Detrended fluctuation analysis and entropy-complexity causality analysis of temperatures in an urbanized mountain stream

We present the results of applying detrended fluctuation analysis (DFA) to study correlations in mountain stream temperatures over a 9-year period for impacted and unimpacted conditions. Permutation entropy and complexity are also computed for stream temperature time series at various locations characterized by varying degrees of human impact, and a graphical representation of the “complexity-entropy causality plane” is used to examine the degree of disturbance caused by human activities. Urban development such as canopy removal and urban infrastructure can lead to a higher degree of anti-persistent correlations indicated by lower values of DFA exponents. This effect is more pronounced downstream due to cumulative urbanization effects with downstream distance. Seasonal variations also influence stream temperature dynamics: less anti-persistent behavior is observed in winter months, and stronger anti-persistent correlations during summer. The position in the complexity-entropy plane, reflecting distribution of short term temperature patterns, is also affected, where most sites experience a shift towards higher entropy values after restoration, and only for one site entropy is reduced. Our results indicate the important role urbanization plays on stream evolution greatly influenced by human activities. This information may provide valuable insights for watershed management and water resources management.     

What is the future fate of estuaries given nutrient over-enrichment,freshwater diversion and low flows?

Freshwater inflow is central to the definition of estuaries and if we lose control of the quantity of freshwater flow or discharge (including seasonal timing) to estuaries, then freshwater water quality has the potential to become a moot issue in estuarine ecosystems (Definition of estuaries: estuaries (aestus = tide) are physico-chemically, geomorphically, and biotically diverse ecosystems. Although numerous definitions of estuaries exist, we prefer the following: an estuary is a partially enclosed coastal water body in which freshwater runoff, often seasonally and episodically pulsed, dilutes salty ocean water and the biotic structure is influenced by dynamic tidal action and associated salinity gradients and reef building organisms and wetlands influence development and evolution of ecological structure and function (see for expanded definition)).     

Research on preservation and enrichment mechanisms of organic matter in muddy sediment and mudstone

Using multidiscipline methodologies, the differences in preservation and enrichment mechanisms of organic matter (OM) in muddy sediment and mudstone are investigated. In clay fractions, concentra- tions of TOC and chloroform bitumen “A” are significantly higher than those in coarser fractions. This indicates that clay minerals (CM) play an important role in enriching OM. The content of chloroform bitumen “A” increases obviously in the clay fraction, which reveals that dissolvable OM is the main composition of coalesce with clay minerals. Furthermore, TG and DTA data show that OM enrichment mechanisms and preservation forms have multiplicity. Several exothermic peaks in the DTA curves demonstrate that muddy sediment and mudstone contain a number of bioclasts and amorphous OM besides dissolvable OM. Through analyzing with XRD and DTA after mudstone samples were pretreated, the conclusions can be arrived at. Firstly, CM interlayer space of XRD curves and exothermic peaks of DTA curves both change as temperature increases. Secondly, the changes of CM interlayer space and exothermic peaks are concordant and stable around 350℃. All these are the features that OM enters CM interlayers to form stable organo-clay complexes. Therefore, the combination format of OM with CM is not only surface adsorption, partial OM enters CM interlayers to form stable organo-clay complexes. Finally, through the research on OM preservation forms and enrichment mechanisms in muddy sedi- ment and mudstone, the hydrocarbon-generation processes and the global carbon cycle and budget can be explained.     

