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1.
本文研究了PAN-S铋的显色反应。配合物的最大吸收峰位于546nm处,表现摩尔吸光系数为1.20×14 ̄4L·mol ̄(-1)·cm ̄(-1),铋量ρ(Bi)/(μg·ml ̄(-1))在0-2.4范围内符合比尔定律,采用疏基棉分离常见干扰离子富集铋,使选择性和灵敏度显著提高,方法用于水及矿石中铋的测定,结果满意。  相似文献   

2.
2-[(5-溴-2-吡啶)偶氮]5-二乙氨基苯酚(简称5-Br-PADAP)是一种高灵敏度显色剂,它与Nb(V)、酒石酸形成蓝色的三元络合物。其最大吸收峰为610nm,表观摩尔吸光系数为5.9×10 ̄4L·mol ̄(-1)·cm ̄(-1),络合物在25ml溶液中,ρ(Nb_2O_5)/(μg·ml ̄(-1))为0-1.6符合比尔定律。络合物可稳定24h以上。以EDTA-Ca消除共存离子的干扰,本法的选择性较好,准确度高,且简便、快速。适用于各种岩矿中微量Nb的测定。  相似文献   

3.
本文研究了在非离子表面活性剂Tritonx-100存在的情况下,邻氯苯基荧光酮(O-Cl-PF)与钛的显色反应。试验表明,在0.10~0.14mol·L ̄(-1)H_2SO_4介质中,O-Cl-PF与钛形成灵敏度极高的红紫色配合物,其最大吸收峰位于540nm处,表现摩尔吸光系数为1.8×10 ̄5L·mol ̄(-1)·cm ̄(-1),钛含量在0~3μg/25ml范围内服从比尔定律。该方法用样少,操作简便,灵敏度高,选择性好,适于测定地质样品中的微量钛。  相似文献   

4.
本文研究了PAN-S与锰的显色反应。配合物的最大吸收峰位于538nm波长处,表观摩尔吸光系数为2.9×10 ̄4L·mol ̄(-1)·cm ̄(-1),锰量在0─1.6μg/ml范围内符合比尔定律,方法用于水和河泥中微量锰的测定,结果良好。  相似文献   

5.
研究了用钼酸铵浸渍处理石墨管、石墨炉原子吸比法测定镓、铟和铊的最挂条件。实验证明,采用硝酸—氢氟酸—硫酸体系溶解样品,涂钼石墨管直接测定样品中的镓、铟和铊,能有效地避免它们在原子化之前以氧化物形式挥发的损失,减少了测定干扰,提高测定的灵敏度。对6个地质标样的测定结果是满意的。木法对镓、铟和铊的检测下限分别为0.9×10 ̄(-11)g,1.7×10 ̄(-11)g和6.2×10 ̄(-11)g;相对标准偏差分别为1.4%、4.8%和3.0%。  相似文献   

6.
何秋玲  蔡苗 《矿物岩石》1995,15(2):90-92
本文研究了微晶萘吸附Pb(Ⅱ)—5—Br—PADAP显色新体系的最佳实验条件。沉定分离洗涤后溶解于丙酮,在波长560nm处测定其吸收光度。在5ml丙酮溶液中铅含量p(Pb)/( μg·ml ̄-1)在0—5范围内符合比尔定律,表现在尔吸光系数为5.6×l0 ̄4L·mol ̄1·cm ̄-1。方法用于水中痕量铅的测定,结果满意。  相似文献   

7.
5‘—硝基水杨基荧光酮与锆显色反应及其应用   总被引:8,自引:0,他引:8  
付佩玉  王正祥 《岩矿测试》1997,16(3):238-240
在0.08 ̄0.10mol/L HCl介质中,溴化十六烷基三甲铵(CTMAB)存在下,Zr(Ⅳ)与5'-硝基水杨基荧光酮(5'-NSF)发生显色反应,形成1:4的桔红色络合物,λmax=540nm,ε为1.46×10^5L·mol^-1·cm^-1,Zr(Ⅳ)含量在0 ̄0.5mg/L符合比尔定律。方法用于氧化铝及陶瓷釉料中锆的测定,结果与ICP-AES法相符,RSD(n=5)在1.3% ̄3.7%。  相似文献   

