The Use of a Standpipe to Evaluate Ground Water Samplers

A standpipe system was developed for testing the reliability of ground water samplers. The unit consists of a stainless steel pipe 5 inches (13 centimeters) in diameter and 100 feet (30.5 meters) in height. It has 14 sampling ports from which control samples can be withdrawn at the same time and position as the samples are collected by a sampler lowered to that position. Test solutions were made in two mixing tanks, totaling 260 gallons (980 liters), by diluting the concentrate of five volatile chlorohydrocarbons in water at two levels of concentration: 10-to-30 and 100-to-200 parts per billion (micrograms per liter).
A gas chromatograph interfaced with a purge-and-trap system was used to perform the analyses. Comparisons of the control samples with the sampler-collected samples have indicated that the three non-pumping samplers had recoveries in the range of 92.4 to 103.5 percent and the three pumping samplers had recoveries ranging from 97.7 to 101.5 percent.     

The Application of Television Borehole Logging to Ground Water Monitoring Programs

Borehole television has been successfully utilized to gather in situ information on boreholes and wells in several ground water monitoring programs. Borehole television surveys are proposed as a viable alternative to other downhole instruments in the subsurface investigation stages of a ground water monitoring program.
The borehole television camera used by the authors was originally developed for use in the examination of nuclear reactor cores; the camera has since been modified for use in borehole investigations. The lens attachments are capable of looking sideward or downward and include built-in lighting assemblies. Use of the camera, lenses and various support equipment are discussed.
The in situ characterization of fractures that can provide pathways for contaminant migration poses a significant challenge. Borehole television inspection can provide information on the frequency, size and orientation of these fractures. Vertical correlations of rock cores in areas where voids are present (i.e. deep mining or karst topography) can also be simplified by this technique. In addition, borehole television can also be used to check monitoring well integrity. Casing inspections are especially useful where construction details are not known. Well screens may be inspected in place to determine if rusting has enlarged the screen openings or if screens have been damaged during emplacement or well development operations (i.e. surge block, air jetting, etc.). This information may prove to be very valuable in the decision to decommission a well. Examples of these successful applications in ground water monitoring programs at several Superfund hazardous waste sites are presented.     

Surface and Borehole Geophysical Methods in Ground Water Investigations

Ground water flow in karst terranes generally occurs in the solution channels of carbonate aquifers. A hydrogeologist may utilize borehole geophysical methods to identify these solution channels in aquifers. Two specific methods that are applicable in karst terrains are:
1. Natural gamma ray logging
2. Borehole caliper logging.
Gamma ray logging can detect the presence of inter-bedded strata in the main limestone unit, such as shale, which emit high levels of gamma radiation. Gamma ray logging can also detect clay deposits in solution channels that may act to restrict the flow of ground water. The areal extent of these rock strata or clay-filled solution channels can be determined when gamma ray logs are conducted at several borehole locations across the site of investigation.
Borehole caliper logging can be employed to determine the presences of solution channels within the aquifer when penetrated by a borehole. In addition, since shale layers and clay filling are less resistant than the surrounding limestone, the caliper log may detect both the presence and the thickness of shale or clay layers in the aquifer.
Gamma ray logs can be used in conjunction with caliper logs to provide data on the stratigraphic location and thickness of solution channels and clay and shale layers within a limestone aquifer. This information is valuable to the hydrogeologist performing investigations at sites located in limestone terranes because ground water flow preferentially occurs along solution channels.     

Diffusion Samplers as an Inexpensive Approach to Monitoring VOCs in Ground Water

Diffusion samplers installed in observation wells were found to be capable of yielding polyethylene to transmit other volatile compounds, such as benzene and toluene, indicates that the samplers can be used for a variety of volatile organic compounds. In wells at the study area, the volatile organic compound concentrations in water samples obtained using the samplers without prior purging were similar to concentrations in water samples obtained from the respective wells using traditional purging and sampling approaches. The low cost associated with this approach makes it a viable option for monitoring large observation-well networks for volatile organic compounds.     

Sampling of VOCs with the BAT Ground Water Sampling System

In the BAT ground water sampling system, a stainless steel probe with a porous filter element is pushed vertically to the desired sampling depth. An evacuated glass sampling tube is then lowered down the penetration rods where it makes contact with the filter via a hypodermic needle and draws a pore fluid sample.
An investigation of the system was carried out at a number of sites contaminated by leaking underground gasoline storage tanks. Ground water samples obtained using the BAT system and adjacent monitoring wells were analyzed for volatile organic compounds (VOCs).
Because the BAT system is an in situ penetration device with a small filter length, it is possible to determine variations in contaminant concentration with depth. BAT samples in general exhibited higher recovery of VOCs than did bailer samples from adjacent monitoring wells screened over large intervals.
Much higher levels of VOCs were recovered when the probe was used with its 316 stainless steel filter than when using the high-density polyethylene (HDPE) filter. Significant sorption apparently occurred on the latter filter.
Because the BAT sample tubes are sealed and remain a closed system, the in situ water pressure is maintained. No significant loss of VOCs was found in sampling tubes containing headspace. Samples from the upper tube in the cascaded setup with headspace recovered levels of VOCs as high, or in a few cases higher, than the lower, no-headspace tubes.     

