Interaction of oil and mineral fines on shorelines: review and assessment

The interaction of fine mineral particles with stranded oil in an aqueous medium reduces the adhesion of the oil to solid surfaces, such as sediments or bedrock. The net result is the formation of stable, micron-sized, oil droplets that disperse into the water column. In turn, the increase in surface area makes the oil more available for biodegradation. This interaction, referred to as oil–mineral aggregate (OMA) formation, can explain how oiled shorelines are cleaned naturally in the absence of wave action in very sheltered coastal environments. OMA formation also plays an important role in the efficacy of shoreline treatment techniques, such as physical mixing and sediment relocation that move oiled sediments into the zone of wave action to promote the interaction between oil and mineral fines. Successful application of these shoreline treatment options has been demonstrated at two spill events (the Tampa Bay response in Florida and the Sea Empress operation in Wales) and at a controlled oil spill experiment in the field (the 1997 Svalbard ITOSS program). Sediment relocation harnesses the hydraulic action of waves so that the processes of fine-particle interaction and physical abrasion usually occur in tandem on open coasts. There has been no evidence of significant detrimental side-effects of residual oil in pelagic or benthic environments associated with the use of these treatment options to enhance rates of dispersion and oil biodegradation.     

Investigation of OMA formation and the effect of minerals

Oil-mineral-aggregates (OMA) have been shown to be effective in oil spills cleanup. Experimental work was carried out to study the effects of physical-chemical properties of natural minerals and chemically modified minerals on OMA formation and oil removal. The results showed that the hydrophobicity, particle sizes and specific surface of minerals played an important role in OMA formation. Appropriate hydrophobicity of minerals can enhance the formation of OMA. The surface property of minerals can also influence the shape of OMA. Spherical mineral-oil aggregates were frequently formed with hydrophilic minerals while irregular shaped OMA were observed with hydrophobic minerals. The sizes of OMA also increased when the minerals changed from hydrophilic to hydrophobic. The effects of dispersant and mixing energy were also carefully studied. The results showed that dispersant were a dominant factor. When dispersant was applied, effects of other factors became minimal.     

Oil droplet interaction with suspended sediment in the seawater column: Influence of physical parameters and chemical dispersants

The interaction of dispersed oil droplets with large diameter suspended particulate materials (SPM) has been little studied. In the current study, particle size, oil characteristics and chemical dispersant significantly influence the adsorption of oil droplets to SPM in seawater. Sediments with a smaller particulate size (clay) approaching that of the oil droplets (2–20 μm) adsorbed more oil per gram than sediments with large particle size (sand). Heavier, more polar oils with a high asphaltene content adsorbed more efficiently to SPM than lighter, less polar oils. A decrease in the smaller, more water soluble oil components in the sediment adsorbed oil was observed for all oil types. Addition of chemical dispersant decreased the adsorption of oil droplets to suspended carbonate sand in an exponential-like manner. No change in the relative distribution of compounds adsorbed to the sediment was observed, indicating dispersants do not alter the dissolution of compounds from oil droplets.     

Consequences of hyperconcentrated flow for process‐based soil erosion modelling on the Chinese Loess Plateau

High sediment concentrations in runoff are a characteristic feature of the Chinese Loess Plateau, and are probably caused by factors such as the occurrence of erodible materials on steep slopes, the characteristics of the loess and the harsh climate that results in low plant cover. When sediment concentration increases, fluid density increases, viscosity increases and settling velocity decreases. These effects become increasingly important with increasing concentration and can result in flow behaviour that is quite different from that of clear water flow. Although the net effect of these changes on the flow is not always apparent, erosion models that deal with high sediment concentrations should consider such effects and could include corrections for some of these effects. A case study in a small catchment on the Loess Plateau indicated that sediment concentrations were considerable, and literature data suggested that for such sediment concentrations, corrections for settling velocity, fluid density and viscosity are needed. Furthermore, a number of corrections are necessary to be able to compare field measurements with results of soil erosion models: sediment volume should be subtracted from runoff volume and a density correction is needed to use data from a pressure transducer. For flumes that were used to measure discharge from smaller areas inside the catchment, the measured water level should be corrected by subtracting the sediment level in the flume from the water level, while the sediment volume should also be subtracted from the discharge. Finally, measured concentration should be corrected to give concentration expressed as grams per litre of clear water, since soil erosion models express sediment concentration in this way. Copyright © 2006 John Wiley & Sons, Ltd.     

