Assessment of groundwater pollution risk as a characteristic of the stability of its quality

Definitions of hazard and risk of groundwater pollution are given. A deterministic method for the assessment of groundwater pollution risk using estimates of groundwater protection against and vulnerability to pollution and stability indicators of groundwater quality is considered. Also presented are the principal methodological approaches to the assessment of groundwater protection against pollution and the formation of the structure of indicators and indices characterizing the stability of groundwater quality. The structure of hazard, risks, and damages associated with groundwater pollution is shown. Expert appraisal method is used for the assessment of groundwater pollution risks.     

Principles of zoning a territory by the hazard and risks of groundwater pollution

Principles of zoning a territory by the pollution hazard to groundwater depending on the pollution sources and their position in the environment are considered. Pollution hazard classifications are proposed for groundwater, pollutants (by their chemical and hydrochemical properties), and groundwater pollution risks, depending on the degree of hazard and the type of pollutant. A procedure is proposed for mapping the hazard and risks of groundwater pollution by various pollutants on the basis of the performed zoning.     

Developing a reliable model for aquifer vulnerability

The assessment of aquifer vulnerability to pollution is crucial for planning a sound management strategy of groundwater quality protection and farmland fertilizer use. This study establishes a reliable model for aquifer vulnerability assessment with an excellent performance for predicting groundwater nitrate-N contamination in the Choushui River alluvial fan, Taiwan based on the DRASTIC method. To promote the prediction performance of aquifer vulnerability assessment, discriminant analysis (DA) was applied to determine the weights of factors in the DRASTIC model by comparing the model results with the observed nitrate-N data. Key factors influencing the presence of groundwater nitrate-N pollution were characterized for different concentration thresholds. The results of analysis reveal that the modified DRASTIC model using DA significantly improves prediction performance for aquifer vulnerability assessment, and groundwater protection zones can be determined correctly based on the modified DRASTIC index. Furthermore, the sensitivity of the factors in the modified DRASTIC model indicates that the depth to the groundwater and aquifer media are critical when the nitrate-N concentration is less than 3 mg/L, while the impact of the vadose zone plays a vital role in controlling nitrate-N pollution of over 5 mg/L.     

Estimation of groundwater vulnerability to pollution based on DRASTIC in the Niipele sub-basin of the Cuvelai Etosha Basin,Namibia

Surface water is a scarce resource in Namibia with about sixty percent of Namibia's population dependent on groundwater for drinking purposes. With increasing population, the country faces water challenges and thus groundwater resources need to be managed properly. One important aspect of Integrated Water Resources Management is the protection of water resources, including protection of groundwater from contamination and over-exploitation. This study explores vulnerability mapping as a basic tool for protecting groundwater resources from pollution. It estimates groundwater vulnerability to pollution in the upper Niipele sub-basin of the Cuvelai-Etosha in Northern Namibia using the DRASTIC index. The DRASTIC index uses GIS to estimate groundwater vulnerability by overlaying different spatially referenced hydrogeological parameters that affect groundwater contamination. The study assesses the discontinuous perched aquifer (KDP) and the Ohangwena multi-layered aquifer 1 (KOH-1). For perched aquifers, point data was regionalized by a hydrotope approach whereas for KOH-1 aquifer, inverse distance weighting was used. The hydrotope approach categorized different parts of the hydrogeological system with similar properties into five hydrotopes. The result suggests that the discontinuous perched aquifers are more vulnerable than Ohangwena multi-layered aquifer 1. This implies that vulnerability increases with decreasing depth to water table because contaminants have short travel time to reach the aquifer when they are introduced on land surface. The nitrate concentration ranges between 2 and 288 mg/l in perched aquifers while in Ohangwena multi-layered aquifer 1, it ranges between 1 and 133 mg/l. It was observed that perched aquifers have high nitrate concentrations than Ohangwena 1 aquifer, which correlates well with the vulnerability results.     

