Zircon U-Pb dating of intermediate-acid intrusive rocks in the middle section of Ningzhen district and their metallogenic implicationsEI北大核心CSCD

The Ningzhen metallogenic district is an important part of the Middle-Lower Yangtze River Valley metallogenic belt. LA-ICP-MS zircon U-Pb dating of the three intermediate-acid intrusions, i.e., Anjishan, Xinqiao, and Shima, in the central part of the Ningzhen district, indicates that those intrusions were emplaced in the Late Early Cretaceous, with ages of 107.0±1.1 Ma-108.0±1.6 Ma, 108.0±1.3 Ma, and 102.5±1.1 Ma, respectively. Combined with the molybdenite Re-Os isotope age (106-108 Ma) of porphyry copper deposit in this regions, the Ningzhen district exists an intensively magmatic-metallogenic-thermal event at 102.5-108.0 Ma. The age of this event is similar with the age of the third period of large scale mineralization in South China, however obviously later than the magmatic activity of other ore field (124-148 Ma) in the Middle-Lower Yangtze River Valley metallogenic belt. It is suggested that the tectonic-magmatic-thermal events in the Ningzhen area is formed under regional lithospheric extension environment, which is also consistent with the tectonic background of the third period of large scale mineralization in South China. The zircon U-Pb ages of the intrusions and the Re-Os ages of molybdenites from the porphyry deposits in the study area demonstrate that the Ningzhen district underwent intensive magmatism and hydrothermal mineralization during the period from 102.5 to 108.0 Ma, which is consistent with the third pulse of large scale mineralization in the South China. ©, 2015, Science Press. All right reserved.     

Lower Paleozoic detrital zircon U-Pb geochronological characteristics of the Baoshan Block in western Yunnan and its constraints on the Proto-Tethys tectonic evolutionSCIEI北大核心CSCD

滇西保山地块是东特提斯构造域的主要微陆块之一,但对其物源和古地理位置仍存在较大争议。本文通过对保山地块西缘早古生代地层进行碎屑锆石U-Pb定年来约束其物源及古地理位置,并进一步探讨原特提斯洋早古生代构造演化模式。保山地块西缘早古生代地层具有相似的年龄分布模式,主年龄峰期为-0.95Ga、次级年龄峰期为-1.2Ga和-2.5Ga。寒武系公养河群最小锆石年龄为526Ma,结合其上部年龄为499.2Ma的火山岩夹层,约束其沉积时代为早寒武世早期。对比保山地块不同区域早古生代地层的碎屑锆石年龄数据,它们都具有相似的锆石年龄分布模式和年龄峰值。-0.95Ga主年龄峰期和-2.5Ga的次级年龄峰期指示保山地块早古生代的沉积物主要来自于印度大陆,而-1.2Ga的次级年龄峰期表明有部分沉积物来自于西澳大利亚,其早古生代古地理位置位于印度和西澳大利亚之间。结合沉积学证据及滇西地区广泛发育的早古生代岩浆作用,本文认为早古生代冈瓦纳大陆北缘为活动大陆边缘。     

The Permian mafic intrusive events in the northwestern margin of the Tarim Basin and their tectonic significanceSCIEI北大核心CSCD

塔里木大火成岩省是我国境内发现的两个重要的二叠纪大火成省之一,不仅有大规模的溢流相玄武岩喷发,还有复杂多样的侵入岩及其组合。以往的研究主要集中在二叠系等显生宙地层发育区,对于前寒武系等古老层系中是否存在二叠纪岩浆侵入未引起重视。本文通过野外地质调查,在阿克苏地区前寒武系中识别出数条侵入南华系的基性岩墙和较大规模侵入震旦系的基性岩床。岩墙、岩床与围岩之间均显示出典型的侵入接触关系,包括岩体内部结晶粗、边部结晶细的淬冷边结构、岩床顶底面显著的切层现象以及包裹围岩团块等;显微镜下观察表明,辉绿岩具有典型的辉绿结构和嵌晶含长结构。锆石U-Pb年代学结果表明,侵入下震旦统的辉绿岩岩床和侵入南华系的辉绿岩岩墙的侵位时代在误差范围内基本一致,约为290Ma。岩石地球化学特征表明,辉绿岩岩床具有与洋岛玄武岩(OIB)相似的稀土及微量元素配分模式,结合Sr-Nb-Pb同位素测试结果,认为它们来源于碳酸盐化的富集型岩石圈地幔部分熔融,而辉绿岩岩墙具有Nb、Ta、Zr、Hf等负异常的地球化学特征,可能来自曾被俯冲相关流体/熔体交代的岩石圈地幔源区。本文的早二叠世辉绿岩岩床和岩墙的形成时代、岩浆源区和岩浆演化...     