The effect of sewage effluent on the population density and size of the clam Parvilucina tenuisculpta

Changes in the population density and size of the clam Parvilucina tenuisculpta were related to municipal waste effluent (in particular, organic nitrogen concentration) off the coast of Palos Verdes, California. Average clam size increased as sediment organic nitrogen concentration increased, but population density increased until organic nitrogen concentration reached a critical level when population density decreased dramatically. These effects were explained in terms of increased available nutrition (in the form of sediment organic nitrogen pollutants) enhancing both population and individual size growth. However, when a critical concentration of organic decomposition products was reached, population density decreased due to the toxicity of the released compounds. It is suggested that Parvilucina tenuisculpta would make a good bioindicator of organic enrichment pollution.     

Biodegradation of petroleum hydrocarbons at low temperature in the presence of the dispersant Corexit 9500

Our study examined the effects of Corexit 9500 and sediment on microbial mineralization of specific aliphatic and aromatic hydrocarbons found in crude oil. We also measured gross mineralization of crude oil, dispersed crude oil and dispersant by a marine microbial consortium in the absence of sediment. When provided as carbon sources, our consortium mineralized Corexit 9500 the most rapidly, followed by fresh oil, and finally weathered oil or dispersed oil. However, mineralization in short term assays favored particular components of crude oil (2-methyl-naphthalene > dodecane > phenanthrene > hexadecane > pyrene) and was not affected by addition of nutrients or sediment (high sand, low organic carbon). Adding dispersant inhibited hexadecane and phenanthrene mineralization but did not affect dodecane and 2-methyl-naphthalene mineralization. Thus, the effect of dispersant on biodegradation of a specific hydrocarbon was not predictable by class. The results were consistent for both high and low oiling experiments and for both fresh and weathered oil. Overall, our results indicate that environmental use of Corexit 9500 could result in either increases or decreases in the toxicity of residual oil through selective microbial mineralization of hydrocarbons.     

Correction factors for estimating suspended sediment export from loess catchments

This study focuses on problems related to estimating the exact exported suspended sediment quantity and quality from flow‐proportional samples taken at a fixed height at the outlet of a small, agricultural catchment in central Belgium. First, a correction factor is introduced to estimate the real suspended sediment concentration. This factor depends on the stream depth and the grain size distribution of the sediment and is necessary because of the presence of a concentration gradient in the stream. Secondly, water depth is corrected for the sediment volume, and thirdly, the grain size distribution of the exported sediment is corrected. The application of these correction factors leads to a reduction of the estimated total sediment export by 18 per cent (from 4810 Mg over a period of three years to 3930 Mg). Furthermore, the importance of small grain size fractions increases, leading to higher enrichment ratios for the clay fraction and lower ratios for the sand fraction. Suspended sediment export is thus more selective than was previously thought. Due to the overestimation of the sediment export, total phosphorus losses from the catchment are also overestimated by 17 per cent. This paper therefore emphasizes that point sampling of suspended sediment is biased and that a method should be incorporated to correct the sediment export in terms of quantity and quality. Copyright © 2001 John Wiley & Sons, Ltd.     

Capacitive sensing technique for silt suspended sediment concentration monitoring

Automated, real-time, and continuous techniques for monitoring suspended sediment concentration in rivers and reservoirs can play an important role in the improvement of the quantity and quality of sediment data, and are valuable to the management of water environment, water conservancy, hazard prevention, and water resources. Research in the monitoring techniques has examined the possibility of using the characteristics of dielectric constants for detecting soil moisture and concentration of air-water two-phase flow, based on the fact that dielectric constants of sediment, air and water are different. A capacitance sensor was developed to monitor the silt suspended sediment concentration (SSSC) in a recent study, following the principle that as SSSC increases in the sediment-water mixture, the apparent dielectric constant of the water sample also increases and therefore the capacitance detected by the sensing system also increases. It is demonstrated that the variations in the concentration of silt sediment correlates positively with the variations in observed capacitance in a linear fashion, and correlates negatively with voltage outputs but also in a linear fashion. The correlation coefficients reached above 0.98. The overall errors in estimated concentrations range between 0.26% and 2.91%. Elements in the capacitance sensor system such as the frequencies of the signal generating system, areas of the electrode plates, and effects of sample temperature have also been evaluated. The results illustrated that the capacitance sensor techniques can be applied to monitoring SSSC automatically and continuously. Also, the range of SSSC in the experiment reached 200 kg/m³; therefore, the application of this technique in practical SSSC monitoring is worthy of further research.     