Modelling water fluxes for the analysis of diffuse pollution at the river basin scale

Diffuse pollution is a significant and sometimes even major component of surface water pollution. Diffuse inputs of pollutants to the surface water are related to runoff of precipitation. This means that the analysis of diffuse pollutant fluxes from the land surface to the surface water requires an analysis of water fluxes. In this paper we have modelled the average long‐term total runoff, groundwater recharge index and groundwater residence times for two large European river basins (Rhine and Elbe). We applied and compared two independently developed and recently published methods. We found that with the available large‐scale databases and methods we could simulate successfully the regional patterns of the average long‐term total runoff. The reported groundwater recharge indices and groundwater residence times should be interpreted as estimates based on available knowledge and databases. They do not represent absolute values, but illustrate the possible travel times and spatial patterns of the different runoff components that have to be taken into account for the analysis of diffuse pollution at large regional and temporal scales. Copyright © 2000 John Wiley & Sons, Ltd.     

On the hydro-spectrum of deep wells and the response ability of well-aquifer system

onclusions 1) A set of period components corresponding well to those of Earth tides and barometric pressure can be separated from the hydro-spectra of deep well. The well-aquifer system responds to these components in some degree, which shows that groundwater regime is influenced by Earth tides and barometric pressure. However, in different frequency bands a well-aquifer system possesses different transfer ability for various inputs. 2) The transfer function quantitatively describes the response ability of well-aquifer system to Earth tides and barometric pressure. It is a characteristic parameter that the system itself possesses. According to the transfer function value of well-aquifer system to a certain input factor, we can objectively understand the influence of the input on the groundwater regime in a deep well. This is of important significance for revealing the formation of groundwater regime in a deep well and for evaluating the seismic supervising well. The work was supported by National Natural Science Foundation of China (No. 49372149).     

Svirsky Dump of Arsenopyrite Concentrate and Its Impact on Water Bodies

The geochemistry of a dry dump of arsenic production wastes and a groundwater protection zone were studied with the use of macro- and microanalysis of aqueous and hydrochloric-acid extracts. The accumulation of water-soluble forms of the microcomplex is maximal in the surface layer of the cinder dump, in sulfate-acid zone. Here, aluminosilicates suffer acid destruction. The downward motion of sulfate-iron front at a decrease in medium acidity is accompanied by gypsum formation and the hydrolysis of sulfate salts with subsequent formation of Fe, Al, and Mn hydroxides. The technogenic geochemical sorption barriers, which form in this process, ensure self-conservation of pollution source. In the protection zone, carbonate-alkaline barrier completes the immobilization process. Over the 70 years of dump existence, only a small part of its immobilization potential have been utilized. The sulfate-acid process can be suppressed through the isolation of the dump from atmospheric moistening. The vulnerability of water objects is zero. The evacuation of the dump is not required, as local reclamation is enough.     

Tracer hydrology of the data-scarce and heterogeneous Central American Isthmus

Numerous socio-economic activities depend on the seasonal rainfall and groundwater recharge cycle across the Central American Isthmus. Population growth and unregulated land use changes resulted in extensive surface water pollution and a large dependency on groundwater resources. This work combines stable isotope variations in rainfall, surface water, and groundwater of Costa Rica, Nicaragua, El Salvador, and Honduras to develop a regionalized rainfall isoscape, isotopic lapse rates, spatial–temporal isotopic variations, and air mass back trajectories determining potential mean recharge elevations, moisture circulation patterns, and surface water–groundwater interactions. Intra-seasonal rainfall modes resulted in two isotopically depleted incursions (W-shaped isotopic pattern) during the wet season and two enriched pulses during the mid-summer drought and the months of the strongest trade winds. Notable isotopic sub-cloud fractionation and near-surface secondary evaporation were identified as common denominators within the Central American Dry Corridor. Groundwater and surface water isotope ratios depicted the strong orographic separation into the Caribbean and Pacific domains, mainly induced by the governing moisture transport from the Caribbean Sea, complex rainfall producing systems across the N-S mountain range, and the subsequent mixing with local evapotranspiration, and, to a lesser degree, the eastern Pacific Ocean fluxes. Groundwater recharge was characterized by (a) depleted recharge in highland areas (72.3%), (b) rapid recharge via preferential flow paths (13.1%), and enriched recharge due to near-surface secondary fractionation (14.6%). Median recharge elevation ranged from 1,104 to 1,979 m a.s.l. These results are intended to enhance forest conservation practices, inform water protection regulations, and facilitate water security and sustainability planning in the Central American Isthmus.     