Provenance and tectonic setting of the Gudongjing Group in Beishan OrogenSCIEI北大核心CSCD

增生造山带中陆源碎屑岩物源区特征的研究可为解剖造山带结构甚至大陆地壳的形成和演化提供关键证据。北山造山带中部的古硐井群被认为是前寒武纪稳定沉积盖层,是北山造山带存在微陆块的重要依据。本文围绕古硐井群的物源区特征,进行了碎屑颗粒和重矿物统计、全岩主微量元素地球化学分析、碎屑锆石U-Pb年代学和Hf同位素测试。古硐井群碎屑岩的碎屑颗粒多呈棱角状,主要为石英、长石,同时含大量硅质岩碎屑和一定数量的火山岩碎屑;重矿物组成以褐铁矿、锆石、白钛石、尖晶石为主,角闪石、电气石、辉石次之,暗示物源区可能存在蛇绿岩、增生杂岩。全岩主量元素以高硅、高铝、富碱、低锰为特征,结合REE、Cr、Co、Sc和Th等惰性元素含量特征共同指示了长英质的物源区。最年轻的碎屑锆石年龄为443.9±13Ma,表明古硐井群最大沉积时限为晚奥陶世。碎屑锆石的年龄高度集中于470Ma附近,且该区间锆石ε_Hf(t)值多为正值,指示物源区存在大量新生地壳物质。本文推测古硐井群可能形成于增生楔楔顶盆地;研究结果支持北山造山带是古生代持续增生造山的产物这一认识。     

Morphotectonics and tectonic processes of the Southwest Indian OceanEI北大核心CSCD

The Southwest Indian mid-ocean ridge (SWIR) is an ultraslow spreading ridge. Based on the submarine bathymetric data, we develop a new division principle on submarine morphotectonics and subdivide the SWIR into the seven-order tectonic geomorphologic units. Taking its submarine morphotectonics in the middle segment and adjacent seafloors of the mid-ocean ridge between Discovery II and Gallieni transform faults as a sample, this paper systematically analyzes its tectonic evolution, segmentation, segmentation and propagation mechanism, the formation of the central rift valley, the ridge-plume interactions, and the ocean ridge jumping. The results showed that the mid-ocean ridges can be divided into four three-order morphotectonics units (i.e., one-order segments of mid-ocean ridge), from west to east, which are separated by the Andrew Bain, the Prince Edwards, the Discovery II, and the Gallieni transform faults, respectively, corresponding to ridge landforms associated with a strongly hotspot-affected ridge, a weakly hotspot-affected ridge, and a normal ultraslow spreading ridge. Each segment can be further subdivided into three or four secondary segments. This paper focuses only on the segmentation and division from fourth-order to seventh-order morphotectonics units between the Discovery II and the Gallieni transform faults (i.e., the fourth-order morphotectonics unit of mid-ocean ridges can be subdivided into other three secondary units). Here the seventh-order morphotectonics unit consists of segments of laterally-aligned rifts (shear zone), en echelon rifts, and other transverse-faulting structures. The mid-ocean ridge segment experienced three oceanic ridge jumping at about 80 Ma, 60 Ma and 40 Ma, respectively, which were affected by the Marion and Crozet hotspots, or the Madagascar Plateau, etc. The oceanic processes of the SWIR are related to the Gondwana breakup, and its tectonic processes has been analyzed in detail as the periodic pull-apart extension, domino-style half-graben, graben subsidence, oceanic core complex, etc. in axial mid-oceanic ridge since 20 Ma. ©, 2015, Science Press. All right reserved.     