8.
樊学忠  朱春华 《岩矿测试》1997,16(3):217-220
在十二烷基硫酸钠存在下,于pH4.8 ̄7.4的缓冲溶液中,2-〔2-(6-甲基苯并噻唑)偶氮〕-5-二乙氨基苯甲酸(6-Me-BTAEB)与Co(Ⅱ)发生显色反应,形成稳定的蓝紫色络合物,其组成为nCo(Ⅱ):n6-Me-BTAEB=1:2,最大吸收波长为650nm,ε为1.38×10^5L·mol^-1·cm^-1,Co(Ⅱ)质量浓度在0 ̄0.32mg/L时服从比尔定律。方法可直接用于维生素B1  相似文献   

9.
对碘偶氮氯膦与铅显色反应及其应用   总被引:2,自引:0,他引:2  
杨敏思  王曙  陈刚莲 《岩矿测试》1995,14(4):292-294
研究了对碘偶氮氯膦(CPA-pI)与Pb ̄2+的显色反应。在pH5.8的(CH_2)_6N。-NO_3缓冲介质中,Pb ̄2+与CPA-pl形成1:2的蓝绿色配合物,在675nm处测定配合物的吸光度,其表现摩尔吸光系数为2.47×10 ̄4L.mol ̄-1·cm ̄-1Pb ̄2+浓度在0~1.16×10 ̄-5mol/L即0~2.4μml)符合比尔定律。试验了20余种共存离子的影响,经共沉淀结合巯基棉分离预处理试样溶液后,测定了硫精砂中微量Pb的含量。  相似文献   

10.
冯泳兰 《岩矿测试》1999,18(4):311-313
研究了新合成的1-(2-羟基-3,5-二硝基苯基)-3-「4-(苯基偶氮)苯基」-三氮烯(HDNPAPT)试剂与铜的显色反应。在乳化剂OP存在下,PH11.0的Na2B4O7-NaOH介质中,铜与HDNPAPT形成的红色配合物,其组成比为1:2,λmax=540nm,表观摩尔吸光系数ε540=1.73×10^5L·mol^-1·cm^-1,铜的质量浓度在0 ̄360μg/L符合比尔定律。方法应用于大  相似文献   

11.
Pant-y-ffynnon Quarry in South Wales yielded a rich cache of fossils in the early 1950s, including articulated specimens of new species (the small sauropodomorph dinosaur Pantydraco caducus and the crocodylomorph Terrestrisuchus gracilis), but no substantial study of the wider fauna of the Pant-y-ffynnon fissure systems has been published. Here, our overview of existing specimens, a few described but mostly undescribed, as well as freshly processed material, provides a comprehensive picture of the Pant-y-ffynnon palaeo-island of the Late Triassic. This was an island with a relatively impoverished fauna dominated by small clevosaurs (rhynchocephalians), including a new species, Clevosaurus cambrica, described here from a partially articulated specimen and isolated bones. The new species has a dental morphology that is intermediate between the Late Triassic Clevosaurus hudsoni, from Cromhall Quarry to the east, and the younger C. convallis from Pant Quarry to the west, suggesting adaptive radiation of clevosaurs in the palaeo-archipelago. The larger reptiles on the palaeo-island do not exceed 1.5?m in length, including a small carnivorous crocodylomorph, Terrestrisuchus, and a possible example of insular dwarfism in the basal dinosaur Pantydraco.  相似文献   

