Inorganic chemistry of O2 in a dense primitive atmosphere

A simple steady-state photochemical model is developed in order to determine typical molecular oxygen concentrations for a comprehensive range of primitive abiotic atmospheres. Carbon dioxide is assumed to be the dominant constituent in these atmospheres since CO2 photodissociation may potentially result in the enhancement of the O2 partial pressure. The respective effects of the H2O content, temperature, eddy diffusion coefficient and UV flux on the results are investigated. It is shown that for any pressure at the surface, the partial pressure of molecular oxygen does not exceed 10 mbar. The peculiar case of a runaway greenhouse which has possibly taken place on Venus is qualitatively envisaged. Although O2 is basically absent in the present Venus atmosphere, a transient presence in a primitive stage cannot be ruled out. Possible mechanisms for O2 removal in such an atmosphere are reviewed. At the present stage, we think that the detection of large O2 amounts would be at least a good clue for the presence of life on an extrasolar planet.     

Collisional vibrational quenching of O2+(v) and other molecular ions in planetary atmospheres

New experimental techniques have yielded several thermal energy vibrational quenching rate constants for O₂⁺(v). Rates for quenching of O₂⁺(v = 1) by O₂, N₂, Ar, CO₂, H₂, and CH₄ are 3(?10), 2(?12), 1(?12), 1(?10), 2.5(?12), and 6(?10) cm³s^?1 at 300 K. The quenching is somewhat faster for O₂⁺(v = 2). The triatomic ions CO₂⁺, NO₂⁺, N₂O⁺, SO₂⁺, and H₂O⁺ are all vibrationally deexcited with an efficiency greater than 10^?3 in Ar or Ne collisions. A theoretical rationalization of the experimental results leads to the prediction that vibrational quenching in planetary atmospheres will generally be efficient, k > 1(?12) cm³s^?1 for almost all ion and neutral gas pairs.     

Virial treatment of the speed of sound in cold, dense atmospheres and application to Titan

The speed of sound in a gas can be used to identify its composition, as has been done on the Earth. We show that, unlike in terrestrial applications, the third virial coefficient cannot be neglected in cold and dense atmospheres. We derive a model for the speed of sound of pure gases and gas mixtures at low temperatures and high pressures, based on the virial equation. After comparing the results of our model to measured data, we apply our model to the atmosphere of Titan. The difference between our third-order virial expansion and the commonly used second-order expansion is significant, showing that the third virial coefficient needs to be taken into account when accurate speed-of-sound measurements are used to derive atmospheric properties under Titan conditions.     

The abundance ratio C/O in the atmospheres of 343 carbon stars

The abundance ratio C/O in the atmospheres of 343 carbon stars in the Orion galactic arm is detected. Method of data reduction and errors of results are discussed.     

Noble gases in planetary atmospheres: Implications for the origin and evolution of atmospheres

The radiogenic and primordial noble gas content of the atmospheres of Venus, Earth, and Mars are compared with one another and with the noble gas content of other extraterrestial samples, especially meteorites. The fourfold depletion of ⁴⁰Ar for Venus relative to the Earth is attributed to the outgassing rates and associated tectonics and volcanic styles for the two planets diverging significantly within the first billion or so years of their history, with the outgassing rate for Venus becoming much less than that for the Earth at subsequent times. This early divergence in the tectonic style of the two planets may be due to a corresponding early onset of the runaway greenhouse on Venus. The 16-fold depletion of ⁴⁰Ar for Mars relative to the Earth may be due to a combination of a mild K depletion for Mars, a smaller fraction of its interior being outgassed, and to an early reduction in its outgassing rate. Venus has lost virtually all of its primordial He and some of its radiogenic He. The escape flux of He may have been quite substantial in Venus' early history, but much diminished at later times, with this time variation being perhaps strongly influenced by massive losses of H₂ resulting from efficient H₂O loss processes.Key trends in the primordial noble gas content of terrestial planetary atmospheres include (1) a several orders of magnitude decrease in ²⁰Ne and ³⁶Ar from Venus to Earth to Mars; (2) a nearly constant ²⁰Ne/³⁶Ar ratio which is comparable to that found in the more primitive carbonaceous chondrites and which is two orders of magnitude smaller than the solar ratio; (3) a sizable fractionation of Ar, Kr, and Xe from their solar ratios, although the degree of fractionation, especially for ³⁶Ar/¹³²Xe, seems to decrease systematically from carbonaceous chondrites to Mars to Earth to Venus; and (4) large differences in Ne and Xe isotopic ratios among Earth, meteorites, and the Sun. Explaining trends (2), (2) and (4), and (1) pose the biggest problems for the solar-wind implantation, primitive atmosphere, and late veneer hypotheses, respectively. It is suggested that the grain-accretion hypothesis can explain all four trends, although the assumptions needed to achieve this agreement are far from proven. In particular, trends (1), (2), (3), and (4) are attributed to large pressure but small temperature differences in various regions of the inner solar system at the times of noble gas incorporation by host phases; similar proportions of the host phases that incorporated most of the He and Ne on the one hand (X) and Ar, Kr, and Xe on the other hand (Q); a decrease in the degree of fractionation with increasing noble-gas partial pressure; and the presence of interstellar carriers containing isotopically anomalous noble gases.Our analysis also suggests that primordial noble gases were incorporated throughout the interior of the outer terrestial planets, i.e., homogeneous accretion is favored over inhomogeneous accretion. In accord with meteorite data, we propose that carbonaceous materials were key hosts for the primordial noble gases incorporated into planets and that they provided a major source of the planets' CO₂ and N₂.     