Characterization of groundwater quality in Kinmen Island using multivariate analysis and geochemical modelling

Kinmen is located in the south‐west of Mainland China and mainly has two islands, Large Kinmen and Leiyu. Residents in Kinmen have drunk groundwater over several decades. This work characterized the quality of groundwater in Kinmen using factor analysis (FA), cluster analysis (CA) and geochemical simulation. The factor scores were plotted spatially to illustrate the groundwater quality and were used to discuss the grouped relationship using CA. Salinization, redox and organic matter factors are identified from 17 hydrochemical measurements in 18 wells. Acidic and oxidizing groundwater with nitrate‐N pollution is distributed mainly in the west of Large Kinmen. Saline groundwater is distributed to the north‐east of Large Kinmen and in the south of Leiyu. Groundwater with organic matter is present throughout Leiyu. Five groups of the groundwater quality divided by CA can be interpreted according to one to three factors. The grouped characteristics of the groundwater quality help the local government and industries to plan the use and protection of groundwater resources. Furthermore, a geochemical simulation was used to demonstrate the formation processes of the acidic and oxidizing groundwater properties in granitic sediments. A large amount of the precipitation of the kaolinite and magnetite releases concentrations of hydrogen ion and raises the redox potential in the aquifers. Copyright © 2007 John Wiley & Sons, Ltd.     

Dynamics of groundwater chemistry in the water-rock system in a megalopolis

The methodological approach developed in this study allows the assessment of the degree of groundwater pollution. It is based on the comparative characteristic of the factual data on water chemistry with model data obtained by simulating the interaction in water-rock system. Prerequisites for the determination of the background composition in a megalopolis are presented. The equilibrium state is calculated for a system consisting of 29 chemical elements with 113 potentially possible minerals and 159 simple and complex particles in an aqueous solution. This equilibrium state is in optimal correspondence with the natural conditions of the groundwater horizon considered.     

Impact of septic tank systems on local groundwater quality and water supply in the Pearl River Delta,China: case study

Located at southern coast of China, the Pearl River Delta (PRD) is facing serious water problems in both quantity and quality after its rapid urbanization in the last decade. Most remarkably, the local groundwater, that was used to be the source of drinking water before the urbanization was polluted due to poor management of the septic tanks. In order to study the effects of suburban development on local groundwater flow and water quality in the PRD region, Fengcun of Guangzhou has been chosen as the study area. In Fengcun, drinking water was groundwater before the 1990s, but now piped reservoir water is used by each family because the groundwater has been polluted. This study clarifies the source and process of the groundwater pollution from septic tanks using isotopic and geochemical characteristics, especially nitrate (NO₃^?) concentrations. Water samples were collected from the wells and ponds in Fengcun in March and July 2005 and in July 2006. Based on the pe–pH diagram, NO₃^? and ammonium of groundwater are from the effect of human activities, rather than from nitrification and ammonification of N₂. NO₃^? pollution of groundwater is from point sources, and NO₃^? concentrations decrease from northeast to southwest. Groundwater is polluted rapidly by the leakage of septic tanks. NO₃^? concentrations of pollution sources were lower than 20 mg l^?1 in March 2005, but had increased to about 120 mg l^?1 in July 2006. This implies that groundwater protection should be strengthened in rural areas of the PRD. Copyright © 2007 John Wiley & Sons, Ltd.     