Geochemical characteristics and LA-ICP-MS zircon U-Pb age of the Lanhualing granite in Ningguo,Anhui ProvinceEI北大核心CSCD

The Lanhualing tungsten-molybdenum deposit is a skarn-type deposit located in Ningguo county, Anhui province. This deposit is mainly hosted in the Yinzhubu Formation and the Yanwashan Formation of Ordovician, and genetically related to the Lanhualing granite. The Lanhualing granite belongs to high-K calc-alkaline series with high alkali (Na2O+K2O=4.00%-7.03%), SiO2 (67.87%-74.92%) and MgO (0.62%-1.23%) contents. The granitic rocks show right-dipping chondrite normalized REE patterns with weak δEu anomalies. The granitic rocks are relatively enriched in large ion lithophile elements (LILE) and depleted in high field strength elements (HFSE). The ore-bearing granite was dated at 148.17±0.94 Ma by LA-ICP-MS zircon U-Pb method. The late Yanshanian is the main tungsten mineralization epoch in the South Anhui-north Jiangxi area; and indeed, the Dongyuan, Zhuxi, Yangchuling, Dahutang and other large and super-large tungsten deposits were formed in this period. Geochemical Characteristics of the Lanhualing granite indicate a crustal source but with mantle input under tectonic regime of compression thickening. ©, 2015, Science Press. All right reserved.     

Geochemical characteristics and petrogenesis of the Dashipo-Heishantuo batholith in Beijing and its geological significanceEI北大核心CSCD

The early Jurassic Dashipo-Heishantuo batholith in Beijing, which consists of the Dashipo hornblende-biotite syenite and Heishantuo granite, exposed in the western Yanshan orogenic belt, eastern North China Craton. The Dashipo syenite is magnesian potassic intermediate rock enriched in large ion lithophile elements such as Rb, Ba, Sr, Pb and LREE, and relatively depleted in high field strength elements such as Nb, Ta, U, Th, Zr, Hf as well as P and Ti, with εNd(t) values from -12.1 to -12.2 and ISr values of 0.70506-0.70464. The Heishantuo granite is magnesian peraluminous high K calc-alkaline, with an enrichment of large ion lithophile elements and radioactive elements such as Rb, Ba, Th, U and Pb, and a depletion of HREE and high field strength elements such as Nb, Ta, Zr and Hf as well as Sr, P and Ti, with εNd(t) values from -15.5 to -18.0 and ISr values of 0.70516-0.70593. The magma of the Dashipo syenite is produced by fractional crystallization of mantle-derived K-rich mafic magma under high pressure. The partial melting of the lower crust, which was heated and metasomatised by the mantle-derived magma, produced granitic magma that intruded into the unconsolidated Dashipo syenite to form the concentric batholith. The petrology and geochemistry of the Dashipo hornblende-biotite syenite indicate that the water weakening was important for the lithospheric destruction within the interior part of the North China Craton. Meanwhile, the partial melting related to the double-diffusion of energy and chemical composition between mantle-derived magma and crustal rocks was an important mechanism for the Mesozoic calc-alkaline felsic magmatism occurred in the interior of the North China Craton. ©, 2015, Science Press. All right reserved.     

Zircon U-Pb geochronology of Early Jurassic-Late cretaceous volcanic rocks in North Yellow Sea BasinEI北大核心CSCD

The X-drilling cores of the North Yellow Sea basin reveal two sets of Mesozoic clastic rocks, which are the dark rocks in lower part and the red rocks in upper part, respectively. There are two layers of volcanic rocks at the bottom and the upper part of the dark rock unit. The volcanic rocks at the bottom part are trachytic dacite while rocks at the upper part are clastic dacite. The zircon grains from the upper and lower units of volcanic rocks are euhedral-subhedral columnar crystals and show oscillatory zoning on cathodoluminescence images. 22 tests of zircons in the trachytic dacite from the bottom part yield an age of 141-151 Ma, with weighted mean 206Pb/238U age of 145±2 Ma. Whereas 18 tests of zircons from the sample at the upper part give 206Pb/238U ages around 139-149 Ma with weighted mean 206Pb/238U age of 141±2 Ma, which implies that the X well volcanic rocks belong to Late Jurassic-Early Cretaceous. Comparing with the age and geochemical characteristics of the Mesozoic igneous rocks in Shandong peninsula, we suggest that the igneous rocks from both the North Yellow Sea basin and Jiaolai basin were formed under same dynamic setting, i.e., the subduction related volcano arc and back-arc extension. ©, 2015, Science Press. All right reserved.     