Helium in stellar atmospheres

Helium, which was first discovered on the sun with the help of spectral analysis, plays, together with hydrogen, a principal role in astrophysics. We consider here two fundamental quantities: primordial helium abundance formed during Big Bang nucleosynthesis and the current initial helium abundances in nearby stars. It is shown that stellar atmospheres are enriched in helium during the main-sequence stage. Observational evidence for helium contamination in close OB-binaries is discussed. Stars with strong abundance anomalies are considered, such as chemically peculiar Ap and Bp helium-deficient stars and some types of objects with helium atmospheres.     

Rayleigh-Cabannes scattering in planetary atmospheres II. Constant internal sources in nonconservative atmospheres

The vector equation of radiative transfer is solved for non-conservative homogeneous plane-parallel atmosphere using the method of discrete ordinates. The scattering processes in the atmosphere bounded by a Lambert bottom are described by the Rayleigh-Cabannes phase matrix. The primary radiation field is generated by constant internal sources. A package of FORTRAN subroutines is compiled to find the axial radiation field for such an atmosphere at arbitrary optical depth.     

Rayleigh-Cabannes scattering in planetary atmospheres III. The Milne problem in conservative atmospheres

The discrete ordinale method by Chandrasekhar is used to solve the conservative Milne problem in a homogeneous plane-parallel atmosphere which scatters the radiation according to the Rayleigh-Cabannes law.The approximate solution which is supposed to converge uniformly to an exact one when increasing the order of approximation is obtained explicitly. In addition to a tabulation of the Hopf vector for different factors of depolarization, the extrapolation distance, the values of c, q and the Rubenson degrees of polarization at the limb are given.     

Three-minute oscillations in sunspots: Seismology of sunspot atmospheres

We show that no eigenmodes of sunspot oscillations with periods of ～ 3 min or shorter exist. A complex spectrum of the 3-min oscillations arises, because the sunspot atmosphere is a multiband filter for slow MHD waves. To ascertain why the filter transmission bands appear, we have investigated the propagation of waves through a sunspot atmosphere using both multilayered isothermal model atmospheres and various empirical model atmospheres. It turns out that there are several different mechanisms responsible for the appearance of transmission bands in the atmospheric filter for slow waves. The filter lowest-frequency transmission band arises from the effect of a Fabry-Perot interference filter at the resonance frequency of the temperature plateau. The frequency of this band is always lower than the cutoff frequency of the temperature minimum. The next (in frequency) transmission band appears at the cutoff frequency. The higher-frequency transmission bands result from the antireflection of the atmosphere, an effect well-known in optics and acoustics. The nonlinearity of the 3-min oscillations observed in the upper chromosphere and transition region has only an indirect effect on the properties of the filter, increasing its transmission in most bands due to a decrease in the amplitude of the wave reflected from the upper atmosphere caused by nonlinear wave absorption. Knowledge of the formation mechanisms for the 3-min oscillation spectrum has allowed us to suggest a technique for estimating the parameters of sunspot atmospheres from the 3-min oscillation spectrum, i.e., to lay the foundations for the seismology of sunspot atmospheres.     

Photoelectron fluxes in cometary atmospheres

The photoelectron fluxes in cometary atmospheres are calculated by a Monte Carlo method. This is the first quantitative model calculation of this kind. A pure H₂O atmosphere is assumed with a sublimation rate of 10³⁰ molecules sec^?1 at 1 AU. Discussions of the energetics of electron gas and of the elementary collisional processes in determining the fluxes largely concern this water atmosphere. Influences on the photoelectron fluxes are also investigated for CO, another possible constituent. The excitation rate of the ${}^1\text{D}$ level of atomic oxygen in electron impacts is evaluated. It is highly improbable that the photoelectrons are responsible for the observed 6300 Å emission of the order of 1 kR at a heliocentric distance of 1 AU. The structure of the heat equation for thermal electrons is analyzed and a drastic change of the plasma behavior within the coma region is expected.     

Rayleigh scattering in planetary atmospheres

The vector equation of radiative transfer is solved both for conservative and non-conservative planetary atmospheres using the method of discrete ordinates. The atmosphere, bounded by a Lambert bottom, is considered plane-parallel and homogeneous. The scattering in the atmosphere obeys the Rayleigh or Rayleigh-Cabannes law. The compiled package of FORTRAN codes allows us to find the Stokes parameters for such an atmosphere at arbitrary optical depth.     