The impact of silt trapping in large reservoirs on downstream morphology: the Yangtze River

The sediment load of the Yangtze River (China) is decreasing because of construction of dams, of which the Three Gorges Dam (TGD) is the best known example. The rate of the decline in sediment load is well known, but changes in the sediment grain size distribution have not been given much attention. The TGD mostly traps sand and silt while clay is flushed through the reservoir. A large amount of sand is available in the Yangtze River downstream of the reservoir, and therefore the pre-dam sand concentration is not substantially reduced. The availability of silt on the Yangtze River bed is limited, and it is expected that most silt will be removed from the riverbed within one to two decades. In order to evaluate the impact of the change in grain size distribution on the tidal flats of the Yangtze Estuary, a highly schematized tidal flat model is setup. This model broadly reveals that the observed deposition rates are exceptionally large because of the high sediment concentration, the abundance of silt, the seasonal dominance of waves (shaping a concave profile), and the offshore tidal asymmetry. The model further suggests that deposition rates will be limitedly influenced by reductions in clay or fine silt but strongly impacted by reductions in median to coarse silt. The response of the downstream morphology to reservoir sedimentation therefore strongly depends on the type of trapped sediment. As a consequence, silt-dominated rivers, such as the Yangtze River and the Yellow River may be more strongly impacted than sand-dominated systems.     

Micro-scale experimental investigation of the effect of flow rate on trapping in sandstone and carbonate rock samples

We present the results of a pore-scale experimental study of residual trapping in consolidated sandstone and carbonate rock samples under confining stress. We investigate how the changes in wetting phase flow rate impacts pore-scale distribution of fluids during imbibition in natural, water-wet porous media. We systematically study pore-scale trapping of the nonwetting phase as well as size and distribution of its disconnected globules. Seven sets of drainage-imbibition experiments were performed with brine and oil as the wetting and nonwetting phases, respectively. We utilized a two-phase miniature core-flooding apparatus integrated with an X-ray microtomography system to examine pore-scale fluid distributions in small Bentheimer sandstone (D = 4.9 mm and L = 13 mm) and Gambier limestone (D = 4.4 mm and L = 75 mm) core samples. The results show that with increase in capillary number, the residual oil saturation at the end of the imbibition reduces from 0.46 to 0.20 in Bemtheimer sandstone and from 0.46 to 0.28 in Gambier limestone. We use pore-scale displacement mechanisms, in-situ wettability characteristics, and pore size distribution information to explain the observed capillary desaturation trends. The reduction was believed to be caused by alteration of the order in which pore-scale displacements took place during imbibition. Furthermore, increase in capillary number produced significantly different pore-scale fluid distributions during imbibition. We explored the pore fluid occupancies and studied size and distribution of the trapped oil clusters during different imbibition experiments. The results clearly show that as the capillary number increases, imbibition produces smaller trapped oil globules. In other words, the volume of individual trapped oil globules decreased at higher brine flow rates. Finally, we observed that the pore space in the limestone sample was considerably altered through matrix dissolution at extremely high brine flow rates. This increased the sample porosity from 44% to 62% and permeability from 7.3 D to 80 D. Imbibition in the altered pore space produced lower residual oil saturation (from 0.28 to 0.22) and significantly different distribution of trapped oil globules.     

Assessment of chemical dispersant effectiveness in a wave tank under regular non-breaking and breaking wave conditions

Current chemical dispersant effectiveness tests for product selection are commonly performed with bench-scale testing apparatus. However, for the assessment of oil dispersant effectiveness under real sea state conditions, test protocols are required to have hydrodynamic conditions closer to the natural environment, including transport and dilution effects. To achieve this goal, Fisheries and Oceans Canada and the US Environmental Protection Agency (EPA) designed and constructed a wave tank system to study chemical dispersant effectiveness under controlled mixing energy conditions (regular non-breaking, spilling breaking, and plunging breaking waves). Quantification of oil dispersant effectiveness was based on observed changes in dispersed oil concentrations and oil-droplet size distribution. The study results quantitatively demonstrated that total dispersed oil concentration and breakup kinetics of oil droplets in the water column were strongly dependent on the presence of chemical dispersants and the influence of breaking waves. These data on the effectiveness of dispersants as a function of sea state will have significant implications in the drafting of future operational guidelines for dispersant use at sea.     