Comparative study on the geochemical characteristics of rare earth elements in deep-sea sediments from different regions of the Pacific OceanSCIEI北大核心CSCD

太平洋深海沉积物中富集稀土元素(REY,包括钇),被认为是富有潜力的新型稀土资源。(含)沸石粘土、深海粘土和多金属软泥是主要的富含REY的沉积物类型,其中(含)沸石粘土和深海粘土在中、西北太平洋海盆大面积分布,而多金属软泥则多分布于靠近东太平洋洋脊热液活动的深海盆地中。目前关于中、西北太平洋海盆的深海粘土和(含)沸石粘土已有较多的研究,但关于多金属软泥中REY的研究较少。不同区域、不同类型深海沉积物中的稀土元素赋存状态有何差异?影响稀土富集的机制又是什么目前尚不清楚,也就进一步影响了对深海沉积物稀土资源的勘查和开发工作。本文分析对比了太平洋不同区域不同类型深海沉积物的地球化学特征及矿物学特征。结果表明,总体上,中、西北太平洋海盆深海沉积物中,尤其是(含)沸石粘土中的REY含量明显高于东太平洋海盆多金属软泥REY含量,其REY的富集主要与磷酸盐有关。超常富集REY(∑REY>2000×10^(-6))的沉积物中的CaO/P_(2)O_(5)比值趋向于一致(~1.4),几乎接近于磷灰石CaO/P2O5比值(~1.3),因此REY主要赋存载体为磷灰石,该区沉积物中REY的富集可能受到磷酸盐化的影响;东太平洋海盆多金属软泥明显受到热液影响,铁和锰的含量明显增加,但其∑REY含量集中于500×10^(-6)~800×10^(-6),不随铁和锰的增加而变化,REY的富集仍与磷酸盐关系密切,而与铁锰物质和铝硅酸盐关系不大。中、西北太平洋海盆富稀土的深海沉积物形成时处于较强的氧化环境,同时又有充足的含磷物质补给,才造成REY在该区沉积物中的超常富集;而东太平洋海盆多金属软泥虽然处于氧化环境,但缺少足够的磷补给,所以其∑REY含量通常低于中、西北太平洋海盆沸石粘土中∑REY含量。     

Zircon U-Pb Geochronology,Geochemistry and Petrogenesis of Early Cretaceous A-type Granites in the Mikengshan Area,Southern Jiangxi ProvinceEI北大核心CSCD

In the Mikengshan-Yanbei area, a special region for the tin mineralization in South China, there are some Yanshanian granites and porphyries and associated porphyry tin deposits (e.g., Yanbei). Although the tin mineralization is closely associated with the granitoids magmatism, the age and petrogenesis of the granites remain controversial. The Mikengshan pluton, which intrudes into the rhyolitic tuff and pyroclastic rocks of the Upper Jurassic Jilongzhang Formation, is the largest one in Mikengshan-Yanbei area and mainly consists of K-feldspar bearing granites. In this study, we report new age and geochemical data for the Mikengshan K-feldspar bearing granites. LA-ICP-MS zircon U-Pb age dating shows that they were generated in the Early Cretaceous (~138 Ma). They have high SiO2 (74.42% to 76.69%), low Al2O3 (12.39% to 13.49%) and Mg# (11 to 19), and negative Eu, Sr and Ba anomalies, and are rich in potassium (most K2O/Na2O=1.37 to 1.94) and high field strength elements (HFSEs), and are weakly peraluminous (A/CNK=1.03 to 1.1) with high 10000×Ga/Al ratios (3.46 to 4.96) and slightly high zircon saturation temperatures (807 ℃ to 817 ℃), showing the characteristics of the typical A-type granites. Moreover, they have high Rb contents 842×10-6 to 1295×10-6, Rb/Sr (90 to 255) ratios and show rare earth elements (REE) tetrad effect, which are similar to those of high fractionated granites. Thus, we suggested that the Mikengshan K-feldspar bearing granites are high fractionated and aluminous A-type granite. Their slightly high εNd(t) values (-3.4 to -4.6) indicate that the mantle components should have played a role during their formation. Taking into account regional igneous rocks and tectonic setting data, we suggest that the Mikengshan K-bearing granites were formed in an extensional setting, which was probably related to the roll-back of the subducted Paleo-Pacific plate. © 2018, Science Press. All right reserved.     