Nucleosynthesis in neutron star atmospheres

The composition of neutron star atmospheres is calculated as a function of time including effects of diffusion, cooling and thermonuclear reactions. A seven-component nuclear reaction network with includes He⁴, C¹², O¹⁶, Ne²⁰, Mg²⁴, Si²⁸ and Fe⁵⁶ is utilized. Neutron star models with different initial nuclear abundances are compared as to subsequent nucleosynthesis. It is found that the final abundances are independent of original composition assuming He⁴ as the major initial constituent. The final composition of the atmosphere is predominantly Fe⁵⁶. Mass loss from an evolving neutron star is examined as a possible source of cosmic rays. It is found that a neutron star contributes only Fe⁵⁶ significantly to the cosmic-ray spectrum.     

Ray propagation in oblate atmospheres

We evaluate the departures from Bouguer's law for the case of an oblate atmosphere. We show that, to lowest order, the plane of refraction is defined by the normal to the atmosphere at closest approach. In next order, however, the ray path is “warped” by the oblateness, which changes slightly the plane of refraction.     

Multiple scattering in planetary atmospheres

Methods for solving radiative transfer problems within the extended visible spectrum in planetary atmospheres are reviewed for use by the nonspecialist. Emphasis is placed on rapid, approximate procedures for the determination of such quantities as the plane and spherical (Bond) albedo, surface illumination, absorbed energy, limb darkening, phase curve, and spectra. Precise numerical methods and analytical results are also discussed. Recent approaches to such complications as atmospheric inhomogeneity and reflection from a porous regolith are described briefly.     

Opacity errors in model atmospheres

Different issues involved in the numerical evaluation of continuous absorption by hydrogenlike atoms and ions have been analyzed. Usually, the calculation of the opacity coefficient is explicitly performed for a predetermined number of levels and the higher ones are treated as an integral; it is shown that there are some cases where as many as 17 discrete levels need to be added before switching to the integral approximation if an error smaller than 0.1% is wanted in the results (a condition not always fulfilled with model atmosphere codes being used). Also, approximations to Gaunt factors are analyzed. Though in some cases approximations can be used which are very good, there are other occasions when it should be advisable to switch to interpolating in original tables, or to use more elaborated expressions (such as Hummer's for the Gaunt free-free factor). A numerical procedure for solving the non linear Pg-Pe-T relation is described in an Appendix.     

Red clouds in reducing atmospheres

A dark reddish-brown high-molecular-weight polymer is produced by long wavelength ultraviolet irradiation of abundant gases in reducing planetary atmospheres. The polymer i examined by paper chromatography, mass spectrometry, and infrared, visible, and ultraviolet spectroscopy. High carbon-number straight-chain alkanes with NH₂ and, probably, OH and CO groups are identified, along with the previously reported amino acids. There are chemical similarities between this polymer and organic compounds recovered from carbonaceous chondrites and precambrian sediments. The visible and near-ultraviolet transmission spectrum of the polymer shows its absorption optical depth to be redder than λ^?2 and perhaps similar in coloration to the clouds of Jupiter, Saturn, and Titan. The near-ultraviolet absorption coefficient is ～10³ cm^?1, and typical grain sizes ～30 μm. The nitrile content is small, and the polymer should be semitransparent in the 5 μm atmospheric window. Such polymers may be a common constituent of clouds in the outer solar system and on the early Earth.     

Functional equations in emitting atmospheres

Astrophysics and Space Science - Starting with the equation of transfer in a plane-parallel inhomogeneous atmosphere which emits and scatters radiation anisotropically, we obtain a set of...     

Lightning generation in planetary atmospheres

The possibilities of lightning generation on other planets are considered, and the basic conditions that exist in terrestrial clouds during lightning discharges and the various theories of charge separation are reviewed. Recent measurements of cloud structure and whistlers, as well as optical observation of lightning on Jupiter, suggest that charge separation and lightning discharges occur on other planets in ways similar to those in which they occur on Earth. Using these terrestrial ideas, it is concluded that lightning on Venus will probably be found in clouds that are located in regions of convection such as those observed downwind of the subsolar point. It is also possible that if volcanoes on Venus are erupting, they too can produce lightning discharges in their plumes although it seems unlikely that this process can account for the observed rate of discharge. Jovian lightning is most probably generated in the lower water-ice clouds. These clouds are of moderate temperatures and have strong convection and large mass loading, all important ingredients for electrical buildup. Lightning is all but ruled out for Mars, even though some electrification is possible owing to the large dust storms on that planet.     

Mean values in inhomogeneous atmospheres

A brief summary of observations of inhomogeneities in the solar atmosphere and progress in the theoretical analysis of two-dimensional model atmospheres is given. In particular, it is asserted that reliable reference models of the mean temperature, pressure, etc. may be derived only by averaging over the horizontal coordinates of a two- or three-dimensional model. In discussion of a wide variety of cases including strong chromospheric lines, weak photospheric lines, and continuum radiation, it is shown that although the derivation of mean values by first averaging over the fluctuations in the data and then applying a one-dimension analysis is an obvious first approximation, it may lead to errors of a gross qualitative nature. Thus the recent deductions by several authors of very small temperature gradients in the upper regions of sunspots are shown to be subject to considerable doubt.