Sources,loads and dispersion of dissolved inorganic nutrients in Paranaguá Bay

The present study focuses on the nutrient sources and gradients in Paranaguá Bay (Southern Brazil), where nutrient inputs are related to losses from fertilizer loading in Paranaguá harbour and the discharge of untreated waste water. The input of dissolved inorganic nutrients to the bay from the harbour and city, as well as from river and atmospheric deposition, amounted to 642 t year⁻¹ DIN-N and 92 t year⁻¹ PO₄-P. Harbour losses accounted for 6 % of total DIN-N and 39 % of total PO₄-P loads to the bay, whereas sewage inputs from the city were responsible for 21 % and 22 %, respectively. River inputs made up 68 % of DIN-N, mainly in the form of nitrate, and 35 % of PO₄-P loads, while atmospheric wet deposition was estimated to be in the order of 5 % of DIN-N and 4 % of PO₄-P loads. Local maxima in nutrient levels deriving from highly concentrated sewage discharge were observed in front of the harbour and city of Paranaguá, but the plumes are diluted rapidly due to short residence times. DIN concentrations are negatively correlated with salinity, indicating the importance of freshwater input as a main factor controlling nitrogen distribution. Elevated phosphate levels in the stratified middle section of the bay may result both from harbour emissions and phosphate remobilization from sediments. Generally lower DIN and PO₄ concentrations during the warmer rainy season are supposed to be due to intensified assimilation rates especially in the middle section of the bay where dense phytoplankton blooms are observed. The bay as a whole cannot be classified as being seriously eutrophic, albeit eutrophication symptoms prevail in some restricted locations in front of Paranaguá harbour.

     

Sources, loads and dispersion of dissolved inorganic nutrients in Paranaguá Bay

The present study focuses on the nutrient sources and gradients in Paranaguá Bay (Southern Brazil), where nutrient inputs are related to losses from fertilizer loading in Paranaguá harbour and the discharge of untreated waste water. The input of dissolved inorganic nutrients to the bay from the harbour and city, as well as from river and atmospheric deposition, amounted to 642?t?year^?1 DIN-N and 92?t?year^?1 PO₄-P. Harbour losses accounted for 6?% of total DIN-N and 39?% of total PO₄-P loads to the bay, whereas sewage inputs from the city were responsible for 21?% and 22?%, respectively. River inputs made up 68?% of DIN-N, mainly in the form of nitrate, and 35?% of PO₄-P loads, while atmospheric wet deposition was estimated to be in the order of 5?% of DIN-N and 4?% of PO₄-P loads. Local maxima in nutrient levels deriving from highly concentrated sewage discharge were observed in front of the harbour and city of Paranaguá, but the plumes are diluted rapidly due to short residence times. DIN concentrations are negatively correlated with salinity, indicating the importance of freshwater input as a main factor controlling nitrogen distribution. Elevated phosphate levels in the stratified middle section of the bay may result both from harbour emissions and phosphate remobilization from sediments. Generally lower DIN and PO₄ concentrations during the warmer rainy season are supposed to be due to intensified assimilation rates especially in the middle section of the bay where dense phytoplankton blooms are observed. The bay as a whole cannot be classified as being seriously eutrophic, albeit eutrophication symptoms prevail in some restricted locations in front of Paranaguá harbour.     

Variation characteristics of heavy metals and nutrients in the core sediments of Taihu Lake and their pollution history

The sedimentary environment change, trophic evolution and heavy metals pollution history of the northern Taihu Lake in the last 100 years are studied according to the sedimentary geo-chemical proxies of the core sediments, such as grain size, nutrients, heavy metals, diatom, etc. The nutrients in the sediments depended mainly on the lake internal circulation and the heavy metals were from natural geogenic sources before the 1920s, which were not influenced by human activities generally, and grain size was one of the key factors influencing heavy metals content in the sediments. The alternation of manner and strength of human activities in Taihu Lake catchment before and after the 1920s made the lake sediments coarser, and hence heavy metals and TP content decreased contrasted with that before the 1920s. TP content in sediments and water increased from the 1950s to late 1970s due to anthropogenic pollutants discharge, and the lake belonging to mesotrophic state. TN and TOC content and C/N ratio increased due to the increasing external pollutants into Taihu Lake by human activities, TP content also increased obviously in water and sediments, and the diatom association was dominated by eutrophic species since the late 1970s, indicating the eutrophication state of Taihu Lake in this period. Meanwhile the increasing in heavy metals content, such as Cu, Mn, Ni, Pb and Zn, and their proportion of valid fractions in the sediments indicates that they all result from human pollutants since the late 1970s. The heavy metals in the surface sediments have certain potential biological toxicity due to the higher SEM/AVS ratio.     