Pre-Cenozoic tectonic attribute and setting of the Song Da zone,VietnamEI北大核心CSCD

Rock association and regional unconformity are identified based on field survey and mapping for the stratigraphy, tectonics, metamorphic rock and igneous rocks in the Song Da zone, the northwestern Vietnam. Pre-Cenozoic in the Song Da zone is divided into three structural layers: (1) the Presinian crystalline basement, (2) the Cambrian-lower part of Upper Triassic, and (3) the upper part of Upper Triassic-Cretaceous. The Pre-Cenozoic structural successions of the Song Da zone show similar features with those of the Yangtze-South China plate: (1) In the Presinian, both of them have TTG complex and Khondalite series of similar ages and experienced similar tectonic evolution; (2) In the Cambrian-early Upper Triassic, the phosphorite and thick-layered limestone are comparable, and the Permian-Triassic basalt in the Song Da zone has genetic mechanism similar to that of the Emeishan basalt; (3) In the late Upper Triassic-Cretaceous, the volcanic-sedimentary faulted basins and thick continental red beds are comparable to those in East China. It can be concluded that the Song Da zone should have been part of the southwestern Yangtze-South China plate, and the boundary between the Yangtze-South China plate and Indochina plate is the Song Ma suture zone which contains ophiolite remnants. Tectonic settings of different structural layers indicate that the Song Da Zone experienced geological events such as the Columbia and Rodinia Supercontinent, sedimentation of the stable platform cover, closure of the Paleo-Tethys, and NW subduction of the Paleo-Pacific plate to the Eurasian plate. The Pre-Cenozoic basement of the Yinggehai Basin is the seaward extension of the Song Da zone, which shows similar tectonic features.     

Paleozoic sedimentary processes and magmatism in Zamenwude area,Mongolia, and their implications for tectonic evolution of the Xingmeng orogenic beltSCIEI北大核心CSCD

兴蒙造山带属于中亚造山带的东段,关于其演化过程存在两种主要观点:一种观点认为它是由古亚洲洋经历整个古生代的连续俯冲-碰撞过程后在早三叠世形成;另一种观点则认为古亚洲洋在晚泥盆世之前就通过俯冲-碰撞过程闭合,形成早-中古生代造山带,随后在石炭-二叠纪又经历了从陆内伸展到再次闭合的过程,并形成陆内造山带。蒙古国东南部扎门乌德地区出露各类古生代沉积岩和岩浆岩,可以为解决上述争议提供典型研究实例。本文通过沉积学、年代学和地球化学等多种手段综合研究,取得以下研究成果:(1)根据年代学和岩性特征,在该地区识别出三类古生代岩石组合,第一类是以黑云母二长花岗岩为代表的中志留世侵入岩,第二类是中泥盆世大套的粗碎屑岩-火山岩沉积旋回,第三类是不整合地沉积于早期造山带之上的二叠纪巨厚火山-沉积岩系。这三类岩石组合分别属于俯冲阶段的大陆边缘岛弧带岩浆岩、碰撞造山后期的上叠盆地以及叠加在早期造山带岩石圈之上的晚古生代陆内伸展时期的裂谷盆地的沉积。(2)利用研究区所有古生代碎屑锆石和岩浆岩全岩资料,揭示了该地区古生代时期地壳厚度变化趋势如下:500~425Ma的俯冲-碰撞过程造成地壳加厚;425~375Ma的碰撞造山后伸展过程使地壳变薄;375~350Ma地壳再次加厚,可能与造山带物质堆叠有关;350~275Ma地壳再次减薄,对应于广泛而强烈的晚石炭世-早二叠世火山岩,证明此时期岩浆活动的构造背景是区域伸展而不是挤压作用。(3)根据研究区出现的三类岩石组合特点,结合研究区以南的艾力格庙地区已有的研究成果,可以划分出五个早-中古生代造山带构造单元和两个叠加其上的晚古生代陆内造山带构造单元,揭示蒙古国扎门乌德地区经历了早-中古生代加积造山带和晚古生代陆内造山带等两个构造演化过程。本文研究为认识兴蒙造山带的两阶段构造发展提供了新资料。     