Risk assessment and ranking of heavy metals concentration in Iran’s Rayen groundwater basin using linear assignment method

Groundwater is an important source of freshwater for domestic, agricultural and industrial uses in Iran. Groundwater quality assessment and environmental evaluation are considered as critical issues in recent years. Intensive human activities have resulted in significant changes in environment leading to serious groundwater contamination. This research proposes a two-part systematic approach to tackle heavy metals contamination problem in Rayen Basin (southeast Iran). The first part consists of determining geochemical characteristics and evaluating groundwater quality through application of water quality index and heavy metal pollution indices (i.e. HPI and MI). The second part includes ranking sampling stations based on heavy metals concentration in groundwater using linear assignment method. Six types of water could be identified according to the dominant cations and anions in samples: Ca–HCO₃, Ca–SO₄, Na–Cl, Na–HCO₃, Na–SO₄ and mixed water type. Calculation of indices revealed that natural and anthropogenic activities are playing a vital role in degrading groundwater quality in the study area. The proposed methodology can help in groundwater resource management and preventative activities by identifying risk factors and recognizing their pollution level. The results of this research provide useful and effective information for water pollution control and management and can be used in environmental studies in order to protect groundwater resources in the future.     

Designing a monitoring network for detecting groundwater pollution with stochastic simulation and a cost model

A method is presented to design monitoring networks for detecting groundwater pollution at industrial sites. The goal is to detect the pollution at some distance from the site’s boundary so that it can be cleaned up or hydrologically contained before contaminating groundwater outside the site. It is assumed that pollution may occur anywhere on the site, that transport is by advection only and that no retardation and chemical reactions take place. However, the approach can be easily extended to include designated (and uncertain) source areas, dispersion and reactive transport. The method starts from the premise that it is impossible to detect 100% of all the contaminant plumes with reasonable costs and therefore seeks a balance between the risk of pollution and network density. The design approach takes account of uncertainty in the flow field by simulating realisations of conductivity, groundwater head and associated flow fields, using geostatistical simulation and a groundwater flow model. The realisations are conditioned to conductivity and head observations that may already be present on the site. The result is an ensemble of flow fields that is further analysed using a particle track program. From this the probability of missing a contaminant plume originating anywhere on the terrain can be estimated for a given network. From this probability follows the risk, i.e. the expected costs of an undetected pollution. The total costs of the monitoring strategy are calculated by adding the risk of pollution to the costs of installing and maintaining the monitoring wells and the routinely performed chemical analyses. By repeating this procedure for networks of varying well numbers, the best network is chosen as the one that minimises total cost. The method is illustrated with a simulated example showing the added worth of exploratory wells for characterising hydraulic conductivity of a site.     

地下水位中地震前兆信息提取方法研究

地下水位观测值的影响因素包含降雨、气压、固体潮、地质构造作用等.为凸显地质构造作用对地下水位的影响,需要滤除降雨、固体潮、气压等因素的影响量.本文首先分离地下水位受固体潮、气压作用的影响量;然后依据降雨影响地下水位可以分为长期和短期变化的思路,利用基流分割方法对地下水位的两种变化进行分离,确定地下水位的降雨影响量;最后分析各分量异常与地震活动性关系,探查其中包含的地震前兆信息.本文的研究思路为地下水位观测值中地震前兆信息研究提供了一套可供尝试的系统技术方法.     

Grey degree and grey prediction of groundwater head

Boundary types and geologic conditions, which possess random and obscure characteristics, produce variations in groundwater heads. In this study, a groundwater flow system was regarded as a grey system and a grey degree defined and quantified those characteristics. Data were obtained from field records in Gao-Shu and De-Xie Stations, which are located in the upper and middle sites of Pingtung Plain, Taiwan, respectively. An estimated interval was used to represent the upper and lower groundwater head limits. The analyses showed that the grey degree in the wet season was smaller than in the dry season. This was due to the greater uncertainty in groundwater pumping and rainfall recharge in the dry season. With high confidence levels, the grey degree of the groundwater heads decreased. Under spatial distribution, the uncertainty of the groundwater pumping and rainfall recharge in the middle zone was greater than in the upper zone because the middle zone included residential districts and agricultural regions. Thus, the grey degree in the upper zone was less than the middle zone. The grey model can be used to predict a groundwater head based on the observed groundwater head data and the random degree in the groundwater head each month can be judged by the grey interval.     