Quantity, composition, and source of sediment collected in sediment traps along the fringing coral reef off Molokai, Hawaii

Sediment traps were used to evaluate the frequency, cause, and relative intensity of sediment mobility/resuspension along the fringing coral reef off southern Molokai (February 2000-May 2002). Two storms with high rainfall, floods, and exceptionally high waves resulted in sediment collection rates>1000 times higher than during non-storm periods, primarily because of sediment resuspension by waves. Based on quantity and composition of trapped sediment, floods recharged the reef flat with land-derived sediment, but had a low potential for burying coral on the fore reef when accompanied by high waves. The trapped sediments have low concentrations of anthropogenic metals. The magnetic properties of trapped sediment may provide information about the sources of land-derived sediment reaching the fore reef. The high trapping rate and low sediment cover indicate that coral surfaces on the fore reef are exposed to transient resuspended sediment, and that the traps do not measure net sediment accumulation on the reef surface.     

Complex behaviour of natural sediment‐carrying streamflows and the geomorphological implications

Based on the data from alluvial rivers in China, the complex mechanical behaviour of sediment‐carrying streamflow of natural rivers has been observed. Channel geometry also exhibits complex behaviour in response to variation in suspended concentration. With the increase in suspended concentration, channel width : depth ratio increases, reaches a maximum and then decreases. The inverse is true for channel sinuosity. When suspended concentration is low, a meandering pattern is dominant. The increase in suspended concentration leads to a transformation from a meandering to a braided pattern. But when the suspended concentration increases further and enters the range of hyperconcentrated flows, the meandering pattern appears. The complex behaviour of channel pattern change may be regarded as a reflection of the complex behaviour of sediment‐carrying streamflows at the river reach scale. Copyright © 2002 John Wiley & Sons, Ltd.     

TEMPORAL AND SPATIAL DYNAMICS OF DIFFERENT PARTICLE SIZE OF SUSPENDED SEDIMENT IN THE LIU RIVER CATCHMENTS,CHINA

1 INTRODUCTION The particle size of sediment eroded from basins can provide basic information about erosion processes (Meyer et al., 1980), which can be divided into sheet wash sediment processes on hill slopes and fluvial sediment processes in rivers. In…     

Patterns of grain‐size dependent sediment transport in low‐ordered,ephemeral channels

Sediment data were analyzed to determine grain‐size dependant factors affecting sediment transport in a low‐ordered, ephemeral watershed. Sediment and flow samples were collected during 22 flow events at the outlet of a 4·53 ha sub‐watershed within the Walnut Gulch Experimental Watershed in south‐eastern Arizona. Measured concentrations ranged from 4191 to 115 045 mg l^?1 and included grain sizes up to 8·0 mm in diameter. Two grain‐size dependent transport patterns were observed, that of the finer grain‐size fraction (approximately < 0·25 mm) and that of a coarser grain‐size fraction (approximately ≥ 0·25 mm). The concentration of the fine fraction decreased with flow duration, peaking near the beginning of a flow event and declining thereafter. The concentration of the fine fraction showed slight trends with season and recovery period. The concentration of the coarse fraction displayed a slight negative trend with instantaneous discharge and was not correlated with event duration. These patterns typically produced a condition where the majority of the fine fraction of the sediment yield was evacuated out of the watershed before the hydrograph peak while the majority of the coarser sediment was evacuated during the falling limb of the hydrograph. Each grain‐size dependent transport pattern was likely influenced by the source of the associated sediment. At the flow event time scale, the fines were primarily wash load, supplied from the hillslopes and the coarser grains were entrained from the channel bed. Because transport patterns differ based on grain size, attempts to define the total sediment concentration and sediment yield by the behavior of a single grain‐size fraction may lead to erroneous results, especially when a large range of sediment grain sizes are present. Copyright © 2010 John Wiley & Sons, Ltd.     

