg/1 to 66,862 mg/1. Thus total waste of about 17.3 × 106 litres with no oxygen and high B. O. D. (9,600 mg/1 … 10,116 mg/1) is let off into the Kalinadi. Hydrometric observations on the Kalinadi show that the pollutional hazard is appreciable during the low flow period of the river. The wastes affect the river in a number of ways:
- - The deposition of cellulose fibres, organic and inorganic matter affects the substratum adversely. The blackish brown colour of the wastes affects the light penetration by limiting the growth of phytoplankton.
- - There appears to be no potential danger to the river from the electrolyte pollution as the specific conductivity lies below limiting values.
- - Changes in pH in river water due to the acidic nature of the wastes do not affect directly the fauna and flora, but the acidic condition becomes lethal in the presence of low oxygen and high temperature values.
- - The high load of organic matter present in the wastes draws heavily on the oxygen budget of the river and adversely changes the water and bottom quality of the river for a stretch of 10 km, which adversely affects the environmental condition of both fish and fish food.
- - The presence of sulphuric acid in distillery waste and hydrogen sulphide in river water is toxic to fish and fish food.
- - The decomposition of organic matter in an anaerobic condition and in another favourable environment, as with a low redox potential, the presence of sufficient organic matter and a constant supply of sulphur-reducing bacteria, produces more hydrogen sulphide which may be detrimental or sublethal in the presence of a low oxygen saturation and high temperature.
- - The oxygen level increases at each succeeding station through reaeration and dilution with the lowering of B. O. D. and C. O. D. The oxygen-sag curve is like a typical spoon with handle-shape.
19.
In the daily exchange of the medium with only 7.1 mg/l Ca2+ and 0.7 mg/l Mg2+ during the batch experiment the LC50,96h for Cyprinus carpio is 0.063 mg/l Cu2+ and 3.12 mg/l Zn2+ at water temperatures of 11 to 14°C. Significant differences in mortality as referred to the LC50,12h occur for copper only after 72 h of exposure and for zinc after 48 h of exposure. The values of LC50,96h are clearly lower for both metals in the investigations described than most data given in literature for different fish species. 相似文献
20.
Jürg Thudium 《Pure and Applied Geophysics》1978,116(1):130-148
Equilibrium water uptake and the sizes of atmospheric aerosol particles have for the first time been determined for high relative humidities, i.e., for humidities above 95 percent, as a function of the particles chemical composition. For that purpose a new treatment of the osmotic coefficient has been developed and experimentally confirmed. It is shown that the equilibrium water uptake and the equilibrium sizes of atmospheric aerosol particles at large relative humidities are significantly dependent on their chemical composition.List of symbols
A
proportionality factor
-
a
w
activity of water in a solution
-
c
p
v
specific heat of water vapour at constant pressure
-
c
w
specific heat of liquid water
-
f
relative humidity
-
l
w
specific heat of evaporation of water
-
M
i
molar mass of solute speciesi
-
M
s
mean molar mass of all the solute species in a solution
-
M
w
molar mass of water
-
m
0
mass of an aerosol particle in dry state
-
m
i
mass of solute speciesi
-
m
s
mass of solute
-
m
w
mass of water taken up by an aerosol particle in equilibrium state
-
m
total molality=number of mols of solute species in 1000 g of water
-
m
i
molality of solute speciesi
-
m
k
total molality of a pure electrolytek
-
O(m
2)
remaining terms being of the second and of higher powers ofm
-
p
+
standard pressure
-
p
total pressure of the gas phase
-
p
pressure within a droplet
-
p
1,p
2,p
3
coefficients in the expansion of M
-
p
1i, p2i, p3i
specific parameters of ioni
-
p
s
saturation vapour pressure
-
p
w
water vapour pressure
-
R
w
individual gas constant of water
-
r
radius of a droplet
-
r
0
equivalent volume radius of an aerosol particle in dry state
-
T
temperature
-
T
0
standard temperature
-
T
1
temperature of the pure water drop in the osmometer
-
v
w
specific volume of pure water
-
z
i
valence of ioni
- i
relativenumber concentration of ioni in a solution
-
correction term due to the adsorption of ions at liquid-solid interfaces
-
activity coefficient of solute speciesi in a solution, related to molalities
- I
bridge current
- T
temperature difference between solution and pure water drop in the osmometer
-
exponential mass increase coefficient
-
w
specific chemical potential of water vapour
-
w
specific chemical potential of water
- 0
w
specific chemical potential of pure water vapour
- 0
w
specific chemical potential of pure water
- 0
density of an aerosol particle in dry state
- w
density of pure water
-
surface tension of a droplet
- 0
surface tension of pure water, i.e., at infinite dilution of the solute
-
osmotic coefficient
- k
osmotic coefficient of a solution of a pure electrolytek
- k
osmotic coefficient of a solution of a mixed solute
- M
fugacity coefficient of water vapour
-
s
i=1 i
z
2
i
This work is part of a Ph.D. thesis carried out at the Meteorological Institute of the Johannes Gutenberg-Universität, Mainz. 相似文献