Geochronology of anorthite-garnetite in Caozhuang Group of eastern Hebei and its geological significanceSCIEI北大核心CSCD

位于华北克拉通的冀东曹庄群是中国最古老的变质火山-沉积岩系,由于后期多次强烈的岩浆-构造事件影响,使得曹庄群的原始产状和原岩特征被强烈改造,导致对曹庄群的认识不清。精细刻画后期地质事件、评估其对原岩改造程度,是解决争议的基础。前人报导曹庄群发育有钙长石-钙榴石岩。本工作继续对该岩性开展地质学、岩相学、地球化学和U-Pb年代学研究,查明斜长石中的钙长石端元比例≥90%、石榴子石属铁铝榴石(14~31)-钙铝榴石(23~47)-钙铁榴石(23~61)固溶体、绿帘石将石榴子石和斜长石两种矿物分隔而开。钙铝-钙铁榴石为均质、全消光、无成分环带、无异常光性特征,亏损轻稀土(LREEs)、富集中稀土(MREEs)、略亏损重稀土(HREEs)、具Eu的负异常,地球化学特征显示钙铝-钙铁榴石是在稳定、封闭,由一期/阶段热液流体,在W/R(水/岩)比值较低的情况下,通过扩散交代作用缓慢结晶而成,并非前人所认为的区域变质作用成因。利用钙质榴石的地球化学特征,进一步反演交代流体的物化性质为弱氧化、中性-弱碱性、富Ca^(2+)、富Cl^(-)、温度在250~500℃。通过钙铝-钙铁榴石原位LA-ICP-MS U-Pb年代学工作,得到不一致曲线的上交点年龄为2529±35Ma(MSWD=1.4,n=35),作为其形成年龄,并与共生热液锆石的SIMS U-Pb年龄在误差范围内一致,推测该期流体交代作用发生于~2530Ma,与研究区内新太古代末(~2.5Ga)经历的区域性麻粒岩相-角闪岩相变质作用时代相近。综合前人工作,初步推断此次交代作用对曹庄群部分岩石Sm-Nd体系的改造程度大于近同时发生的区域变质作用。     

New Zircon U-Pb Ages of the Granodiorites in the Southern Great Xing’an Range and their Tectonic Implications

The Southern Great Xing'an Range,Northeast China,is located in the eastern part of the Central Asian Orogenic Belt.It is considered to be one of the most important metallogenic belts,commonly hosting a series of skarn.porphyry and magmatic hydrothermal Pb-Zn-Ag-Cu Mo-Sn polymetallic deposits(Fig.1).Complex tectonic events have occurred in this region,including the closure of the Palco-Asian Ocean in the Late Palaeozoic,the opening and closure of the Mongol Okhotsk Ocean and the subduction of the Paleo-Pacific Ocean in the Mesozoic.     

Basin-range coupling structure and deformation features of the eastern cenozoic foreland basin in SW TarimEI北大核心CSCD

The Cenozoic foreland basin at the southwestern Tarim basin was inflicted by both N-S compression of the west Kunlun orogen and northward indentation of the Pamir, which led to significant variations in structural architecture and deformation style. New results from interpretations of seismic profiles in the east segment of the basin are presented here to discuss such spatial variation in structural deformation and temporal variation in structural evolution. The results suggest that the segment commonly exhibits significant northward thrusting, coupled with flexural basin subsidence. Broad fold-and-thrust belt (FTB) is evidenced in the profiles with its front reaching Jiede anticline, resulting in a structural architecture of superposition of the FTB and foredeep of the flexural basin. In the vertical view, the segment is featured by basement-involved deformation belt overlain by detachment deformation belt. The first row of the deformation belt presents spatial variation in structure. The west Kedong portion exhibits anticlines controlled by thrust wedge that has been reworked by dextrally strike-slipping. In contrast, the east Keliyang portion is featured by mainly thrust deformation. Combined with the results from growth strata and magnetostratigraphy, we suggest that the segment presents a northwardly forward breaking pattern, with the deformation occurring along the Kedong belt during the early Pliocene, within the Kekeya belt at early- to mid-Pliocene and in the Guman-Heshitage belt during early- to mid-Pleistocene. ©, 2015, Science Press. All right reserved.     