Adsorption of cadmium on riverine sediments: quantitative treatment of the large particles

The effects of solution pH, sediment dose, contact time, and particle size on the adsorption of cadmium ions on bed sediments have been studied for a highly polluted river in western Uttar Pradesh, India. The role of the coarser sediment and the clay and silt fractions has been examined. The optimum contact time needed to reach equilibrium is of the order of 30 and 60 min for 0–75 μm and 210–250 μm sediment size, respectively. The extent of cadmium adsorption increases with increasing pH and adsorbent doses and decreases with adsorbent particle size. The important geochemical phases, iron and manganese oxide, provide the active support material for the adsorption of cadmium. The competitive experiments conducted in the presence of lead and zinc ions indicate that both the ions suppress the ability of cadmium to adsorb on to sediments. The Langmuir and Freundlich adsorption models were used to determine the mechanistic parameters associated with the adsorption process. Copyright © 2000 John Wiley & Sons, Ltd.     

Non-equilibrium concentration profile formulas of suspended sediment and their preliminary applications

The vertical concentration profiles in non-equilibrium sediment transport processes generally deviate from the equilibrium concentration distribution of suspended sediment. The non-equilibrium concentration profile formulas currently available are those of Han and Brown, respectively. However, the complexity of these formulas limits their use in practical calculations. To improve the usefulness of these formulas, the unknown parameters in Han’s formula are reduced from three to two, and the thre...     

A short-term predictive system for surface currents from a rapidly deployed coastal HF radar network

In order to address the need for surface trajectory forecasts following deployment of coastal HF radar systems during emergency-response situations (e.g., search and rescue, oil spill), a short-term predictive system (STPS) based on only a few hours data background is presented. First, open-modal analysis (OMA) coefficients are fitted to 1-D surface currents from all available radar stations at each time interval. OMA has the effect of applying a spatial low-pass filter to the data, fills gaps, and can extend coverage to areas where radial vectors are available from a single radar only. Then, a set of temporal modes is fitted to the time series of OMA coefficients, typically over a short 12-h trailing period. These modes include tidal and inertial harmonics, as well as constant and linear trends. This temporal model is the STPS basis for producing up to a 12-h current vector forecast from which a trajectory forecast can be derived. We show results of this method applied to data gathered during the September 2010 rapid-response demonstration in northern Norway. Forecasted coefficients, currents, and trajectories are compared with the same measured quantities, and statistics of skill are assessed employing 16 24-h data sets. Forecasted and measured kinetic variances of the OMA coefficients typically agreed to within 10–15%. In one case where errors were larger, strong wind changes are suspected and examined as the cause. Sudden wind variability is not included properly within the STPS attack we presently employ and will be a subject for future improvement.     

Photosynthetic pigments and peroxidase activity as indicators of heavy metal stress in the Grey mangrove, Avicennia marina (Forsk.) Vierh

Mangroves have been observed to possess a tolerance to high levels of heavy metals, yet accumulated metals may induce subcellular biochemical changes, which can impact on processes at the organism level. Six month-old seedlings of the grey mangrove, Avicennia marina (Forsk.) Vierh, were exposed to a range of Cu (0-800 micrograms/g), Pb (0-800 micrograms/g) and Zn (0-1000 micrograms/g) concentrations in sediments under laboratory conditions, to determine leaf tissue metal accumulation patterns, effects on photosynthetic pigments (chlorophyll a, chlorophyll b and carotenoids), and the activity of the antioxidant enzyme peroxidase. Limited Cu uptake to leaves was observed at low sediment Cu levels, with saturation and visible toxicity to Cu at sediment levels greater than 400 micrograms/g. Leaf Pb concentrations remained low over a range of Pb sediment concentrations, up to 400 micrograms/g Pb, above which it appeared that unrestricted transport of Pb occurred, although no visible signs of Pb toxicity were observed. Zn was accumulated linearly with sediment zinc concentration, and visible toxicity occurring at the highest concentration, 1000 micrograms/g Zn. Significant increases in peroxidase activity and decreases in photopigments were found with Cu and Zn at concentrations lower than those inducing visible toxicity. Significant increases in peroxidase activity only, were found when plants were exposed to Pb. Positive linear relationships between peroxidase activity and leaf tissue metal concentrations were found for all metals. Significant linear decreases in photosynthetic pigments with increasing leaf tissue metal concentrations were observed with Cu and Zn only. Photosynthetic pigments and peroxidase activity may be applicable as sensitive biological indicators of Cu and Zn stress, and peroxidase activity for Pb stress in A. marina.     

MATHEMATIC MODEL AND EXPERIMENTAL STUDY ON ADSORBING OIL BY SEDIMENT *

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