Tracer Test to Evaluate Dilution of Ground Water from Lost Circulation

Lost circulation, the inadvertent injection of drilling fluids into a highly permeable and/or fractured aquifer during rotary drilling, may result in collection of spurious information if the lost drilling fluids are not adequately purged before sampling the ground water. The purpose of this study was to determine whether removal of the volume of water lost during coring of a monitoring well in the carbonate Scotch Grove Formation (Silurian, east central Iowa) necessarily ensures collection of representative ground water samples. To monitor dilution of the ground water due to lost circulation, rhodamine dye was added to the drilling water and dye recovery was measured in samples collected during purging of five separate 5- to 10-foot intervals.
Circulation loss occurred in all five intervals, ranging from nearly 200 gallons in the upper permeable portion of the Scotch Grove to 25 gallons in the less permeable Buck Creek Member below. When the volume of water purged from the upper three intervals corresponded to the volume of water lost during coring, the purge water still contained 11 to 20 percent dyed drilling water. As purging continued, the proportion of drilling water in the samples decreased slowly. After purging more than 200 gallons of water, 86 to 98 percent of the dyed drilling water was recovered from the five test intervals. Four traditionally measured water quality parameters-pH, temperature, specific conductance, and dissolved oxygen — were less useful than the dye recovery for distinguishing drilling water from formation water in those zones in which the ground water quality was similar to the drilling water. These results indicate that the determination of the quantity of water to be purged prior to sampling must be based, at least in part, on aquifer lithology and hydraulic characteristics.     

Vertical Distribution of Methane in Baikal Water

Water Resources - Data on the vertical distribution of dissolved methane in Baikal water column are analyzed. The zone of open lake now shows an increase in the concentrations of dissolved methane...     

A Simple, Low-Cost Method to Monitor Duration of Ground Water Pumping

Monitoring ground water withdrawals for agriculture is a difficult task, while agricultural development leads frequently to overexploitation of the aquifers. To fix the problem, sustainable management is required based on the knowledge of water uses. This paper introduces a simple and inexpensive direct method to determine the duration of pumping of a well by measuring the temperature of its water outlet pipe. A pumping phase is characterized by a steady temperature value close to ground water temperature. The method involves recording the temperature of the outlet pipe and identifying the different stages of pumping. It is based on the use of the low-cost and small-size Thermochron iButton temperature logger and can be applied to any well, provided that a water outlet pipe is accessible. The temperature time series are analyzed to determine the duration of pumping through manual and automatic posttreatments. The method was tested and applied in South India for irrigation wells using electricity-powered pumps. The duration of pumping obtained by the iButton method is fully consistent with the duration of power supply (1.5% difference).     

Demonstration of a Microbiologically Enhanced Vertical Ground Water Circulation Well Technology at a Superfund Site

A full-scale ground water circulation well (GCW) system was installed and operated to demonstrate in situ remediation of soil and ground water impacted with a mixture of chlorinated and nonchlorinated organic compounds at a Superfund site in upstate New York. System performance and applicability under site-specific conditions were evaluated based on the system's ability to meet the New York State Department of Environmental Conservation (NYSDEC) cleanup goals for target compounds in ground water and soil. Contaminants from the unsaturated zone were mobilized (volatilized) by one-way vacuum extraction, and treated via enhanced biodegradation (bioventing). In the saturated zone, contaminants were mobilized by soil flushing (solubilized) and treated by a combination of air stripping and biodegradation. An in situ aqueous phase bioreactor, and an ex situ gas phase bioreactor, were integrated into the system to enhance treatment via bioremediation. After 15 months of operation, the mass of target contaminants in soil and ground water combined had been reduced by 75%. Removal by biological mechanisms ranged from 35% to 56% of the total observed mass reduction. The in situ and the ex situ bioreactors mineralized 79% and 76%, respectively, of their target biodegradable contaminant loads. Results indicate that some mass reduction in target contaminants may have been from aerobic and aerobic processes within the circulation cell. Nonchlorinated compounds were relatively easy to mobilize (volatilize, solubilize, and/or transport) and treat when compared to chlorinated compounds. The data collected during the 15-month study indicate that remediation could be accomplished at the Sweden-3 Chapman site using the technology tested.     

Modeling Electrical Field Distribution in Layered Geological Rock Formations with a Borehole Using the Coulomb Charges Method

The Coulomb charges method is used to model apparent resistivity measurements carried out in layered geological formations with a borehole using various devices. It is characterized by a high level of effectiveness and accuracy. The results are compared with the theoretical solutions for a homogenous medium with the borehole and invaded zone for point current source lateral devices. The relative error was less than 2% for different values of the range of the invaded zone and resistivity of invaded and true resistivity of formation.     

Laboratory Column Experiments Using Polymer Mats to Remove Selected VOCs, PAHs, and Pesticides from Ground Water

Large-scale column experiments were undertaken to evaluate the potential of polymer mats to remove selected volatile organic compounds, polycyclic aromatic hydrocarbons, and pesticides (atrazine and fenamiphos) from ground water and potentially to act as permeable reactive barriers in contaminated ground water environments. The polymer mats, composed of interwoven silicone (dimethylsiloxane) tubes and purged with air, were installed in 2 m long flow-through columns. The polymer mats proved efficient in physically removing (stripping) benzene and naphthalene from contaminated water. Removal efficiencies for both these compounds from an aqueous phase flowing past a polymer mat were 75% or greater. However, for atrazine and fenamiphos, removal efficiencies were 5% or less, probably as a result of their lower Henry's law constants and possibly lower polymer diffusion coefficients.
These experiments indicate that, at least for relatively volatile compounds, polymer mats can provide a remediation technique for the removal of organic compounds from contaminated water. Application of this technique may be well suited as a longer-term, semipassive strategy to remediate contaminated ground water, using natural ground water flow to deliver contaminated ground water to polymer mats engineered as sorption-stripping barriers.
Additional benefits of this technique may include targeted delivery of gaseous chemical amendments, such as oxygen, to enhance aerobic biodegradation and to further reduce any residual concentrations of contaminants.