Distribution characteristics and differential enrichment mechanism of rhenium in molybdenite in the Dexing copper ore fieldSCIEI北大核心CSCD

世界上绝大部分Re赋存在斑岩型矿床的辉钼矿之中,且分布极不均匀。在矿床-矿石-矿物颗粒等不同尺度上,Re含量均存在较大差异,但造成这些差异的因素目前尚不清楚。本文以德兴矿田中富家坞和铜厂二个矿床的辉钼矿为研究对象,在细致的矿相学研究的基础上,对其开展了EPMA、LA-ICP-MS和XRD分析,同时结合前人研究资料,详细探讨了Re在这两个矿床辉钼矿中的分布规律及差异性富集机制。结果显示:富家坞和铜厂均普遍发育两种形态的辉钼矿(细粒集合体型和粗粒片状型),Re在两种辉钼矿中的分布均极为不均,但细粒集合体型相对更富Re,而同一形态辉钼矿铜厂矿床则具有更高的Re含量;同一矿床中辉钼矿结晶越晚,往往越富集Re;个别辉钼矿可见扭结现象,且扭结部位的Re含量更低,暗示后期构造变形可能导致了Re的丢失;两个矿床高Re辉钼矿和低Re辉钼矿的结构均为2H多型,表明Re含量与辉钼矿晶体结构无关。结合前人资料,本文认为成矿流体性质(如温度、盐度等)是导致铜厂和富家坞辉钼矿Re含量差异的主要因素。     

General characteristics and research progress of tellurium mineralizationSCIEI北大核心CSCD

碲作为稀散元素,很少形成独立矿床,主要以共伴生形式产出于多个类型矿床中,包括铜镍硫化物和铂族矿床、铁氧化物铜金(IOCG)矿床、块状硫化物(VMS)矿床、斑岩矿床、矽卡岩矿床、造山型金矿、卡林型金矿和浅成低温热液矿床等。研究表明,碲元素可以形成上百种碲矿物,除了自然碲之外,多与Au、Ag、Pb、Bi、Cu等形成碲化物,与S或者Se形成碲的硫化物或硒化物,也可以形成碲酸盐、硅酸盐、磷酸盐、硫酸盐等矿物;此外Te还可以以类质同象形式替换寄主矿物中的元素。在成矿带尺度、矿床尺度及其矿石中碲均表现出极不均匀的分布特征,与主矿种Cu、Au、Ag等具有成因关系。碲具有多来源特征,可以源自地幔,也可以是浅部壳源岩浆或是围岩地层提供。碲矿化一般发生在成矿的中晚阶段,流体可通过混合作用、水岩反应、沸腾作用等改变体系的物理化学条件(如pH值、硫逸度、氧逸度、碲逸度、温度等),导致流体pH值升高、硫逸度和氧逸度降低,碲逸度升高,这是诱发碲矿物富集和沉淀的主要机制。碲由于其受控成矿条件较为特殊,需要着重加强碲富集成矿的关键控制因素、成矿物质来源和富集沉淀机制的研究。     

The feature and tectonic setting of Dongqiao podiform chromitite in the central segment of the Bangong Lake-Nujiang suture zone in TibetSCIEI北大核心CSCD