12.
Robert L. Linnen   《Lithos》2005,80(1-4):267-280
The solubilities of columbite, tantalite, wolframite, rutile, zircon and hafnon were determined as a function of the water contents in peralkaline and subaluminous granite melts. All experiments were conducted at 1035 °C and 2 kbar and the water contents of the melts ranged from nominally dry to approximately 6 wt.% H2O. Accessory phase solubilities are not affected by the water content of the peralkaline melt. By contrast, solubilities are affected by the water content of the subaluminous melt, where the solubilities of all the accessory phases examined increase with the water content of the melt, up to 2 wt.% H2O. At higher water contents, solubilities are nearly constant. It can be concluded that water is not an important control of accessory phase solubility, although the water content will affect diffusivities of components in the melt, thus whether or not accessory phases will be present as restite material. The solubility behaviour in the subaluminous and peralkaline melts supports previous spectroscopic studies, which have observed differences in the coordination of high field strength elements in dry vs. wet subaluminous granitic glasses, but not for peralkaline granitic glasses. Lastly, the fact that wolframite solubility increases with increasing water content in the subaluminous melt suggests that tungsten dissolved as a hexavalent species.  相似文献   

13.
Calcite samples were extracted both from the rock matrix and the superficial coating of a karstified fault plane of an underground quarry, located in the eastern border of the Paris basin. The karstification is dated as Quaternary. Analysis of mechanical calcite twinning reveals that only the calcite matrix has also undergone a compression trending WNW that can be attributed to the Mio-Pliocene alpine collision. Both coating and matrix have undergone a strike-slip regime with σ1 roughly trending north–south, that could correspond to the regional present-day state of stress, a strike-slip compression rather trending NNW, modified by local phenomena. To cite this article: M. Rocher et al., C. R. Geoscience 335 (2003).  相似文献   

14.
HYDROGEOLOGY     
正20141756 Chen Ruige(Mathematical College,China University of Geosciences,Beijing100083,China);Zhou Xun Numerical Simulation of Groundwater Level Fluctuation in a Coastal Confined Aquifer with Sloping Initial Groundwater Level Induced by the Tide(Geological Bulletin of China,ISSN1671-2552,CN11-4648/P,32(7),2013,p.1099-1104,6 illus.,16 refs.) Key words:confined water,groundwater level  相似文献   

15.
正20141408 Cai Jia(Institute of Geology,Chinese Academy of Geological Sciences,Beijing100037,China);Liu Fulai Petrogenesis and Metamorphic P-T Conditions of Garnet-Spinel-Biotitebearing Paragneiss in Danangou Area,Daqingshan-Wulashan Metamorphic Complex Belt(Acta Petrologica Sinica,ISSN1000-0569,CN11-1922/P,29(7),  相似文献   

16.
17.
正20142386An Guoying(China Aero Geophysical Survey and Remote Sensing Center for Land and Resources,Beijing 100083,China)Application of Satellite Remote Sensing in Regional Hydrogeological Investigation:Taking Cenozoic Strata in Wenquan Sheet(1∶250 000)of Karakoram Range as an Example(Geosci-  相似文献   

18.
正20141016An Chengbang(Key Laboratory of Western China’s Environmental Systems,Ministry of Education,Lanzhou University,Lanzhou 730000,China);Zhao Yongtao Lake Records during the Last Glacial Maximum from Xinjiang,NW China and Their Climatic Impli-  相似文献   

19.
正20141538 Cao Qing(School of Earth Sciences and Engineering,Xi’an Petroleum University,Xi’an 710065,China);Zhao Jingzhou Characteristics and Significance of Fluid Inclusions from Majiagou Formation,Yichuan Huangling Area,Ordos Basin(Advances in Earth Science,ISSN1001-8166,CN62-1091/P,28(7),2013,p.819-828,7 illus.,3 tables,43 refs.)  相似文献   

20.
GEOCHEMISTRY     
正20142002 Wei Hualing(Institute of Geophysical and Geochemical Exploration,Chinese Academy of Geological Sciences,Langfang065000,China);Zhou Guohua Element Content and Mineral Compositions in Different Sizes of Soil in Tongling Area,Anhui Province(Geological Bulletin of China,ISSN1671-2552,CN11-4648/P,32(11),2013,p.1861  相似文献   

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