Empirical approaches in prediction of reservoir sediment distribution——An experience of 57 reservoirs in the USA and India

An accurate prediction of sediment distribution may minimize economic losses through proper and timely planning of the functional activities of a reservoir.This study assesses different temporal and spatial factors that affect for sediment deposition in a reservoir and its distribution.This study also focuses on evaluation of two popular distribution prediction methodologies,Area Increment and Empirical Area Reduction,based on experience with sediment distribution in 57 reservoirs in the USA and India.A non-iterative processed empirical distribution model(NPEDM) and a linear regression trend model(LRTM) are proposed to predict sediment distribution.Silt contributing area and inflow entering a reservoir are found to be the most significant factors affecting in reservoir sediment deposition.Compared to the Empirical Area Reduction method,the Area Increment method provided better prediction.The reservoir classification approach and empirical design distribution type curves given by Borland and Miller(1960) are found to be rational.Shape factor values for different periods indicate that reservoir shape(type) changes with time.Thus,long term prediction is not desirable in Type-Ⅱ Ⅲ reservoirs using the Empirical Area Reduction method.Newly developed the NPEDM shows reasonably good prediction of sediment distribution.The NPEDM is very easy to apply and can be used in any reservoir of any size.Extrapolation of the trend of sediment distribution obtained from the LRTM indicates an accurate short term prediction in a few reservoirs as causes of temporal and spatial variations of sediment distribution including the factors of uncertainties of sediment deposition are implicit within the methodology.     

Modeling preasymptotic transport in flows with significant inertial and trapping effects – The importance of velocity correlations and a spatial Markov model

We study solute transport in a periodic channel with a sinusoidal wavy boundary when inertial flow effects are sufficiently large to be important, but do not give rise to turbulence. This configuration and setup are known to result in large recirculation zones that can act as traps for solutes; these traps can significantly affect dispersion of the solute as it moves through the domain. Previous studies have considered the effect of inertia on asymptotic dispersion in such geometries. Here we develop an effective spatial Markov model that aims to describe transport all the way from preasymptotic to asymptotic times. In particular we demonstrate that correlation effects must be included in such an effective model when Péclet numbers are larger than O(100) in order to reliably predict observed breakthrough curves and the temporal evolution of second centered moments. For smaller Péclet numbers correlation effects, while present, are weak and do not appear to play a significant role. For many systems of practical interest, if Reynolds numbers are large, it may be typical that Péclet numbers are large also given that Schmidt numbers for typical fluids and solutes can vary between 1 and 500. This suggests that when Reynolds numbers are large, any effective theories of transport should incorporate correlation as part of the upscaling procedure, which many conventional approaches currently do not do. We define a novel parameter to quantify the importance of this correlation. Next, using the theory of CTRWs we explain a to date unexplained phenomenon of why dispersion coefficients for a fixed Péclet number increase with increasing Reynolds number, but saturate above a certain value. Finally we also demonstrate that effective preasymptotic models that do not adequately account for velocity correlations will also not predict asymptotic dispersion coefficients correctly.     

Trace elements in tree rings and their environmental effects: A case study in Xi’an City

Using wet digested method and ICP mass spectrometer, we analyzed the concentration of five trace elements (Cd, Mn, P, Zn and Pb) for the tree rings from both urban and suburbs of Xi’an. At the urban sampling site, one Chinese mahogany (Toona sinensis) disc and one phoenix tree (Firmiana simplex) disc were sampled from a steelworks in Xi’an City. At the suburb site, a Chinese mahogany disc was collected from a village in the south of the City. In addition, some soils near the roots of the sampled trees were ...     