早侏罗世东巧蛇绿岩位于班公湖-怒江缝合带(班怒带)东段,蕴含较为丰富的豆荚状铬铁矿资源。东巧地幔橄榄岩主体由方辉橄榄岩组成,铬铁矿赋存在其内部的纯橄岩脉中。方辉橄榄岩和纯橄岩均显示出弧前橄榄岩的特征。方辉橄榄岩中橄榄石的Fo值为89.8~92.2,斜方辉石的和单斜辉石的Mg^(#)值分别变化于89.7~92.0和92.7~95.1,铬尖晶石的Cr^(#)值(Cr^(#)=100×Cr/(Cr+Al))为60.8~75.9;纯橄岩中橄榄石的Fo值为91.7~92.5,斜方辉石Mg^(#)值变化于91.7~92.1,单斜辉石的Mg^(#)值变化于94.0~94.6,铬尖晶石的Cr^(#)值为69.0~83.1。铬铁矿主要呈致密块状和浸染状构造,其中铬尖晶石的矿物包裹体有橄榄石、斜方辉石、单斜辉石、角闪石和铂族矿物等。矿石中的铬尖晶石与橄榄岩中的铬尖晶石相比,具有较高的Cr^(#)值(72.5~86.9)和Mg^(#)值(52.8~70.5),较低的Al_(2)O_(3)(6.25%~13.6%)、TiO_(2)(0.06%~0.16%)和Zn(518×10^(-6)~714×10^(-6)),属于高铬型铬铁矿,平衡熔体与玻安质熔体有亲缘性。方辉橄榄岩中铂族元素(PGE)总含量(14.01×10^(-9)~32.81×10^(-9))近似于原始地幔,IPGE(Os、Ir和Ru)/PPGE(Rh、Pt和Pd)的比值均大于1;纯橄岩的PGE总量(13.36×10^(-9)~16.08×10^(-9))略低于原始地幔,IPGE和PPGE富集程度近似;铬铁矿的铂族元素总量(108.4×10^(-9)~645.7×10^(-9))远远高于原始地幔和地幔橄榄岩中PGE的含量,且IPGE以及Rh相对原始地幔富集,而Pt和Pd相对亏损,具明显右倾特征的配分模式,指示东巧地幔橄榄岩和铬铁矿形成过程经历了熔体抽取和交代作用。通过与全球典型豆荚状铬铁矿矿床的特征对比,认为班怒带的蛇绿岩应该有良好的铬铁矿成矿背景。     

U-Pb ages and Hf isotope compositions of detrital zircons from the sandstone in the early cretaceous Wawukuang formation in the Jiaolai Basin,Shandong Province and its tectonic implicationsEI北大核心CSCD

LA-ICP-MS U-Pb dating and in situ Hf isotope analysis were carried out for the detrital zircons to constrain the depositional age and provenance of the Wawukuang Formation, which is believed as the earliest unit of the Laiyang Group in the Jiaolai Basin, and its implications. Most of these detrital zircons from the feldspar quartz sandstone in the Wawukuang Formation are magmatic in origin, which are euhedral-subhedral and display oscillatory zoning in CL images; whereas few Late Triassic detrital zircons are metamorphic in origin and structureless in CL images. U-Pb isotopic dating of 82 zircon grains yields age populations at ca. 129 Ma, 158 Ma, 224 Ma, 253 Ma, 461 Ma, 724 Ma, 1851 Ma and 2456 Ma. U-Pb dating and Hf isotopic results indicate that: 1) the Wawukuang Formation deposited during the Early Cretaceous (129-106 Ma); 2) the detrital zircons with the ages of 1851 Ma and 2456 Ma mainly sourced from the Precambrian basement rocks of the North China Craton; the Neoproterozoic (729-721 Ma) magmatic zircons and the Late Triassic (226-216 Ma) metamorphic zircons sourced from the Su-Lu terrane; The Late Paleozoic detrital zircons could source from the Late Paleozoic igneous rocks in the northern margin of the North China Craton; the Late Triassic (231-223 Ma) magmatic zircons and the 158-129 Ma zircons sourced from the coeval igneous rocks in the Jiaobei and Jiaodong; 3) the deposition age and provenance of the Jiaolai Basin are different from those of the Hefei Basin; 4) the recognition of clastic sediments from the Su-Lu terrane in the Wawukuang Formation suggests that the Su-Lu terrane was under denudation in the Early Cretaceous. ©, 2015, Science Press. All right reserved.