Complex Isotopic and Hydrogeochemical Studies of Groundwater in the Kirov Region

Uranium-isotopic and multi-element hydrogeochemical methods are used to assess the natural pollution of fresh groundwater in horizons under development due to a modern intrusion of hypogene water with increased boron and fluorine contents in zones of old tectonic dislocations. The total index of the abovestandard (>MAC) pollution of groundwater in the region of the city of Kirov (the Kirov area) reaches 15. To reduce the effect of natural groundwater pollutants on the health of population, it is recommended that the groundwater intake should be regulated, purifiers should be used, and prospects revealed by the isotopic-and-hydrogeochemical data should be explored. The feasibility of modeling the groundwater formation and tracing the neotectonic dislocations in geological platforms is shown.     

Isotopic characteristics of groundwater in Changzhou,Wuxi and Suzhou area and their implications

Based on the study of groundwater isotope(2H and 18O, 34S, 15N, 3H, 14C) in Changzhou, Wuxi and Suzhou area, it is found that the deep confined groundwater has no pollution on the whole, whereas the shallow groundwater is polluted to a different degree in the area. The deep confined aquifers (main exploitation aquifers) in Changzhou area and in Wuxi and Suzhou area likely belong to two different aquifers. The main exploitation aquifers in Changzhou area are not connected with those in Wuxi and Suzhou area, or they are connected but not expedited. The lateral run-off of groundwater is at present directed to the exploitation center because of overexploitation of the deep groundwater for a long time, but the flowing speed of groundwater is still extremely slow. The deep confined groundwater is in a close to half close state. The 14C age of groundwater varies from 10000 a BP to 38000 a BP, with the oldest groundwater found at the nearest exploitation center (along the line of three cities of Changzhou, Wuxi and Suzhou) and the youngest at the furthest exploitation center.     

Urgent problems of surface and subsurface water quality in Altai krai and possible ways of their solution

Characteristics of surface and subsurface waters in Altai krai are discussed and the potentialities of the use of groundwater from different aquifers for domestic needs are evaluated. The degree of pollution of water bodies by heavy metal compounds and oil products is analyzed.     

Basic Environmental–Hydrogeological Studies in the Territory of European Russia Affected by Chernobyl Accident

Water Resources - A procedure for assessing the protection of groundwater against pollution is considered. This is a basic procedure for tentative forecast estimates of changes in the...     

Distribution of petroleum hydrocarbons in soils and the underlying unsaturated subsurface at an abandoned petrochemical site,North China

Contamination characteristics of petroleum hydrocarbons in soils and the underlying unsaturated subsurface were analysed by investigating and sampling at different depth of five boreholes named SH1 through SH5 at a typical petrochemical site, North China. Topsoil volatile organic gas measurement revealed that SH‐3 was the center of one pollution plume. Soil samples analysis showed that aromatic hydrocarbons and chlorinated hydrocarbons were major pollutants. Their maximum concentration was found at 6.5 and 14.6 m of SH‐2, 13 m of SH‐5, and 18.5 m of SH‐3. These pollutants are mostly accumulated on the interface between two different lithological layers, especially between the sand and silt clay layers. Denitrifying and iron reducing were main biogeochemical processes in this site. Under the influence of groundwater level fluctuation, free NAPLs passed through the boundary and dissolved into the lower groundwater. Knowledge of these associations between contaminant distributions and affecting factors could have implications for soil and groundwater pollution prevention and control. Copyright © 2013 John Wiley & Sons, Ltd.