Hillslope and point based soil erosion – an evaluation of a Landscape Evolution Model

Excessive soil erosion and deposition is recognised as a significant land degradation issue. Quantifying soil erosion and deposition is a non-trivial task. One of these methods has been the mathematical modelling of soil erosion and deposition patterns and the processes that drive them. Here we examine the capability of a landscape evolution model to predict both soil erosion rate and pattern of erosion and deposition. This numerical model (SIBERIA) uses a Digital Elevation Model (DEM) to represent the landscape and calculates erosion and deposition at each grid point in the DEM. To assess field soil redistribution rates (SRR) and patterns the distribution of the environmental tracer ¹³⁷Cs has been analysed. Net hill slope SRR predicted by SIBERIA (a soil loss rate of 1.7 to 4.3 t ha^-1 yr^-1) were found to be in good agreement with ¹³⁷Cs based estimates (2.1 – 3.4 t ha^-1 yr^-1) providing confidence in the predictive ability of the model at the hillslope scale. However some differences in predicted erosion/deposition patterns were noted due to historical changes in landscape form (i.e. the addition of a contour bank) and possible causes discussed, as is the finding that soil erosion rates are an order of magnitude higher than likely soil production rates. The finding that SIBERIA can approximate independently quantified erosion and deposition patterns and rates is encouraging, providing confidence in the employment of DEM based models to quantify hillslope erosion rates and demonstrating the potential to upscale for the prediction of whole catchment erosion and deposition. The findings of this study suggest that LEMs can be a reliable alternative to complex and time consuming methods such as that using environmental tracers for the determination of erosion rates. The model and approach demonstrates a new approach to assessing soil erosion that can be employed elsewhere. © 2018 John Wiley & Sons, Ltd.     

Origin of natural sulphur-bearing immiscible inclusions and H_2S in oolite gas reservoir, Eastern Sichuan

Fluid inclusions as captured in homogeneous fluids in rocks and minerals have been extensively studied and successfully applied to exploring the metalloge- netic temperature and pressure of metallic ore deposits and in investigating hydrocarbon generation, migra- tion, etc.[1―6]. In regard to multiple forms of immis- cible inclusions in rocks and minerals, a significant amount of research has already been conducted toward the immiscible inclusions and “boiling” inclusions in CO2-H2O system…     

Ionospheric quiet-day currents and their effects on the interpretation of upper mantle conductivity – A review

A review of ionospheric currents,the external part of geomagnetic solar quiet (Sq)variation and the internal part of the induced currentwithin the Earth, has been carried out.The theoretical background has been reviewed,and the method of analysis, specificallythe spherical harmonic analysis (SHA),is presented. Various works are reviewed andfully discussed. It has been noted that anew model of the Sq current system could beused to obtain a mantle electrical conductivityprofile for hemispheres. It is suggested thatfurther research work be carriedout in other hemispheres using similarmodels for more robust interpretations.     

Predicting the effects of sediment based internal nutrient loads on eutrophication in Kücükcekmece Lagoon for rehabilitation planning

In deep stratified coastal lagoons, hypoxic waters that result from phytoplankton decomposition in the stratified bottom waters are often associated with eutrophication. Decomposing biomass reaches the bottom sediments and enriches them with nutrients and organic matter. Nutrients trapped in sediments are released with time and promote excessive phytoplankton growth in the surface water. Because eutrophication in lentic ecosystems progresses in a self-fuelling cycle, outflow is the only available process for exporting excess nutrients to recover from eutrophication. Thus, rehabilitation of eutrophic coastal lagoons that have limited seawater interactions is a long term process. The importance of nutrient release from sediments on eutrophication and the delay effect of internal nutrient loading on the rehabilitation of a eutrophic coastal lagoon with limited seawater exchange were analysed in this study.An ecological model that couples the water column and the sediment diagenesis processes, was developed for water quality management purposes. Our findings indicate that the recovery of the Lagoon from eutrophication will be taken decades even in the absence of external nutrient loading. Therefore, we suggest applying rehabilitation strategies that control the nutrient fluxes from sediments for a faster recovery from heavily eutrophic conditions. Land-based nutrient sources must also be controlled because they feed water column and the bottom sediments with nutrients.     

The nutrient forms, cycling and exchange flux in the sediment and overlying water system in lakes from the middle and lower reaches of Yangtze River

This paper is a review of research works concerning the nutrient transportation, transformation and exchange between water, sediment and biota in the lakes from the middle and lower reaches of the Yangtze River conducted in the context of project entitled "The Processes and Mechanism of Lake Eutrophication in Middle and Lower Reaches of Yangtze River". All the lakes from this area are shallow lakes. According to the typical lake site research, the lakes from the middle and lower reaches of Yangtze River have a higher baseline of nutrition in the history. Normally the trophic status of these lakes can be categorized into medium-trophic or eutrophic. Human activities have been enhanced during the last decades, which speed up the lake eutrophic process. Lake eutrophication control needs to reduce not only the external nutrient inputs from watershed but also the internal loading from the sediments. Investigations revealed that the lake sediments in this area are considerablly high in nutrition in which at most about 30% of phosphorus exists in the form of bio-available in the sediment. The surface sediment will exert great effects on the nutrient exchange between water-sediment interface via adsorption and release of nutrient. The nutrient release from the sediment in these shallow lakes is mainly in two ways, i.e. in the undisturbed condition the nutrient is released through diffusion created by the nutrient gradient from sediment to overlying water; whereas in disturbed condition, the nutrient release is determined by the hydrodynamic forcing intensity and the sediment resuspension. Metallic elements such as the iron, manganese and aluminium and the aerobic-anaerobic ambience will affect the release of nutrients. The disturbed release will increase the total nutrients in the water column significantly in the short period. At the beginning of sediment resuspension, the dissolved nutrient concentration will increase. This increase will be damped if the ferric oxide and aluminium are rich in sediment because of the adsorption and flocculation. This means that the lakes have capability of eliminating the nutrient loadings. Investigations for the lakes from middle and down stream of Yangtze River have suggested that most lakes have the self-cleaning capability. Dredging the control of the internal loading, therefore, is only applicable to the small lakes or undisturbed bays which normally are situated nearby the city or town and rich in organic materials in the sediment. In addition, the strong reduction condition and weak aeration of these lakes and bays make these small lakes and bays release much more bio-available nutrient and without much self-eliminating capability. Moreover, eutrophication induced algal bloom in these lakes will change the pH of water, which further induces the increase in the nutrient release. In turn, the increase in nutrient release promotes the growth of phytoplankton and results in severe algal bloom. For the heavily polluted water, research suggests that the biomass of bacteria and alkaline phosphatase activity will be higher corresponding to the higher concentration of nutrients, which accelerates the nutrient recycling between water, sediment and biota. Quick recycling of nutrient, in turn, promotes the production and biomass growth of microorganism and leads to more severe eutrophication. Further research work should focus on the nutrient transformation mechanism and the effects of microbial loop on the eutrophication.     

Spatiotemporal dynamics of water sources in a mountain river basin inferred through δ2H and δ18O of water

In mountainous river basins of the Pacific Northwest, climate models predict that winter warming will result in increased precipitation falling as rain and decreased snowpack. A detailed understanding of the spatial and temporal dynamics of water sources across river networks will help illuminate climate change impacts on river flow regimes. Because the stable isotopic composition of precipitation varies geographically, variation in surface water isotope ratios indicates the volume-weighted integration of upstream source water. We measured the stable isotope ratios of surface water samples collected in the Snoqualmie River basin in western Washington over June and September 2017 and the 2018 water year. We used ordinary least squares regression and geostatistical Spatial Stream Network models to relate surface water isotope ratios to mean watershed elevation (MWE) across seasons. Geologic and discharge data was integrated with water isotopes to create a conceptual model of streamflow generation for the Snoqualmie River. We found that surface water stable isotope ratios were lowest in the spring and highest in the dry, Mediterranean summer, but related strongly to MWE throughout the year. Low isotope ratios in spring reflect the input of snowmelt into high elevation tributaries. High summer isotope ratios suggest that groundwater is sourced from low elevation areas and recharged by winter precipitation. Overall, our results suggest that baseflow in the Snoqualmie River may be relatively resilient to predicted warming and subsequent changes to snowpack in the Pacific Northwest.